Explore the vast range of titles available.

[This corrects the article DOI: 10.1155/2024/9799127.].

The present paper studied the effects of calcination temperatures (200–800 °C) on the appearance, mineral composition, and active SiO2 content in attapulgite and investigated the effects of attapulgite before and after calcination on the chemically bonded water content, the degree of reaction of cement paste, and the mechanical properties such as the flexural strength, compressive strength, and splitting-tensile strength of cement mortar. The results indicate that the calcination temperature changes the mineral composition of attapulgite, thereby affecting the hydration activity of cement-based materials. The attapulgite calcined at 500 °C (AT500) has the best enhancement on the hydration activity of cement-based materials. The calcination at 500 °C is most beneficial to the dissolution of SiO2, and the content of SiO2 reaches 20.96%. The contents of chemically bonded water in the samples incorporated with calcined attapulgite reduced and that of the samples incorporated with AT500 at 28 d is the same as that of the control group. The reaction degree of AT500 is 78.61% at 28 days. Calcined attapulgite clay can reduce the energy consumption of the cement industry and promote the sustainable development of attapulgite clay.

To enhance the sorption efficacy of attapulgite for heavy metals, mercapto-functionalized attapulgite (ATP-SH) was synthesized with mercaptan functional groups. When the mass-to-volume ratio of calcined attapulgite (ATP-C) to 3-Mercapropyltrimethoxysilane (MPTMS) was 1 g:0.5 mL (ATP-SH-0.5) and the pH was set to 8, a strong adsorption capacity for Cd (II) and Pb (II) was demonstrated. This indicates excellent adsorption performance for these heavy metals. ATP-SH-0.5 exhibited a maximum adsorption capacity of 43.81 mg/g and 274.83 mg/g for Cd (II) and Pb (II), respectively, in a single ion system. In a binary ion system, the maximum adsorption capacity was 31.86 mg/L and 254.45 mg/L for Cd (II) and Pb (II), respectively. Various characterizations and experiments showed that the adsorption of Cd (II) and Pb (II) onto ATP-SH-0.5 involves ion exchange reactions involving hydroxyl and thiol functional group complexation reactions. This adsorption process follows a single-molecule layer adsorption mechanism. XPS results indicate that hydroxyl and grafted thiol functional groups on the surface of mercapto-functionalized attapulgite participated in surface complexation reactions with Cd (II) and Pb (II), resulting in the formation of Cd-S and Pb-S species. Overall, this study provides a promising mercapto-functionalized modification material for the remediation of polluted water and soil.

Attapulgite (ATP) is a low-cost hydrated clay mineral of aluminum and magnesium and can be used for the preparation of linear low-density polyethylene (LLDPE) nanocomposites. However, the ATP contains accessory minerals that can harm their performance and hinder their polymer interaction. Then, a purification process of this clay mineral is necessary to raise the interactions between ATP and LLDPE. Furthermore, the non-polar nature of LLDPE can also hinder these interactions. One way to improve these interactions is the surface modification of ATP. In this way, the ATP was modified using aminosilane (3-aminopropyl) triethoxysilane (APTES). Raw ATP (ATPr), purified ATP (ATPp), and silanized ATP (ATPs) were characterized, and LLDPE/ATP nanocomposites with 3 and 5 wt% of ATPr, ATPp, and ATPs were prepared by extrusion. The nanocomposites were characterized by scanning electron microscopy (SEM), mechanical properties (tensile tests, Shore D hardness, and impact strength), and X-ray diffraction. APTES was grafted onto the clay surface. The APTES did not modify the crystal structure of ATP and, in addition, it improved the mechanical properties of LLDPE/ATPs nanocomposites. The addition of 5 wt% of ATPs increases the tensile strength, elastic modulus, and Shore D hardness, in addition to improving the dispersion of nanoclay in the polymer matrix.

In this research, the sorption characteristics and mechanism of phosphate on zirconium-modified attapulgite (Zr-ATP), iron-modified attapulgite (Fe-ATP), and zirconium/iron co-modified attapulgite (Zr/Fe-ATP) prepared by a simple impregnation method were studied, and the impacts of Zr-ATP, Fe-ATP, and Zr/Fe-ATP amendment and capping on the migration of phosphorus (P) from sediments to overlying waters were investigated. The results showed that Zr-ATP and Zr/Fe-ATP possessed stronger adsorption ability for phosphate in aqueous solution than Fe-ATP. The ligand replacement of the hydroxyl group with the phosphate anion to form the inner-sphere phosphate complex played a crucial role in the adsorption process of phosphate on Zr-ATP, Fe-ATP, and Zr/Fe-ATP. Most of the phosphate ions bound by Zr-ATP and Zr/Fe-ATP were in the form of caustic soda solution-extractable inorganic P (NaOH-IP) and residual P (Res-P), and it is hard for these P species to be re-released into water under the circumstances of reducing environment and normal pH (5–9). The ratio of mobile P to total P of Fe-ATP loaded with phosphate was much higher than those of Zr-ATP and Zr/Fe-ATP loaded with phosphate, indicating that Fe-ATP-bound phosphate has a higher re-releasing risk than Zr-ATP-bound and Zr/Fe-ATP-bound phosphate. Zr-ATP, Fe-ATP, and Zr/Fe-ATP amendment all can reduce the releasing risk of P from sediments to overlying waters. The amendment of sediment with Zr-ATP and Zr/Fe-ATP can both induce the conversion of redox-sensitive P (BD-P) to NaOH-IP and Res-P in the sediment, making the phosphorus in the sediment more stable. However, the amendment of sediment with Fe-ATP can only induce the conversion of HCl-P to NaOH-IP in the sediment and had a negligible effect on the inorganic P activity in the sediment. Zr-ATP, Fe-ATP, and Zr/Fe-ATP capping all can reduce the risk of P release from sediment into the overlying water, and Zr-ATP and Zr/Fe-ATP capping had a better reduction efficiency of internal P liberation to the overlying water than Fe-ATP capping. Zr-ATP, Fe-ATP, and Zr/Fe-ATP capping all can give rise to the reduction of pore water SRP and diffusive gradient in thin-film (DGT)-labile P in the upper sediment. This is beneficial to the control of P releasing from sediment into the overlying water by the Zr-ATP, Fe-ATP, and Zr/Fe-ATP capping. The findings of this work suggest that Zr-ATP and Zr/Fe-ATP are promising active capping or amendment materials for internal P loading management in surface water bodies.

The extensive use of sulfonamides seriously threatens the safety and stability of the ecological environment. Developing green inexpensive and effective adsorbents is critically needed for the elimination of sulfonamides from wastewater. The non-modified biochar exhibited limited adsorption capacity for sulfonamides. In this study, the attapulgite-doped biochar adsorbent (ATP/BC) was produced from attapulgite and rice straw by calcination. Compared with non-modified biochar, the specific surface area of ATP/BC increased by 73.53–131.26%, and the average pore width of ATP/BC decreased 1.77–3.60 nm. The removal rates of sulfadiazine and sulfamethazine by ATP/BC were 98.63% and 98.24%, respectively, at the mass ratio of ATP to rice straw = 1:10, time = 4 h, dosage = 2 g∙L−1, pH = 5, initial concentration = 1 mg∙L−1, and temperature = 20 °C. A pseudo-second-order kinetic model (R2 = 0.99) and the Freundlich isothermal model (R2 = 0.99) well described the process of sulfonamide adsorption on ATP/BC. Thermodynamic calculations showed that the adsorption behavior of sulfonamides on the ATP/BC was an endothermic (ΔH > 0), random (ΔS > 0), spontaneous reaction (ΔG < 0) that was dominated by chemisorption (−20 kJ∙mol−1 > ΔG). The potential adsorption mechanisms include electrostatic interaction, hydrogen bonding, π–π interaction, and Lewis acid–base interactions. This study provides an optional material to treat sulfonamides in wastewater and groundwater.

Accelerated industrialization and surging energy demands have led to continuously rising atmospheric CO[sub.2] concentrations. Developing sustainable methods to reduce atmospheric CO[sub.2] levels is crucial for achieving carbon neutrality. Concurrently, the rapid development of new energy vehicles has driven a significant increase in demand for lithium-ion batteries (LIBs), which are now approaching an end-of-life peak. Efficient recycling of valuable metals from spent LIBs represents a critical challenge. This study employs conventional hydrometallurgical processing to recover valuable metals from spent LIBs. Subsequently, Ni-doped Co[sub.3]O[sub.4] (Ni:Co[sub.3]O[sub.4]) supported on the natural mineral attapulgite (ATP) was synthesized via a sol–gel method. The incorporation of a small amount of Ni into the Co[sub.3]O[sub.4] lattice generates oxygen vacancies, inducing a localized surface plasmon resonance (LSPR) effect, which significantly enhances charge carrier transport and separation efficiency. During the photocatalytic reduction of CO[sub.2], the primary product CO generated by the Ni:Co[sub.3]O[sub.4]/ATP composite achieved a high production rate of 30.1 μmol·g[sup.−1]·h[sup.−1]. Furthermore, the composite maintains robust catalytic activity even after five consecutive reaction cycles.

With the increasing demand for air pollution control, the development of efficient and stable catalysts to degrade hazardous VOCs such as toluene has become particularly important. Herein, various copper-doped attapulgite-supported cobalt oxide spinel composites (Cu[sub.x]Co[sub.3−x]O[sub.4]/ATP) were synthesized using an ultrasonic-assisted precipitation method. The results showed that the abundant Si-OH groups on the surface of ATP played a crucial role in anchoring Co, and the instantaneous high-energy input of ultrasonication facilitated the formation of Si-O-Co bonds in Co[sub.3]O[sub.4]/ATP. The doping of Cu ions induced the expansion of the Co[sub.3]O[sub.4] lattice, resulting in a significant number of oxygen vacancies. The ultrasound-induced synthesized Cu[sub.0.1]Co[sub.2.9]O[sub.4]/ATP catalyst exhibited the best catalytic oxidation performance, achieving a 99% toluene degradation rate at 300 °C under a weight hourly space velocity (WHSV) of 10,000 mL·g[sup.−1] h[sup.−1] and initial toluene concentration of 1000 ppm, along with high stability during 12 h of continuous running. This work presents a new strategy for the cost-effective catalytic elimination of VOCs.

In this study, the cationic polymer poly-epichlorohydrin-dimethylamine was immobilized on natural attapulgite to improve the dye adsorption capacities. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction, nitrogen adsorption-desorption isotherms, scanning electron microscope (SEM) analysis, zeta potential analysis, and particle size analysis were used to determine the characteristics of modified attapulgite. Results showed that the poly-epichlorohydrin-dimethylamine had been successfully grafted onto the surface of attapulgite without altering its crystal structure. After cationic modification, the specific surface area of attapulgite obviously decreased, and its surface zeta potentials possessed positive values in the pH range from 3 to 11. The cation-modified attapulgite displayed high adsorption capacities for anionic dyes, and its maximum adsorption capacities were 237.4 mg/g for Reactive Black 5 and 228.3 mg/g for Reactive Red 239; this is corroborated by Langmuir’s isotherm studies. It was demonstrated that the two reactive dyes could be 100% removed from effluents when cation-modified attapulgite was used in column operation modes. Its treatment capacities were more than three times larger than that of activated carbon. The regeneration study verified better utilization and stability of the fabricated adsorbent in column operation. This work has conclusively confirmed the potential of the new modified attapulgite for effectively treating dye wastewaters.