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result(s) for
"石墨复合材料"
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High densities of magnetic nanoparticles supported on graphene fabricated by atomic layer deposition and their use as efficient synergistic microwave absorbers
by
Guizhen wang Zhe Gao Gengping Wan Shiwei Lin Peng Yang Yong Qin
in
Absorption
,
Atomic/Molecular Structure and Spectra
,
Biomedicine
2014
An atomic layer deposition (ALD) method has been employed to synthesize Fe3O4/graphene and Ni/graphene composites. The structure and microwave absorbing properties of the as-prepared composites are investigated. The surfaces of graphene are densely covered by Fe3O4 or Ni nanoparticles with a narrow size distribution, and the magnetic nanoparticles are well distributed on each graphene sheet without significant conglomeration or large vacancies. The coated graphene materials exhibit remarkably improved electromagnetic (EM) absorption properties compared to the pristine graphene. The optimal reflection loss (RL) reaches -46.4 dB at 15.6 GHz with a thickness of only 1.4 mm for the Fe3O4/graphene composites obtained by applying 100 cycles of Fe2O3 deposition followed by a hydrogen reduction. The enhanced absorption ability arises from the effective impedance matching, multiple interfacial polarization and increased magnetic loss from the added magnetic constituents. Moreover, compared with other recently reported materials, the composites have a lower filling ratio and smaller coating thickness resulting in significantly increased EM absorption properties. This demonstrates that nanoscale surface modification of magnetic particles on graphene by ALD is a very promising way to design lightweight and high-efficiency microwave absorbers.
Journal Article
Al–TiO2–Gr powder metallurgy hybrid composites with cold upset forging
by
Ravichandran, M.
,
Anandakrishnan, V.
,
Naveen Sait, A.
in
Biomaterials
,
Chemistry and Materials Science
,
Cold upsetting
2014
The cold upsetting studies were carried out for the aluminium metal matrix hybrid composites in the present study. Aluminium metal matrix hybrid composites were synthesised through powder metallurgy route from ball-milled powders to yield the following compositions:Al + 2.5 wt% TiO2+ 2 wt% Gr, Al + 2.5 wt% TiO2+ 4 wt% Gr, Al + 5.0 wt% TiO2+ 2 wt% Gr and Al + 5.0 wt% TiO2+ 4 wt% Gr. The compaction process was carried out using suitable punch and die in 40 k N hydraulic press, and sintering was done in an electric muffle furnace at the temperature of 590 °C for 3 h. The sintered preforms were subjected to incremental compressive loading of 10 k N until the cracks were found at the free surface. The true axial stress, true hoop stress, true hydrostatic stress and true effective stress were calculated for all the preforms, and all these stresses are correlated with the true axial strain. The stress ratio parameters(rz/reff, rh/reff, rz/rmand rh/rm) of the all preforms were correlated with true axial strain. The maximum true axial stress, true hoop stress, true effective stress and hydrostatic static stress are obtained for the composite containing5 wt% of TiO2 and 4 wt% of graphite and the minimum ones are obtained for composite containing 2.5 wt% of TiO2 and 2 wt% of graphite.
Journal Article
Direct synthesis of highly conductive poly(3,4- ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS)/graphene composites and their applications in energy harvesting systems
2014
We report for the first time highly conductive poly(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) (PEDOT:PSS)/graphene composites fabricated by in situ polymerization and their applications in a thermoelectric device and a platinum (Pt)-free dye-sensitized solar cell (DSSC) as energy harvesting systems. Graphene was dispersed in a solution of poly(4-styrenesulfonate) (PSS) and polymerization was directly carried out by addition of 3,4-ethylenedioxythiophene (EDOT) monomer to the dispersion. The content of the graphene was varied and optimized to give the highest electrical conductivity. The composite solution was ready to use without any reduction process because reduced graphene oxide was used. The fabricated film had a conductivity of 637 S.cm-1, corresponding to an enhancement of 41%, after the introduction of 3 wt.% graphene without any further complicated reduction processes of graphene being required. The highly conductive composite films were employed in an organic thermoelectric device, and the device showed a power factor of 45.7 μW·m^-1K^-2 which is 93% higher than a device based on pristine PEDOT:PSS. In addition, the highly conductive composite films were used in Pt-free DSSCs, showing an energy conversion efficiency of 5.4%, which is 21% higher than that of a DSSC based on PEDOT:PSS.
Journal Article
Two-Step Synthesis of Sulfur/Graphene Composite Cathode for Reehargeable Lithium Sulfur Batteries
2015
Sulfur/graphene composites with different sulfur contents were prepared by two-step synthesis, where graphene was regarded as a carrier of sulfur active substance. The surface structure and crystal form of the composites obtained were characterized and compared by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). It was found that sulfur was partially coated by graphene. The graphene folds provided more nano-pores and electron transport channels for sulfur. From TGA results, the sulfur contents of the sulfur/graphene compositcs measured were about 42.32 wt%, 54.94 wt%, and 65.23 wt%. Electrochemical tests demonstrated that sulfur/graphene composite (x=54.94 wt%) cathode exhibited better capacity retention (40.13%) compared with the pure cathode (20.46%), where an initial discharge capacity was up to 1 500 mAh.g-t and it remained about 600 mAh·g-1 after 30 cycles. Furthermore, the electrochemical reaction mechanism and the state of reaction interface for Li/S battery were analyzed by cyclic voltammogram and AC-impedance spectra. The results indicated that the sulfur/graphene composite with a sulfur content of 54.94 wt%, based on a two-step synthesis, contributed to improving electrochemical properties of lithium/sulfur battery
Journal Article
A Simple Way to Prepare Silicon Carbide Reinforced Graphite Composite Lubricating Materials
by
Yongjun YAN qingzhi LI Xianhui
in
Advanced Materials
,
Blocking
,
Chemistry and Materials Science
2015
SiC reinforced graphite composites were prepared via introducing carbide silicon into the natural graphite flakes(NGF) by hot-pressing process. Their physical and mechanical properties, including density, open porosity, flexural strength, and friction behavior were investigated. The addition of 30vol% Si C increased the bending strength of composites materials to 127 MPa, 2 times higher than 60 MPa of commercial pure graphite block. What was particularly interesting was that the as-obtained graphite composite with 30vol% Si C kept the same low friction coefficient of about 0.1 as pure graphite, and the wear resistance of composites increased.
Journal Article
Al^3+/graphene composites for electrochemical detection of DNA cleavage
2013
Herein, we present the electrochemical co-deposition of Al3+/graphene composites directly from an aqueous mixture containing graphene oxide (GO) and Al3+. The obtained Al3+/graphene composites with good electrochemical activity were regarded as an appropriate immobilization platform for double-stranded DNA (dsDNA). The nontoxic redox probe xanthurenic acid (XA) was successfully applied to recognize single-stranded DNA and dsDNA. We illustrated that the scission of dsDNA caused by GO combining with some metal ions could be detected by monitoring the electrochemical signals of XA.
Journal Article
A Facile One-Step Synthesis of TiOe/Graphene Composites for Photodegradation of Methyl Orange
by
Haijiao Zhang Panpan Xu Guidong Du Zhiwen Chen Kokyo Oh Dengyu Pan Zheng Jiao
in
TiO2纳米粒子
,
X射线光电子能谱
,
一步合成
2011
TiO2/graphene composite photocatalysts have been prepared by a simple liquid phase deposition method using titanium tetrafluoride and electron beam (EB) irradiation-pretreated graphene as the raw materials. The products were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The effects of varying the synthesis parameters such as graphene content, concentration of titanium tetrafluoride solution and irradiation dose were investigated. It was found that the preparation conditions had a significant effect on the structure and properties of the final products. The irradiated graphene was covered with petal-like anatase TiO2 nanoparticles, which were more uniform and smaller in size than those in products synthesized without EB irradiation-pretreated graphene. The photocatalytic activities of the products were evaluated using the photocatalytic degradation of methyl orange as a probe reaction. The results showed that the products synthesized using EB irradiation-pretreated graphene exhibited higher photocatalytic activities than those using graphene without EB irradiation pretreatment.
Journal Article