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Obtaining zinc coatings by the batch hot-dip galvanizing process currently represents one of the most effective and economical methods of protecting steel products and structures against corrosion. The batch hot-dip galvanizing process has been used for over 150 years, but for several decades, there has been a dynamic development of this technology, the purpose of which is to improve the efficiency of zinc use and reduce its consumption and improve the quality of the coating. The appropriate selection of the chemical composition of the galvanizing bath enables us to control the reactivity of steel, improve the drainage of liquid zinc from the product surface, and reduce the amount of waste, which directly affects the quality of the coating and the technology of the galvanizing process. For this purpose, the effect of many alloying additives to the zinc bath on the structure and thickness of the coating was tested. The article reviews the influence of various elements introduced into the bath individually and in different configurations, discusses the positive and negative effects of their influence on the galvanizing process. The current development in the field of the chemical composition of galvanizing baths is also presented and the best-used solutions for the selection and management of the chemical composition of the bath are indicated.

A lisimetria tem sido um método muito utilizado no manejo da irrigação, sendo de fundamental importância para o bom desempenho do equipamento. Assim, o objetivo deste trabalho foi construir, instalar, calibrar e analisar a performance de dois lisímetros de pesagem para estudo da demanda hídrica da cultura da cana-de-açúcar (Saccharum spp.). Os lisímetros foram instalados numa área experimental na Fazenda Capiatã da Usina Coruripe, em Coruripe-AL. Foram construídos com chapas de aço galvanizado e instalados sobre uma estrutura metálica montada sobre barras transversais, a fim de concentrar a massa do conjunto sobre uma célula de carga localizada no centro do sistema. Após o preenchimento do lisímetro com solo, foi realizada a análise dos dados de calibração do mesmo por meio de análise de regressão linear. Posteriormente, com os dados gerados foi observada a histerese do sistema por meio da curva de histerese e da curva de erro. Os dois lisímetros de pesagem instalados e calibrados, obtiveram alto coeficiente de determinação na equação de calibração, excelente sensibilidade e resolução, detectando variações de massa devido à chuva, irrigações, evapotranspiração e vento, durante períodos inferiores a 1 hora. O lisímetro 2 obteve maior exatidão que o lisímetro 1 no estudo da demanda hídrica da cultura. A evapotranspiração média da cana-de-açúcar foi de 4,82 e 4,90 mm dia-1 no lisímetro 1 e 4,72 e 4,87 mm dia-1 no lisímetro 2. A metodologia para determinação da evapotranspiração da cultura utilizando o somatório das diferenças das massas pode ser utilizada com exatidão.

The prospects for light-emitting diodes and lasers based on perovskite materials are reviewed. The field of solution-processed semiconductors has made great strides; however, it has yet to enable electrically driven lasers. To achieve this goal, improved materials are required that combine efficient (>50% quantum yield) radiative recombination under high injection, large and balanced charge-carrier mobilities in excess of 10 cm 2 V −1 s −1 , free-carrier densities greater than 10 17 cm −3 and gain coefficients exceeding 10 4 cm −1 . Solid-state perovskites are — in addition to galvanizing the field of solar electricity — showing great promise in photonic sources, and may be the answer to realizing solution-cast laser diodes. Here, we discuss the properties of perovskites that benefit light emission, review recent progress in perovskite electroluminescent diodes and optically pumped lasers, and examine the remaining challenges in achieving continuous-wave and electrically driven lasing.

Crop improvements can help us to meet the challenge of feeding a population of 10 billion, but can we breed better varieties fast enough? Technologies such as genotyping, marker-assisted selection, high-throughput phenotyping, genome editing, genomic selection and de novo domestication could be galvanized by using speed breeding to enable plant breeders to keep pace with a changing environment and ever-increasing human population.

The discovery of the highly efficient site-specific nuclease system CRISPR–Cas9 from Streptococcus pyogenes has galvanized the field of gene therapy1,2. The immunogenicity of Cas9 nuclease has been demonstrated in mice3,4. Preexisting immunity against therapeutic gene vectors or their cargo can decrease the efficacy of a potentially curative treatment and may pose significant safety issues3–6. S. pyogenes is a common cause for infectious diseases in humans, but it remains unclear whether it induces a T cell memory against the Cas9 nuclease7,8. Here, we show the presence of a preexisting ubiquitous effector T cell response directed toward the most widely used Cas9 homolog from S. pyogenes (SpCas9) within healthy humans. We characterize SpCas9-reactive T cells within the CD4/CD8 compartments for multi-effector potency, cytotoxicity, and lineage determination. In-depth analysis of SpCas9-reactive T cells reveals a high frequency of SpCas9-reactive regulatory T cells that can mitigate SpCas9-reactive effector T cell proliferation and function in vitro. Our results shed light on T cell–mediated immunity toward CRISPR-associated nucleases and offer a possible solution to overcome the problem of preexisting immunity.

There is growing awareness among governments, businesses, and the general public of risks arising from changes to our climate on time scales from months through to decades. Some climatic changes could be unprecedented in their harmful socioeconomic impacts, while others with adequate forewarning and planning could offer benefits. There is therefore a pressing need for decision-makers, including policy-makers, to have access to and to use high-quality, accessible, relevant, and credible climate information about the past, present, and future to help make better-informed decisions and policies. We refer to the provision and use of such information as climate services. Established programs of research and operational activities are improving observations and climate monitoring, our understanding of climate processes, climate variability and change, and predictions and projections of the future climate. Delivering climate information (including data and knowledge) in a way that is usable and useful for decision-makers has had less attention, and society has yet to optimally benefit from the available information. While weather services routinely help weather-sensitive decision-making, similar services for decisions on longer time scales are less well established. Many organizations are now actively developing climate services, and a growing number of decision-makers are keen to benefit from such services. This article describes progress made over the past decade developing, delivering, and using climate services, in particular from the worldwide effort galvanizing around the Global Framework for Climate Services under the coordination of UN agencies. The article highlights challenges in making further progress and proposes potential new directions to address such challenges.

Modern high-strength steels achieve their strength exclusively through the manufacturing process, as the chemical composition of these steels is very similar to the composition of standard-quality steels. Typically, hot-dip galvanizing is used to form a protective zinc layer on the steel parts of structures; nonetheless, the material is exposed to high temperatures during the process. With high-strength steels, this can lead to deterioration of the mechanical properties. This study aims to experimentally examine and evaluate the extent of deterioration of the mechanical properties of high-strength-steel members. The effect was studied on specimens made of three different types of steel with the yield strength ranging from 460 to 1250 MPa. For each type of steel, selected mechanical properties—yield strength, tensile strength, and hardness—were determined on specimens with and without hot-dip galvanization, and the obtained results were mutually compared. Our study shows a significant impact of the hot-dip galvanization process on the mechanical properties of some high-strength steels. With the studied types of steel, the yield strength decreased by up to 18%, the tensile strength by up to 13%, and the hardness by up to 55%.

In recent decades, batch hot-dip galvanized (HDG) steel has proven itself in practical applications due to the good corrosion resistance of its components. Despite the importance of the mechanical-load-bearing capacity of these coatings, the wear behavior has, so far, only been investigated very sporadically and not systematically, so a quantification of the wear behavior and statements on the mechanisms are vague. Therefore, two body wear tests with bonded abrasive grain were carried out. Varying the friction rolls, load, and total number of cycles, the wear behavior was investigated. The mass loss and the layer thickness reduction were measured at different intervals. After the test, the microstructure in the cross-section and the hardness according to Vickers (0.01 HV) were evaluated. The results showed that the wear behavior of HDG coatings against abrasive loads can be characterized with the selected test conditions. Initially, the applied load removed the soft η-phase. As the total number of cycles increases, the η- and ζ-phases deform plastically, resulting in a lower mass reduction compared to that expected from the measured layer thickness. The characteristic structure of a batch HDG coating with hard intermetallic Zn-Fe phases and an outer pure zinc phase has demonstrated effective resistance to abrasion.

Nature's survey was sent to several thousand people worldwide, most of whom are affiliated to the International Network of Government Science Advice (INGSA), a global association of researchers and policymakers, based in Auckland, New Zealand. Anotherrequirementisarepertoire of people skills: the ability to communicate complex ideas in succinct, everyday language; the capacity to build trusting relationships, so that politicians have faith in the information they receive and that their confidences will not be breached; being able to respectfully understand others' views and priorities, however different. Today's challenges are galvanizing interest in science policy among young people who see it as a more direct way to have ап impact than pure research.

Structural bonding of batch hot-dip galvanized components poses a particular challenge against the background of the build-up of the zinc coating in the form of different zinc-iron phases. As part of a research project, parameters influencing the zinc coating, the pre-treatment of the zinc substrate, and the adhesive were investigated with regard to the load-bearing capacity of a bonded joint. The variation of the zinc coatings was achieved by using four different steel grades in combination with four batch galvanizing processes. Therefore, small-scale, thick shear tensile specimens were uniformly fabricated, galvanized, bonded in pairs, and mechanically tested. A second series of tests was aimed at the feasibility of an adhesive bond of batch galvanized, medium-scale components under realistic boundary conditions. The test specimens were produced by varying the surface preparation and the adhesive and tested mechanically to shear failure. The results of both test series show that zinc-coated components can be adhesively bonded well and reliably, and, by this, a high load-bearing capacity can be achieved in the bonded joint. The small-scale tests clearly show that the type of zinc coating and its structure obviously have a significant influence on the load-bearing capacity. In summary, it can be stated that the relevant material and process-related influences on the shear load-bearing behavior of bonded joints of batch hot-dip galvanized components were demonstrated by means of the two test series, and the basis for implementing such joints on real load-bearing structures was laid. The presented procedure (small-scale tests and component tests) can be used as a suggestion for a later application in practice.