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Bioenergy deployment offers significant potential for climate change mitigation, but also carries considerable risks. In this review, we bring together perspectives of various communities involved in the research and regulation of bioenergy deployment in the context of climate change mitigation: Land‐use and energy experts, land‐use and integrated assessment modelers, human geographers, ecosystem researchers, climate scientists and two different strands of life‐cycle assessment experts. We summarize technological options, outline the state‐of‐the‐art knowledge on various climate effects, provide an update on estimates of technical resource potential and comprehensively identify sustainability effects. Cellulosic feedstocks, increased end‐use efficiency, improved land carbon‐stock management and residue use, and, when fully developed, BECCS appear as the most promising options, depending on development costs, implementation, learning, and risk management. Combined heat and power, efficient biomass cookstoves and small‐scale power generation for rural areas can help to promote energy access and sustainable development, along with reduced emissions. We estimate the sustainable technical potential as up to 100 EJ: high agreement; 100–300 EJ: medium agreement; above 300 EJ: low agreement. Stabilization scenarios indicate that bioenergy may supply from 10 to 245 EJ yr−1 to global primary energy supply by 2050. Models indicate that, if technological and governance preconditions are met, large‐scale deployment (>200 EJ), together with BECCS, could help to keep global warming below 2° degrees of preindustrial levels; but such high deployment of land‐intensive bioenergy feedstocks could also lead to detrimental climate effects, negatively impact ecosystems, biodiversity and livelihoods. The integration of bioenergy systems into agriculture and forest landscapes can improve land and water use efficiency and help address concerns about environmental impacts. We conclude that the high variability in pathways, uncertainties in technological development and ambiguity in political decision render forecasts on deployment levels and climate effects very difficult. However, uncertainty about projections should not preclude pursuing beneficial bioenergy options.

Sustainability has been recognized as a major concern globally since the Brudtland Report, in 1987, and further reinforced in 2015 by the United Nations Sustainable Development Goals (UNSDG) 2030. This paper reviews the methodologies and criteria of sustainability applied to fashion products, regarding products’ environmental footprint (environmental life cycle assessment/analysis; e-LCA), the social issues (including the social life cycle assessment/analysis; s-LCA) and the transparency in reporting sustainability. In our review we seek KPIs (key performance indicators) that allow classification of a pair of shoes or a piece of cloth on a scale from A to E, i.e., products can be compared with a benchmark and classified accordingly with a simple labelling scheme, which is easily understandable by the consumers. This approach is similar to those used to classify electrical appliances, housing energy consumption for thermal comfort, food Nutri-Scores, CO2 levels of road vehicles, and tire performance. In this review we aim to identify the initiatives and measures being put into practice by the top global fashion brands. We found that, despite the existence of GRI (global sustainability reporting initiative) standard reporting, most companies follow their own methods or others created within the industry rather than those created in the scientific community. Examples include the Higg index, the Transparency Index, and the Social Codes of Conduct (CoC). In this study, we conducted an extensive review of certification schemes and labels already applied to fashion products, and identified a multitude of labels and lack of harmonization in communicating sustainability. As result, we compiled a summary table of all criteria, methodologies, and possible KPIs that can be considered the basis for a benchmark and score of a fashion product. This topic is crucial to avoid “green washing” and a lack of transparency for the buyer’s community, i.e., business to consumer (B2C), and for the business community, i.e., business to business (B2B) relationships, which comprise a complex multi-layer supply chain of suppliers and sub-suppliers. The UNSDG 2030 “Responsible Consumption and Production” frames these efforts to facilitate standardization of KPIs in terms of structure, criteria, and their measurement. The most common KPI is environmental global warming impact (expressed as CO2eq) based on life cycle assessment/analysis (LCA) principles (established in 2000), which provide an appropriate base to monitor and benchmark products. However, in our innovative review of t-shirt e-LCA, we identified a wide range of e-LCA assumptions, relating to different boundaries, allocations, functional units, and impact categories, which represent a major challenge in benchmarking.

PurposeWith a contribution of 39% to greenhouse gas (GHG) emissions, reducing the environmental impacts of buildings plays an undisputed role in achieving climate goals. Therefore, the development of projects with a low carbon footprint is of crucial importance. Although several active and passive solutions as well as design strategies have been developed, identifying critical levers to minimise GHG emissions and the cost of future building projects is still a problem faced every day by designers.MethodsMotivated by this knowledge gap in this study, we conducted a life cycle assessment (LCA) and life cycle cost analysis (LCCA) of a residential building situated in Austria. To identify the critical levers for reducing impacts and cost, 37 scenarios with three different advanced energetic standards are created. The scenarios with the various standards are developed through the combination of different construction materials, insulation materials and technical building equipment. In the eco-efficiency assessment (LCA and LCCA), a reference study period of 50 years is assumed. The life cycle of the building scenarios was analysed according to the European standard EN-15978.ResultsResults show that improving the energetic standard does not yield an overall cost savings potential. The additional construction cost (23%) for energy efficiency measures, including thermal insulation and change of technical building equipment, is higher than the reduction potential in operating cost over 50 years. On the other hand, the improvement of energetic standards allows a reduction of the environmental impacts by 25%.ConclusionsTo ensure a cost-optimal environmental improvement of buildings, it is crucial to conduct an eco-efficiency assessment during the design process of energy-efficient buildings. This study shows how improving the energetic standard of buildings can reduce environmental impacts with slightly increased life cycle cost.

Silver particles (AgPs) are increasingly used across a range of industries, including personal care, household, and food packaging, but conventional synthesis methods involve high production costs and negative environmental impacts. Green synthesis using plant extracts offers a sustainable alternative, though limited comparative data on economic and environmental performance exist. This study evaluates three green methods—BX3 (a patented extract), lemon juice (LJ), and green tea (GT)—against a conventional method using sodium borohydride (NaBH₄). Equal‐volume reactions are analyzed via ICP‐MS, UV–vis spectroscopy, and dynamic light scattering. Techno‐economic analysis and life cycle assessment (LCA) assessed costs and environmental impact. BX3 emerged as the most cost‐effective and environmentally friendly option, producing AgPs at$13,000/kg with a 75% yield and a global warming potential of 1,900 kg CO₂‐Eq/kg. In contrast, NaBH₄ yielded 7.35% at $ 195,000/kg, 15x more expensive than the BX3 method, and a global warming potential of 74,000 kg CO₂‐Eq/kg. GT, while a green method, has the highest cost $690,000/kg, the lowest yield (1.13%), and the worst environmental impact, including a human toxicity value of 92,000 kg 1,4‐DCB‐Eq/kg‐even surpassing the toxic NaBH₄ process. These findings highlight BX3's promise for scalable, low‐impact AgP production and broader industrial use. With increasing interest in colloidal silver for applications in healthcare, cosmetics, and pharmaceuticals, information on their synthesis methods and associated economic and environmental impacts remains limited. This study examines various green synthesis approaches, conducting a techno‐economic analysis and life‐cycle assessment, and compares them to conventional chemical synthesis to assess their implications for future colloidal silver production.

Sorghum is a major cereal crop in the USA. However, sorghum has been underutilized as a renewable feedstock for bioenergy. The goal of this research was to improve the bioconversion efficiency for biofuels and biobased products from processed sorghum. The main focus was to understand the relationship among “genetics-structure-function-conversion” and the key factors impacting ethanol production, as well as to develop an energy life cycle analysis model (ELCAM) to quantify and prioritize the saving potential from factors identified in this research. Genetic lines with extremely high and low ethanol fermentation efficiency and some specific attributes that may be manipulated to improve the bioconversion rate of sorghum were identified. In general, ethanol yield increased as starch content increased. However, no linear relationship between starch content and fermentation efficiency was found. Key factors affecting the ethanol fermentation efficiency of sorghum include protein digestibility, level of extractable proteins, protein and starch interaction, mash viscosity, amount of phenolic compounds, ratio of amylose to amylopectin, and formation of amylose-lipid complexes in the mash. A platform ELCAM with a base case showed a positive net energy value (NEV) = 25,500 Btu/gal EtOH. ELCAM cases were used to identify factors that most impact sorghum use. For example, a yield increase of 40 bu/ac resulted in NEV increasing from 7 million to 12 million Btu/ac. An 8% increase in starch provided an incremental 1.2 million Btu/ac.

Purpose Buildings are responsible for more than 40 % of global energy used, and as much as 30 % of global greenhouse gas emissions. In order to quantify the energy and material inputs and environmental releases associated with each stage of construction sector, life cycle energy, greenhouse gas emissions, and cost analysis of contemporary residential buildings have been conducted within two parts. Methods This paper is the first part of the study which includes the literature review and methodology used for such a comprehensive analysis. It was determined that there are three basic methods used in life cycle analysis: process analysis, input–output (I–O) analysis, and hybrid analysis. In this study, Inventory of Carbon and Energy (ICE) is used for the calculation of primary energy requirements and greenhouse gas emissions. The second part of this study is about the application of the methodology which considers two actual buildings constructed in Gaziantep, Turkey. Results and discussion The proposed research focused on building construction, operating, and demolition phases. Energy efficiency, emission parameters, and costs are defined for the building per square meter basis. It is seen that the primary energy use and emissions of residential buildings around the world falls in the range of about 10 to 40 GJ/m 2 and 1–10 t CO 2 /m 2 respectively. Conclusions The literature survey demonstrates that there are limited number of studies about life cycle cost assessment (LCCA) of residential buildings in the world. It was decided to use the ICE database as it is one of the most comprehensive databases for building materials, globally. The results of the study show that minimizing energy, material, and land use by considering potential impacts to the environment on a life cycle basis are the basic steps in designing an energy-efficient and environmental-friendly building.

PurposeIn social life cycle assessment (S-LCA), we can distinguish two main types of impact assessment (LCIA): type I can be seen as a reporting approach with the use of performance reference points and type II aims at including cause-effect chains or impact pathways in the analysis. Given the heterogeneity of those type II approaches, this review provides a classification of existing type II approaches.MethodsWe reviewed a total of 28 articles against the background of their main purpose, the method used, the issues covered and the origin of data (observation/characterization/ measurement). We checked the articles against (i) the reflection of an impact pathway, (ii) the availability of so-called inventory and impact indicators, and (iii) the presence of characterization models or factors translating correlations or causality.Results and discussionThe analysis reveals three main paths to include impact pathways in S-LCA, which differ in authors’ intentions: (1) some studies identify and propose variables composing impact pathways, or frameworks gathering several pathways; (2) other studies investigate or test known pathways empirically, and until now seek mainly to link income data with health impacts at a macro scale, and (3) a last batch applies known and already quantified characterization models or factors from other research works in case studies. Until now, these case studies focus mainly on income-related social effects or on health impacts. Further, each path is further characterized and classified under nine approaches. Our findings highlight not only the heterogeneous nature of approaches, but also their common denominator which is to not consider phenomena or impacts in isolation but to consider them in relation to their sources or further impacts. It should be noted that type II studies are not only limited to quantitative approaches and variables, but can also use more qualitative variables and methods.ConclusionsThe presented classification may be used as a guidance tool for authors to make their methodological choices. Also, our findings indicate the opportunity of extending future type II S-LCA research to variables tackled in type I studies (e.g., safe and fair employment and working conditions), beyond pathways including incomes and health impacts. This can be done by using theories from social sciences for the identification of impact pathways. Those could then further be investigated through statistical approaches or in the framework of S-LCA case studies, with specific data and potentially more qualitative methods to analyze causality or social mechanisms.

Purpose Residential buildings play an important role in consumption of energy resources. About 40 % of all primary energy is used in buildings all over the world. This paper is the second part of the study on the life-cycle energy (LCEA), emissions (LCCO 2 A) and cost (LCCA) assessment of two residential buildings constructed in urban and rural areas. Methods In the first part, the methodology, formulations and procedure for such a comprehensive analysis are provided, while this paper provides an application of the methodology that considers two actual buildings located in Gaziantep, Turkey. The proposed model focused on building construction, operation and demolition phases to estimate energy use, carbon emissions and costs per square meter over a 50-year lifespan. The optimum thickness of insulation used to reduce energy consumption and emissions per square meter is determined. Results and discussion It is found that the operating phase is dominant in both urban and rural residential buildings and contributes 87–85 % of the primary energy requirements and 88–82 % of CO 2 emissions, respectively. Life-cycle greenhouse gas emissions were 5.8 and 3.9 tons CO 2 eqv. for BT1 and BT2, respectively. It is calculated that the life-cycle energy consumption and CO 2 emissions of the residential buildings can be reduced by up to 22.8 and 23.4 %, respectively, by using a proper insulation material for the external walls. The life-cycle cost, consisting of mortgage, energy, maintenance, service and demolition payments are calculated to be 7.28 and 1.72 million USD for BT1 and BT2, respectively. Conclusions Building envelope developments, such as better wall insulation, provide noteworthy potential energy savings and contribute to the reductions from cooling and space heating. Therefore, primary strategies and technologies needed for efficient buildings include optimal insulation of external walls. The economic insulation thickness of the residential buildings in Gaziantep is determined to be 80 mm by using a life-cycle cost analysis. The results show that because of the differences in building structures and living standards, life-cycle energy intensity and CO 2 emissions in urban residential buildings are 29 and 25 % higher than in rural conditions.

Lignocellulosic biomass offers a renewable carbon source which can be anaerobically digested to produce short-chain carboxylic acids. Here, we assess fuel properties of oxygenates accessible from catalytic upgrading of these acids a priori for their potential to serve as diesel bioblendstocks. Ethers derived from C₂ and C₄ carboxylic acids are identified as advantaged fuel candidates with significantly improved ignition quality (>56% cetane number increase) and reduced sooting (>86% yield sooting index reduction) when compared to commercial petrodiesel. The prescreening process informed conversion pathway selection toward a C11 branched ether, 4-butoxyheptane, which showed promise for fuel performance and health- and safety-related attributes. A continuous, solvent-free production process was then developed using metal oxide acidic catalysts to provide improved thermal stability, water tolerance, and yields. Liter-scale production of 4-butoxyheptane enabled fuel property testing to confirm predicted fuel properties, while incorporation into petrodiesel at 20 vol % demonstrated 10% improvement in ignition quality and 20% reduction in intrinsic sooting tendency. Storage stability of the pure bioblendstock and 20 vol % blend was confirmed with a common fuel antioxidant, as was compatibility with elastomeric components within existing engine and fueling infrastructure. Technoeconomic analysis of the conversion process identified major cost drivers to guide further research and development. Life-cycle analysis determined the potential to reduce greenhouse gas emissions by 50 to 271% relative to petrodiesel, depending on treatment of coproducts.

Small and medium enterprises and research institutes engaged on eco-innovative research projects are often required to account for environmental benefits of new products, processes, or services. This article describes an environmental assessment methodology for calculating auditable environmental benefits, highlighting case studies as examples. It addresses the challenges involved in conducting assessments of products that have yet to be commercialized by taking into account the quality and confidence of the data and enabling nonexperts to engage with the process to a well-informed level. The method draws on the most pertinent and accessible information to develop a reliable overview of the reportable outputs while minimizing the resource and expertise required by measuring only the change in circumstance. The process is flexible enough to cater to projects from a range of sectors, with different expertise levels, but in-depth enough to be considered an acceptable quantification of environmental outputs by rigid external reporting requirements.