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The ultraviolet radiation (UVR) from the Sun on the Earth surface depends on the altitude and surface albedo of the site, solar zenith angle (SZA), attenuation in the atmosphere (absorption by ozone and other trace gases, molecular scattering, scattering by clouds, and scattering and absorption by aerosols). Belo Horizonte (BH, 20° S, 44° W, 858 m a.s.l.) and Saint-Denis La Reunion (SDR, 21° S, 55° E, 85 m a.s.l.) are two very-similar-latitude tropical sites to which the incidence of solar UVR is compared. Despite the statistically significant difference in both altitude and total ozone column (TOC), where SDR has lower altitude and higher TOC, the annual averages of climatological daily erythemal dose (DED) from the Ozone Monitoring Instrument (OMI) for the sites show only -1% difference ( [Formula omitted]): 4486 ± 1621 (1 standard deviation) J m.sup.-2 for BH and 4434 ± 1687 J m.sup.-2 for SDR. Equivalent ground-based data are 13% and 11% ( [Formula omitted]), respectively, lower: 3976 ± 1072 J m.sup.-2 for BH and 4012 ± 1199 J m.sup.-2 for SDR with 1% difference between them. The comparison between the sites of atmospheric geophysical parameters of TOC, cloud fraction (CF), and UV aerosol index (AI) from OMI indicates clouds and aerosols as the main culprit to such a small difference. After clouds, aerosols play an important role, as BH is a metropolis polluted mainly by by-products from fossil-fuel and ethanol combustion and smoke from surrounding biomass burning sources, while SDR is virtually a pristine seashore locality affected by marine and long-distance biomass burning aerosols.

We investigate the impacts of increased CO.sub.2 concentration on migrating diurnal tide (DW1). A future climate simulation is conducted using a WACCM-X model, with surface CO.sub.2 levels increasing according to the RCP8.5 scenario. The DW1 (1,1) mode, a propagating tide peaking near the equator, exhibits a statistically significant positive trend in a range of 20-70 km, and a significant negative trend in a range of 90-110 km. The positive trend is likely driven by a reduction in atmospheric density in the mesosphere and enhanced equatorial convective activity, while the negative trend appears in the mesosphere, which overwhelms the positive trend. Two potential mechanisms may explain the negative trend. First, increasing CO.sub.2 enhances mesospheric stability, reducing tidal vertical wavelengths. In our simulation, equatorial temperatures around â¼50-70 km become cooler than those in â¼70-90 km. This strong cooling could be linked to CO.sub.2 mixing and transport, as well as the contraction of the mesospheric ozone layer due to atmospheric descent induced by CO.sub.2 -driven cooling. Second, stronger convective activity intensifies gravity wave generation, increasing gravity wave diffusion in the mesosphere. This strong convective activity also likely intensifies the tide below â¼70 km. While our positive DW1 trend is consistent with McLandress and Fomichev (2006), the negative trend in the lower thermosphere contrasts with their results. This discrepancy might arise because their model used a time-independent diffusion coefficient, whereas WACCM-X accounts for CO.sub.2 -driven changes in gravity wave diffusion. The negative trend is confirmed in SABER observation for the last two decades, while the positive trend is not verified.

\"The true story of how Mexican-American scientist Mario Molina helped solve the ozone crisis of the 1980s and went on to become a Nobel laureate and a recipient of the Presidential Medal of Freedom. His inspiring story gives hope in the fight against global warming\"--Publisher's description.

The evolution of tropospheric ozone from 1850 to 2100 has been studied using data from Phase 6 of the Coupled Model Intercomparison Project (CMIP6). We evaluate long-term changes using coupled atmosphere–ocean chemistry–climate models, focusing on the CMIP Historical and ScenarioMIP ssp370 experiments, for which detailed tropospheric-ozone diagnostics were archived. The model ensemble has been evaluated against a suite of surface, sonde and satellite observations of the past several decades and found to reproduce well the salient spatial, seasonal and decadal variability and trends. The multi-model mean tropospheric-ozone burden increases from 247 ± 36 Tg in 1850 to a mean value of 356 ± 31 Tg for the period 2005–2014, an increase of 44 %. Modelled present-day values agree well with previous determinations (ACCENT: 336 ± 27 Tg; Atmospheric Chemistry and Climate Model Intercomparison Project, ACCMIP: 337 ± 23 Tg; Tropospheric Ozone Assessment Report, TOAR: 340 ± 34 Tg). In the ssp370 experiments, the ozone burden increases to 416 ± 35 Tg by 2100. The ozone budget has been examined over the same period using lumped ozone production (PO3) and loss (LO3) diagnostics. Both ozone production and chemical loss terms increase steadily over the period 1850 to 2100, with net chemical production (PO3-LO3) reaching a maximum around the year 2000. The residual term, which contains contributions from stratosphere–troposphere transport reaches a minimum around the same time before recovering in the 21st century, while dry deposition increases steadily over the period 1850–2100. Differences between the model residual terms are explained in terms of variation in tropopause height and stratospheric ozone burden.

Past studies have suggested that ozone in the troposphere has increased globally throughout much of the 20th century due to increases in anthropogenic emissions and transport. We show, by combining satellite measurements with a chemical transport model, that during the last four decades tropospheric ozone does indeed indicate increases that are global in nature, yet still highly regional. Satellite ozone measurements from Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) are merged with ozone measurements from the Aura Ozone Monitoring Instrument/Microwave Limb Sounder (OMI/MLS) to determine trends in tropospheric ozone for 1979–2016. Both TOMS (1979–2005) and OMI/MLS (2005–2016) depict large increases in tropospheric ozone from the Near East to India and East Asia and further eastward over the Pacific Ocean. The 38-year merged satellite record shows total net change over this region of about +6 to +7 Dobson units (DU) (i.e., ∼15 %–20 % of average background ozone), with the largest increase (∼4 DU) occurring during the 2005–2016 Aura period. The Global Modeling Initiative (GMI) chemical transport model with time-varying emissions is used to aid in the interpretation of tropospheric ozone trends for 1980–2016. The GMI simulation for the combined record also depicts the greatest increases of +6 to +7 DU over India and East Asia, very similar to the satellite measurements. In regions of significant increases in tropospheric column ozone (TCO) the trends are a factor of 2–2.5 larger for the Aura record when compared to the earlier TOMS record; for India and East Asia the trends in TCO for both GMI and satellite measurements are ∼+3 DU decade(exp −1) or greater during 2005–2016 compared to about +1.2 to +1.4 DU decade(exp −1) for 1979–2005. The GMI simulation and satellite data also reveal a tropospheric ozone increases in ∼+4 to +5 DU for the 38-year record over central Africa and the tropical Atlantic Ocean. Both the GMI simulation and satellite-measured tropospheric ozone during the latter Aura time period show increases of ∼+3 DU decade−1 over the N Atlantic and NE Pacific.

In this study, a perovskite-based mixed cation/anion ultraviolet photodetector with an added halide material is fabricated using perovskite combined with an ABX_3 structure. Mixed cation/anion perovskite thin films of MAPbI[sub.3]/FABr are manufactured through a relatively simple solution process and employed as light-absorption layers. In the produced thin film, SnO[sub.2]–sodium dodecylbenzenesulfonate acts as an electron transport layer and spiro-OMeTAD acts as a hole injection layer. Compared to a single cation/anion perovskite, the fabricated device exhibits phase stability and optoelectronic properties, and demonstrates a responsivity of 72.2 mA/W and a detectability of 4.67 × 10[sup.13] Jones. In addition, the films show an external quantum efficiency of 56%. This suggests that mixed cation/anion films can replace single cation/anion perovskite films. Thus, photodetectors based on lead halides that can be applied in various fields have recently been manufactured.

Bromine released from the decomposition of short-lived brominated source gases contributes as a sink of ozone in the lower stratosphere. The two major contributors are CH.sub.2 Br.sub.2 and CHBr.sub.3 . In this study, we investigate the global seasonal distribution of these two substances, based on four High Altitude and Long Range Research Aircraft (HALO) missions, the HIAPER Pole-to-Pole Observations (HIPPO) mission, and the Atmospheric Tomography (ATom) mission. Observations of CH.sub.2 Br.sub.2 in the free and upper troposphere indicate a pronounced seasonality in both hemispheres, with slightly larger mixing ratios in the Northern Hemisphere (NH). Compared to CH.sub.2 Br.sub.2, CHBr.sub.3 in these regions shows larger variability and less clear seasonality, presenting larger mixing ratios in winter and autumn in NH midlatitudes to high latitudes. The lowermost stratosphere of SH and NH shows a very similar distribution of CH.sub.2 Br.sub.2 in hemispheric spring with differences well below 0.1 ppt, while the differences in hemispheric autumn are much larger with substantially smaller values in the SH than in the NH. This suggests that transport processes may be different in both hemispheric autumn seasons, which implies that the influx of tropospheric air (\"flushing\") into the NH lowermost stratosphere is more efficient than in the SH. The observations of CHBr.sub.3 support the suggestion, with a steeper vertical gradient in the upper troposphere and lower stratosphere in SH autumn than in NH autumn. However, the SH database is insufficient to quantify this difference. We further compare the observations to model estimates of TOMCAT (Toulouse Off-line Model of Chemistry And Transport) and CAM-Chem (Community Atmosphere Model with Chemistry, version 4), both using the same emission inventory of Ordóñez et al. (2012). The pronounced tropospheric seasonality of CH.sub.2 Br.sub.2 in the SH is not reproduced by the models, presumably due to erroneous seasonal emissions or atmospheric photochemical decomposition efficiencies. In contrast, model simulations of CHBr.sub.3 show a pronounced seasonality in both hemispheres, which is not confirmed by observations. The distributions of both species in the lowermost stratosphere of the Northern and Southern hemispheres are overall well captured by the models with the exception of southern hemispheric autumn, where both models present a bias that maximizes in the lowest 40 K above the tropopause, with considerably lower mixing ratios in the observations. Thus, both models reproduce equivalent flushing in both hemispheres, which is not confirmed by the limited available observations. Our study emphasizes the need for more extensive observations in the SH to fully understand the impact of CH.sub.2 Br.sub.2 and CHBr.sub.3 on lowermost-stratospheric ozone loss and to help constrain emissions.

Volatile organic compounds (VOCs) regulate atmospheric oxidation capacity, and the reactions of VOCs are key in understanding ozone formation and its mitigation strategies. When evaluating their impact, most previous studies did not fully consider the role of oxygenated VOCs due to limitations of measurement technology. By using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) combined with a gas chromatograph–mass spectrometer (GC–MS), a large number of oxygenated VOCs (OVOCs) have been quantified in Guangzhou city, China. Based on the new dataset, we demonstrate that constraints using OVOC observations are essential in modeling radical and ozone production, as modeled OVOCs can be substantially lower than measurements, potentially due to primary emissions and/or missing secondary sources. Non-formaldehyde (HCHO) OVOCs can contribute large fractions (22 %–44 %) of total ROx radical production, which are comparable to or larger than the contributions from nitrous acid and formaldehyde. Our results show that models without OVOC constraints using ambient measurements will underestimate the production rates of ROx and ozone, and they may also affect the determination of sensitivity regime in ozone formation. Therefore, a thorough quantification of photodegradable OVOC species is in urgent need to understand accurately the ozone chemistry and to develop effective control strategies.