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Geopolymers are created by mixing a source of aluminosilicates, which can be natural or by-products from other industries, with an alkaline solution. These materials based on by-products from other industries have proven to be a less polluting alternative for concrete production than ordinary Portland cement (OPC). Geopolymers offer many advantages over OPC, such as excellent mechanical strength, increased durability, thermal resistance, and excellent stability in acidic and alkaline environments. Within these properties, mechanical strength, more specifically compressive strength, is the most important property for analyzing geopolymers as a construction material. For this reason, this study compiled information on the different variables that affect the compressive strength of geopolymers, such as Si/Al ratio, curing temperature and time, type and concentration of alkaline activator, water content, and the effect of impurities. From the information collected, it can be mentioned that geopolymers with Si/Al ratios between 1.5 and 2.0 obtained the highest compressive strengths for the different cases. On the other hand, high moderate temperatures (between 80 and 90 °C) induced higher compressive strengths in geopolymers, because the temperature favors the geopolymerization process. Moreover, longer curing times helped to obtain higher compressive strengths for all the cases analyzed. Furthermore, it was found that the most common practice is the use of sodium hydroxide combined with sodium silicate to obtain geopolymers with good mechanical strength, where the optimum SS/NaOH ratio depends on the source of aluminosilicates to be used. Generally speaking, it was observed that higher water contents lead to a decrease in compressive strength. The presence of calcium was found to be favorable in controlled proportions as it increases the compressive strength of geopolymers, on the other hand, impurities such as heavy metals have a negative effect on the compressive strength of geopolymers.

In situ parameters, for example curing stress, drainage conditions as well as backfilling rate, have substantial effects on the geotechnical properties and stability of cemented paste backfill (CPB), which is an evolutive cemented soil mainly used for underground mine support. An in-depth knowledge of the shear characteristics of the interface between CPB and rock is important for the cost-effective and safe design of underground CPB structures. But, no studies to date have investigated the effects of curing stress, drainage conditions and backfilling rates on the shear characteristics of the interface between CPB and surrounding rock mass. Hence, an experimental study is performed to assess the influence of curing stress (0 kPa, 50 kPa, and 150 kPa), drainage conditions (drained and undrained) and backfilling rate (20 kPa/3 h, 30 kPa/3 h, and 40 kPa/3 h) of CPB on the shear characteristics (behavior, properties) of the interface between CPB and rock. It is found that higher curing stress and backfilling rate contribute to the shear strength development of the studied interface because of the increased effective stress and matrix suction at the interface. Moreover, in comparison to undrained condition, the drained condition contributes to the shear strength acquisition at the interface. The findings provide technical information for improving the stability analysis of backfill structures and are practically important for opening barricades and designing filling sequences.

This study investigated the influence of different curing conditions on the compressive strength (CS) of the different alkali activated concrete (AAC) specimens at the ages of 2, 28, and 90 days for the structural utilization and standardization process of AAC instead of OPC concrete. For this aim, 100% slag (S100), 75% slag and 25% fly ash (S75FA25), and 50% slag and 50% fly ash based (S50FA50) AAC specimens were produced. Based on the oven-curing (O), water-curing (W), and ambient-curing (A) methods, the influence of 2O for 2 days, 26A2O, 2O26A, 28A, 28W, 26W2O, and 2O26W for 28 days, and 88A2O, 2O88A, 90A, 88W2O, 2O88W, 90W for 90 days on the CS of the AAC were examined in details. In addition, the influence of delayed oven-curing conditions on CS development was also investigated. The results indicated that curing conditions significantly affected on the CS and the water-curing condition could provide a better CS for those of AAC at 90 days. Although, the oven-curing enhanced CS of the S100 specimens at initial ages (first oven-curing applied), delayed oven-curing (oven-curing applied later) was found significant for S75FA25 and S50FA50 specimens. The delayed oven-curing affected more on the CS of the AAC when fly ash content increased. The most of AAC specimens with oven-curing had significantly enhanced the CS at 28 days, but S50FA50 at the age of 90 days decreased. Different curing regimes were proposed for the superior compressive strength values for each AAC specimens at the ages of 28 and 90 days.

Understanding the flow process of cemented tailings backfill (CTB) is important for successful pumping into underground stopes. This study examines the effects of solid content (SC), cement/tailings (c/t) ratio, and curing time (CT) on rheological and mechanical properties of CTB mixes. The slurry concentration of the mixes was 65, 67, and 69 wt. %, with c/t ratios ranging from 1:4 to 1:20. Unconfined compressive strength (UCS) tests were performed on hardened CTB mixes after curing 3, 7, and 28 days. The rheological properties of CTB slurries are mainly related to SC. The yield stress and viscosity of fresh mixes increase with increasing SC, but the pipeline resistance loss (PRL) also increases with increasing SC. According to the analysis of variance, the SC and flow rate are the most significant parameters which greatly affect the PRL performance. The c/t and CT parameters are the most significant parameters for affecting the shrinkage rate. The findings offer a reference for theoretical optimization for mine filling systems of similar type.

Soil stabilization using additives is considered as one of the sustainable alternative techniques to deal with acute material shortages. Critically reviewing the contemporary works on soil stabilization would help practitioners and researchers to comprehend the merits and demerits of each stabilization method, influential parameters, and associated constraints. Furthermore, the critical analysis might aid the authorities to develop standard protocols about the use of various additives for soil stabilization, which would persuade the industry personnel to adopt sustainable practices. This paper presents a methodical review of the present soil stabilization methods under five key areas namely, underlying chemistry, the influential factors, performance indicators, economic and environmental aspects, and industrial perspectives. Findings of the review indicate that cement-based stabilizers perform well irrespective of soil type and curing conditions, on the contrary, lime-based stabilizers require appropriate temperature and pH for strength development. The degree of stabilization depends mainly on soil type, compaction level, and curing type and condition. Most of the soils treated with different additives exhibited a reduction in plasticity index, and maximum dry density against stabilizer dosage irrespective of soil type. The typical values of unconfined compressive strength and California bearing ratio of inorganic and organic soils except for peat, treated with a 5% dosage of all common types of stabilizers, fall in between 700 and 1,500 kPa and 30–60%, respectively. Cement and cementitious blends exhibited better cost-to-strength, energy-to-strength, and CO2 emission-to-strength ratios for soils with low plasticity whereas lime-blended stabilizers seemed effective for high-plastic soils.

PurposeThis research presents experimental results of dredged lakebed sediment-stabilised with ordinary Portland cement (OPC) and fly ash (FA) for use as pavement materials in road infrastructure. The work also proposed empirical correlations for the strength and stiffness parameters of chemically stabilised dredged sediments intended for pavement engineering.Materials and methodsThe dredged sediment was collected from the drop-off area around Phayao Lake in Thailand. The sediment’s optimal moisture content was determined by a Proctor compaction test. The OPC and FA content ranged from 3 to 10% and 5 to 20% per dry weight of sediment. The shear strength of treated sediments at different curing time was measured using the unconfined compression (UC) test.Results and discussionThe optimum FA content proved to be most effective in generating the highest material strengths and stiffnesses from the stabilised sediments, regardless of OPC contents and curing duration. A suitable replacement ratio of cement with fly ash was 15%. The results were compared with data on other types of chemically stabilised sediments available in literature. Correlations between engineering properties and design parameters such as UCS, E50, εf, and eot can be suggested based on the comprehensive experimental results.ConclusionsUsing OPC and FA as admixes together provided the greatest improvement in the strength characteristic of dredged sediment. In addition, the study presented an empirical correlation between the strength and stiffness of adding fly ash on cement-stabilised lakebed sediment for using in geotechnical and pavement works.

Coal char-cement grout has emerged as an alternative material that counters the limitations of traditional cement grout. Recent studies underscore its efficacy in enhancing cement grout properties across diverse temperatures. However, there are no relevant studies comprehensively investigating the effects of curing temperature and environmental conditions on the properties of coal char-cement grout. This research systematically assesses coal char-cement grout performance, considering a spectrum of curing temperatures (5 °C, room temperature, and 35 °C) and environmental conditions (sealed, soaked, and mud). The evaluation centers on comprehensive macroscopic and material characterization tests. A declining trend in bulk density is evident, primarily attributed to increased porosity resulting from char addition. Nevertheless, minimal bulk density variations (1–3%) persist in the grouts, irrespective of curing conditions and duration. The microstructural analysis highlights the prevalence of empty pores in char particles, contributing to a reduction in the strength of coal char-grout samples across all curing conditions. This study sheds light on the intricate interplay between coal char-cement grouts, curing parameters, and resulting material characteristics, offering valuable insights for improving construction practices.

The efficiency of typical chemical and mechanical soil stabilization techniques in mitigating the swelling problem of an expansive soil is investigated through a comprehensive experimental study. Chemical stabilization was generated by traditional agents consisting of lime and cement, and by a commercially branded polymer (CBR PLUS). Mechanical stabilization was applied by means of fiber-reinforcement and swell–shrink cycles. Chemically-treated and fiber-reinforced soil samples were tested for swelling potential in a conventional oedometer apparatus; while swell–shrink cycles were applied using a modified temperature-controlled oedometer. Swell–shrink cycles were applied under room temperature for wetting cycles while the drying process was conducted under a constant temperature of 40 ± 5 °C, and swelling and shrinkage potential were recorded during successive cycles to a point in which swell–shrink equilibrium was attained. Typical strength tests were also conducted for each stabilization scenario which led to maximum reduction in swelling potential. In addition to the experimental program, the swell–time relationship for various stabilization scenarios was simulated using a two-parameter rectangular hyperbola function (2P-RH). Results indicated that all of the proposed stabilization scenarios can guarantee a significant reduction in swelling potential. In the case of lime and cement, reduction in swelling potential was observed to be a function of agent percentage and curing time; whereas for polymer-treated samples the effect of curing was found to be insignificant. Regarding fiber-reinforced samples, reduction in swelling potential was a function of fiber percentage, aspect ratio and fiber tensile strength. Overall, traditional agents proved to be more effective compared to non-traditional techniques. The proposed non-traditional methods, however, displayed promising results posing as great alternatives to lime and cement.

Lost circulation, a recurring peril during drilling operations, entails substantial loss of drilling fluid and dire consequences upon its infiltration into the formation. As drilling depth escalates, the formation temperature and pressure intensify, imposing exacting demands on plug materials. In this study, a kind of controllable curing resin with dense cross-network structure was prepared by the method of solution stepwise ring-opening polymerization. The resin plugging material investigated in this study is a continuous phase material that offers effortless injection, robust filling capabilities, exceptional retention, and underground curing or crosslinking with high strength. Its versatility is not constrained by fracture-cavity lose channels, making it suitable for fulfilling the essential needs of various fracture-cavity combinations when plugging fracture-cavity carbonate rocks. Notably, the curing duration can be fine-tuned within the span of 3–7 h, catering to the plugging of drilling fluid losing of diverse fracture dimensions. Experimental scrutiny encompassed the rheological properties and curing behavior of the resin plugging system, unraveling the intricacies of the curing process and establishing a cogent kinetic model. The experimental results show that the urea-formaldehyde resin plugging material has a tight chain or network structure. When the concentration of the urea-formaldehyde resin plugging system solution remains below 30%, the viscosity clocks in at a meager 10 mPa·s. Optimum curing transpires at 60 °C, showcasing impressive resilience to saline conditions. Remarkably, when immersed in a composite saltwater environment containing 50000 mg/L NaCl and 100000 mg/L CaCl2, the urea-formaldehyde resin consolidates into an even more compact network structure, culminating in an outstanding compressive strength of 41.5 MPa. Through resolving the correlation between conversion and the apparent activation energy of the non-isothermal DSC curing reaction parameters, the study attests to the fulfillment of the kinetic equation for the urea-formaldehyde resin plugging system. This discerning analysis illuminates the nuanced shifts in the microscopic reaction mechanism of the urea-formaldehyde resin plugging system. Furthermore, the pressure bearing plugging capacity of the resin plugging system for fractures of different sizes is also studied. It is found that the resin plugging system can effectively resident in parallel and wedge-shaped fractures of different sizes, and form high-strength consolidation under certain temperature conditions. The maximum plugging pressure of resin plugging system for parallel fractures with outlet size 3 mm can reach 9.92 MPa, and the maximum plugging pressure for wedge-shaped fractures with outlet size 5 mm can reach 9.90 MPa. Consequently, the exploration and application of urea-formaldehyde resin plugging material precipitate a paradigm shift, proffering novel concepts and methodologies in resolving the practical quandaries afflicting drilling fluid plugging.

This study investigates the time-dependent rheological behavior of cemented paste backfill (CPB) that contains alkali-activated slag (AAS) as a binder. Rheological measurements with the controlled shear strain method have been conducted on various AAS-CPB samples with different binder contents, silicate modulus (Ms: SiO2/Na2O molar ratio), fineness of slag and curing temperatures. The Bingham model afforded a good fit to all of the CPB mixtures. The results show that AAS-CPB samples with high binder content demonstrate a more rapid rate of gain in yield stress and plastic viscosity. AAS-CPB also shows better rheological behavior than CPB samples made up of ordinary Portland cement (OPC) at identical binder contents. It is found that increasing Ms yields lower yield stress and plastic viscosity and the rate of gain in these parameters. Increases in the fineness of slag has an adverse effect on rheological behavior of AAS-CPB. The rheological behavior of both OPC- and AAS-CPB samples is also strongly enhanced at higher temperatures. AAS-CPB samples are found to be more sensitive to the variation in curing temperatures than OPC-CPB samples with respect to the rate of gain in yield stress and plastic viscosity. As a result, the findings of this study will contribute to well understand the flow and transport features of fresh CPB mixtures under various conditions and their changes with time.