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"Cold gas"
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Cold War energy : a transnational history of Soviet oil and gas
\"This book examines the role of Soviet energy during the Cold War. Based on hitherto little known documents from Western and Eastern European archives, it combines the story of Soviet oil and gas with general Cold War history. This volume breaks new ground by framing Soviet energy in a multi-national context, taking into account not only the view from Moscow, but also the perspectives of communist Eastern Europe, the US, NATO, as well as several Western European countries--namely Italy, France, and West Germany. This book challenges some of the long-standing assumptions of East-West bloc relations, as well as shedding new light on relations within the blocs regarding the issue of energy. By bringing together a range of junior and senior historians and specialists from Europe, Russia and the US, this book represents a pioneering endeavour to approach the role of Soviet energy during the Cold War in transnational perspective.\"-- Provided by publisher.
Quench Dynamics of a Fermi Gas with Strong Nonlocal Interactions
by
Spar, Benjamin M.
,
Belyansky, Ron
,
Guardado-Sanchez, Elmer
in
Charge density waves
,
Cold gas
,
cold gases in optical lattices
2021
We induce strong nonlocal interactions in a 2D Fermi gas in an optical lattice using Rydberg dressing. The system is approximately described by a
model on a square lattice where the fermions experience isotropic nearest-neighbor interactions and are free to hop only along one direction. We measure the interactions using many-body Ramsey interferometry and study the lifetime of the gas in the presence of tunneling, finding that tunneling does not reduce the lifetime. To probe the interplay of nonlocal interactions with tunneling, we investigate the short-time-relaxation dynamics of charge-density waves in the gas. We find that strong nearest-neighbor interactions slow down the relaxation. Our work opens the door for quantum simulations of systems with strong nonlocal interactions such as extended Fermi-Hubbard models.
Journal Article
The Potential of High-Velocity Air-Fuel Spraying (HVAF) to Manufacture Bond Coats for Thermal Barrier Coating Systems
by
Rauwald, Karl-Heinz
,
Sohn, Yoo Jung
,
Vaßen, Robert
in
Analytical Chemistry
,
Characterization and Evaluation of Materials
,
Chemistry and Materials Science
2024
Driven by the search for an optimum combination of particle velocity and process temperature to achieve dense hard metal coatings at high deposition efficiencies and powder feed rates, the high-velocity air-fuel spraying process (HVAF) was developed. In terms of achievable particle velocities and temperatures, this process can be classified between high-velocity oxy-fuel spraying (HVOF) and cold gas spraying (CGS). The particular advantages of HVAF regarding moderate process temperatures, high particle velocities as well as high productivity and efficiency suggest that the application of HVAF should be also investigated for the manufacture of MCrAlY (M = Co and/or Ni) bond coats (BCs) in thermal barrier coating (TBC) systems. In this work, corresponding HVAF spray parameters were developed based on detailed process analyses. Different diagnostics were carried out to characterize the working gas jet and the particles in flight. The coatings were investigated with respect to their microstructure, surface roughness and oxygen content. The spray process was assessed for its effectiveness. Process diagnostics as well as calculations of the gas flow in the jet and the particle acceleration and heating were applied to explain the governing mechanisms on the coating characteristics. The results show that HVAF is a promising alternative manufacturing process.
Journal Article
Metal Knitting: A New Strategy for Cold Gas Spray Additive Manufacturing
by
Vaz, Rodolpho F.
,
Ocaña, Unai
,
Canales, Horacio
in
3D printing
,
Additive manufacturing
,
Aluminum
2022
Cold Spray Additive Manufacturing (CSAM) is an emergent technique to produce parts by the additive method, and, like other technologies, it has pros and cons. Some advantages are using oxygen-sensitive materials to make parts, such as Ti alloys, with fast production due to the high deposition rate, and lower harmful residual stress levels. However, the limitation in the range of the parts’ geometries is a huge CSAM con. This work presents a new conceptual strategy for CSAM spraying. The controlled manipulation of the robot arm combined with the proper spraying parameters aims to optimize the deposition efficiency and the adhesion of particles on the part sidewalls, resulting in geometries from thin straight walls, less than 5 mm thick, up to large bulks. This new strategy, Metal Knitting, is presented regarding its fundamentals and by comparing the parts’ geometries produced by Metal Knitting with the traditional strategy. The Metal Knitting described here made parts with vertical sidewalls, in contrast to the 40 degrees of inclination obtained by the traditional strategy. Their mechanical properties, microstructures, hardness, and porosity are also compared for Cu, Ti, Ti6Al4V, 316L stainless steel, and Al.
Journal Article
Characteristics of hydrogen energy yield in steam gasification of coffee residues
by
Liang, Dan-Kai
,
Prabu, Samikannu
,
Chiang, Kung-Yuh
in
Aquatic Pollution
,
Atmospheric Protection/Air Quality Control/Air Pollution
,
Calorific value
2024
Coffee residues (CRs) were gasified using a laboratory-scale fluidized bed gasifier with an air/steam mixture as the carrier gas. The gasification was conducted at an equivalence ratio (ER) of 0.3, and different operation temperatures (700, 800, and 900 °C) and steam-to-biomass (S/B) ratios (0, 0.75, and 1.5) were applied. Increasing temperature without steam boosted H
2
and CO concentrations in producer gas, raising lower heating value (LHV) and cold gas efficiency (CGE) through endothermic reactions like Boudouard, tar cracking, and water-gas formation. At 900 °C, gas had LHV of 3.76 MJ/Nm
3
and CGE of 22.47%. It was elevating temperature from 700 to 900 °C and S/B ratio to 1.5 raised H
2
and CO concentrations from 2.04 to 8.60% and from 9.56 to 11.8%, respectively. This also increased LHV from 2.23 to 3.89 MJ/Nm
3
and CGE from 11.28 to 25.08%. The steam gasification reaction was found to increase the H
2
concentration and was thus considered effective in converting CRs to syngas and increasing energy production. Overall, the study successfully demonstrated the feasibility of steam gasification as a means of converting coffee residues to syngas and increasing energy production. The results also highlighted the importance of operating temperature and S/B ratio in improving the gasification process.
Journal Article
Wear Mechanisms of Cold-Sprayed Stellite-6 During Reciprocated Dry Sliding Under Different Sliding Speeds
by
Maletta, C.
,
Magarò, P.
,
Furgiuele, F.
in
Abrasive wear
,
Analytical Chemistry
,
Characterization and Evaluation of Materials
2023
Cobalt–chromium alloys are often employed in those environments that require reliable wear and friction properties. Cold Gas Dynamic Spray offers the opportunity to obtain good quality deposits of Stellite-6, that can be successfully used in harsh environments, where good surface performance, in terms of wear resistance, is required. It is also well-known that Stellite-6 is subjected to several physical changes at the interface during dry sliding, that are often related to the loading conditions. As a consequence, wear behavior of this alloy can undergo some variations that linear models are not able to capture, since micro-structural modifications occur during operation. To better understand the wear mechanisms of cold-sprayed Stellite-6 coatings together with the occurring physical phenomena, a systematic experimental study was performed, in fact, to date, no such in-depth tribological studies have been performed. Tests were conducted under combinations of two sliding speeds (0.1 and 0.5 m/s) and four contact pressure in the range of 2-5 MPa. In low-speed tests, abrasive wear is evident, where detachment and pull-out phenomena mainly affect the worn surface of coatings. On the other hand, subsurface cracking was observed in high-speed tests, as well as evidence of plastic deformation on the wear surface. These results suggest that observed wear mechanisms are more likely a consequence of adhesive wear. Unique to this study, the cross-sectional nano-indentation tests showed how the stiffness of the coating, near to wear interface, increases significantly in the case of the lowest value of sliding speed (i.e.,
v
= 0.1 m/s), whereas tends to decrease at high speeds, i.e.,
v
= 0.5 m/s, as a consequence of the formation of subsurface cracks into the coating.
Journal Article
Resistance spot welding of dissimilar material joints with a cold-gas-sprayed inlayer
by
Ossenbrink, Ralf
,
Hagen, Christian
,
Klinkenberg, Franz-Josef
in
Aluminum
,
Cold gas
,
Cold welding
2023
In this publication, cold gas spraying (CGS) is investigated as an enabler for aluminum-steel joints. Using a powder-based coating process to adhere a steel layer to an aluminum substrate allows a steel component to be welded to the deposited layer by resistance spot welding. This method permits the metallurgical connection between similar materials to be separated, while mechanical bonding ensures the connection at the dissimilar aluminum-to-inlayer interface. A modification of the porous CGS layer, as well as the creation of the remelted zone in the aluminum, can be observed during the resistance spot welding process. Electron backscatter diffraction (EBSD) analyses show that the severely prestressed particles in the CGS coating recrystallize, which coincides with a decrease in defect density and hardness in the heat-affected zone. Microscopy of the aluminum substrate shows the creation of metallurgical pores as well as the expansion of pores attributed to the casting process. The rise in remelted aluminum hardness and decrease in the heat-affected zone of the CGS layer indicate the formation of a metallurgical notch.
Journal Article
Establishment and Analysis of a General Mass Model for Solenoid Valves Used in Space Propulsion Systems
2026
The solenoid valve component is the core part affecting the total mass of space propulsion system, and the accuracy of the solenoid valve mass model directly impacts the accuracy of the system mass estimation and optimization design. This study focuses on the solenoid valves used in gas path control for cold gas propulsion systems. The relationship between the gas flow rate and volume flow rate of the solenoid valve is derived. By analyzing the parameters affecting the mass of the solenoid valves, a general calculation mass model of the gas solenoid valve used in cold gas propulsion is proposed based on strength theory. Combining with the existing general calculation mass model for liquid solenoid valves and collecting mass data of 16 gas solenoid valves and 33 liquid solenoid valves used in space propulsion system, the mass calculation formulas of the gas and liquid solenoid valves are obtained by employing several mathematical fitting methods, including quadratic polynomial surface, Manski formula, bivariate power function, and pressure-corrected polynomial. The accuracy of different mass model formulas is compared to assess their performance in calculating the solenoid valve mass. The results show that the quadratic surface formula can better reflect the relationship between the mass of the gas solenoid valves and the valve parameters within the medium volume flow range of 1 × 10−9 to 3.9 × 10−3 m3/s and the proof pressure range of 0.4 to 49.74 MPa. For the calculation of liquid solenoid valve mass, the accuracy of quadratic polynomial surface fitting, bivariate power function equation, and univariate polynomial equation with pressure correction is comparable within the liquid volume flow range of 1.8 × 10−7 to 1.28 × 10−4 m3/s and the inlet pressure range of 0.99 to 4.24 MPa; the appropriate calculation formula can be selected based on the pressure conditions in the liquid solenoid valve chamber in practical applications. Sensitivity analysis shows a consistent trend for gas and liquid solenoid valves: proof pressure (gas valves) or inlet working pressure (liquid valves) are the dominant factors affecting valve mass, while volume flow rate has a moderate impact. The proposed solenoid valve mass model in this study can be used to calculate the mass of gas solenoid valves for space cold gas propulsion systems and liquid solenoid valves for liquid rocket thrusters with thrust below 1000 N, providing an important reference for the mass modeling and optimization design of the space propulsion systems.
Journal Article
Tungsten-Steel Functionally Graded Coatings for Nuclear Fusion Applications Manufactured by Cold Gas Spraying
by
Rauwald, Karl-Heinz
,
Mauer, Georg
,
Sohn, Yoo Jung
in
Analytical Chemistry
,
Characterization and Evaluation of Materials
,
Chemistry and Materials Science
2023
In nuclear fusion reactors, the first wall is the name given to the surface which is in direct contact with the plasma. A part of it is the divertor which is a device that removes fusion products from the plasma and impurities that have entered into it from the vessel lining. It is covered with water cooled tiles which have to withstand high temperatures and high heat fluxes. Moreover, resistance to neutron bombardment, low tritium absorption and low hydrogen permeation are additional demands. One materials concept under research is the application of a Reduced Activation Ferritic Martensitic Steel (RAFM) as a structural material with a tungsten protective coating. Since there is a considerable thermal mismatch between, a functional-graded materials concept was proposed.
As the formation of undesired intermetallic Fe-W phases as well as oxidation should be avoided, cold gas spraying was chosen as manufacturing process. Two powder blends of EUROFER97 RAFM steel and a fine tungsten powder cut on the one hand and a coarser one on the other hand were tested in different ratios. The coatings were characterized with respect to their porosity and surface structure. Furthermore, the deposition efficiencies for steel and tungsten were determined each. It turned out that the deposition process is a complex mixed situation of bonding and erosion mechanisms as the deposition windows of these very different materials obviously diverge. Thus, a lower working gas temperature and pressure was advantageous in some cases. Unexpectedly, the coarser tungsten powder in general enabled to achieve better results.
Journal Article
Influence of Different Copper Feedstock Powders on the Microstructure and Corrosion Resistance of Coatings Prepared by Cold Gas Spray
by
da Silva, F. S.
,
Benedetti, A. V.
,
Dosta, S.
in
Abrasive wear
,
Analytical Chemistry
,
Atomizing
2024
The purpose of this study is to investigate the effect of copper powder oxidation on the deposition efficiency, microstructure, wear and corrosion resistance. The gas-atomized copper powders in the as-received (Cu-Safina and Cu-FST) and oxidized states (Cu-treat, oxidized in air, 25 °C for 5 months; Cu-treat1, oxidized at 100 °C for 1 h; and Cu-treat2, oxidized at 200 °C for 1 h) were used to prepare the coatings by cold gas spray (CGS). XPS analysis detected Cu
2
O and CuO for all feedstock powders, increasing for oxidized ones. The deposition efficiency and thickness of the coatings followed the order: Cu-Safina > Cu-FST > Cu-treat1 > Cu-treat > Cu-treat2. For oxidized coatings, SEM images showed more defected microstructure, increase in pores, and microcracks. Cu-FST coating showed a sliding wear rate of (0.13 ± 0.01) × 10
-4
mm
3
N
−1
m
−1
), and abrasive wear rate of (3.2 ± 0.2) × 10
−4
mm
3
N
−1
m
−1
. Gas-atomized powder coatings showed a better corrosion resistance performance. The electrolyte did not reach the substrate/coating interface for
t
≥ 700 h and the coatings resisted for 2000 h in salt fog tests. However, oxidized coatings showed low corrosion resistance due to the presence of cracks and defects, and the coating/substrate was severely damaged after ≈100 h in 3.5wt.%NaCl solution.
Journal Article