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This article reports the elastoplastic and viscoelastic response of an industrially cured CAD/CAM resin-based composite (Brilliant Crios, Coltene) at different scales, spatial locations, aging conditions, and shading. Mechanical tests were performed at the macroscopic scale to investigate material strength, elastic modulus, fracture mechanisms and reliability. An instrumented indentation test (IIT) was performed at the microscopic level in a quasi-static mode to assess the elastic and plastic deformation upon indentation, either by mapping transverse areas of the CAD/CAM block or at randomly selected locations. A dynamic-mechanical analysis was then carried out, in which chewing-relevant frequencies were included (0.5 to 5 Hz). Characteristics measured at the nano- and micro-scale were more discriminative in identifying the impact of variables as those measured at macro scale. Anisotropy as a function of the spatial location was identified in all shades, with gradual variation in properties from the center of the block to peripheral locations. Depending on the scale of observation, differences in shade and translucency are very small or not statistically significant. The aging effect is classified as low, but measurable on all scales, with the same pattern of variation occurring in all shades. Aging affects plastic deformation more than elastic deformation and affects elastic deformation more than viscous deformation.

Commercial filaments of poly(lactic acid) (PLA) composites with particulate filler, carbon fiber, and copper powder with different contents were fabricated by FDM 3D printing in XZ-direction at bed temperatures of 45 °C and 60 °C. The effects of additives and bed temperatures on layer adhesion, fracture behavior, and mechanical performance of the PLA composites 3D printing were evaluated. Rheological properties informed viscous nature of all filaments and interface bonding in the PLA composites, which improved printability and dimensional stability of the 3D printing. Crystallinity of the PLA composites 3D printing increased with increasing bed temperature resulting in an improvement of storage modulus, tensile, and flexural properties. On the contrary, the ductility of the 3D printing was raised when printed at low bed temperature. Dynamic mechanical properties, the degree of entanglement, the adhesion factor, the effectiveness coefficient, the reinforcing efficiency factor, and the Cole–Cole analysis were used to understand the layer adhesion, and the interfacial interaction of the composites as compared to the compression molded sheets. SEM images revealed good adhesion between the additives and the PLA matrix. However, the additives induced faster solidification and showed larger voids in the 3D printing, which indicated lower layer adhesion as compared to neat PLA. It can be noted that the combination of the additives and the optimized 3D printing conditions would be obtain superior mechanical performance even layer adhesion has been restricted.

Several industry sectors have sought to develop materials that combine lightness, strength and cost-effectiveness. Natural lignocellulosic natural fibers have demonstrated to be efficient in replacing synthetic fibers, owing to several advantages such as costs 50% lower than that of synthetic fibers and promising mechanical specific properties. Polymeric matrix composites that use kenaf fibers as reinforcement have shown strength increases of over 600%. This work aims to evaluate the performance of epoxy matrix composites reinforced with kenaf fibers, by means of dynamic-mechanical analysis (DMA) and ballistic test. Through DMA, it was possible to obtain the curves of storage modulus (E′), loss modulus (E″) and damping factor, Tan δ, of the composites. The variation of E′ displayed an increase from 1540 MPa for the plain epoxy to 6550 MPa for the 30 vol.% kenaf fiber composites, which evidences the increase in viscoelastic stiffness of the composite. The increase in kenaf fiber content induced greater internal friction, resulting in superior E″. The Tan δ was considerably reduced with increasing reinforcement fraction, indicating better interfacial adhesion between the fiber and the matrix. Ballistic tests against 0.22 caliber ammunition revealed similar performance in terms of both residual and limit velocities for plain epoxy and 30 vol.% kenaf fiber composites. These results confirm the use of kenaf fiber as a promising reinforcement of polymer composites for automotive parts and encourage its possible application as a ballistic armor component.

Viscoelastic damping materials are an effective means to control structural vibration, and are widely used in various fields. In this paper, we use the Dynamic Mechanical Analysis (DMA) characterization data of viscoelastic damping materials and dynamic characteristics experiments to study the dynamic characteristics of structural damping, analyze and summarize the relationship between the performance of damping materials with temperature and frequency, and explore the influencing factors of damping materials on structural vibration. The research shows that temperature and frequency have great influence on the performance of damping material, and the storage modulus and loss factor change regularly. The modal experiment analysis verifies that the viscoelastic damping material has a good suppression effect on structural vibration, which provides a theoretical basis for the development of damping materials with controllable temperature and frequency domains.

Powder-free natural rubber gloves for chemical migration resistance of food-contact grade are prepared using a variety of fillers, including ground calcium carbonate (GCC), precipitated calcium carbonate (PCC), aluminum silicate (AS), and barium sulfate (BS)-filled natural rubber (NR), respectively. The properties of NR gloves, including mechanical, dynamic mechanical, and thermal properties, were investigated. Furthermore, the overall migration test of NR gloves was conducted according to the regulations for food contact gloves (EU Regulation No. 10/2011), using 3% acetic acid as the simulant. Among the fillers studied, the plate-like particles of AS facilitated the most effective filler-rubber interactions and reinforce-mentin AS-filled natural rubber (NR/AS). Consequently, the highest crosslink density, force at break, and damping properties of NR gloves were achieved by applying AS in the NR matrix. Moreover, the lowest overall migration level was observed for NR/AS with a value of 5.35 mg/dm2, which complies with EU Regulation (overall migration of food simulants shall not exceed 10 mg/dm2). Therefore, NR gloves filled with AS are suitable for food-contacting NR gloves.

In this work, the mechanical and dynamic thermomechanical properties of PEEK based on FDM are experimentally investigated and evaluated comprehensively. The tensile failure mechanism of PEEK prepared by FDM and extrusion modeling (EM) was analyzed by fracture morphology observation. By conducting a differential scanning calorimetry (DSC) test, the crystallinity of PEEK prepared by FDM and EM was measured. The dynamic thermomechanical properties of PEEK were tested and analyzed by dynamic mechanical analysis (DMA). For FDM-prepared PEEK samples, the yield strength and elongation were 98.3 ± 0.49 MPa and 22.86 ± 2.12%, respectively. Compared with the yield strength of PEEK prepared by EM, the yield strength of PEEK prepared by FDM increased by 65.38%. The crystallinity of FDM-prepared and EM-prepared samples was calculated as 34.81% and 31.55%, respectively. Different processing methods resulted in differences in the microscopic morphology and crystallinity of two types of PEEK parts, leading to differences in mechanical properties. The internal micropores generated during the FDM processing of PEEK significantly reduced the elongation. Moreover, according to the DMA results, the glass transition activation energy of PEEK was obtained as ΔE = 685.07 kJ/mol based on the Arrhenius equation. Due to the excellent mechanical properties of PEEK prepared by FDM processing, it is promising for high-performance polymer applications in different fields.

This study focusses on imrpoving the mechanical performance of epoxy resin by reinforcing it with microcrystalline cellulose (MCC). Epoxy composites with varying MCC mass fractions (0.5%, 1%, 1.5%, and 2%) are prepared and characterised to assess the influence of MCC on strain-rate-dependent flexural properties, impact resistance, and nonlinear viscoelastic behaviour. Three-point bending tests at different strain rates reveal that MCC notably increases the flexural strength and leads to nonlinear mechanical behaviour. It is shown that stiffness, strength and elongation at break increase with rising MCC content. Charpy impact tests show improved energy absorption and toughness, while Dynamic Mechanical Analysis (DMA) demonstrates that the materials prepared exhibit increased storage modulus and improved damping across a frequency range. These results indicate that MCC serves as an effective bio-based reinforcement, significantly boosting the strength and toughness of epoxy composites. The findings contribute to the development of sustainable, high-performance materials for advanced engineering applications.

The present study focuses on the mechanical and viscoelastic characterization of 3D-printed PLA, fabricated in three different printing orientations (0°, 45°, and 90°) and four different nozzle temperatures (210, 220, 230, and 240 °C). By employing a combination of static and dynamic mechanical analysis (DMA) testing, as well as differential scanning calorimetry (DSC) analysis, this work aims to investigate the relationship between processing parameters and the resulting properties of PLA. DSC results showed that higher nozzle temperatures enhance the degree of crystallinity, which in turn affects the mechanical and viscoelastic behavior of PLA. Regardless of the nozzle temperature, the flexural strength decreased as the printing orientation degrees increased. However, it was found that the higher the nozzle temperature, the higher the flexural strength for the same orientation, and the smaller the strength deviations per specimen. DMA results indicated that as the printing orientation increased, glass transition temperature (Tg) values increased while storage modulus values decreased. At the same time, in both cases, by increasing nozzle temperature, an increase in Tg and a respective increase in storage modulus values is observed due to the increase in the degree of crystallinity.

The study of biomimetics lattice structures, which frequently exhibit outstanding mechanical capabilities, is one of the hottest fields in modern new material/structural technology. The goal of this study is to analyze the nature optimize design of the Molluscs (Sea Shell) porous structure and bio-mimic the sea shell structure design for crashworthiness based on the structure’s energy absorption nature and pore distribution. Initially, a micro-CT investigation was conducted to better understand the internal design structure and distribution of pores in the Costapex gastropod mollusks sea shell. Based on the examination of internal design structure and pattern, three different biomimetics designs, such as (a) shell with solid betel shape (SBS) structure, (b) shell with hollow betel shape (HBS) structure, (c) shell with concentrated hollow betel shape (CHBS) structure, were modeled on Abaqus simulia software and fabricated by additive manufacturing by utilizing ABS-M30i material. The computational and experiments compressive analysis at 0.5%, 1%, and 10% strain rate were conducted to study its mechanical properties, while digital image correlation (DIC) was performed simultaneously to study the strain field of the design structures. Furthermore, the dynamic mechanical analysis (DMA) was performed at 0.5% strain rate at different frequency to study the viscoelasticity nature of the design structure and the various outcomes of the simulation, experimental, DIC, and DMA analysis are summarizing in results section.

Bio-based oils have recently attained interest due to rising environmental concerns and the depletion of petrochemical resources. Bio-based oils high in unsaturated fatty acids, including palm oil, soybean oil, castor oil, sunflower oil, and linseed oil, have attracted attention as an alternative to petroleum-based processing oils in rubber composites. Elastomers could potentially employ bio-based oil instead of mineral oil derived from petroleum in the future as a plasticizer. Mineral oil has a reputation for being damaging to the environment and for being a resource that does not replenish itself. Even though bio-based process oils have some benefits, they are not used very often in the rubber industry because they are cold-flowing oils with low thermo-oxidation, hydrolytic stability, and a plasticizing effect that could mess up rubber processes. However, modification of the carbon–carbon double bond in bio-based oils can improve both the processability and mechanical properties of rubber composites. Thus, this study addresses cure properties in general, emphasizing cure rate, delta torque, scorch time, and cure rate index (CRI) of unmodified and modified bio-based oils in various rubber composites. The wet skid and rolling resistance performance of rubber composites used in tyre tread applications are detailed by the tanδ values at 0 and 60 ℃ from the laboratory dynamic mechanical analysis (DMA) tests. There are often compromises between tyre rolling resistance and tyre wet traction. Therefore, academics and professionals in the bio-based processing oils and rubber industries will benefit from this evaluation. Graphical abstract