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Due to the high pressure of confined water in deep mines, the incidence of water inrush disasters in China caused by geological structures, especially faults, are becoming more frequent and more complicated. Using the Comsol numerical simulation software, we analyzed the formation and evolution of a water inrush channel in the floor of a deep mine with buried faults. The numerical model was set up using geological data from an actual coal mine that is highly threatened by confined water with buried faults. The results show that the stress became more and more concentrated near the buried fault as the working face advanced. The flow velocity inside the fault was much greater than in the floor, which means that the buried structure was important in the ascension of the confined water and destruction of the floor. A water inrush channel formed when the failure zone connected with the fissures of the buried fault.

The effectiveness of load-reduction techniques often diminishes due to creep behavior observed in geomaterials, as loess backfill is used, the load reduction rate of high-filled cut-and-cover tunnels (HFCCTs) after creep will decrease by 10.83%, posing a threat to the long-term stability of deeply buried structures such as HFCCTs. Therefore, a geotechnical solution is crucial to ensuring sustained effectiveness in load-reduction strategies over time. This study utilizes a finite-difference method to examine three promising measures for mitigating creep effects. Our analysis focuses on the time-dependent changes in earth pressure atop the cut-and-cover tunnel (CCT) and the internal distribution of cross-sectional forces, including bending moment, shear force, axial force, and displacement. Results indicate that the creep behavior of load-reduction materials significantly influences the internal force distribution. Furthermore, sustained load reduction is achieved when utilizing low-creep materials like dry sandy gravel as backfill soil, which needs to be borrowed from other sites. Additionally, integrating concrete wedges with load-reduction techniques facilitates a more uniform stress distribution atop CCTs.

This paper investigates the dependency of shape factor of the axis-symmetric fully sunken structures (viz. cubical, square prismatic, pyramidal, and cylindrical) in terms of their depth and orientation. Experimental evaluations of the shape factor in reducedscale models were carried out at laboratory using thermal simulation method in different conditions. The method was used to determine shape factor, which can be used to determine heat loss from ground to structure or structure to ground fully sunken with different orientations. Maximum and minimum values of the shape factor in set-I and setli conditions were calculated as 90.18 and 9.93, respectively. In set-II condition, the value varied from 16.49 to 35.28. At D/L = 2, the shape factor in set-VI condition (17.26%) was compared to that in set-VII condition. Similarly, the shape factor in set-IX (33.47%) was compared to that in set-VIII condition. This comparison helps design a better building structure of fully buried nature to ensure higher thermal comfort.

Perovskite solar cells with an inverted architecture provide a key pathway for commercializing this emerging photovoltaic technology because of the better power conversion efficiency and operational stability compared with the normal device structure. Specifically, power conversion efficiencies of the inverted perovskite solar cells have exceeded 25% owing to the development of improved self-assembled molecules 1 – 5 and passivation strategies 6 – 8 . However, poor wettability and agglomeration of self-assembled molecules 9 – 12 cause interfacial losses, impeding further improvement in the power conversion efficiency and stability. Here we report a molecular hybrid at the buried interface in inverted perovskite solar cells that co-assembled the popular self-assembled molecule [4-(3,6-dimethyl-9 H -carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) with the multiple aromatic carboxylic acid 4,4′,4″-nitrilotribenzoic acid (NA) to improve the heterojunction interface. The molecular hybrid of Me-4PACz with NA could substantially improve the interfacial characteristics. The resulting inverted perovskite solar cells demonstrated a record certified steady-state efficiency of 26.54%. Crucially, this strategy aligns seamlessly with large-scale manufacturing, achieving one of the highest certified power conversion efficiencies for inverted mini-modules at 22.74% (aperture area 11.1 cm 2 ). Our device also maintained 96.1% of its initial power conversion efficiency after more than 2,400 h of 1-sun operation in ambient air. High efficiency in perovskite solar cells is achieved by using a molecular hybrid of a self-assembled monolayer with nitrilotribenzoic acid.

Self-assembled monolayers (SAMs) have become pivotal in achieving high-performance perovskite solar cells (PSCs) and organic solar cells (OSCs) by significantly minimizing interfacial energy losses. In this study, we propose a co-adsorb (CA) strategy employing a novel small molecule, 2-chloro-5-(trifluoromethyl)isonicotinic acid (PyCA-3F), introducing at the buried interface between 2PACz and the perovskite/organic layers. This approach effectively diminishes 2PACz’s aggregation, enhancing surface smoothness and increasing work function for the modified SAM layer, thereby providing a flattened buried interface with a favorable heterointerface for perovskite. The resultant improvements in crystallinity, minimized trap states, and augmented hole extraction and transfer capabilities have propelled power conversion efficiencies (PCEs) beyond 25% in PSCs with a p-i-n structure (certified at 24.68%). OSCs employing the CA strategy achieve remarkable PCEs of 19.51% based on PM1:PTQ10:m-BTP-PhC6 photoactive system. Notably, universal improvements have also been achieved for the other two popular OSC systems. After a 1000-hour maximal power point tracking, the encapsulated PSCs and OSCs retain approximately 90% and 80% of their initial PCEs, respectively. This work introduces a facile, rational, and effective method to enhance the performance of SAMs, realizing efficiency breakthroughs in both PSCs and OSCs with a favorable p-i-n device structure, along with improved operational stability. Self-assembled monolayers are essential for achieving high performance solar cells by minimizing interfacial energy losses. Here, authors the develop a co-adsorb strategy with a small molecule to provide a favorable heterointerface, realizing high efficiency in p-i-n perovskite and organic devices.

Targeted protein degradation via “hijacking” of the ubiquitin-proteasome system using proteolysis targeting chimeras (PROTACs) has evolved into a novel therapeutic modality. The design of PROTACs is challenging; multiple steps involved in PROTAC-induced degradation make it difficult to establish coherent structure-activity relationships. Herein, we characterize PROTAC-mediated ternary complex formation and degradation by employing von Hippel–Lindau protein (VHL) recruiting PROTACs for two different target proteins, SMARCA2 and BRD4. Ternary-complex attributes and degradation activity parameters are evaluated by varying components of the PROTAC’s architecture. Ternary complex binding affinity and cooperativity correlates well with degradation potency and initial rates of degradation. Additionally, we develop a ternary-complex structure modeling workflow to calculate the total buried surface area at the interface, which is in agreement with the measured ternary complex binding affinity. Our findings establish a predictive framework to guide the design of potent degraders. Targeted protein degradation using proteolysis targeting chimeras (PROTACs) represents an emergent therapeutic modality, however, the design of PROTACs is challenging due to multiple steps involved in PROTAC-induced degradation. Here, the authors establish a predictive framework to guide the design of potent degraders.

For designing and studying an electrical substation grounding system [GS], a simple remote substation is considered according to the safety procedures indicated in the IEEE 80 Standard. Buried metallic materials or nearby metallic structures permanently endanger human life when electrical faults occur. Scenarios related to the design of electrical substations that consider the transfer of electrical potentials that can occur between the GS and buried metallic materials in their vicinity are presented, the behavior of potential transfer is evaluated, values of transferred voltages are calculated, and the main variables that influence the transferred voltage levels are identified. The simulations are performed with the CYMGRD software specific for GS calculations. Its analysis generates real results in the potential transfer that must be considered by the GS design engineer, which enables to avoid designing isolated substations without taking into account existing elements that may affect the substation surroundings.

Two-dimensional (2D) transition-metal dichalcogenides (TMDs) materials, such as molybdenum disulfide (MoS2), stand out due to their atomically thin layered structure and exceptional electrical properties. Consequently, they could potentially become one of the main materials for future integrated high-performance logic circuits. However, the local back-gate-based MoS2 transistors on a silicon substrate can lead to the degradation of electrical characteristics. This degradation is caused by the abnormal effect of gate sidewalls, leading to non-uniform field controllability. Therefore, the buried-gate-based MoS2 transistors where the gate electrodes are embedded into the silicon substrate are fabricated. The several device parameters such as field-effect mobility, on/off current ratio, and breakdown voltage of gate dielectric are dramatically enhanced by field-effect mobility (from 0.166 to 1.08 cm2/V·s), on/off current ratio (from 4.90 × 105 to 1.52 × 107), and breakdown voltage (from 15.73 to 27.48 V) compared with a local back-gate-based MoS2 transistor, respectively. Integrated logic circuits, including inverters, NAND, NOR, AND, and OR gates, were successfully fabricated by 2-inch wafer-scale through the integration of a buried-gate MoS2 transistor array.

Gravity models are powerful tools for mapping tectonic structures, especially in the deep ocean basins where the topography remains unmapped by ships or is buried by thick sediment. We combined new radar altimeter measurements from satellites CryoSat-2 and Jason-1 with existing data to construct a global marine gravity model that is two times more accurate than previous models. We found an extinct spreading ridge in the Gulf of Mexico, a major propagating rift in the South Atlantic Ocean, abyssal hill fabric on slow-spreading ridges, and thousands of previously uncharted seamounts. These discoveries allow us to understand regional tectonic processes and highlight the importance of satellite-derived gravity models as one of the primary tools for the investigation of remote ocean basins.

Diversion tunnels play a critical role in water conservancy and hydropower projects. However, due to complex geological conditions, especially the influence of buried fault structures that are difficult to observe below the surface directly, construction processes often face significant challenges such as rock mass instability, seepage, and abrupt geological changes. Audio magnetotelluric (AMT) technology, as a high-resolution electromagnetic exploration method, demonstrates remarkable advantages in detecting buried fault structures due to its sensitivity to deep subsurface features and wide applicability. This study focuses on a specific diversion tunnel project, conducting a detailed analysis of the distribution characteristics of buried faults along the tunnel alignment. These include the orientation, scale, depth, and relationship of the faults with surrounding geological structures. By comparing and validating the detection results, the study further establishes the applicability and reliability of the AMT method under complex geological conditions.