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17,357 result(s) for "Kinetic theory"
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Self-assembly coupled to liquid-liquid phase separation
Liquid condensate droplets with distinct compositions of proteins and nucleic acids are widespread in biological cells. While it is known that such droplets, or compartments, can regulate irreversible protein aggregation, their effect on reversible self-assembly remains largely unexplored. In this article, we use kinetic theory and solution thermodynamics to investigate the effect of liquid-liquid phase separation on the reversible self-assembly of structures with well-defined sizes and architectures. We find that, when assembling subunits preferentially partition into liquid compartments, robustness against kinetic traps and maximum achievable assembly rates can be significantly increased. In particular, both the range of solution conditions leading to productive assembly and the corresponding assembly rates can increase by orders of magnitude. We analyze the rate equation predictions using simple scaling estimates to identify effects of liquid-liquid phase separation as a function of relevant control parameters. These results may elucidate self-assembly processes that underlie normal cellular functions or pathogenesis, and suggest strategies for designing efficient bottom-up assembly for nanomaterials applications.
Casimir effect in kinetic theory
We study Casimir effect in equilibrium and non-equilibrium photon gas in the frame of quantum kinetic theory for U (1) gauge field. We derive first the transport, constraint and gauge fixing equations for the photon number distribution from Maxwell’s equations, and then calculate the energy variation and Casimir force for a finite system by considering boundary condition on the surface of the system. The Casimir force in vacuum is suppressed by the thermal motion of photons in equilibrium state, when considering two adiabatic plates. In non-equilibrium state, the photon induced Casimir force oscillates and decays with time and finally disappears.
Clustering instabilities in sedimenting fluid–solid systems: critical assessment of kinetic-theory-based predictions using direct numerical simulation data
In this work the quantitative and qualitative ability of a kinetic-theory-based two-fluid model (KT-TFM) is assessed in a state of fully periodic sedimentation (fluidization), with a focus on statistically steady, unstable (clustered) states. The accuracy of KT-TFM predictions is evaluated via direct comparison to direct numerical simulation (DNS) data. The KT-TFM and DNS results span a rather wide parameter space: mean-flow Reynolds numbers on the order of 1 and 10, mean solid volume fractions from 0.1 to 0.4, solid-to-fluid density ratios from 10 to 1000 and elastic and moderately inelastic (restitution coefficient of 0.9) conditions. Data from both KT-TFM and DNS display a rich variety of statistically steady yet unstable structures (clusters). Instantaneous snapshots of KT-TFM and DNS demonstrate remarkable qualitative agreement. This qualitative agreement is quantified by calculating the critical density ratio at which the structure transitions from a chaotic, dynamic state to a regular, plug-flow state, with good overall comparisons. Further quantitative assessments of mean and fluctuating velocities show good agreement at high density ratios but weaker agreement at intermediate to low density ratios depending on the mean-flow Reynolds numbers and solid fractions. Deviations of the KT-TFM results from the DNS data were traced to a breakdown in one of the underlying assumptions of the kinetic theory derivation: high thermal Stokes number. Surprisingly, however, even though the low Knudsen number assumption, also associated with the kinetic theory derivation, is violated throughout most of the parameter space, it does not seem to affect the good quantitative accuracy of KT-TFM simulations.
Microscopic Foundations of Kinetic Plasma Theory: The Relativistic Vlasov–Maxwell Equations and Their Radiation-Reaction-Corrected Generalization
It is argued that the relativistic Vlasov–Maxwell equations of the kinetic theory of plasma approximately describe a relativistic system of N charged point particles interacting with the electromagnetic Maxwell fields in a Bopp–Landé–Thomas–Podolsky (BLTP) vacuum, provided the microscopic dynamics lasts long enough. The purpose of this work is not to supply an entirely rigorous vindication, but to lay down a conceptual road map for the microscopic foundations of the kinetic theory of special-relativistic plasma, and to emphasize that a rigorous derivation seems feasible. Rather than working with a BBGKY-type hierarchy of n -point marginal probability measures, the approach proposed in this paper works with the distributional PDE of the actual empirical 1-point measure, which involves the actual empirical 2-point measure in a convolution term. The approximation of the empirical 1-point measure by a continuum density, and of the empirical 2-point measure by a (tensor) product of this continuum density with itself, yields a finite- N Vlasov-like set of kinetic equations which includes radiation-reaction and nontrivial finite- N corrections to the Vlasov–Maxwell–BLTP model. The finite- N corrections formally vanish in a mathematical scaling limit N → ∞ in which charges ∝ 1 / √ N . The radiation-reaction term vanishes in this limit, too. The subsequent formal limit sending Bopp’s parameter ϰ → ∞ yields the Vlasov–Maxwell model.
Propagation Speeds of Relativistic Conformal Particles from a Generalized Relaxation Time Approximation
The propagation speeds of excitations are a crucial input in the modeling of interacting systems of particles. In this paper, we assume the microscopic physics is described by a kinetic theory for massless particles, which is approximated by a generalized relaxation time approximation (RTA) where the relaxation time depends on the energy of the particles involved. We seek a solution of the kinetic equation by assuming a parameterized one-particle distribution function (1-pdf) which generalizes the Chapman–Enskog (Ch-En) solution to the RTA. If developed to all orders, this would yield an asymptotic solution to the kinetic equation; we restrict ourselves to an approximate solution by truncating the Ch-En series to the second order. Our generalized Ch-En solution contains undetermined space-time-dependent parameters, and we derive a set of dynamical equations for them by applying the moments method. We check that these dynamical equations lead to energy–momentum conservation and positive entropy production. Finally, we compute the propagation speeds for fluctuations away from equilibrium from the linearized form of the dynamical equations. Considering relaxation times of the form τ=τ0(−βμpμ)−a, with −∞
Inversion of the transverse force on a spinning sphere moving in a rarefied gas
The flow around a spinning sphere moving in a rarefied gas is considered in the following situation: (i) the translational velocity of the sphere is small (i.e. the Mach number is small); (ii) the Knudsen number, the ratio of the molecular mean free path to the sphere radius, is of the order of unity (the case with small Knudsen numbers is also discussed); and (iii) the ratio between the equatorial surface velocity and the translational velocity of the sphere is of the order of unity. The behaviour of the gas, particularly the transverse force acting on the sphere, is investigated through an asymptotic analysis of the Boltzmann equation for small Mach numbers. It is shown that the transverse force is expressed as $\\boldsymbol{F}_L = {\\rm \\pi}\\rho a^3 (\\boldsymbol{\\varOmega} \\times \\boldsymbol{v}) \\bar{h}_L$, where $\\rho$ is the density of the surrounding gas, a is the radius of the sphere, $\\boldsymbol {\\varOmega }$ is its angular velocity, $\\boldsymbol {v}$ is its velocity and $\\bar {h}_L$ is a numerical factor that depends on the Knudsen number. Then, $\\bar {h}_L$ is obtained numerically based on the Bhatnagar–Gross–Krook model of the Boltzmann equation for a wide range of Knudsen number. It is shown that $\\bar {h}_L$ varies with the Knudsen number monotonically from 1 (the continuum limit) to $-\\tfrac {2}{3}$ (the free molecular limit), vanishing at an intermediate Knudsen number. The present analysis is intended to clarify the transition of the transverse force, which is previously known to have different signs in the continuum and the free molecular limits.
Static and dynamic contact angle measurements using a custom-made contact angle goniometer
Contact angle is a physical quantity used to evaluate the interaction between a solid surface and a liquid. However, many research laboratories or educational institutions with budget constraints have limited access to a commercial contact-angle goniometer with a high-resolution imaging system. In this study, we fabricated a custom-made contact angle goniometer with a smartphone and quantified the contact angles of water on various surfaces. We found that the receding contact angles on the surfaces were sensitive to the change in flow rates. The receding angle sharply decreases when the flow rate exceeds 50 µl/min, indicating that accurate flow control is required in contact angle measurements. The dynamic contact angles could also be quantified by the developed goniometer in an extremely low-capillary number regime. The dynamic advancing and receding contact angles on tested surfaces followed the molecular-kinetic theory.
Computation of flow rates in rarefied gas flow through circular tubes via machine learning techniques
Kinetic theory and modeling have been proven extremely suitable in computing the flow rates in rarefied gas pipe flows, but they are computationally expensive and more importantly not practical in design and optimization of micro- and vacuum systems. In an effort to reduce the computational cost and improve accessibility when dealing with such systems, two efficient methods are employed by leveraging machine learning (ML). More specifically, random forest regression (RFR) and symbolic regression (SR) have been adopted, suggesting a framework capable of extracting numerical predictions and analytical equations, respectively, exclusively derived from data. The database of the reduced flow rates W used in the current ML framework has been obtained using kinetic modeling and it refers to nonlinear flows through circular tubes (tube length over radius l∈[0,5] and downstream over upstream pressure p∈[0,0.9]) in a very wide range of the gas rarefaction parameter δ∈[0,103]. The accuracy of both RFR and SR models is assessed using statistical metrics, as well as the relative error between the ML predictions and the kinetic database. The predictions obtained by RFR show very good fit on the simulation data, having a maximum absolute relative error of less than 12.5%. Various expressions of the form of W=W(p,l,δ) with different accuracy and complexity are acquired from SR. The proposed equation, valid in the whole range of the relevant parameters, exhibits a maximum absolute relative error less than 17%. To further improve the accuracy, the dataset is divided into three subsets in terms of δ and one SR-based closed-form expression of each subset is proposed, achieving a maximum absolute relative error smaller than 9%. Very good performance of all proposed equations is observed, as indicated by the obtained accuracy measures. Overall, the present ML-predicted data may be very useful in gaseous microfluidics and vacuum technology for engineering purposes.
Kinetic Theory with Casimir Invariants—Toward Understanding of Self-Organization by Topological Constraints
A topological constraint, characterized by the Casimir invariant, imparts non-trivial structures in a complex system. We construct a kinetic theory in a constrained phase space (infinite-dimensional function space of macroscopic fields), and characterize a self-organized structure as a thermal equilibrium on a leaf of foliated phase space. By introducing a model of a grand canonical ensemble, the Casimir invariant is interpreted as the number of topological particles.
Generalized kinetic theory of coarse-grained systems. I. Partial equilibrium and Markov approximations
The general kinetic theory of coarse-grained systems is presented in the abstract formalism of communication theory developed by Shannon and Weaver, Khinchin and Kolmogorov. The martingale theory shows that, under reasonable, general hypotheses, coarse-grained systems can be approximated by generalized Markov systems. For mixing systems, the Kolmogorov entropy production can be defined for nonstationary processes as Kolmogorov defined it for stationary processes.