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22,805 result(s) for "Chemical evolution"
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Sciencia : mathematics, physics, chemistry, biology, and astronomy for all
\"From the structure of the cosmos to that of the human body, the discoveries of science over the past few hundred years have been remarkable. Sciencia spans the realms of mathematics, physics, chemistry, biology, and astronomy, offering an invaluable introduction to each. Curious about quarks, quasars, and the fantastic universe around you? Ever wanted to explore a mathematical proof? Need an introduction to biochemistry? Beautifully illustrated with engravings, woodcuts, and original drawings and diagrams, Sciencia will inspire inquisitive readers of all ages to appreciate the interconnected knowledge of the modern sciences\"--Page 4 of cover.
Four-hundred Very Metal-poor Stars Studied with LAMOST and Subaru. II. Elemental Abundances
We present homogeneous abundance analysis of over 20 elements for 385 very metal-poor (VMP) stars based on the LAMOST survey and follow-up observations with the Subaru Telescope. It is the largest high-resolution VMP sample (including 363 new objects) studied by a single program, and the first attempt to accurately determine evolutionary stages for such a large sample based on Gaia parallaxes. The sample covers a wide metallicity range from [Fe/H] ≲ −1.7 down to [Fe/H] ∼ −4.3, including over 110 objects with [Fe/H] ≤ −3.0. The expanded coverage in evolutionary status makes it possible to define the abundance trends respectively for giants and turnoff stars. The newly obtained abundance data confirm most abundance trends found by previous studies, but also provide useful updates and new samples of outliers. The Li plateau is seen in main-sequence turnoff stars with −2.5 < [Fe/H] < −1.7 in our sample, whereas the average Li abundance is clearly lower at lower metallicity. Mg, Si, and Ca are overabundant with respect to Fe, showing decreasing trend with increasing metallicity. Comparisons with chemical evolution models indicate that the overabundance of Ti, Sc, and Co are not well reproduced by current theoretical predictions. Correlations are seen between Sc and α-elements, while Zn shows a detectable correlation only with Ti but not with other α-elements. The fraction of carbon-enhanced stars ([C/Fe] > 0.7) is in the range of 20%–30% for turnoff stars depending on the treatment of objects for which C abundance is not determined, which is much higher than that in giants (∼8%). Twelve Mg-poor stars ([Mg/Fe] < 0.0) have been identified in a wide metallicity range from [Fe/H] ∼ −3.8 through −1.7. Twelve Eu-rich stars ([Eu/Fe] > 1.0) have been discovered in −3.4 < [Fe/H] < −2.0, enlarging the sample of r-process-enhanced stars with relatively high metallicity.
EMPRESS. XIII. Chemical Enrichment of Young Galaxies Near and Far at z ∼ 0 and 4–10: Fe/O, Ar/O, S/O, and N/O Measurements with a Comparison of Chemical Evolution Models
We present gas-phase elemental abundance ratios of thirteen local extremely metal-poor galaxies (EMPGs), including our new Keck/LRIS spectroscopy determinations together with 33 James Webb Space Telescope z ∼ 4–10 star-forming galaxies in the literature, and compare chemical evolution models. We develop chemical evolution models with the yields of core-collapse supernovae (CCSNe), Type Ia SNe, hypernovae (HNe), and pair-instability supernovae (PISNe), and compare the EMPGs and high-z galaxies in conjunction with dust depletion contributions. We find that high Fe/O values of EMPGs can (cannot) be explained by PISN metal enrichments (CCSN/HN enrichments even with the mixing-and-fallback mechanism enhancing iron abundance), while the observed Ar/O and S/O values are much smaller than the predictions of the PISN models. The abundance ratios of EMPGs can be explained by the combination of Type Ia SNe and CCSNe/HNe whose inner layers of argon and sulfur mostly fallback, which are comparable to the Sculptor stellar chemical abundance distribution, suggesting that early chemical enrichment has taken place in the EMPGs. Comparing our chemical evolution models with the star-forming galaxies at z ∼ 4–10, we find that the Ar/O and S/O ratios of the high-z galaxies are comparable to those of the CCSN/HN models, while the majority of high-z galaxies do not have constraints good enough to rule out contributions from PISNe. The high N/O ratio recently reported in GN-z11 cannot be explained even by rotating PISNe, but could be reproduced by the winds of rotating Wolf–Rayet stars that end up as a direct collapse.
Universal motifs and the diversity of autocatalytic systems
Autocatalysis is essential for the origin of life and chemical evolution. However, the lack of a unified framework so far prevents a systematic study of autocatalysis. Here, we derive, from basic principles, general stoichiometric conditions for catalysis and autocatalysis in chemical reaction networks. This allows for a classification of minimal autocatalytic motifs called cores. While all known autocatalytic systems indeed contain minimal motifs, the classification also reveals hitherto unidentified motifs. We further examine conditions for kinetic viability of such networks, which depends on the autocatalytic motifs they contain and is notably increased by internal catalytic cycles. Finally, we show how this framework extends the range of conceivable autocatalytic systems, by applying our stoichiometric and kinetic analysis to autocatalysis emerging from coupled compartments. The unified approach to autocatalysis presented in this work lays a foundation toward the building of a systems-level theory of chemical evolution.
Figuring Out Gas and Galaxies In Enzo (FOGGIE). VIII. Complex and Stochastic Metallicity Gradients at z > 2
Gas-phase metallicity gradients are a crucial element in understanding the chemical evolution of galaxies. We use the FOGGIE simulations to study the metallicity gradients (∇Z) of six Milky Way–like galaxies throughout their evolution. FOGGIE galaxies generally exhibit steep negative gradients for most of their history, with only a few short-lived instances reaching positive slopes that appear to arise mainly from interactions with other galaxies. FOGGIE concurs with other simulation results but disagrees with the robust observational finding that flat and positive gradients are common at z > 1. By tracking the metallicity gradient at a rapid cadence of simulation outputs (∼5–10 Myr), we find that theoretical gradients are highly stochastic: the FOGGIE galaxies spend ∼30%–50% of their time far away from a smoothed trajectory inferred from analytic models or other, less high-cadence simulations. This rapid variation makes instantaneous gradients from observations more difficult to interpret in terms of physical processes. Because of these geometric and stochastic complications, we explore nonparametric methods of quantifying the evolving metallicity distribution at z > 1. We investigate how efficiently nonparametric measures of the 2D metallicity distribution respond to metal production and mixing. Our results suggest that new methods of quantifying and interpreting gas-phase metallicity will be needed to relate trends in upcoming high-z James Webb Space Telescope observations with the underlying physics of gas accretion, expulsion, and recycling in early galaxies.
Can Neutron Star Mergers Alone Explain the r-process Enrichment of the Milky Way?
Comparing Galactic chemical evolution models to the observed elemental abundances in the Milky Way, we show that neutron star mergers can be a leading r-process site only if at low metallicities such mergers have very short delay times and significant ejecta masses that are facilitated by the masses of the compact objects. Namely, black hole–neutron star mergers, depending on the black hole spins, can play an important role in the early chemical enrichment of the Milky Way. We also show that none of the binary population synthesis models used in this Letter, i.e., COMPAS, StarTrack, Brussels, ComBinE, and BPASS, can currently reproduce the elemental abundance observations. The predictions are problematic not only for neutron star mergers, but also for Type Ia supernovae, which may point to shortcomings in binary evolution models.
Nucleobase synthesis in interstellar ices
The synthesis of nucleobases in natural environments, especially in interstellar molecular clouds, is the focus of a long-standing debate regarding prebiotic chemical evolution. Here we report the simultaneous detection of all three pyrimidine (cytosine, uracil and thymine) and three purine nucleobases (adenine, xanthine and hypoxanthine) in interstellar ice analogues composed of simple molecules including H 2 O, CO, NH 3 and CH 3 OH after exposure to ultraviolet photons followed by thermal processes, that is, in conditions that simulate the chemical processes accompanying star formation from molecular clouds. Photolysis of primitive gas molecules at 10 K might be one of the key steps in the production of nucleobases. The present results strongly suggest that the evolution from molecular clouds to stars and planets provides a suitable environment for nucleobase synthesis in space. The formation of nucleobases can take place in extraterrestrial environments. Here the authors show the simultaneous synthesis of three purine nucleobases and three pyrimidine from interstellar ice analogues that suggest the evolution from molecular clouds to stars and planets provide suitable environment for nucleobase synthesis in space.
Galactic Chemical Evolution Models Favor an Extended Type Ia Supernova Delay-time Distribution
Type Ia supernovae (SNe Ia) produce most of the Fe-peak elements in the Universe and therefore are a crucial ingredient in galactic chemical evolution models. SNe Ia do not explode immediately after star formation, and the delay-time distribution (DTD) has not been definitively determined by supernova surveys or theoretical models. Because the DTD also affects the relationship among age, [Fe/H], and [α/Fe] in chemical evolution models, comparison with observations of stars in the Milky Way is an important consistency check for any proposed DTD. We implement several popular forms of the DTD in combination with multiple star formation histories for the Milky Way in multizone chemical evolution models that include radial stellar migration. We compare our predicted interstellar medium abundance tracks, stellar abundance distributions, and stellar age distributions to the final data release of the Apache Point Observatory Galactic Evolution Experiment. We find that the DTD has the largest effect on the [α/Fe] distribution: a DTD with more prompt SNe Ia produces a stellar abundance distribution that is skewed toward a lower [α/Fe] ratio. While the DTD alone cannot explain the observed bimodality in the [α/Fe] distribution, in combination with an appropriate star formation history it affects the goodness of fit between the predicted and observed high-α sequence. Our model results favor an extended DTD with fewer prompt SNe Ia than the fiducial t −1 power law.
The Milky Way Radial Metallicity Gradient as an Equilibrium Phenomenon: Why Old Stars Are Metal Rich
Metallicities of both gas and stars decline toward large radii in spiral galaxies, a trend known as the radial metallicity gradient. We quantify the evolution of the metallicity gradient in the Milky Way as traced by APOGEE red giants with age estimates from machine learning algorithms. Stars up to ages of ∼9 Gyr follow a similar relation between metallicity and Galactocentric radius. This constancy challenges current models of Galactic chemical evolution, which typically predict lower metallicities for older stellar populations. Our results favor an equilibrium scenario, in which the gas-phase gradient reaches a nearly constant normalization early in the disk lifetime. Using a fiducial choice of parameters, we demonstrate that one possible origin of this behavior is an outflow that more readily ejects gas from the interstellar medium (ISM) with increasing Galactocentric radius. A direct effect of the outflow is that baryons do not remain in the ISM for long, which causes the ratio of star formation to accretion, Σ̇⋆/Σ̇in , to quickly become constant. This ratio is closely related to the local equilibrium metallicity, since its numerator and denominator set the rates of metal production by stars and hydrogen gained through accretion, respectively. Building in a merger event results in a perturbation that evolves back toward the equilibrium state on ∼Gyr timescales. Under the equilibrium scenario, the radial metallicity gradient is not a consequence of the inside-out growth of the disk but instead reflects a trend of declining Σ̇⋆/Σ̇in with increasing Galactocentric radius.
Chemical Evolution History of MaNGA Galaxies
We show the results of a study using the spectral synthesis technique study for the full MaNGA sample showing their chemical enrichment history (ChEH) as well as the evolution of the stellar mass–metallicity relation (MZR) over cosmic time. We find that the more massive galaxies became enriched first and the lower-mass galaxies did so later, producing a change in the MZR that becomes shallower in time. Separating the sample into morphology and star-forming status bins, some particularly interesting results appear: The mass dependence of the MZR becomes less relevant for later morphological types, to the extent that it inverts for Sd/Irr galaxies, suggesting that morphology is at least as important a factor as mass in the chemical evolution. The MZR for the full sample shows a flattening at the high-mass end and another in the low-mass range, but the former only appears for retired galaxies, while the latter only appears for star-forming galaxies. We also find that the average metallicity gradient is currently negative for all mass bins, but for low-mass galaxies, it was inverted at some point in the past, before which all galaxies had a positive gradient. We also compare how diverse the ChEHs are in the different bins we considered, as well as what primarily drives the diversity: By how much galaxies become enriched, or how quickly they do so.