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Microplastics have been noticed as widespread in an aquatic environment at the microscale. They have nonstop increased due to the increase in the production of synthetic plastics, population and poor waste management. They are ubiquitous in nature and slowly degrade in water and soil. They are emerging pollutants that have received interest from public audiences and research communities. They have great stability and can adsorb various other pollutants like pesticides, heavy metals, etc. After entering the freshwater environment, microplastics can be stored in the tissue of organisms and stay for a long time. They can generate a serious threat to freshwater ecosystems and can cause physical damage to organisms. Visual identification, Raman spectroscopy, pyrolysis–gas chromatography–mass spectrometry (Pyro–GC–MS), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and combined methods are the commonly known methods for the quantification and identification of microplastics. The detected concentration of microplastics depends on the sampling method, locations and identification techniques. The authors assessed the sources, transport, impacts, identification and characterization, and treatment of microplastics in freshwater environments in detail. The authors are also giving some recommendations for the minimization of the MPs from the freshwater environment. This review article will provide the baseline facts for the investigators to do more research on microplastic pollution in the future. Graphical Abstract

The coastal plain of Rio Grande do Sul is considered to be a Se-deficient region in terms of its population dietary habit, making it the focus of this study. Selenium dietary deficiency is a concern when we consider its potential critical health effects on the local population. Therefore, this study contributes new information on the levels of Se in several species of marine and freshwater fish in the region of the Patos-Mirim Lagoon system, coupled with a comparative analysis of the metalloid contents between both fish groups. The Se contents in the fish species ranged from 88 ± 13 to 688 ± 19 μg.kg −1 . The average Se concentration in the muscle tissue of the freshwater species (251 ± 96 μg kg −1 ) was significantly lower than that of the marine species (412 ± 143 μg kg −1 ). Likewise, no evidence of Se biomagnification was found among the fish from both the marine and freshwater environments, suggesting the absence of trophic transfer of Se. We note that to ensure that the RDA (Recommended Daily Allowance, 55 μg day −1 ) of Se dietary intake for adults is met, at least 134 g of freshwater or 82 g of marine fish fillet could be incorporated into the diet of the population of Rio Grande do Sul. According to target hazard quotients (THQ) and the permissible safety limits, consumption of the fish species analyzed is safe for human health.

This investigation examines the corrosion behavior and mechanisms of 304 stainless steel shielded metal arc welding (SMAW) and gas metal arc welding (GMAW) joints in the simulated reservoir environment through electrochemical testing, stress-free hanging specimens and U-bend specimen immersion experiments, and microstructural characterization. The electrochemical results demonstrate that both welded joints exhibit a superior corrosion resistance in this environment, with a sensitivity of intergranular corrosion (IGC) below 1% and a corrosion rate below 0.005 mm/a. Increasing chloride concentrations elevate the passivation current densities for both the base metal and welded joints. The immersion testing revealed that after 90 days of exposure across the investigated chloride concentrations (50–300 mg/L), all welded specimens maintained surface integrity with no visible corrosion. Furthermore, U-bend specimens demonstrated no evidence of stress corrosion cracking, confirming a low stress corrosion susceptibility.

Nano-SiO 2 , a highly acclaimed nanomaterial for enhancing cemented soil, has shown remarkable improvements in the physical properties and microstructure of cemented soil. The organic matter content in soil plays a crucial role in determining the engineering quality of cemented soil, regardless of whether it is in a freshwater or seawater environment. Therefore, when employing Nano-SiO 2 as an amendment for cemented soil, it is crucial to consider the influence of different soil types and environmental conditions on the effectiveness of the enhancement. This study presents a scientific approach for enhancing the consolidation of cemented soil by incorporating Nano-SiO 2 as an additive in both freshwater and seawater environments. To ensure consistency with practical construction practices, the experiments were divided into freshwater preparation and curing groups, as well as seawater preparation and curing groups. In soils with distinct characteristics, we utilized five different gradient levels of Nano-SiO 2 additives and subjected the cemented soil specimens to a 60-day immersion curing process. Subsequently, unconfined compressive strength (UCS) tests were performed on samples that had reached the specified curing age to investigate the alterations in the mechanical properties of cemented soil caused by Nano-SiO 2 . The internal microstructure and chemical composition of the cemented soil were analyzed utilizing scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The UCS and deformation modulus of cement soil composed of silty clay A and silty clay D with low organic matter content in fresh water environment increased by 109%, 24.7% and 117%, 43% respectively after adding 3.2% Nano-SiO 2 ; In freshwater environments, the cemented soil composed of high-organic-matter content mucky silty clay B, muddy soil C, and dredged silt E experienced respective increases of 16% and − 27%, 2% and 42%, 6% and − 6% in UCS and deformation modulus after adding 3.2% Nano-SiO 2 ; The UCS and deformation modulus of cemented soil with high organic matter content in seawater and freshwater environment increased by 3% and 6% ( Soil B), 12% and 67% ( Soil C), 23% and 27% ( Soil E), respectively, after adding 3.2% Nano-SiO 2 ; The increase of UCS and deformation modulus of cement soil by adding Nano-SiO 2 is negatively correlated with the content of organic matter. in the case of cemented soil with high organic matter content in a seawater environment, the specific type of soil not only impacts UCS and deformation modulus of the soil but also influences the effectiveness of enhancement. Due to the organic matter, the rate of hydration reaction in cemented soil is reduced, resulting in a decrease in the formation of pozzolanic reaction products with SiO 2 . As a result, the improvement in Nano-SiO 2 effectiveness is diminished.

Microplastics, as an emerging pollutant, are widely distributed in freshwater environments such as rivers and lakes, posing immeasurable potential risks to aquatic ecosystems and human health. The migration behaviour of microplastics can exacerbate the degree or scope of risk. A complete understanding of the migration behaviour of microplastics in freshwater environments, such as rivers and lakes, can help assess the state of occurrence and environmental risk of microplastics and provide a theoretical basis for microplastic pollution control. Firstly, this review presents the hazards of microplastics in freshwater environments and the current research focus. Then, this review systematically describes the migration behaviours of microplastics, such as aggregation, horizontal transport, sedimentation, infiltration, stranding, resuspension, bed load, and the affecting factors. These migration behaviours are influenced by the nature of the microplastics themselves (shape, size, density, surface modifications, ageing), environmental conditions (ionic strength, cation type, pH, co-existing pollutants, rainfall, flow regime), biology (vegetation, microbes, fish), etc. They can occur cyclically or can end spontaneously. Finally, an outlook for future research is given.

Tire polymers (TPs) are the most prevalent type of microplastics and are of great concern due to their potential environmental risks. This study aims to determine the toxicity of TPs with the help of molecular-dynamics simulations of their interactions with receptors and to highlight the differences in the toxicity characteristics of TPs in different environmental media (marine environment, freshwater environment, soil environment). For this purpose, five TPs—natural rubber, styrene–butadiene rubber (SBR), butadiene rubber, nitrile–butadiene rubber, and isobutylene–isoprene rubber—were analyzed. Molecular-dynamics calculations were conducted on their binding energies to neurotoxic, developmental, and reproductive receptors of various organisms to characterize the toxic effects of the five TPs. The organisms included freshwater species (freshwater nematodes, snails, shrimp, and freshwater fish), marine species (marine nematodes, mussels, crab, and marine fish), and soil species (soil nematodes, springtails, earthworms, and spiders). A multilevel empowerment method was used to determine the bio-toxicity of the TPs in various environmental media. A coupled-normalization method–principal-component analysis–factor-analysis weighting method—was used to calculate the weights of the TP toxicity (first level) categories. The results revealed that the TPs were the most biologically neurotoxic to three environmental media (20.79% and 10.57% higher compared with developmental and reproductive toxicity, respectively). Regarding the effects of TPs on organisms in various environmental media (second level), using a subjective empowerment approach, a gradual increase in toxicity was observed with increasing trophic levels due to the enrichment of TPs and the feeding behavior of organisms. TPs had the greatest influence in the freshwater-environment organisms according to the subjective empowerment approach employed to weight the three environmental media (third level). Therefore, using the minimum-value method coupled with the feature-aggregation method, the interval-deflation method coupled with the entropy-weighting method, and the standard-deviation normalization method, the three toxicity characteristics of SBR in three environmental media and four organisms were determined. SBR was found to have the greatest impact on the overall toxicity of the freshwater environment (12.38% and 9.33% higher than the marine and soil environments, respectively). The greatest contribution to neurotoxicity (26.01% and 15.95% higher than developmental and reproductive toxicity, respectively) and the greatest impact on snails and shrimp among organisms in the freshwater environment were observed. The causes of the heterogeneity of SBR’s toxicity were elucidated using amino-acid-residue analysis. SBR primarily interacted with toxic receptors through van der Waals, hydrophobic, π-π, and π-sigma interactions, and the more stable the binding, the more toxic the effect. The toxicity characteristics of TMPs to various organisms in different environments identified in this paper provide a theoretical basis for subsequent studies on the prevention and control of TMPs in the environment.

The increasing trend towards electrification in transportation highlights the potential for electric ships and the demand for safe, rapid charging systems. Underwater capacitive power transfer (UCPT) is considered a suitable solution due to its high power density potential. This article presents research on and optimization of UCPT for shore-to-ship charging in freshwater environments. It proposes a design for an insulation coupler and explores the influence of parasitic capacitance in the environment. This study demonstrates how the ship and shore impact the coupler’s coupling coefficient and mutual capacitance, thereby affecting the power and efficiency. Through theoretical calculations and finite element analysis, a kW-level UCPT coupler is designed. Experimental verification under different cases confirms the efficiency and constant current output characteristics, with superior performance observed when the coupler is positioned further away from the ship or shore. This study showcases the potential of UCPT to provide reliable and efficient power supply for electric ships, while emphasizing the importance of considering environmental factors and parasitic effects in system design and operation. These findings contribute to advancing UCPT technology and offer insights for further optimization to enhance practical applicability.

Plastic contamination is ubiquitous, with plastic found in hundreds of species of aquatic wildlife, including fish. Lacking a broad and comprehensive view of this global issue across aquatic environments, we collated and synthesised the literature that focuses on microplastic ingestion in fish from marine, freshwater and estuarine environments. First, we assessed how the approaches used to investigate microplastic in fish have changed through time, comparing studies globally. A greater understanding of this changing landscape is essential for rigorous and coherent comparisons with only 42% of published studies following recommended approaches of chemical digestions and verifying plastic via polymer identification. Then, using this subset of studies, we found that 49% of all fish sampled globally for microplastic ingestion had plastic (average of 3.5 pieces per fish), with fish from North America ingesting more plastic than fish from other regions. We then evaluated the role of environment, habitat, feeding strategy and source (i.e. aquaculture or wild-caught) in the ingestion of microplastic. Research from marine environments dominated (82% of species) but freshwater fish ingested more plastic, as did detritivores, fish in deeper waters and those from aquaculture sources. By collating global microplastic research we identified regional disparities and key knowledge gaps that support research towards freshwater environments and aquaculture sources. Overall, we highlight the need for consistent guidelines in methods used to evaluate microplastic in fish, to ensure data are unambiguous, comparable and can be widely used to support mitigation and management strategies, inform potential policy actions, and evaluations of environmental, food safety, and human health goals.Graphic abstract

Atmospheric water is a resource equivalent to ~10% of all fresh water in lakes on Earth. However, an efficient process for capturing and delivering water from air, especially at low humidity levels (down to 20%), has not been developed. We report the design and demonstration of a device based on a porous metal-organic framework {MOF-801, [Zr₆O₄(OH)₄(fumarate)₆]} that captures water from the atmosphere at ambient conditions by using low-grade heat from natural sunlight at a flux of less than 1 sun (1 kilowatt per square meter). This device is capable of harvesting 2.8 liters of water per kilogram of MOFdaily at relative humidity levels as low as 20% and requires no additional input of energy.

The presence of sulfated polysaccharides in of seaweeds is considered to be a consequence of the physiological adaptation to the high salinity of the marine environment. Recently, it was found that sulfated polysaccharides were present in certain freshwater species and some vascular plants. (Ulvophyceae, Chlorophyta) is one of the largest genera of green algae that are able to grow in both, seas and freshwater courses. Previous studies carried out on the water-soluble polysaccharides of the marine species established the presence of sulfated xylogalactoarabinans constituted by a backbone of 4-linked β-L-arabinopyranose units partially sulfated mainly on C3 and also on C2 with partial glycosylation, mostly on C2, with terminal β-D-xylopyranose or β-D-galactofuranose units. Besides, minor amounts of 3-, 6- and/or 3,6-linked β-D-galactan structures, with galactose in the pyranosic form were detected. In this work, the main water soluble cell wall polysaccharides from the freshwater alga were characterized. It was found that this green alga biosynthesizes sulfated polysaccharides, with a structure similar to those found in marine species of this genus. Calibration of molecular clock with fossil data suggests that colonization of freshwater environments occurred during the Miocene by its ancestor. Therefore, the presence of sulfated polysaccharides in the freshwater green macroalga could be, in this case, an adaptation to transient desiccation and changes in ionic strength. Retention of sulfated polysaccharides at the cell walls may represent a snapshot of an evolutionary event, and, thus constitutes an excellent model for further studies on the mechanisms of sulfation on cell wall polysaccharides and environmental stress co-evolution.