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result(s) for
"639/301/1023/1026"
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Superior Strength and Multiple Strengthening Mechanisms in Nanocrystalline TWIP Steel
by
Abramova, Marina M.
,
Kim, Jung Gi
,
Karavaeva, Marina V.
in
639/301/1023/1026
,
639/301/1023/303
,
Deformation
2018
The strengthening mechanism of the metallic material is related to the hindrance of the dislocation motion, and it is possible to achieve superior strength by maximizing these obstacles. In this study, the multiple strengthening mechanism-based nanostructured steel with high density of defects was fabricated using high-pressure torsion at room and elevated temperatures. By combining multiple strengthening mechanisms, we enhanced the strength of Fe-15 Mn-0.6C-1.5 Al steel to 2.6 GPa. We have found that solute segregation at grain boundaries achieves nanograined and nanotwinned structures with higher strength than the segregation-free counterparts. The importance of the use of multiple deformation mechanism suggests the development of a wide range of strong nanotwinned and nanostructured materials via severe plastic deformation process.
Journal Article
High entropy alloys as a bold step forward in alloy development
2019
Diluting a base element with small amounts of another has served as the basis for developing alloys for thousands of years since the advent of bronze. Today, a fundamentally new idea where alloys have no single dominant element is giving new traction to materials discovery.
Journal Article
Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures
by
Hohenwarter, Anton
,
Ritchie, Robert O.
,
Gludovatz, Bernd
in
639/301/1023/1026
,
639/301/1023/303
,
639/925
2016
High-entropy alloys are an intriguing new class of metallic materials that derive their properties from being multi-element systems that can crystallize as a single phase, despite containing high concentrations of five or more elements with different crystal structures. Here we examine an equiatomic medium-entropy alloy containing only three elements, CrCoNi, as a single-phase face-centred cubic solid solution, which displays strength-toughness properties that exceed those of all high-entropy alloys and most multi-phase alloys. At room temperature, the alloy shows tensile strengths of almost 1 GPa, failure strains of ∼70% and
K
JIc
fracture-toughness values above 200 MPa m
1/2
; at cryogenic temperatures strength, ductility and toughness of the CrCoNi alloy improve to strength levels above 1.3 GPa, failure strains up to 90% and
K
JIc
values of 275 MPa m
1/2
. Such properties appear to result from continuous steady strain hardening, which acts to suppress plastic instability, resulting from pronounced dislocation activity and deformation-induced nano-twinning.
High-entropy alloys derive their properties from being multi-element systems that can crystallize as a single phase. Here, the authors examine a medium-entropy alloy, CrCoNi, which displays strength-toughness properties exceeding those of high-entropy alloys and resulting from steady strain hardening.
Journal Article
Topological nodal-line fermions in spin-orbit metal PbTaSe2
by
Huang, Shin-Ming
,
Lin, Hsin
,
Neupane, Madhab
in
639/301/1023/1026
,
639/301/119
,
Humanities and Social Sciences
2016
Topological semimetals can support one-dimensional Fermi lines or zero-dimensional Weyl points in momentum space, where the valence and conduction bands touch. While the degeneracy points in Weyl semimetals are robust against any perturbation that preserves translational symmetry, nodal lines require protection by additional crystalline symmetries such as mirror reflection. Here we report, based on a systematic theoretical study and a detailed experimental characterization, the existence of topological nodal-line states in the non-centrosymmetric compound PbTaSe
2
with strong spin-orbit coupling. Remarkably, the spin-orbit nodal lines in PbTaSe
2
are not only protected by the reflection symmetry but also characterized by an integer topological invariant. Our detailed angle-resolved photoemission measurements, first-principles simulations and theoretical topological analysis illustrate the physical mechanism underlying the formation of the topological nodal-line states and associated surface states for the first time, thus paving the way towards exploring the exotic properties of the topological nodal-line fermions in condensed matter systems.
Nodal-line shaped bands appearing near the Fermi level host unique properties in topological matter, which has yet to be confirmed in real materials. Here, the authors report the existence of topological nodal-line states in the non-centrosymmetric single-crystalline spin-orbit semimetal PbTaSe
2
.
Journal Article
Ultrahigh strength and ductility in newly developed materials with coherent nanolamellar architectures
2020
Nano-lamellar materials with ultrahigh strengths and unusual physical properties are of technological importance for structural applications. However, these materials generally suffer from low tensile ductility, which severely limits their practical utility. Here we show that markedly enhanced tensile ductility can be achieved in coherent nano-lamellar alloys, which exhibit an unprecedented combination of over 2 GPa yield strength and 16% uniform tensile ductility. The ultrahigh strength originates mainly from the lamellar boundary strengthening, whereas the large ductility correlates to a progressive work-hardening mechanism regulated by the unique nano-lamellar architecture. The coherent lamellar boundaries facilitate the dislocation transmission, which eliminates the stress concentrations at the boundaries. Meanwhile, deformation-induced hierarchical stacking-fault networks and associated high-density Lomer-Cottrell locks enhance the work hardening response, leading to unusually large tensile ductilities. The coherent nano-lamellar strategy can potentially be applied to many other alloys and open new avenues for designing ultrastrong yet ductile materials for technological applications.
Nano-lamellar materials with ultrahigh strengths are highly desirable for technological applications. Here the authors report a nanolamellar architecturing approach by utilizing coherent L12 structures to achieve ultrahigh strength and ductility in Ni-Fe-Co-Cr-Al-Ti multicomponent alloys.
Journal Article
Accelerated search for materials with targeted properties by adaptive design
by
Xue, Deqing
,
Balachandran, Prasanna V.
,
Hogden, John
in
119/118
,
639/301/1023/1026
,
639/301/119
2016
Finding new materials with targeted properties has traditionally been guided by intuition, and trial and error. With increasing chemical complexity, the combinatorial possibilities are too large for an Edisonian approach to be practical. Here we show how an adaptive design strategy, tightly coupled with experiments, can accelerate the discovery process by sequentially identifying the next experiments or calculations, to effectively navigate the complex search space. Our strategy uses inference and global optimization to balance the trade-off between exploitation and exploration of the search space. We demonstrate this by finding very low thermal hysteresis (Δ
T
) NiTi-based shape memory alloys, with Ti
50.0
Ni
46.7
Cu
0.8
Fe
2.3
Pd
0.2
possessing the smallest Δ
T
(1.84 K). We synthesize and characterize 36 predicted compositions (9 feedback loops) from a potential space of ∼800,000 compositions. Of these, 14 had smaller Δ
T
than any of the 22 in the original data set.
Design of materials with targeted properties requires innovative approaches to guide researchers through complex search space. Here, the authors report an adaptive design strategy, using inference and global optimization methods, which can find shape memory alloys with very low thermal hysteresis.
Journal Article
Materials design for hypersonics
by
Chen, Samuel
,
Curtarolo, Stefano
,
Zhang, Dajie
in
639/301/1023/1024
,
639/301/1023/1025
,
639/301/1023/1026
2024
Hypersonic vehicles must withstand extreme conditions during flights that exceed five times the speed of sound. These systems have the potential to facilitate rapid access to space, bolster defense capabilities, and create a new paradigm for transcontinental earth-to-earth travel. However, extreme aerothermal environments create significant challenges for vehicle materials and structures. This work addresses the critical need to develop resilient refractory alloys, composites, and ceramics. We will highlight key design principles for critical vehicle areas such as primary structures, thermal protection, and propulsion systems; the role of theory and computation; and strategies for advancing laboratory-scale materials to manufacturable flight-ready components.
Hypersonic vehicles experience extreme temperatures, high heat fluxes, and aggressive oxidizing environments. Here, the authors highlight key materials design principles for critical vehicle areas and strategies for advancing laboratory-scale materials to flight-ready components.
Journal Article
Strong yet ductile nanolamellar high-entropy alloys by additive manufacturing
2022
Additive manufacturing produces net-shaped components layer by layer for engineering applications
1
–
7
. The additive manufacture of metal alloys by laser powder bed fusion (L-PBF) involves large temperature gradients and rapid cooling
2
,
6
, which enables microstructural refinement at the nanoscale to achieve high strength. However, high-strength nanostructured alloys produced by laser additive manufacturing often have limited ductility
3
. Here we use L-PBF to print dual-phase nanolamellar high-entropy alloys (HEAs) of AlCoCrFeNi
2.1
that exhibit a combination of a high yield strength of about 1.3 gigapascals and a large uniform elongation of about 14 per cent, which surpasses those of other state-of-the-art additively manufactured metal alloys. The high yield strength stems from the strong strengthening effects of the dual-phase structures that consist of alternating face-centred cubic and body-centred cubic nanolamellae; the body-centred cubic nanolamellae exhibit higher strengths and higher hardening rates than the face-centred cubic nanolamellae. The large tensile ductility arises owing to the high work-hardening capability of the as-printed hierarchical microstructures in the form of dual-phase nanolamellae embedded in microscale eutectic colonies, which have nearly random orientations to promote isotropic mechanical properties. The mechanistic insights into the deformation behaviour of additively manufactured HEAs have broad implications for the development of hierarchical, dual- and multi-phase, nanostructured alloys with exceptional mechanical properties.
An additive manufacturing strategy is used to produce dual-phase nanolamellar high-entropy alloys that show a combination of enhanced high yield strength and high tensile ductility.
Journal Article
Nanoscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi
by
Zhang, Ze
,
Wang, Jiangwei
,
Ritchie, Robert O.
in
639/301/1023/1026
,
639/301/1023/303
,
639/925
2015
Damage tolerance can be an elusive characteristic of structural materials requiring both high strength and ductility, properties that are often mutually exclusive. High-entropy alloys are of interest in this regard. Specifically, the single-phase CrMnFeCoNi alloy displays tensile strength levels of ∼1 GPa, excellent ductility (∼60–70%) and exceptional fracture toughness (
K
JIc
>200 MPa√m). Here through the use of
in situ
straining in an aberration-corrected transmission electron microscope, we report on the salient atomistic to micro-scale mechanisms underlying the origin of these properties. We identify a synergy of multiple deformation mechanisms, rarely achieved in metallic alloys, which generates high strength, work hardening and ductility, including the easy motion of Shockley partials, their interactions to form stacking-fault parallelepipeds, and arrest at planar slip bands of undissociated dislocations. We further show that crack propagation is impeded by twinned, nanoscale bridges that form between the near-tip crack faces and delay fracture by shielding the crack tip.
Single-phase high-entropy alloys, such as CrMnFeCoNi, display excellent ductility and fracture toughness. Here, the authors use in situ mechanical loading in an aberration-corrected transmission electron microscope to probe the atomistic to micro-scale mechanisms underlying these properties.
Journal Article
Strain-hardening and suppression of shear-banding in rejuvenated bulk metallic glass
by
Zhou, W. H.
,
Greer, A. L.
,
Ivanov, Yu. P.
in
639/301/1023/1026
,
639/301/1023/218
,
639/301/1023/303
2020
Strain-hardening (the increase of flow stress with plastic strain) is the most important phenomenon in the mechanical behaviour of engineering alloys because it ensures that flow is delocalized, enhances tensile ductility and inhibits catastrophic mechanical failure
1
,
2
. Metallic glasses (MGs) lack the crystallinity of conventional engineering alloys, and some of their properties—such as higher yield stress and elastic strain limit
3
—are greatly improved relative to their crystalline counterparts. MGs can have high fracture toughness and have the highest known ‘damage tolerance’ (defined as the product of yield stress and fracture toughness)
4
among all structural materials. However, the use of MGs in structural applications is largely limited by the fact that they show strain-softening instead of strain-hardening; this leads to extreme localization of plastic flow in shear bands, and is associated with early catastrophic failure in tension. Although rejuvenation of an MG (raising its energy to values that are typical of glass formation at a higher cooling rate) lowers its yield stress, which might enable strain-hardening
5
, it is unclear whether sufficient rejuvenation can be achieved in bulk samples while retaining their glassy structure. Here we show that plastic deformation under triaxial compression at room temperature can rejuvenate bulk MG samples sufficiently to enable strain-hardening through a mechanism that has not been previously observed in the metallic state. This transformed behaviour suppresses shear-banding in bulk samples in normal uniaxial (tensile or compressive) tests, prevents catastrophic failure and leads to higher ultimate flow stress. The rejuvenated MGs are stable at room temperature and show exceptionally efficient strain-hardening, greatly increasing their potential use in structural applications.
Bulk metallic glasses can acquire the ability to strain-harden through a mechanical rejuvenation treatment at room temperature that retains their non-crystalline structure.
Journal Article