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Carbon dioxide (CO2) has been anticipated as an ideal carbon building block for organic synthesis due to the noble properties of CO2, which are abundant renewable carbon feedstock, non-toxic nature, and contributing to a more sustainable use of resources. Several green and proficient routes have been established for chemical CO2 fixation. Among the prominent routes, this review epitomizes the reactions involving cycloaddition of epoxides with CO2 in producing cyclic carbonate. Cyclic carbonate has been widely used as a polar aprotic solvent, as an electrolyte in Li-ion batteries, and as precursors for various forms of chemical synthesis such as polycarbonates and polyurethanes. This review provides an overview in terms of the reaction mechanistic pathway and recent advances in the development of several classes of catalysts, including homogeneous organocatalysts (e.g., organic salt, ionic liquid, deep eutectic solvents), organometallic (e.g., mono-, bi-, and tri-metal salen complexes and non-salen complexes) and heterogeneous supported catalysts, and metal organic framework (MOF). Selection of effective catalysts for various epoxide substrates is very important in determining the cycloaddition operating condition. Under their catalytic systems, all classes of these catalysts, with regard to recent developments, can exhibit CO2 cycloaddition of terminal epoxide substrates at ambient temperatures and low CO2 pressure. Although highly desired conversion can be achieved for internal epoxide substrates, higher temperature and pressure are normally required. This includes fatty acid-derived terminal epoxides for oleochemical carbonate production. The production of fully renewable resources by employment of bio-based epoxy with biorefinery concept and potential enhancement of cycloaddition reactions are pointed out as well.

Near-critical and supercritical carbon dioxide (SC-CO2) is extensively utilized in high-pressure separation, extraction, polymer processing, and carbon capture and utilization (CCU) technologies owing to its tunable density, low viscosity, high diffusivity, and environmentally benign nature. Reliable phase equilibrium data are indispensable for process design and optimization, especially in the near-critical region characterized by pronounced non-idealities, high compressibility, and density fluctuations. This review synthesizes experimental phase behaviour studies for binary mixtures of CO2 with diverse components, including hydrocarbons, alcohols, ethers, esters, ketones, water, monomers/polymers, ionic liquids (ILs), and deep eutectic solvents (DESs), compiling extensive vapour–liquid equilibrium (VLE), liquid–liquid equilibrium (LLE), and critical data across industrially relevant pressure (up to 40 MPa) and temperature (up to 400 K) ranges. It critically evaluates analytical (sampling and non-sampling) and synthetic methodologies, addressing challenges in CO2-rich phase handling, depressurization artefacts, and near-critical phenomena, while assessing data consistency against established reliability criteria. Key trends emerge, such as enhanced solubility with increasing pressure and CO2 density, chain-length dependencies in hydrocarbons and alcohols, and Lewis acid–base interactions driving solvation in polar systems. The review highlights gaps in multicomponent data and proposes integrating high-quality experiments with advanced thermodynamic modelling to enhance predictive accuracy. Future directions emphasize high-precision in situ techniques, expanded datasets for complex mixtures, and novel CO2-philic solvents to advance sustainable SC-CO2 applications.

Plastic production has been increasing at enormous rates. Particularly, the socioenvironmental problems resulting from the linear economy model have been widely discussed, especially regarding plastic pieces intended for single use and disposed improperly in the environment. Nonetheless, greenhouse gas emissions caused by inappropriate disposal or recycling and by the many production stages have not been discussed thoroughly. Regarding the manufacturing processes, carbon dioxide is produced mainly through heating of process streams and intrinsic chemical transformations, explaining why first-generation petrochemical industries are among the top five most greenhouse gas (GHG)-polluting businesses. Consequently, the plastics market must pursue full integration with the circular economy approach, promoting the simultaneous recycling of plastic wastes and sequestration and reuse of CO2 through carbon capture and utilization (CCU) strategies, which can be employed for the manufacture of olefins (among other process streams) and reduction of fossil-fuel demands and environmental impacts. Considering the previous remarks, the present manuscript’s purpose is to provide a review regarding CO2 emissions, capture, and utilization in the plastics industry. A detailed bibliometric review of both the scientific and the patent literature available is presented, including the description of key players and critical discussions and suggestions about the main technologies. As shown throughout the text, the number of documents has grown steadily, illustrating the increasing importance of CCU strategies in the field of plastics manufacture.

In this study, the task of integrating capture and conversion of CO2 into a single material platform is realized by developing bifunctional membranes based on polymer ionic liquids (PILs). The novelty of this work lies in the fabrication and comprehensive evaluation of PIL-based membrane materials that combine catalytic activity toward CO2 conversion with gas separation performance within one material system. In contrast to most previously reported imidazolium-based PILs, which have mainly been considered either as catalysts or as membrane materials, the present approach focuses on their dual functionality under both catalytic and gas transport conditions. A series of imidazolium-based PILs, including homopolymers and block copolymers with polystyrene, were synthesized. The materials were characterized to determine their catalytic activity during the cycloaddition of CO2 to epichlorohydrin and to determine their gas transport properties using pure gases (N2, O2, CO2) and a simulated dry flue gas mixture; membrane morphology was studied by scanning electron microscopy. Block copolymers exhibited higher catalytic conversions (up to 82.7%) than homopolymers, with selectivities above 93%. Chloride-containing block copolymers gave the best combination of CO2 permeability (up to 7.5 Barrer) and CO2/N2 selectivity (18–22) under mixed-gas conditions. Iodide-containing analogs demonstrated higher selectivity (up to 30) but lower CO2 permeability. Morphological analysis confirmed the presence of dense, defect-free structures in materials with the chloride anion, while materials with the iodide anion showed increased free volume and microheterogeneity. These results indicate that by altering the polymer and anion architecture, PIL-based membranes can effectively combine catalytic activity with selective CO2 transport, providing a promising avenue for enhancing carbon capture and utilization processes.

The current scenario where the effects of global warming are more and more evident, has motivated different initiatives for facing this, such as the creation of global policies with a clear environmental guideline. Within these policies, the control of Greenhouse Gase (GHG) emissions has been defined as mandatory, but for carrying out this, a smart strategy is proposed. This is the application of a circular economy model, which seeks to minimize the generation of waste and maximize the efficient use of resources. From this point of view, CO2 recycling is an alternative to reduce emissions to the atmosphere, and we need to look for new business models which valorization this compound which now must be considered as a renewable carbon source. This has renewed the interest in known processes for the chemical transformation of CO2 but that have not been applied at industrial level because they do not offer evident profitability. For example, the methane produced in the Sabatier reaction has a great potential for application, but this depends on the existence of a sustainable supply of hydrogen and a greater efficiency during the process that allows maximizing energy efficiency and thermal control to maximize the methane yield. Regarding energy efficiency and thermal control of the process, the use of structured reactors is an appropriate strategy. The evolution of new technologies, such as 3D printing, and the consolidation of knowledge in the structing of catalysts has enabled the use of these reactors to develop a wide range of possibilities in the field. In this sense, the present review presents a brief description of the main policies that have motivated the transition to a circular economy model and within this, to CO2 recycling. This allows understanding, why efforts are being focused on the development of different reactions for CO2 valorization. Special attention to the case of the Sabatier reaction and in the application of structured reactors for such process is paid.

The need to limit anthropogenic climate change to 1.5–2 °C, as agreed in the Paris Agreement, requires a significant reduction of CO2 emissions resulting from the use of fossil carbon. However, based on current knowledge, carbon is expected to remain crucial in certain industrial sectors, e.g., the chemical industry. Consequently, it is essential to identify and utilize sustainable carbon sources in the future. In this context, various carbon sources were examined and classified in terms of their disruption of the Earth’s (fast) carbon cycle. Furthermore, the examined carbon sources were qualitatively analyzed with regard to their technical readiness level, their energy expenditure, and their current and future availability, as well as legal regulation within the European Union. As a result, only biogenic and mixed carbon from the ambient air can be considered genuinely sustainable within the Earth’s (fast) carbon cycle. Mixed carbon streams, e.g., from waste recycling, fall into a gray area. The same applies to certain process-related emissions that originally descend from fossil fuel energy. In terms of energy considerations, technical maturity, and exploitable potentials, prioritizing the utilization of biogenic carbon sources is advisable for the time being, especially for CO2 produced as a by-product originating from biogenic carbon carriers.

The mitigation of climate change impacts from the automotive sector is important for sustainable development, and for that purpose, synthetic liquid fuel vehicles (SLF-Vs) are being considered as a potential clean option alongside electric vehicles (EVs). However, the energy-intensive production of synthetic liquid fuels (SLFs) requires a thorough life-cycle analysis, as CO2 emissions vary significantly depending on the power sources and feedstock production technologies. This study evaluates the life-cycle CO2 emissions of SLF-Vs in Japan through long-term multiple scenarios up to 2050 and compares them with those of gasoline vehicles (GVs), hybrid electric vehicles (HEVs), and battery electric vehicles (BEVs). The results reveal that, in 2020, SLF-Vs’ life-cycle CO2 emissions were more than 2.9 times higher than those of GVs. By 2050, SLF-Vs’ emissions could only decrease to BEV-like levels if Japan achieves significant decarbonization of its power grid. Even if hydrogen is produced via water electrolysis in Australia, where renewable energy is abundant, and then imported, emissions remain high if Japan’s power grid remains insufficiently decarbonized. This highlights the critical importance of expanding domestic decarbonized power sources, particularly renewable energy, to reduce the life-cycle CO2 emissions of SLF-Vs in Japan.

The achievement of global climate targets outlined in the Paris Agreement represents a critical challenge in the coming decades. Certain industry sectors cannot completely avoid all emissions from their processes. In this context, the term unavoidable or Hard-to-abate emissions is used. Carbon Capture and Utilization (CCU) and Carbon Capture and Storage (CCS) are recognized as essential components for addressing those emissions to achieve Net Zero Emissions. To identify effective Carbon Management Strategies, balancing future CO2 sources and possible sinks for achieving long-term climate targets is essential. Especially in Austria hardly any comprehensive studies have been carried out. This work presents a comprehensive analysis of Austria’s CO2 point sources as well as their projected development until 2050 based on technology-based scenarios. Geological CO2 storage in Austria is primarily feasible in former hydrocarbon reservoirs and saline aquifers. Future demands for CO2 as CCU feedstock will arise in the chemical industry. By 2050, industry will emit approximately 4 Mt of unavoidable CO2 annually. These emissions must be stored in the long term and correspond to the minimum demand for CCS. Fugitive emissions from agriculture, for example, cannot be captured. Thus, they are not subject of CCU/S measures. Negative emissions are therefore necessary to achieve the climate targets. These negative emissions and the possible use of CO2 as feedstock are covered by biogenic CO2.

Utilization of coal in the current energy sector requires implementation of highly-efficient technologies to meet the dual targets of increased energy-efficiency and reduced carbon footprint. Efforts are being made to develop gasification systems with lower unit emissions of carbon dioxide and other contaminants, capable of handling various feedstocks and flexible in terms of products generated (synthesis gas, hydrogen, heat and electricity). The utilization of captured carbon dioxide and waste heat in industrial processes are considered to further contribute to the advancements in energy-efficient and low-emission technological solutions. This paper presents the experimental results on the incorporation of carbon dioxide into the valorization cycle as a reactant in coal gasification. Tests were performed on a laboratory scale moving bed gasifier using three system configurations with various simulated waste heat utilization scenarios. The temperature range covered 700, 800 and 900 °C and the gasification agents used were carbon dioxide, oxygen and the mixture of 30 vol.% carbon dioxide in oxygen. The combined effect of the process parameters applied on the efficiency of coal processing in terms of the gas yields, composition and calorific value was studied and the experimental data were explored using Principal Component Analysis.

Climate change is a constant global challenge. An approach to help mitigate climate change is carbon capture and utilization (CCU), in which captured CO2 is reused as raw material for consumer products. Because innovations like CCU are unfamiliar to the general public, their communication is critical for a successful rollout. To date, sustainability innovation research has largely neglected the empirical study of communication. The present study contributes to studying the information and communication needs of laypeople based on perceptions and acceptance patterns for CCU by focusing on acceptance profiles for CCU-based insulation boards. In an empirical two-step approach, a qualitative interview prestudy was followed by a quantitative questionnaire measurement (N = 643). Using k-means clustering, the respondents were divided into three acceptance groups: rejecters (15%), tentative accepters (51%), and strong accepters (34%). Analysis showed that regarding their demographics and personality traits, tentative accepters and rejecters were similar. All segments trusted science and health experts best, and only the rejecters distrusted some specific actors. Information on the product's risks and functional properties was most important for all acceptance groups. Based on the study's insights, both general and targeted managerial communication and policy guidelines were formulated.