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The amount of fly ash from the incineration of sewage sludge is increasing all over the world, and its utilization is becoming a serious environmental problem. In the study, a type of sewage sludge ash (SSA) collected directly from the municipal sewage treatment plant was used. Five levels of cement replacement (2.5%, 5%, 7.5%, 10% and 20%) and unchanged water-to-binder (w/b) ratio (0.55) were used. The purpose of the study was to evaluate the effect of sewage sludge ash (SSA) on the hydration heat process of cement mortars. The heat of the hydration of cement mortars was monitored by the isothermal calorimetric method for 7 days at 23 °C. The analysis of chemical composition and particle size distribution was performed on the tested material. The tests carried out have shown that SSA particles have irregular grain morphology and, taking into account the chemical composition consists mainly of oxides such as CaO, P2O5, SiO2 and Al2O3. The concentration of these compounds affects the hydration process of cement mortars doped with SSA. In turn, the content of selected heavy metals in the tested ash should not pose a threat to the environment. Calorimetric studies proved that the hydration process is influenced by the presence of SSA in cement mortars. The studies showed that the rate of heat generation decreased (especially in the initial setting period) with the increasing replacement of cement by SSA, which also reduced the amount of total heat compared to the control cement mortar. With increasing mass of the replacement of cement with SSA up to 20%, the 7-day compressive strength of the mortar samples decreases.

The rapid drop in internal temperature of mass concrete can readily lead to temperature cracks. Hydration heat inhibitors reduce the risk of concrete cracking by reducing the temperature during the hydration heating phase of cement-based material but may reduce the early strength of the cement-based material. Therefore, in this paper, the influence of commercially available hydration temperature rise inhibitors on concrete temperature rise is studied from the aspects of macroscopic performance and microstructure characteristics, and their mechanism of action is analyzed. A fixed mix ratio of 64% cement, 20% fly ash, 8% mineral powder and 8% magnesium oxide was used. The variable was different admixtures of hydration temperature rise inhibitors at 0%, 0.5%, 1.0% and 1.5% of the total cement-based materials. The results showed that the hydration temperature rise inhibitors significantly reduced the early compressive strength of concrete at 3 d, and the greater the amount of hydration temperature rise inhibitors, the more obvious the decrease in concrete strength. With the increase in age, the influence of hydration temperature rise inhibitor on the compressive strength of concrete gradually decreased, and the decrease in compressive strength at 7 d was less than that at 3 d. At 28 d, the compressive strength of the hydration temperature rise inhibitor was about 90% in the blank group. XRD and TG confirmed that hydration temperature rise inhibitors delay early hydration of cement. SEM showed that hydration temperature rise inhibitors delayed the hydration of Mg(OH)2.

This paper presents the results of research into the heat of hydration and activation energy of calcium sulphoaluminate (CSA) cement in terms of the dependence on curing temperature and water/cement ratio. Cement pastes with water/cement ratios in the range of 0.3–0.6 were tested by isothermal calorimetry at 20 °C, 35 °C and 50 °C, with the evolved hydration heat and its rate monitored for 168 h from mixing water with cement. Reference pastes with ordinary Portland cement (OPC) were also tested in the same range. The apparent activation energy of CSA and OPC was determined based on the results of the measurements. CSA pastes exhibited complex thermal behaviour that differed significantly from the thermal behaviour of ordinary Portland cement. The results show that both the w/c ratio and elevated temperature have a meaningful effect on the heat emission and the hydration process of CSA cement pastes. The determined apparent activation energy of CSA revealed its substantial variability and dependence, both on the w/c ratio and the curing temperature.

The deterioration of early-age concrete performance caused by SO42− internal diffusion in concrete is a critical factor of concrete durability. In this study, the mechanical properties, heat of hydration, and pore structure of early-age cast-in-situ concrete with different sodium sulfate (Na2SO4) concentrations were studied. The mechanism of SO42− internal corrosion was evaluated by measuring the dynamic elastic modulus, compressive strength, and heat of hydration rate. Scanning electron microscopy, energy dispersive spectroscopy, X-ray computed tomography, X-ray diffraction, thermogravimetry-derivative thermogravimetry, and differential scanning calorimetry were applied to analyze microstructural variations and complex mineral assemblages of concrete samples. The results indicated that during the hardening process of cast-in-situ concrete, Na2SO4 first promoted and then hindered the hydration rate of cement, and also hindered the early strength development of the cement. As the concentration of Na2SO4 solution increases, the corrosion products of ettringite (AFt) and gypsum (Gyp) gradually increase, causing cross cracks in the concrete. The proportion of small and medium pores first increases and then decreases, and the large pores first decrease and then increase. The mechanical properties of concrete gradually decrease and diminish the mechanical properties of the concrete (thereby accelerating the damage to the concrete).

The paper presents the results of a study on the hydration heat of ultralight cementitious foams envisaged as insulation materials for building envelopes. The examined porous foam-cement material was additionally enhanced by embedded microencapsulated phase change material (PCM) to improve the desired thermal properties of the material. The heat emission and heat flow were measured at 20 °C and 30 °C for 168 h using the isothermal calorimeter. The experimental study comprised composites with dry densities of 240 kg m −3 and 480 kg m −3 , two concentrations of protein-based foaming agent (2% and 4%) and two dosages of the embedded PCM material (10% and 20%). The reference composite without PCM was also tested. The effect of the necessary admixtures used to achieve the stability of ultralight cementitious foams was also examined. The results showed that hydration in ultralight foam-cement composites is retarded, and the values of heat released are lower than those of the paste used to produce the composites. In this regard, the main factors contributing to the lower heat released and its lower rate are the excess water from the foam, the dosage of the foaming agent and the admixtures introduced to achieve the stability of the ultralight composite. The stabiliser was found to be the most retarding admixture. Considering PCM, which was added at 10% and 20% of the paste volume, a rather low influence on the course of the hydration process was observed due to the overall composition of ultralight cementitious foams specially modified for each assumed content of PCM.

In the last decades, nano-silica (NS), nano-alumina (NA), and nano-calcium oxide (NC) particles have been incorporated into cementitious materials, and it seems that each one of them contributes uniquely to the materials’ properties. This research explores the influence of each nanomaterial on the fresh properties of cement pastes and their compressive strength evolution over one year. Low proportions (1.5% by weight) of nanomaterials were added to cement pastes, and their fresh properties, such as heat of hydration and X-ray diffraction patterns in the first hours, were analyzed. The compressive strength and open porosity were also measured long-term. The acceleration of hydration heat in NA-cement pastes is linked to enhanced hydration product formation at early ages. Among the tested nanomaterials, NA increased compressive strength by 10% at later ages. Although the fresh properties of NC-cement pastes remained unaffected, their open porosity decreased by 54% at 28 days. In contrast, the increase in heat of hydration in NS-cement pastes did not result in significant strength improvement. Based on these findings, NA was selected for ultra-high-performance cement (UHPC)-based material use. Its incorporation not only preserved the ultra-high-performance (UHP) properties but also provided additional benefits such as an increase in compressive strength under a CO2 atmosphere. Through detailed analysis, this research establishes that nano-alumina incorporation optimizes the microstructural development and compressive strength of ultra-high-performance cement-based systems, presenting a novel advancement in enhancing the mechanical properties and durability of these materials under various environmental conditions.

In this paper, recycled concrete powder (RCP) was used as a supplementary cementitious material (SCM) in an alkali-activation system. The contents of RCP in the cementitious materials were 0%, 10%, 20%, 30% and 40%, respectively. The fluidity, rheological properties and mechanical properties were tested, while the effects of RCP on the hydration properties of the alkali-activated system were studied by XRD, SEM-EDS, thermogravimetric analysis and the heat of hydration. The results show that the addition of RCP improves the fluidity of alkali-activated slag cementitious materials and changes the rheological index of paste. The change is greatest when the RCP content is 30%, which is 8.5% higher than that without RCP. With the increase in RCP content, the compressive strength of alkali-activated slag cementitious materials first increases and then decreases. The optimum compressive strength was attained with an RCP of 10%. The addition of RCP has little effect on the types of alkali-activated hydration products, but increases the quantity of hydration products. Further, the inactive particles in RCP combine with hydration products to form a dense microstructure. The addition of RCP reduces the early and total hydration heat of alkali-activated slag cementitious material, and delays the emergence of the second exothermic peak after the first peak.

In this study, a steam ejector is introduced before the reactor along the desorption flow path, and also a mechanical compression unit is used along the sorption vapor flow path in the reactor line path to pressurize the vapor in a conventional thermochemical heat storage (TCHS) system. The main goal was to increase the useful output heat and overall performance of the system relative to the conventional operating condition using anhydrous salts Al 2 (SO 4 ) 3 , NH 4 Al(SO 4 ) 2, and KAl(SO 4 ) 2 . The analysis was carried out using a mathematical model with respect to compression ratio, compression output temperature, and charging temperature. The analysis result shows that the useful output heat of hydration and coefficient of performance (COP) significantly increase when the compression ratio increases for all the materials used in this analysis. The useful output heat, or heat released during hydration, increased from 719.67 kJ to 822.33 kJ, 621.94 kJ–724.57 kJ, and 590.66 kJ–684.65 kJ for the hydrating of the materials Al 2 (SO 4 ) 3 , NH 4 Al(SO 4 ) 2 , and KAl(SO 4 ) 2, respectively. Similarly, the COP for hydration materials, Al 2 (SO 4 ) 3 , NH 4 Al(SO 4 ) 2 , and KAl(SO 4 ) 2 at the specified working conditions increased 14.26%, 16.501%, and 15.91%, respectively. However, the useful heat output linearly decreases with increasing charging temperature. The results show a significant improvement in hydration heat and total COP. Therefore, introducing an optimal compression pressurizing unit in a TCHS system can improve the performance of the system as well as conciliation with the heat demand of end users. The annual base‐levelized energy storage cost analysis showed that the system with compression units is more feasible than the system working without a vapor compression unit and mechanical compression equipment. The system working using Al 2 (SO 4 ) 3 , NH 4 Al(SO 4 ) 2 , and KAl(SO 4 ) 2 without compression units showed 14.28%, 22.48%, and 15.94% levelized storage cost (LCOS), respectively.

The effects of different contents of a MgO expansive agent and phosphorus slag on the mechanical properties, shrinkage behavior, and the heat of hydration of concrete were studied. The slump flow, setting time, dry shrinkage, and hydration heat were used as sensitive parameters to assess the response of the considered specimens. As shown by the results, in general, with an increase in the phosphorus slag content, the hydration heat of concrete decreases for all ages, but the early strength displays a downward trend and the dry shrinkage rate increases. The 90-d strength and dry shrinkage of concrete could be improved with a phosphorus residue content between 0%–20%, with the best performances in terms of mechanical properties and shrinkage characteristics being achieved for a content of 20 kg/m3. On the basis of these results, it can be concluded that appropriate amounts of phosphorus slag and MgO expansive agent can be used to improve the compressive strength of concrete in the later stage by reducing the hydration heat and dry shrinkage rate, respectively.

The behavior of long-span concrete-filled steel tube (CFST) arch bridges during the pouring stage is complex. The coupling effect of the time-varying hydration heat and the evolution of the elastic modulus is crucial for the linear control of the structure. Most of the existing models focus on static self-weight analysis but generally ignore the above-mentioned dynamic heat–force interaction, resulting in significant prediction deviations. In response to this limitation, this paper proposes an analysis method for the injection stage considering the time-varying heat of hydration and elastic modulus of concrete inside the pipe. Firstly, based on the composite index model of the hydration heat and through the reduction of the participating materials, the heat source function of the hydration heat of the arch rib was obtained, and its accuracy was verified by using two test components. Secondly, the equivalent application method of the hydration heat temperature field of the bar system model was proposed. Combined with the modified time-varying model of the elastic modulus at the initial age, the analysis method for the pouring stage of concrete-filled steel tube arch bridges was established. Finally, the accuracy of the proposed method was verified by analysis and calculation combined with engineering examples and comparison with the measured results. The results show that the time-varying heat of hydration and the time-varying elastic modulus during the concrete pouring stage inside the pipe can lead to residual deflection after the arch rib is poured. The calculated value of the example reaches 154 mm, while the influence of the lateral displacement is relatively small and recoverable. The proposed method improves the calculation accuracy by 44.19% compared with the traditional method, which is of great significance for the actual engineering construction control.