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12,859 result(s) for "Heavy elements"
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Origin of the heavy elements in binary neutron-star mergers from a gravitational-wave event
Modelling the electromagnetic emission of kilonovae enables the mass, velocity and composition (with some heavy elements) of the ejecta from a neutron-star merger to be derived from the observations. When neutron stars collide Merging neutron stars are potential sources of gravitational waves and have long been predicted to produce jets of material as part of a low-luminosity transient known as a 'kilonova'. There is growing evidence that neutron-star mergers also give rise to short, hard gamma-ray bursts. A group of papers in this issue report observations of a transient associated with the gravitational-wave event GW170817—a signature of two neutron stars merging and a gamma-ray flash—that was detected in August 2017. The observed gamma-ray, X-ray, optical and infrared radiation signatures support the predictions of an outflow of matter from double neutron-star mergers and present a clear origin for gamma-ray bursts. Previous predictions differ over whether the jet material would combine to form light or heavy elements. These papers now show that the early part of the outflow was associated with lighter elements whereas the later observations can be explained by heavier elements, the origins of which have been uncertain. However, one paper (by Stephen Smartt and colleagues) argues that only light elements are needed for the entire event. Additionally, Eleonora Troja and colleagues report X-ray observations and radio emissions that suggest that the 'kilonova' jet was observed off-axis, which could explain why gamma-ray-burst detections are seen as dim. The cosmic origin of elements heavier than iron has long been uncertain. Theoretical modelling 1 , 2 , 3 , 4 , 5 , 6 , 7 shows that the matter that is expelled in the violent merger of two neutron stars can assemble into heavy elements such as gold and platinum in a process known as rapid neutron capture (r-process) nucleosynthesis. The radioactive decay of isotopes of the heavy elements is predicted 8 , 9 , 10 , 11 , 12 to power a distinctive thermal glow (a ‘kilonova’). The discovery of an electromagnetic counterpart to the gravitational-wave source 13 GW170817 represents the first opportunity to detect and scrutinize a sample of freshly synthesized r-process elements 14 , 15 , 16 , 17 , 18 . Here we report models that predict the electromagnetic emission of kilonovae in detail and enable the mass, velocity and composition of ejecta to be derived from observations. We compare the models to the optical and infrared radiation associated with the GW170817 event to argue that the observed source is a kilonova. We infer the presence of two distinct components of ejecta, one composed primarily of light (atomic mass number less than 140) and one of heavy (atomic mass number greater than 140) r-process elements. The ejected mass and a merger rate inferred from GW170817 imply that such mergers are a dominant mode of r-process production in the Universe.
Heavy‐element damage seeding in proteins under XFEL illumination
Serial femtosecond X‐ray crystallography (SFX) captures the structure and dynamics of biological macromolecules at high spatial and temporal resolutions. The ultrashort pulse produced by an X‐ray free‐electron laser (XFEL) `outruns' much of the radiation damage that impairs conventional crystallography. However, the rapid onset of `electronic damage' due to ionization limits this benefit. Here, we distinguish the influence of different atomic species on the ionization of protein crystals by employing a plasma code that tracks the unbound electrons as a continuous energy distribution. The simulations show that trace quantities of heavy atoms (Z > 10) contribute a substantial proportion of global radiation damage by rapidly seeding electron ionization cascades. In a typical protein crystal, sulfur atoms and solvated salts induce a substantial fraction of light‐atom ionization. In further modeling of various targets, global ionization peaks at photon energies roughly 2 keV above inner‐shell absorption edges, where sub‐2 keV photoelectrons ejected from these shells initiate ionization cascades that are briefer than the XFEL pulse. These results indicate that relatively small quantities of heavy elements can substantially affect global radiation damage in XFEL experiments. Plasma simulations with detailed modeling of unbound electron dynamics predict that heavy elements contribute significantly to radiation damage suffered by proteins in serial femtosecond crystallography. New methods to mitigate radiation damage in this regime are highlighted.
Nucleosynthesis and observation of the heaviest elements
The rapid neutron capture or ‘ r process’ of nucleosynthesis is believed to be responsible for the production of approximately half the natural abundance of heavy elements found on the periodic table above iron (with proton number Z = 26 ) and all of the heavy elements above bismuth ( Z = 83 ). In the course of creating the actinides and potentially superheavies, the r process must necessarily synthesize superheavy nuclei (those with extreme proton numbers, neutron numbers or both) far from isotopes accessible in the laboratory. Many questions about this process remain unanswered, such as ‘where in nature may this process occur?’ and ‘what are the heaviest species created by this process?’ In this review, we survey at a high level the nuclear properties relevant for the heaviest elements thought to be created in the r process. We provide a synopsis of the production and destruction mechanisms of these heavy species, in particular the actinides and superheavies, and discuss these heavy elements in relation to the astrophysical r process. We review the observational evidence of actinides found in the Solar system and in metal-poor stars and comment on the prospective of observing heavy-element production in explosive astrophysical events. Finally, we discuss the possibility that future observations and laboratory experiments will provide new information in understanding the production of the heaviest elements.
Reduction of Thermal Conductivity for Icosahedral Al-Cu-Fe Quasicrystal through Heavy Element Substitution
Icosahedral Al-Cu-Fe quasicrystal (QC) shows moderate electrical conductivity and low thermal conductivity, and both p- and n-type conduction can be controlled by tuning the sample composition, making it potentially suited for thermoelectric materials. In this work, we investigated the effect of introducing chemical disorder through heavy element substitution on the thermal conductivity of Al-Cu-Fe QC. We substituted Au and Pt elements for Cu up to 3 at% in a composition of Al63Cu25Fe12, i.e., Al63Cu25−x(Au,Pt)xFe12 (x = 0, 1, 2, 3). The substitutions of Au and Pt for Cu reduced the phonon thermal conductivity at 300 K (κph,300K) by up to 17%. The reduction of κph,300K is attributed to a decrease in the specific heat and phonon relaxation time through heavy element substitution. We found that increasing the Pt content reduced the specific heat at high temperatures, which may be caused by the locked state of phasons. The observed glass-like low values of κph,300K (0.9–1.1 W m−1 K−1 at 300 K) for Al63Cu25−x(Au,Pt)xFe12 are close to the lower limit calculated using the Cahill model.
Production of Lithium and Heavy Elements in AGB Stars Experiencing PIEs
Asymptotic giant branch (AGB) stars can experience proton ingestion events (PIEs), leading to a rich nucleosynthesis. During a PIE, the intermediate neutron capture process (i-process) develops, leading to the production of trans-iron elements. It is also suggested that lithium is produced during these events. We investigate the production of lithium and trans-iron elements in AGB stars experiencing a PIE with 1
Biosorption to removing heavy metals from wastewater
In this research, the efficacy of walnuts shell as bio adsorbent surface has been evaluated in the process of heavy elements removing from aqueous solution. Heavy metals concentrations are determined using X-ray fluorescence (XRF) techniques in walnuts shell and using the atomic absorption spectrometer to determined heavy elements concentrations in wastewater from the southern Rustumiya station, as Chromium (Cr), Nikel (Ni), Zinc (Zn), Copper (Cu), Mercury (Hg), Cadmium (Cd) and Lead (Pb). XRF technique is a viable and precise for analyzing a variety of harm materials and environmental samples with different advantages compared with conventional laboratory analysis ways.
Spatial distribution of pollution characteristics and human health risk assessment of exposure to heavy elements in road dust from different functional areas of Zhengzhou, China
Road dust from different sources directly contacts the human body and has potential effects on public health. In this study, a total number of 87 road dust samples were collected at 29 sampling sites from five different functional areas (commercial area (CA), residential area (RA), educational area (EA), industrial area (IA), and park area (PA)) in Zhengzhou to study the contamination status, distribution, source identification, ecological risk assessment, and spatial distribution of human health risks due to eight heavy elements. The geo-accumulation index ( I geo ) and pollution index (PI) revealed that there was very high contamination with Cd and Hg caused by atmospheric deposition, which should be paid special attention. Additionally, the source identification indicated that Cr, Ni, Cu, Zn, Cd, and Pb originate from anthropogenic activities related to traffic, and Hg can originate from medical equipment and agricultural chemicals, while the extremely low level of pollution with As could be explained by geographic sources. Moreover, the calculated ecological risk index values were increased in the order of CA > RA > EA > IA > PA in different functional areas. According to the human health risks of the whole city, children exposed to Pb have the highest health risk, especially for CA and IA, as calculated by the noncarcinogenic hazard index (HI). For adults and children, health risks caused by Cu, Zn, and Pb were higher in the CA, RA, and PA of the downtown area, whereas Cr and Ni had the highest noncarcinogenic exposure risk in northwestern Zhengzhou due to point source pollution. Calculations of the carcinogenic risk (CR) values for Cr, Ni, As, and Cd indicate that the value of Cr is highest (1.17 × 10 −7 ), especially inside the industrial area (8.55 × 10 −7 ), which is close to the lower limit of the threshold values (10 −6 to 10 −4 ). These results can provide a theoretical basis and data support for air treatment, pollution control, and the implementation of public prevention in different functional areas of Zhengzhou.
Assessment the Heavy elements in Policemen's Serum using FAAS
Determination of lead, cadmium and nickel concentrations in serum samples (n=50), collected from policemen at difference checkpoint in Karbala governorate, was carried out by flam atomic absorption spectrometer. The results show, that the Pb, Cd and Ni mean value were (1.016±0.052)ppb, (0.043±0.007)ppb and (0.212±0.015)ppb respectively. The result also show that the mean values of heavy elements in serum samples were higher in policemen group when compared to control group, where the statistically significantly difference (p<0.05), except for Ni were statistically non- significantly difference (p>0.05).
Swope Supernova Survey 2017a (SSS17a), the optical counterpart to a gravitational wave source
On 17 August 2017, the Laser Interferometer Gravitational-Wave Observatory (LIGO) and the Virgo interferometer detected gravitational waves (GWs) emanating from a binary neutron star merger, GW170817. Nearly simultaneously, the Fermi and INTEGRAL (INTErnational Gamma-Ray Astrophysics Laboratory) telescopes detected a gamma-ray transient, GRB 170817A. At 10.9 hours after the GW trigger, we discovered a transient and fading optical source, Swope Supernova Survey 2017a (SSS17a), coincident with GW170817. SSS17a is located in NGC 4993, an S0 galaxy at a distance of 40 megaparsecs. The precise location of GW170817 provides an opportunity to probe the nature of these cataclysmic events by combining electromagnetic and GW observations.