Explore the vast range of titles available.

The Re-Os isotopic system is largely considered the geochronometer of choice to date partial melting of terrestrial peridotites and in constraining the evolution of Earth's dynamics from the mantle viewpoint. While whole-rock peridotite Re-Os isotopic signatures are the core of such investigations, the Re-Os dating of individual peridotite minerals - base metal sulfides (BMS) and platinum group minerals (PGM) - that are the main hosts for Re and Os in the mantle peridotites came into play two decades ago. These nanometric-micrometric BMS and PGM display an extreme complexity and heterogeneity in their 187Os/188Os and 187Re/188Os signatures that result from the origin of the BMS±PGM grains (residual vs. metasomatic), the nature of the metasomatic agents, the transport/precipitation mechanisms, BMS±PGM mineralogy, and subsequent Re/Os fractionation. Corresponding whole-rock host peridotites, typically plot within the 187Os/188Os and 187Re/188Os ranges defined by the BMS±PGM, clearly demonstrating that their Re-Os signatures represent the average of the different BMS±PGM populations. The difference between the 187Os/188Os ratios of the least radiogenic BMS±PGM and the respective host peridotite increases with the fertility of the peridotite reflecting the increasing contribution of metasomatic BMS±PGM to the whole-rock mass balance of Re and Os concentrations and Os isotope compositions. Corollaries to these observations are that (1) BMS may provide a record of much older partial melting event, pushing back in time the age of the lithospheric mantle stabilization, (2) if only whole-rock peridotite Re-Os isotopic measurements are possible, then the best targets for constraining the timing of lithospheric stabilization are BMS-free/BMS-poor ultra-refractory spinel-bearing peridotites with very minimal metasomatic overprint, as their 187Os/188Os signatures may be geologically meaningful, (3) while lherzolites are \"fertile\" in terms of their geochemical composition, they do not have a \"primitive,\" unmodified composition, certainly in terms of their highly siderophile elements (HSE) and Re-Os isotopic systematics, and (4) the combined Re-Os isotopic investigations of BMS and whole-rock in BMS-rich mantle peridotites would provide a complementary view on the timing and nature of the petrological events responsible for the chemical and isotopic evolution and destruction of the lithospheric mantle. In addition, the 187Os/188Os composition of the BMS±PGM (both residual and metasomatic) within any single peridotite may define several age clusters - in contrast to the single whole-rock value - and thus provide a more accurate picture of the complex petrogenetic history of the lithospheric mantle. When coupled with a detailed BMS±PGM petrographical study and whole-rock lithophile and HSE systematics, these BMS age clusters highlight the timing and nature of the petrological events contributing to the formation and chemical and isotopic evolution of the lithospheric mantle. These BMS±PGM age clusters may match regional or the local crustal ages, suggesting that the formation and evolution of the lithospheric mantle and its overlying crust are linked, providing mirror records of their geological and chemical history. This is, however, not a rule of thumb as clear evidence of crust-mantle age decoupling also exist. Although the BMS±PGM Re-Os model ages push back in time the stabilization of lithospheric mantle, the dichotomy between Archean cratonic and circum-cratonic peridotites, and post-Archean non-cratonic peridotites and tectonites is preserved. This ability of BMS±PGM to preserve older ages than their host peridotite also underscores their survival for billions of years without being reset or reequilibrated despite the complex petrogenetic processes recorded by their host mantle peridotites. As such, they are the mantle equivalents of crustal zircons. Preservation of such old signatures in \"young\" oceanic peridotites ultimately rules out the use of the Re-Os signatures in both oceanic peridotites and their BMS to estimate the timescales of isotopic homogenization of the convecting mantle.

Palladium and Pt are present in magmatic sulfide deposits mainly as discrete platinum-group minerals (PGM) closely associated with base metal sulfides (BMS). It is always debated whether these PGM phases are of magmatic or subsolidus origin. The mechanism by which Pt- and Pd-mineral phases form depends on how Pd and Pt are accommodated in magmatic sulfide phases: as cation substitutions or as stable nano Pd- and Pt-ligand particles. To know how Pd and Pt are hosted in magmatic sulfides and how they behave during cooling, we have investigated magmatic monosulfide solid solution (MSS) (quenched from 950 °C) and low-temperature (slowly cooled from 950 to 25 °C) decomposed MSS, both synthesized from PdSb, PdTe 2 , PdBi 2 , PtSb 2 , PtTe 2 -or PtBi 2 -saturated CuNiFe-sulfide mixture. Transmission Electron Microscopy (TEM) revealed that at 950 °C, Pd is hosted in MSS as nano Pd-telluride and antimonide melt droplets. Platinum is hosted in MSS as PtTe 2 (moncheite), PtS (cooperite) and PtSb 2 (geversite) nanocrystals. Moncheite and cooperite nanoparticles are aligned along the (0001) plane, and share one crystallographic plane (hkl) with the host, hexagonal MSS. At 25 °C, the Pd-telluride and antimonide melt droplets crystallized to merenskyite (PdTe 2 ) and Ni-rich sudburyite (Pd(Ni)Sb). The Pt nano phases at 25 °C keep their composition and fabric and show no preference to pyrrhotite and pentlandite. Results imply that Pt and Pd minerals nucleate at magmatic temperature and grow by assembling PGE-ligand nanoparticles, not by exsolution of cationic and anionic metal species from BMS. Results also prove a weak Pd-S chemical affinity at the magmatic stage; Pd atoms are incorporated in MSS and the intermediate solid solution (ISS) when semimetals are not available. During subsolidus transformations of MSS and ISS, Pd preferentially concentrates in pentlandite.

Aims The retreat of glaciers is exposing new terrains to primary plant succession around the globe. To improve the understanding of vegetation development along a glacier retreat chronosequence, we (i) evaluated a possible link between base metal (Ca, Mg, K, Na) supply and vegetation establishment, (ii) determined the rates of the establishment of soil and plant base metal stocks, and (iii) estimated the size of the main base metal fluxes. Methods We determined base metal stocks in the soil organic layer, the mineral topsoil (0–10 cm), and in leaves/needles, trunk, bark, branches and roots of the dominating shrub and tree species and estimated fluxes of atmospheric deposition, plant uptake and leaching losses along the 127-yr Hailuogou chronosequence. Results Total ecosystem Ca and Mg stocks decreased along the chronosequence, while those of K and Na were unrelated with ecosystem age. Fortyfour and 30% of the initial stocks of Ca and Mg, respectively, were leached during the first 47 years, at rates of 130 ± 10.6 g m −2  year −1 Ca and 35 ± 3.1 g m −2  year −1  Mg. The organic layer accumulated at a mean rate of 288 g m −2  year −1 providing a bioavailable base metal stock, which was especially important for K cycling. Conclusions We suggest that the initial high Ca bioavailability because of a moderately alkaline soil pH and carbonate depletion in 47 years, together with the dissolution of easily-weatherable silicates providing enough Mg and K to the pioneer vegetation, contributed to the establishment of the mature forest in ca. 80 years.

The nickel-based superalloy GH4099 was diffusion-bonded with 2–10 μm thick pure nickel interlayer. The joint microstructure was characterized by scanning electron microscopy, electron probe micro-analyzer and electron backscattered diffraction; the joint mechanical properties were evaluated by nanoindentation, tensile and Charpy impact tests. It was observed that with the reduction in interlayer thickness, element distribution and hardness across the joining interface became more homogeneous and subsequently produced sound joints due to the suppression of precipitated carbides on joining interface. The strengths of joints were in the range of the base metal as-received. When bonding time or temperatures increased, the bond line of the 2 μm interlayer joint was partially eliminated by the recrystallization across the joining interface, and the strength and elongation (or the absorbed energy) of the joint were same as (or close to) the base metal which underwent the same heating process. However, due to the microstructure degradation induced by the grain coarsening, the absorbed energy of the 2 μm interlayer joint reaches the maximum when the joint bonded under the moderate condition of 1120 °C and 90 min.

Base metal catalyzed regioselective cage B–H functionalization has been achieved. Under the assistance of a bidentate directing group, Cu-catalyzed [4+2] annulation of carboranyl amides with internal alkynes affords unprecedented C,B-substituted carborane-fused-pyridone derivatives, whereas the use of terminal alkynes leads to B–H/C(sp)–H dehydrocoupling products. The isolation and structural identification of a notably stable Cu(I) intermediate shed light on the reaction mechanism, which is proposed to involve a Cu(III) intermediate.

Numerous mineral microinclusions discovered in the Triassic Ildeus mafic–ultramafic intrusion are dominated by base metal sulfides, gold, silver, and their alloys, as well as rare earth element (REE) minerals. These mineral microinclusions were formed through both the magmatic differentiation of the Ildeus intrusion and the multi-stage interaction of intrusive rocks with late-magmatic, post-magmatic and post-collisional fluids. A comparison of the results of our microinclusions study with ore mineralization discovered within the Ildeus intrusion suggests that microinclusion assemblages in igneous rocks are, in some cases, precursors of potentially economic mineralization. In the case of the Ildeus rocks, sulfide microinclusions correspond to potentially economic disseminated nickel–cobalt sulfide ores, while microinclusions of gold and its alloys correlate with intrusion-hosted, erratic gold mineralization. The occurrence of silver and rare earth element minerals in Ildeus plutonic rocks indicates the possible presence of silver and REE mineralization, which is supported by sub-economic whole-rock silver and REE grades in parts of the Ildeus intrusion. The results of our investigation suggest that studies of mineral microinclusions in magmatic rocks may be useful in the evaluation of their metallogenic specialization and ore-forming potential and could possibly be utilized as an additional prospecting tool in the regional exploration for precious, base, and rare metals.

Ensuring a secure bond between a framework structure and layering composite resin veneer is essential for a long-lasting dental restoration. A variety of primer systems are available to facilitate the adhesive bonding. Nevertheless, the growing preference for efficiency and simplicity in dentistry has made the one-bottle universal primers a desirable option. This study aims to compare the effectiveness of universal primers on the shear bond strength (SBS) of base metal alloy (BMA) and zirconia to layering composite resin. Each 160 BMA and zirconia 20 × 10 × 5 mm test specimen was fabricated. Eight different primers (SunCera Metal Primer, Metal Primer Z, Reliance Metal Primer, Alloy Primer, MKZ Primer, Monobond Plus, ArtPrime Plus, and Clearfil Ceramic Primer Plus) were applied to 20 specimens in each group. Subsequently, a 5 × 2 mm composite resin build-up was applied. SBS tests were performed after 24 h of water storage and after thermocycling (25,000 cycles, 5–55 °C). On BMA, after water storage for 24 h, the bond strength values ranged from 26.53 ± 3.28 MPa (Metal Primer Z) to 29.72 ± 2.00 MPa (MKZ Primer), while after thermocycling, bond strength values ranged from 25.19 ± 1.73 MPa (MKZ Primer) to 27.69 ± 2.37 MPa (Clearfil Ceramic Primer Plus). On a zirconia base, after 24 h, the bond strengths values ranged from 22.63 ± 2.28 MPa (Reliance Primer) to 29.96 ± 2.37 MPa (MKZ Primer) and from 23.77 ± 3.86 MPa (Metal Primer Z) to 28.88 ± 3.09 MPa (Monobond Plus) after thermocycling. While no significant difference in bond strength was found between the primers on the BMA base, five primer combinations differed significantly from each other on zirconia (p = 0.002–0.043). All primers achieved a bond strength greater than 23 MPa on both framework materials after thermocycling. Thus, all primers tested can be applied to both framework materials with comparable results.

Base metal mining in the Rhenohercynian Zone has a long history. Middle-Upper Devonian to Lower Carboniferous sediment-hosted massive sulfide deposits (SHMS), volcanic-hosted massive sulfide deposits (VHMS) and Lahn-Dill-type iron, and base metal ores occur at several sites in the Rhenohercynian Zone that stretches from the South Portuguese Zone, through the Lizard area, the Rhenish Massif and the Harz Mountain to the Moravo-Silesian Zone of SW Bohemia. During Devonian to Early Carboniferous times, the Rhenohercynian Zone is seen as an evolving rift system developed on subsiding shelf areas of the Old Red continent. A reappraisal of the geotectonic setting of these ore deposits is proposed. The Middle-Upper Devonian to Early Carboniferous time period was characterized by detrital sedimentation, continental intraplate and subduction-related volcanism. The large shelf of the Devonian Old Red continent was the place of thermal subsidence with contemporaneous mobilization of rising thermal fluids along activated Early Devonian growth faults. Hydrothermal brines equilibrated with the basement and overlying Middle-Upper Devonian detrital deposits forming the SHMS deposits in the southern part of the Pyrite Belt, in the Rhenish Massif and in the Harz areas. Volcanic-hosted massive sulfide deposits (VHMS) formed in the more eastern localities of the Rhenohercynian domain. In contrast, since the Tournaisian period of ore formation, dominant pull-apart triggered magmatic emplacement of acidic rocks, and their metasomatic replacement in the apical zones of felsic domes and sediments in the northern part of the Iberian Pyrite belt, thus changing the general conditions of ore precipitation. This two-step evolution is thought to be controlled by syn- to post-tectonic phases in the Variscan framework, specifically by the transition of geotectonic setting dominated by crustal extension to a one characterized by the subduction of the supposed northern slab of the Rheic Ocean preceding the general Late Variscan crustal shortening and oroclinal bending.

The Mesoproterozoic Aggeneys-Gamsberg ore district, South Africa, is one of the world´s largest sulfidic base metal concentrations and well-known as a prime example of Broken Hill-type base metal deposits, traditionally interpreted as metamorphosed SEDEX deposits. Within this district, the Gamsberg deposit stands out for its huge size and strongly Zn-dominated ore ( >14 Mt contained Zn). New electron microprobe analyses and element abundance maps of sulfides and silicates point to fluid-driven sulfidation during retrograde metamorphism. Differences in the chemistry of sulfide inclusions within zoned garnet grains reflect different degrees of interaction of sulfides with high metal/sulfur-ratio with a sulfur-rich metamorphic fluid. Independent evidence of sulfidation during retrograde metamorphism comes from graphic-textured sulfide aggregates that previously have been interpreted as quenched sulfidic melts, replacement of pyrrhotite by pyrite along micro-fractures, and sulfides in phyllic alteration zones. Limited availability of fluid under retrograde conditions caused locally different degrees of segregation of Fe-rich sphalerite into Zn-rich sphalerite and pyrite, and thus considerable heterogeneity in sphalerite chemistry. The invoked sulfur-rich metamorphic fluids would have been able to sulfidize base metal-rich zones in the whole deposit and thus camouflage a potential pre-metamorphic oxidation. These findings support the recently established hypothesis of a pre-Klondikean weathering-induced oxidation event and challenge the traditional explanation of Broken Hill-type deposits as merely metamorphosed SEDEX deposits. Instead, we suggest that the massive sulfide deposits experienced a complex history, starting with initial SEDEX-type mineralization, followed by near-surface oxidation with spatial metal separation, and then sulfidation of this oxidized ore during medium- to high-grade metamorphism.

Softening in the heat-affected zone (HAZ) of high-strength pipeline welds compromises its service safety but the corresponding softening mechanism is not well-understood. Softening behavior in the HAZ of two X80 pipeline girth welds with different base metal microstructures, i.e., acicular ferrite (AF)-dominated (X80-AF) and granular bainite (GB)-dominated (X80-GB), were investigated through microhardness tests and detailed microstructure characterization. The results showed that softening in the HAZ of two girth welds primarily occurred in the fine-grained (FG) HAZ, while hardening was found in the coarse-grained (CG) HAZ. X80-AF showed higher softening resistance than X80-GB, with softening ratios of 3.44% vs. 12.46%, and softened zone widths of 2.1 mm vs. 3.9 mm, respectively. Due to its high dislocation density and refined interlocking structure, AF could effectively inhibit phase transformation and grain coarsening during reheating, which resulted in smaller grains and a lower fraction of polygonal ferrite (PF) in the FGHAZ (28%). In contrast, coarse GB was more prone to grain coarsening and hence engendered higher PF proportion (68%). Therefore, for the microstructural design of high-strength pipeline steels, increasing the proportion of refined AF is beneficial to the softening resistance and thereby elevates the service safety of pipelines.