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The introduction of any new disruptive technology in a traditionally well-established industry, such as the road construction industry, is usually associated with considerable resistance. This is especially relevant when the new technology is based on the use of granular materials traditionally considered to be of an unacceptable quality in combination with relatively new concepts such as New-age (Nano) Modified Emulsions (NME). In such cases, the fact that the material design methods are based on fundamental scientific principles and have been proven in both laboratories and through Accelerated Pavement Testing (APT) may be of little influence. However, the general acceptance of new disruptive technologies, e.g., telecommunications and Information Technologies (IT), have been based on the considerable advantages it presented. The same principles are applicable to the general acceptance and use of the NME stabilisation/enhancement of materials in the road construction industry. This article is aimed at the practical cost-effective demonstration of the general application of the use of nanos-silane-modified emulsions in the construction of the highest order roads, i.e., inter-city multi-lane highways, lower-order roads (including Low-Volume Roads (LVR)), and even local accesses to farms and in villages/townships. The implementation of NME technologies is directly associated with ease of use, time, and cost savings, and with the addressing and reduction of risks applicable to the use thereof.

Behaviour of granular soils subjected to internal erosion involves complex coupling between solid–fluid interaction, skeleton deformation and microstructural evolutions. This paper presents a micro–macro investigation on suffusion in idealized gap-graded and well-graded soils using the coupled computational fluid dynamics and discrete element method. The interaction between soil particles and seepage flow is modelled via momentum exchange between two phases. The progressive loss of fine particles subjected to upward seepage flow at various hydraulic gradients is investigated. The fines content, volumetric contraction and void ratio are monitored to identify the changes of macroscopic states of the soil skeleton. In addition, the microstructural evolution is tracked via particle-scale descriptors such as coordination numbers and force chain statistics. Several clogging–unclogging events which are responsible for the sudden changes of fines content and skeleton response are observed during suffusion. A parametric study indicates that the initial fines content and the hydraulic gradient significantly affect the kinetics of suffusion. Microstructural analyses reveal that the removal of fines is accompanied by the reduction in weak contact pairs and particles with low connectivity.

The dynamics of granular materials are critical to many natural and industrial processes; granular motion is often strikingly similar to flow in conventional liquids. Food, pharmaceutical, and clean energy processes utilize bubbling fluidized beds, systems in which gas is flowed upward through granular particles, suspending the particles in a liquid-like state through which gas voids or bubbles rise. Here, we demonstrate that vibrating these systems at a resonant frequency can transform the normally chaotic motion of these bubbles into a dynamically structured configuration, creating reproducible, controlled motion of particles and gas. The resonant frequency is independent of particle properties and system size, and a simple harmonic oscillator model captures this frequency. Discrete particle simulations show that bubble structuring forms because of rapid, local transitions between solid-like and fluid-like behavior in the grains induced by vibration. Existing continuummodels for gas–solid flows struggle to capture these fluid–solid transitions and thus cannot predict the bubble structuring. We propose a constitutive relationship for solids stress that predicts fluid–solid transitions and hence captures the experimental structured bubbling patterns. Similar structuring has been observed by oscillating gas flowin bubbling fluidized beds. We show that vibrating bubbling fluidized beds can produce a more ordered structure, particularly as system size is increased. The scalable structure and continuum model proposed here provide the potential to address major issues with scale-up and optimal operation, which currently limit the use of bubbling fluidized beds in existing and emerging technologies.

The collapse of a quasi-two-dimensional column of cohesive granular media is investigated experimentally and numerically in the framework of a continuum model. The configuration is an initial parallelepiped-shaped granular pile, which is suddenly released by opening a retaining door. The experiments rely on a model material developed by Gans et al. (Phys. Rev. E, vol. 101, 2020, 032904) made of silica particles coated with polyborosiloxane, for which the adhesive interparticle force can be tuned by controlling the thickness of the coating. Numerically, the collapse is simulated using a simple cohesive rheological model implemented in a two-dimensional Navier–Stokes solver. We investigate the role of cohesion on the stability of the column, the mode of failure, the flow dynamics and the geometry of the final deposit. Our results show that the continuum model captures the main features observed experimentally.

Particle segregation in dense flowing size-disperse granular mixtures is driven by gravity and shear, but predicting the associated segregation force due to both effects has remained an unresolved challenge. Here, a model of the combined gravity- and kinematics-induced segregation force on a single intruder particle is integrated with a model of the concentration dependence of the gravity-induced segregation force. The result is a general model of the net particle segregation force in flowing size-bidisperse granular mixtures. Using discrete element method simulations for comparison, the model correctly predicts the segregation force for a variety of mixture concentrations and flow conditions in both idealized and natural shear flows.

The drag force on a spherical intruder in dense granular shear flows is studied using discrete element method simulations. Three regimes of the intruder dynamics are observed depending on the magnitude of the drag force (or the corresponding intruder velocity) and the flow inertial number: a fluctuation-dominated regime for small drag forces; a viscous regime for intermediate drag forces; and an inertial (cavity formation) regime for large drag forces. The transition from the viscous regime (linear force-velocity relation) to the inertial regime (quadratic force-velocity relation) depends further on the inertial number. Despite these distinct intruder dynamics, we find a quantitative similarity between the intruder drag in granular shear flows and the Stokesian drag on a sphere in a viscous fluid for intruder Reynolds numbers spanning five orders of magnitude. Beyond this first-order description, a modified Stokes drag model is developed that accounts for the secondary dependence of the drag coefficient on the inertial number and the intruder size and density ratios. When the drag model is coupled with a segregation force model for intruders in dense granular flows, it is possible to predict the velocity of gravity-driven segregation of an intruder particle in shear flow simulations.

Particle segregation is common in natural and industrial processes involving flowing granular materials. Complex, and seemingly contradictory, segregation phenomena have been observed for different boundary conditions and forcing. Using discrete element method simulations, we show that segregation of a single particle intruder can be described in a unified manner across different flow configurations. A scaling relation for the net segregation force is obtained by measuring forces on an intruder particle in controlled-velocity flows where gravity and flow kinematics are varied independently. The scaling law consists of two additive terms: a buoyancy-like gravity-induced pressure gradient term and a shear rate gradient term, both of which depend on the particle size ratio. The shear rate gradient term reflects a kinematics-driven mechanism whereby larger (smaller) intruders are pushed toward higher (lower) shear rate regions. The scaling is validated, without refitting, in wall-driven flows, inclined wall-driven flows, vertical silo flows, and free-surface flows down inclines. Comparing the segregation force with the intruder weight results in predictions of the segregation direction that match experimental and computational results for various flow configurations.

Something big in zeolites Zeolites, microporous aluminosilciates with a cage-like framework, are industrially important in catalysis and separation. The bigger the pore size that can be achieved in a zeolite, the bigger and more complex the reactant molecules that can be accommodated for catalytic or other purposes. A new zeolite landmark is reported in this issue, the synthesis of ITQ-37, a new germanosilicate zeolite with the largest pores to date, about 25 Å across. Materials with pores of this size have previously been mostly amorphous. ITQ-37 has a single-channel system, so that the pores are readily accessible, and has chiral pores, useful for the separation of enantiomorphic molecules. With extralarge pores, zeolites could catalyse reactions between larger molecules. Here a zeolite with the largest pores to date is synthesized, about 25 ångstroms across; the structure is also chiral, which is useful in the separation of enantiomorphic molecules. The synthesis is done by crystallization of a gel of germanate and silicate dissolved in a bulky organic molecular template, using high-throughput techniques. The synthesis of crystalline molecular sieves with pore dimensions that fill the gap between microporous and mesoporous materials is a matter of fundamental and industrial interest 1 , 2 , 3 . The preparation of zeolitic materials with extralarge pores and chiral frameworks would permit many new applications. Two important steps in this direction include the synthesis 4 of ITQ-33, a stable zeolite with 18 × 10 × 10 ring windows, and the synthesis 5 of SU-32, which has an intrinsically chiral zeolite structure and where each crystal exhibits only one handedness. Here we present a germanosilicate zeolite (ITQ-37) with extralarge 30-ring windows. Its structure was determined by combining selected area electron diffraction (SAED) and powder X-ray diffraction (PXRD) in a charge-flipping algorithm 6 . The framework follows the SrSi 2 (srs) minimal net 7 and forms two unique cavities, each of which is connected to three other cavities to form a gyroidal channel system. These cavities comprise the enantiomorphous srs net of the framework. ITQ-37 is the first chiral zeolite with one single gyroidal channel. It has the lowest framework density (10.3 T atoms per 1,000 Å 3 ) of all existing 4-coordinated crystalline oxide frameworks, and the pore volume of the corresponding silica polymorph would be 0.38 cm 3  g -1 .

The motion and mixing of granular media are observed in several contexts in nature, often displaying striking similarities to liquids. Granular dynamics occur in geological phenomena and also enable technologies ranging from pharmaceuticals production to carbon capture. Here, we report the discovery of a family of gravitational instabilities in granular particle mixtures subject to vertical vibration and upward gas flow, including a Rayleigh–Taylor (RT)-like instability in which lighter grains rise through heavier grains in the form of “fingers” and “granular bubbles.” We demonstrate that this RT-like instability arises due to a competition between upward drag force increased locally by gas channeling and downward contact forces, and thus the physical mechanism is entirely different from that found in liquids. This gas channeling mechanism also generates other gravitational instabilities: the rise of a granular bubble which leaves a trail of particles behind it and the cascading branching of a descending granular droplet. These instabilities suggest opportunities for patterning within granular mixtures.