Explore the vast range of titles available.

Methane gas hydrates, crystalline inclusion compounds formed from methane and water, are found in marine continental margin and permafrost sediments worldwide. This article reviews the current understanding of phenomena involved in gas hydrate formation and the physical properties of hydrate‐bearing sediments. Formation phenomena include pore‐scale habit, solubility, spatial variability, and host sediment aggregate properties. Physical properties include thermal properties, permeability, electrical conductivity and permittivity, small‐strain elastic P and S wave velocities, shear strength, and volume changes resulting from hydrate dissociation. The magnitudes and interdependencies of these properties are critically important for predicting and quantifying macroscale responses of hydrate‐bearing sediments to changes in mechanical, thermal, or chemical boundary conditions. These predictions are vital for mitigating borehole, local, and regional slope stability hazards; optimizing recovery techniques for extracting methane from hydrate‐bearing sediments or sequestering carbon dioxide in gas hydrate; and evaluating the role of gas hydrate in the global carbon cycle.

Effective production of natural gas from hydrate-bearing sediments by using various strategies (such as depressurization) is an important way to solve the current global energy crisis. Nevertheless, hydrate dissociation during gas production can weaken sediment strength, influencing reservoir stability and subsequent gas production. Previous studies focused mainly on the analysis of production behavior of natural gas from hydrates, but few on reservoir stability. In this work, evolution of gas production, reservoir characteristics and sediment deformation were analyzed thoroughly with ABAQUS platform. Investigation on gas production revealed that the average production rate was 5.57 × 10 4 m 3 /day, indicating that development strategies mentioned herein can achieve the goal of commercial development of gas hydrates. Although the changes of hydrate saturation and effective stress both affected the characteristics of hydrate reservoir throughout hydrate development operation, hydrate saturation was the main influencing factor. The contour of the distribution nephogram of reservoir characteristics basically coincided with that of the hydrate saturation distribution nephogram. Meanwhile, the yield area around wellbore appearing in the early stage of development operation corresponded to the area prone to sand production. However, the yield area near the seabed appearing in the late stage of development operation corresponded to the area prone to submarine landslide. Finally, investigation on sediment deformation indicated, except for the dissociation area, which experienced significant compaction, the sediments in other areas in the confined space experienced continuous subsidence. This study is expected to lay a theoretical foundation for proposing engineering measures to avoid uncontrollable geological disasters in the process of hydrate development.

Most marine gas hydrate systems follow a vertical pattern with hydrate overlying free gas. Here we document the discovery of a gas to hydrate system in a horizontal sand layer in the Qiongdongnan Basin of the South China Sea. Eight wells were drilled by the Guangzhou Marine Geological Survey in 2021–2022 to investigate the occurrence and mechanisms responsible for the formation of the system. We describe a free gas‐bearing sand reservoir at the center of the system sustained by advecting hot fluids and gas; away from the advecting zone, the cooler, surrounding sand reservoir is filled with hydrate. Observations at this site show that advective heat has a large control on hydrate formation in sands and may be a key mechanism which allows gas migration within the hydrate stability zone and the formation of high‐saturation hydrate in sand layers. Plain Language Summary Natural gas hydrate, an ice‐like substance composed of water and gas, is commonly found in sediments under the ocean. Most marine hydrate systems follow a vertical pattern where hydrate‐bearing sediments overlie free gas‐bearing sediments; in addition, most hydrate is hosted in marine muds at low concentration. Here we document a horizontal system that transitions from high concentrations of free gas to high concentrations of hydrate in a horizontal sand layer in the northern South China Sea. Two recent drilling expeditions are conducted to explore this unique system. Seismic and logging data suggests that multiple processes including focused fluid flow, capillary sealing and heat transfer control the formation of the system. Key Points We discover a gas hydrate system where gas transitions to hydrate in a flat‐lying sand layer in the northern South China Sea Capillary sealing occurs at the sand‐clay interface, preventing upward fluid advection and causes fluids to migrate laterally Advecting warm fluids and gas are the primary control on the hydrate and free gas system in this sand layer

Seafloor methane release due to the thermal dissociation of gas hydrates is pervasive across the continental margins of the Arctic Ocean. Furthermore, there is increasing awareness that shallow hydrate-related methane seeps have appeared due to enhanced warming of Arctic Ocean bottom water during the last century. Although it has been argued that a gas hydrate gun could trigger abrupt climate change, the processes and rates of subsurface/ atmospheric natural gas exchange remain uncertain. Here we investigate the dynamics between gas hydrate stability and environmental changes from the height of the last glaciation through to the present day. Using geophysical observations from offshore Svalbard to constrain a coupled ice sheet/gas hydrate model, we identify distinct phases of subglacial methane sequestration and subsequent release on ice sheet retreat that led to the formation of a suite of seafloor domes. Reconstructing the evolution of this dome field, we find that incursions of warm Atlantic bottom water forced rapid gas hydrate dissociation and enhanced methane emissions during the penultimate Heinrich event, the Bølling and Allerød interstadials, and the Holocene optimum. Our results highlight the complex interplay between the cryosphere, geosphere, and atmosphere over the last 30,000 y that led to extensive changes in subseafloor carbon storage that forced distinct episodes of methane release due to natural climate variability well before recent anthropogenic warming.

The mechanisms involved in the formation/dissociation of methane hydrate confined at the nanometer scale are unraveled using advanced molecular modeling techniques combined with a mesoscale thermodynamic approach. Using atom-scale simulations probing coexistence upon confinement and free energy calculations, phase stability of confined methane hydrate is shown to be restricted to a narrower temperature and pressure domain than its bulk counterpart. The melting point depression at a given pressure, which is consistent with available experimental data, is shown to be quantitatively described using the Gibbs–Thomson formalism if used with accurate estimates for the pore/liquid and pore/hydrate interfacial tensions. The metastability barrier upon hydrate formation and dissociation is found to decrease upon confinement, therefore providing a molecular-scale picture for the faster kinetics observed in experiments on confined gas hydrates. By considering different formation mechanisms—bulk homogeneous nucleation, external surface nucleation, and confined nucleation within the porosity—we identify a cross-over in the nucleation process; the critical nucleus formed in the pore corresponds either to a hemispherical cap or to a bridge nucleus depending on temperature, contact angle, and pore size. Using the classical nucleation theory, for both mechanisms, the typical induction time is shown to scale with the pore volume to surface ratio and hence the pore size. These findings for the critical nucleus and nucleation rate associated with such complex transitions provide a means to rationalize and predict methane hydrate formation in any porous media from simple thermodynamic data.

Despite the industrial implications and worldwide abundance of gas hydrates, the formation mechanism of these compounds remains poorly understood. We report direct molecular dynamics simulations of the spontaneous nucleation and growth of methane hydrate. The multiple-microsecond trajectories offer detailed insight into the process of hydrate nucleation. Cooperative organization is observed to lead to methane adsorption onto planar faces of water and the fluctuating formation and dissociation of early hydrate cages. The early cages are mostly face-sharing partial small cages, favoring structure II; however, larger cages subsequently appear as a result of steric constraints and thermodynamic preference for the structure I phase. The resulting structure after nucleation and growth is a combination of the two dominant types of hydrate crystals (structure I and structure II), which are linked by uncommon 5¹²6³ cages that facilitate structure coexistence without an energetically unfavorable interface.

By harnessing both hypothetical, synthetic basin and gas hydrate (GH) system models and real‐world models of well‐studied salt diapir‐associated GH sites at Green Canyon (Gulf of Mexico) and Blake Ridge (U.S. Atlantic coast), we propose and demonstrate salt movement (and in particular, diapirism) to be a new mechanism for the recycling of marine GH. At Green Canyon, for example, we show that by considering this newly proposed diapir‐driven recycling mechanism in conjunction with previously proposed lithological control on sandy‐reservoir‐hosted hydrate at the base of the GH stability zone (BGHSZ; ∼bottom‐simulating reflector, BSR), modeled GH saturations match drilling data. Overall, salt diapir movement‐induced GH recycling provides a temperature‐driven mechanism by which GH saturations at the BGHSZ may reach >90 vol. % and by which GH volumes near and free gas volumes beneath the BGHSZ may be increased significantly through time. Interestingly, comparison of salt diapir‐driven recycling and sediment burial‐driven recycling scenarios suggests notably higher rates of recycling via diapir‐driven versus burial‐driven processes. Our results suggest that GH and associated free gas accumulations above salt diapir crests represent particularly attractive targets for unconventional and conventional hydrocarbon resource exploration and for scientific and academic drilling expeditions aimed at exploiting GH systems. Salt basins containing GH systems—including passive margin basins of the Gulf of Mexico, southeastern Brazil, and southwestern Africa—are therefore compelling localities for studying salt‐driven GH recycling and for salt diapir‐associated natural gas exploration. Plain Language Summary Gas hydrates (GHs) are ice‐like solids widely distributed in permafrost settings and marine sediments of continental margins. Hydrate deposits contain vast amounts of carbon, mostly in the form of entrapped methane, and are therefore critical components of the global carbon cycle. High‐saturation GH accumulations are attractive as potentially extractable energy resources, and the processes resulting in concentrated hydrate deposits are therefore of particular scientific and economic interest. Here, we explore GH recycling, a process by which hydrates pushed below their pressure‐ and temperature‐defined stability zone destabilizes and releases buoyant gas that may be reincorporated into the upward‐shifted zone of hydrate stability, leading to increasingly elevated hydrate saturations. Using computational basin modeling and two‐dimensional forward modeling of both theoretical and real‐world GH systems, we present a new mechanism for GH recycling: the ascent of salt diapirs. Key Points We demonstrate salt diapir movement and associated thermal changes to be a mechanism for gas hydrate recycling Hydrate at the base of hydrate stability can reach saturations >90 vol. % and trap large free gas accumulations via diapir‐driven recycling Diapir‐driven recycling helps explain Green Canyon hydrate saturations and implies that salt basins with hydrate are attractive for exploration

Natural gas hydrates represent a promising clean energy source with vast reserves. Their efficient development is crucial for ensuring the sustainable advancement of human society. However, wellhead instability occurred in the long-term development, which poses a significant challenge that impacts its commercial development. In the present work, the properties of hydrate-bearing sediments were experimentally investigated. It was found that the elastic modulus, cohesion, and internal friction angle of hydrate-bearing sediments exhibit an increase with the effective stress. As an example, when the effective stress increases from 0 MPa to 25 MPa, the normalized elastic modulus exhibits a rise from 1.00 to 1.36. Conversely, the Poisson’s ratio, permeability, and porosity demonstrate a decline in accordance with this trend. As an example, both normalized porosity and permeability decrease to values below 0.40 as the effective stress increases to 25 MPa. Based on the experimental results and previous work, a comprehensive model for describing the effect of both hydrate saturation and effective stress on physical parameters was obtained. Subsequently, a multi-field coupled investigation methodology was developed to evaluate wellhead stability during the long-term development of hydrate-bearing sediments, and the evolution characteristics and mechanisms of wellhead instability were numerically explored. It reveals that development operation using the vertical wellbore decomposes hydrates in the surrounding sediments only within a radius of 19.52 m, which significantly undermines the wellhead stability. Moreover, the wellhead system not only sinks with sediment subsidence but also experiences additional sinking due to the failure of bonding between the wellhead system and sediments. Furthermore, the latter accounts for a significant portion, amounting to approximately 68.15% of the total sinking under the research conditions. This study can provide methodological prerequisites for exploring the impact of various factors on wellhead stability during the long-term hydrate development process.

Applications of clathrate hydrate require fast formation kinetics of it, which is the long-standing technological bottleneck due to mass transfer and heat transfer limitations. Although several methods, such as surfactants and mechanical stirring, have been employed to accelerate gas hydrate formation, the problems they bring are not negligible. Recently, a new water-in-air dispersion stabilized by hydrophobic nanosilica, dry water, has been used as an effective promoter for hydrate formation. In this review, we summarize the preparation procedure of dry water and factors affecting the physical properties of dry water dispersion. The effect of dry water dispersion on gas hydrate formation is discussed from the thermodynamic and kinetic points of view. Dry water dispersion shifts the gas hydrate phase boundary to milder conditions. Dry water increases the gas hydrate formation rate and improves gas storage capacity by enhancing water-guest gas contact. The performance comparison and synergy of dry water with other common hydrate promoters are also summarized. The self-preservation effect of dry water hydrate was investigated. Despite the prominent effect of dry water in promoting gas hydrate formation, its reusability problem still remains to be solved. We present and compare several methods to improve its reusability. Finally, we propose knowledge gaps in dry water hydrate research and future research directions.

Anthropogenic global warming may be accelerated by a positive feedback from the mobilization of methane from thawing Arctic permafrost. There are large uncertainties about the size of carbon stocks and the magnitude of possible methane emissions. Methane cannot only be produced from the microbial decay of organic matter within the thawing permafrost soils (microbial methane) but can also come from natural gas (thermogenic methane) trapped under or within the permafrost layer and released when it thaws. In the Taymyr Peninsula and surroundings in North Siberia, the area of the worldwide largest positive surface temperature anomaly for 2020, atmospheric methane concentrations have increased considerably during and after the 2020 heat wave. Two elongated areas of increased atmospheric methane concentration that appeared during summer coincide with two stripes of Paleozoic carbonates exposed at the southern and northern borders of the Yenisey-Khatanga Basin, a hydrocarbon-bearing sedimentary basin between the Siberian Craton to the south and the Taymyr Fold Belt to the north. Over the carbonates, soils are thin to nonexistent and wetlands are scarce. The maxima are thus unlikely to be caused by microbial methane from soils or wetlands. We suggest that gas hydrates in fractures and pockets of the carbonate rocks in the permafrost zone became unstable due to warming from the surface. This process may add unknown quantities of methane to the atmosphere in the near future.