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Chemical cleaning is one of the key technical means to control membrane fouling, restore membrane flux and ensure the stable operation of membrane systems. In the experiment, the six most representative chemical cleaning agents for ceramic membranes, such as sulfuric acid (H2SO4), sodium hydroxide (NaOH), sodium hypochlorite (NaClO), ethylenediaminetetraacetic acid disodium salt (EDTA-Na2), sodium dodecyl sulfate (SDS) and nonylphenol polyoxyethylene ether (OP-10), were used as research objects. The cleaning effect of the two-step combined cleaning of chemical cleaning agents on the fouled membrane was systematically investigated. Results showed that the order of the chemical cleaning agent had a significant effect on the cleaning effect. The best chemical cleaning program was determined to be NaClO first and then SDS: the fouled ceramic membrane was soaked in NaClO solution at 0.15% for 2.5 h and further soaked in SDS solution at five times its own critical micelle concentration for 2.5 h. The predicted long-term lifespan of the ceramic membranes was 4.91 years. Scanning electron microscopy–energy spectrum analysis showed that the surface roughness of the cleaned ceramic membrane was slightly higher than that of the new membrane. The contact angle was slightly lower than that of the new membrane.

To achieve an atomically clean surface of single-crystal aluminum nitride (AlN) substrates, this study systematically evaluated the effects of each step in ex situ wet chemical cleaning (solvent, piranha solution, HF, HCl) and in situ hydrogen annealing. X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) analyses revealed that while the combination of solvent and piranha solution exposed step morphology, its effectiveness in removing organic contaminants was limited. HF cleaning efficiently removed the oxide layer but introduced fluorine residues, whereas HCl cleaning left no chlorine residues but exhibited lower efficiency in oxide removal. In situ hydrogen annealing significantly reduced carbon and oxygen contamination, albeit accompanied by a transformation of the surface morphology from step to island mode. By modulating the low V/III ratio during low-temperature metal–organic chemical vapor deposition (MOCVD) growth, a controlled transition from 3D island growth to 2D step-flow growth was achieved. This research provides a basis for optimizing AlN substrate surface treatment, offering important insights for advancing nitride-based optoelectronic and power devices.

FO membrane fouling mitigation during the concentration of cows’ urine was investigated. In particular, the effects on the permeability recovery of cleaning methods such as membrane washing with deionized (DI) water, osmotic backwash, and chemical cleaning were studied. The characterization of foulants that accumulated on the membrane surface was found to be rich in sugars and proteins. The foulants were effectively removed by de-ionized water circulation (washing) and osmotic backwash. While osmotic back was more effective, it did not fully recover the permeability of the membrane. The foulants absorbed in the membrane pores were found to be mainly composed of sugars. Soaking the membrane in a solution of NaClO enabled the removal of foulants absorbed inside the membrane. It was revealed that soaking in 1% NaClO solution for 30 min achieved the best results (83% permeability recovery), while soaking for a longer time (10 h) using 0.2% NaClO resulted in counterproductive results.

The possibility of monitoring the chemical purity of the surface of optical components by an ellipsometric method is analyzed. The rationale for the possible measurement of the parameters of contaminating films on the optical surface of components by an ellipsometric method is examined. A simplified process for determining the thickness of a contaminating film with an extension of the feasibility of its measurement on optical components of different materials is illustrated. Ellipsometric studies of freshly polished and used metallic mirrors of copper and copper alloy (zirconium bronze), aluminum and its alloys AMG-6, AL-9, and AL-24 are carried out. Studies are also made of components composed of K-8 and K-108 (GOST 3514-94) optical glasses, the most typical materials used in manufacturing optical parts for laser technology in the visible and near IR, as well as of monocrystalline NaCl, BaF2, and sapphire (Al2O3). The parameters of contaminated films on surfaces of these components are measured. It is found that the ellipsometric technique is appropropriate for use in input (prior to physical-chemical cleaning) and output (following cleaning) monitoring of optical components for evaluating the contamination of an optical surface, as well as for quantitative analysis of the concentration of contaminants on the optical surface of components in the course of completing the techniques for their physical-chemical cleaning.

Membrane fouling is one of the main drawbacks encountered during the practical application of membrane separation processes. Cleaning of a membrane is important to reduce fouling and improve membrane performance. Accordingly, an effective cleaning method is currently of crucial importance for membrane separation processes in water treatment. To clean the fouling and improve the overall efficiency of membranes, deep research on the cleaning procedures is needed. So far, physical, chemical, or combination techniques have been used for membrane cleaning. In the current work, we critically reviewed the fouling mechanisms affecting factors of fouling such as the size of particle or solute; membrane microstructure; the interactions between membrane, solute, and solvent; and porosity of the membrane and also examined cleaning methods of microfiltration (MF) membranes such as physical cleaning and chemical cleaning. Herein, we mainly focused on the chemical cleaning process. Factors affecting the chemical cleaning performance, including cleaning time, the concentration of chemical cleaning, and temperature of the cleaning process, were discussed in detail. This review is carried out to enable a better understanding of the membrane cleaning process for an effective membrane separation process.

Pressure-driven membranes is a widely used separation technology in a range of industries, such as water purification, bioprocessing, food processing and chemical production 1 , 2 . Despite their numerous advantages, such as modular design and minimal footprint, inevitable membrane fouling is the key challenge in most practical applications 3 . Fouling limits membrane performance by reducing permeate flux or increasing pressure requirements, which results in higher energetic operation and maintenance costs 4 – 7 . Here we report a hydraulic-pressure-responsive membrane (PiezoMem) to transform pressure pulses into electroactive responses for in situ self-cleaning. A transient hydraulic pressure fluctuation across the membrane results in generation of current pulses and rapid voltage oscillations (peak, +5.0/−3.2 V) capable of foulant degradation and repulsion without the need for supplementary chemical cleaning agents, secondary waste disposal or further external stimuli 3 , 8 – 13 . PiezoMem showed broad-spectrum antifouling action towards a range of membrane foulants, including organic molecules, oil droplets, proteins, bacteria and inorganic colloids, through reactive oxygen species (ROS) production and dielectrophoretic repulsion. The PiezoMem membrane responsive to hydraulic pressure is introduced, showing the ability to convert pressure pulses into electroactive responses for in situ self-cleaning and enabling broad-spectrum antifouling action towards a range of membrane foulants.

The features of organic fouling have been revealed for highly basic anion exchange membranes during prolonged electrodialysis in solutions containing the aromatic amino acid tyrosine. With increased operation time when using MA-41 heterogeneous membranes in tyrosine solution, an increase in hydrophobicity and roughness characteristics of the material surface is detected. A reduction in tyrosine flux through the membrane occurs which is caused by its pores plugging and deposition of the amino acid at the membrane surface induced by tyrosine adsorption and local supersaturation of the solution in the membrane phase. The long-term contact of the anion exchange membrane with a solution of tyrosine leads to some structural changes in the anion exchange material. An accumulation of the studied amino acid with phenolic fragment and tyrosine oxidation products (DOPA, DOPA-quinone) is found and confirmed by IR- and UV-spectroscopy techniques. The organic fouling is accompanied by an increase in density and a decrease in moisture content of the studied membrane. A comparative analysis of the chemical and electrochemical cleaning results for fouled samples of the MA-41 membrane demonstrates a partial restoration of the material transport characteristics using electrochemical cleaning in the intensive current mode of electrodialysis. The best efficiency of regeneration is reached when carrying out chemical cleaning with a solution of hydrochloric acid, providing almost complete restoration of the membrane characteristics.

This experiment involved membrane pollution cycle experiments to identify the optimal pretreatment method, which was found to be raw water combined with PAC, effectively reducing membrane fouling. Following pretreatment, the first-stage recovery rate reaches 80%, the chemical cleaning cycle spans approximately 90 hours, and the conductivity of the concentrated water ranges between 35 ms/cm and 40 ms/cm.

Inorganic membrane science and technology is an attractive field of membrane separation technology, which has been dominated by polymer membranes. Recently, the inorganic membrane has been undergoing rapid development and innovation. Inorganic membranes have the advantage of resisting harsh chemical cleaning, high temperature and wear resistance, high chemical stability, long lifetime, and autoclavable. All of these outstanding properties made inorganic membranes good candidates to be used for water treatment and desalination applications. This paper is a state of the art review on the synthesis, development, and application of different inorganic membranes for water and wastewater treatment. The inorganic membranes reviewed in this paper include liquid membranes, dynamic membranes, various ceramic membranes, carbon based membranes, silica membranes, and zeolite membranes. A brief description of the different synthesis routes for the development of inorganic membranes for application in water industry is given and each synthesis rout is critically reviewed and compared. Thereafter, the recent studies on different application of inorganic membrane and their properties for water treatment and desalination in literature are critically summarized. It was reported that inorganic membranes despite their high synthesis cost, showed very promising results with high flux, full salt rejection, and very low or no fouling.

Membrane fouling is one of the most significant issues to overcome in membrane-based technologies as it causes a decrease in the membrane flux and increases operational costs. This study investigates the effect of common chemical cleaning agents on polymeric nanofibrous membranes (PNM) prepared by polyvinylidene fluoride (PVDF), polyacrylonitrile (PAN), and polyamide 6 (PA6) nanofibers. Common alkaline and acid membrane cleaners were selected as the chemical cleaning agents. Membrane surface morphology was investigated. The PAN PNM were selected and fouled by engine oil and then cleaned by the different chemical cleaning agents at various ratios. The SEM results indicated that the use of chemical agents had some effects on the surface of the nanofibrous membranes. Moreover, alkaline cleaning of the fouled membrane using the Triton X 100 surfactant showed a two to five times higher flux recovery than without using a surfactant. Among the tested chemical agents, the highest flux recovery rate was obtained by a binary solution of 5% sodium hydroxide + Triton for alkaline cleaning, and an individual solution of 1% citric acid for acidic cleaning. The results presented here provide one of the first investigations into the chemical cleaning of nanofiber membranes.