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Protection of metals in neutral media with pH 5.0–9.0 (in humid atmospheres and various aqueous solutions) can be achieved by formation of thin coatings (up to several tens of nm) on their surfaces due to adsorption and more complex chemical interactions of organic corrosion inhibitors (OCIs) with the metal to be protected. The review contains three sections. The first section deals with coatings formed in aqueous solutions, while the second one, with those formed in organic and water-organic solvents. Here we consider metal protection by coatings mainly formed by the best-known classes of OCI (carboxylates, organophosphates and phosphonates) and estimation of its efficiency. The third section discusses the peculiarities of protection of metals in the vapor-gas phase, i.e., by volatile OCIs, and a relatively new type of metal protection against atmospheric corrosion by the so-called chamber inhibitors. OCIs with relatively low volatility under normal conditions can be used as chamber OCIs. To obtain a protective coating on the surfaces of metal items, they are placed in a chamber inside which an increased concentration of vapors of a chamber OCI is maintained by increasing the temperature. This review mainly focuses on the protection of iron, steels, copper and zinc.

The pipeline system in the oil and gas industry is the heart for transportation of crude and refined petroleum. Nevertheless, continuous exposure of the pipeline surfaces to impurities and sources of corrosion such as sulfur and chromate is totally unavoidable. Vast employment of commercial corrosion inhibitors to minimize the corrosion is being restrained due to toxicity towards the environment. The emergence of “green” chemistry has led to the use of plant extracts and fruit wastes which have proven to be good corrosion inhibitors. This paper aims to provide insight into carrying out further investigation under this research theme for accurate inhibition efficiency measurement.

Corrosion is a major challenge in various industries and can cause significant damage to metal structures. Organic corrosion inhibitors are compounds that are used to reduce or prevent corrosion by forming a protective film on metal surfaces. The present review article focuses on natural and synthetic organic corrosion inhibitors and their classifications, active functional groups, and efficiency estimations. Furthermore, previous studies on the use of natural and synthetic organic inhibitors are discussed, along with adsorption isotherms and mechanisms of organic corrosion inhibitors. The kinetics of corrosion modeling are also discussed, providing insights into the effectiveness of organic inhibitors at reducing corrosion. This review aims to provide a comprehensive overview of the current knowledge on organic corrosion inhibitors, with the aim of promoting their wider use in corrosion protection.

Corrosion is the process of damaging materials, and corrosion of metallic materials frequently results in serious consequences. The addition of corrosion inhibitors is the most effective means of preventing metal corrosion. Until now, researchers have made unremitting efforts in the research of high-efficiency green corrosion inhibitors, and research on biomass corrosion inhibitors in a class of environmentally friendly corrosion inhibitors is currently quite promising. This work presents the classification of green biomass corrosion inhibitors in detail, including plant-based corrosion inhibitors, amino acid corrosion inhibitors, and biosurfactant corrosion inhibitors, based on the advantages of easy preparation, environmental friendliness, high corrosion inhibition efficiency, and a wide application range of biomass corrosion inhibitors. This work also introduces the preparation methods of biomass corrosion inhibitors, including hydrolysis, enzymatic digestion, the heating reflux method, and microwave extraction. In addition, the corrosion inhibition mechanisms of green biomass corrosion inhibitors, including physical adsorption, chemisorption, and film-forming adsorption, and evaluation methods of biomass corrosion inhibitors are also explicitly described. This study provides valuable insights into the development of green corrosion inhibitors.

Using traditional weight-loss tests, as well as different electrochemical techniques (potentiodynamic polarization and electrochemical impedance spectroscopy), we investigated the corrosion-inhibition performance of 2,2′-(1,4-phenylenebis(methanylylidene)) bis(N-(3-methoxyphenyl) hydrazinecarbothioamide) (PMBMH) as an inhibitor for mild steel in a 1 M hydrochloric acid solution. The maximum protection efficacy of 0.0005 M of PMBMH was 95%. Due to the creation of a protective adsorption layer instead of the adsorbed H2O molecules and acidic chloride ions, the existence of the investigated inhibitor reduced the corrosion rate and increased the inhibitory efficacy. The inhibition efficiency increased as the inhibitor concentration increased, but it decreased as the temperature increased. The PMBMH adsorption mode followed the Langmuir adsorption isotherm, with high adsorption-inhibition activity. Furthermore, the value of the ∆Gadso  indicated that PMBMH contributed to the physical and chemical adsorption onto the mild-steel surface. Moreover, density functional theory (DFT) helped in the calculation of the quantum chemical parameters for finding the correlation between the inhibition activity and the molecular structure. The experimental and theoretical findings in this investigation are in good agreement.

Corrosion has been a predominate problem for industries ranging from oil and gas to automobile. Various methods have been utilized to combat this phenomenon, some methods have causes great environmental effect that are harmful to humans. This has necessitated the use of green corrosion inhibitors. This review paper delves into the subject matter and reports the inhibition efficiency of green corrosion inhibitors that have been used for combating corrosion, because of their eco-friendly nature.

Corrosion is an inevitable and persistent issue that affects various metallic infrastructures, leading to significant economic losses and safety concerns, particularly in areas near or in contact with saline solutions such as seawater. Green corrosion inhibitors are compounds derived from natural sources that are biodegradable in various environments, offering a promising alternative to their conventional counterparts. Despite their potential, green corrosion inhibitors still face several limitations and challenges when exposed to NaCl environments. This comprehensive review delves into these limitations and associated challenges, shedding light on the progress made in addressing these issues and potential future developments as tools in corrosion management. Explicitly the following aspects are covered: (1) attributes of corrosion inhibitors, (2) general corrosion mechanism, (3) mechanism of corrosion inhibition in NaCl, (4) typical electrochemical and surface characterization techniques, (5) theoretical simulations by Density Functional Theory, and (6) corrosion testing standards and general guidelines for corrosion inhibitor selection. This review is expected to advance the knowledge of green corrosion inhibitors and promote further research and applications.

In this work, a tetrafunctional epoxy resin entitled 2,3,4,5-tetraglycidyloxy pentanal (TGP) was tested and investigated as a potential corrosion inhibitor for mild steel (MS) in 0.5 M H2SO4 solution. The corrosion inhibition process for mild steel was employed alongside various techniques, such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), temperature effect (TE), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and theoretical approaches (DFT, MC, RDF and MD). Further, the corrosion efficacies obtained at the optimum concentration (10−3 M of the TGP) were 85.5% (EIS) and 88.6% (PDP), respectively. The PDP results indicated that the TGP tetrafunctional epoxy resin acted the same as an anodic inhibitor type in 0.5 M H2SO4 solution. SEM and EDS analyses found that the protective layer formed on the MS electrode surface in the presence of TGP could prevent the attack of the sulfur ions. The DFT calculation provided more information regarding the reactivity, geometric properties and the active centers of the corrosion inhibitory efficiency of the tested epoxy resin. RDF, MC and MD simulations showed that the investigated inhibitory resin have a maximum inhibition efficiency in 0.5 M H2SO4 solution.

Over the past century, a substantial amount of research focused on developing corrosion inhibitors, with a special focus on green “plant-based” corrosion inhibitors. Among the various types of inhibitors, polyphenols emerged as a promising candidate due to their advantageous characteristics, which include being inexpensive, biodegradable, renewable, and, most importantly, safe for both the environment and humans. Their performance as sustainable corrosion inhibitors have encouraged many electrochemical experiments as well as theoretical, mechanistic, and computational studies, with many papers reporting inhibition efficiencies of over 85%. In this review, the majority of literature contributions on the inhibition of various types of polyphenols, their natural extraction techniques, and their applications as “greener” corrosion inhibitors for metals are thoroughly described and discussed with a focus on their preparation, inhibition mechanism, and performance. Based on the reviewed literature, it can be concluded that polyphenols have a very promising potential to be used as both green and powerful corrosion inhibitors; therefore, further investigations, experimental or computational, are still required to realize higher inhibition efficiencies reaching up to ≈ 100%.

This study focuses on the synthesis, theoretical analysis, and application of the corrosion inhibitor known as benzimidazolone, specifically 1-(cyclohex-1-enyl)-1,3-dihydro-2H-benzimiazol-2-one (CHBI). The structure of CHBI was determined by X-ray diffraction (XRD). The inhibitory properties of CHBI were investigated in a 3.5 wt.% NaCl solution on pure copper using various electrochemical techniques such as potentiodynamic polarization curves (PDPs) and electrochemical impedance spectroscopy (EIS), as well as scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), UV-visible spectroscopy, and theoretical calculations. The obtained results indicate that CHBI is an excellent inhibitor, exhibiting remarkable effectiveness with an inhibition rate of 86.49% at 10−3 M. To further confirm the extent of adsorption of the inhibitory molecule on the copper surface, density functional theory (DFT) and Monte Carlo (MC) simulation studies were conducted. The results of this study demonstrate the synthesis and characterization of CHBI as a corrosion inhibitor. The experimental and theoretical analyses provide valuable insights into the inhibitory performance of CHBI, indicating its strong adsorption on the copper surface.