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Obtaining of TiO2 nanotubes could be performed by anodized Ti in fluoride based electrolyte. During the growth of TiO2 nanotubes within the influence of anodizing process of Ti, a certain parameters are required, electrolyte composition, voltage, and time. The TiO2 nanotube array was synthesized electrochemically in a fluoride containing electrolyte by anodisation method of a pure titanium plate. The anodisation procedure was carried out in ethylene glycol electrolyte; the applied voltage was 60 volt. The average inner diameter of the nanotube was (67 nm) and the average outer diameter was (80 nm). Characterization of the nanotubes crystal structure, morphology, and oxide composition were performed via field emission scanning electron microscopy (FE-SEM) and energy dispersion spectroscopy (EDS). Elemental analysis by EDS shows the presence of fluoride, and confirm the formation of TiO2 nanotubes. The results show the possibility of study the distribution of the composition of the tubes elements using the scanning electron microscope-mapping. Synthesized TiO2 nanotubes were applied for the degradation of organic dye methylene blue as water dye pollutant. It is found that rate of degradation of MB in presence of TiO2 nanotubes was greater than in case of degradation without TiO2 nanotubes. It is clear that the main reason for this behavior belongs to the high surface area of TiO2 nanotubes. For (5) ppm of methylene blue, the degradation in presence of TiO2 nanotubes has done completely after (5 hours)

Abstract Objective: The use of methylene blue dye (MB) to highlight anatomical structures in urology has been well-established. Urethral stricture may extend about a centimeter beyond the abnormal area seen on urethrogram. Although the current literature suggests a tension-free and end- to- end anastomosis after excision of the strictured urethral segment with spongiofibrosis and surrounding corpus spongiosum in short bulbar strictures, some centers dealing with urethroplasty prefer anastomosis for short bulbar strictures while others prefer augmentation. With this study, use of MB for delineating stricture line and assessing spongiofibrosis in the diagnosis of urethral stricture was evaluated.   Material and methods: Five cc MB including 10 mg/mL is diluted with 10 cc saline. In the first scenario, MB is gently injected into urethra via the meatus before the urethroplasty procedure. Meanwhile, the extent of urethral segment stained by MB is noted. In the second scenario (MB spongiosography) in short bulbar stricture, insulin needles are inserted in spongiosa of the stricture site distally and proximally. MB is gently injected with distal needle. The two remaining needles are then observed. Presence of MB efflux in proximal needle implies deficiency of significant spongiofibrosis, so buccal augmentation is performed. Absence of efflux of MB implies significant spongiofibrosis and anastomotik site excised.   Results: Four hundred and ninety-two consecutive cases prospectively evaluated between 2010 and 2014. Precise staining of stricture was successfully observed in 464 (94%) patients. Grossly normal appearing urothelium remained pink. Histopathology confirmed that the stained urethra had a stricture. Of the 22 short bulbar idiopathic strictures, in 18 (82%) MB was seen across the stricture and urethral transection was avoided. Anastomosis was performed in 4 (18%) cases where no MB went across the primary excision. There were no known allergic complications.   Conclusion: MB aids in delineating the urethral lumen and exact site of stricture that needs augmentation. MB Spongiography in short bulbar strictures could be used as a beneficial guide in relation to the type of urethral repair to be performed in terms of augmentation versus excision and anastomosis.     Cite this article as: Joshi P, Kaya C, Surana S, Desai DJ, Orabi H, Iyer S, et al. A novel method in decision making of anterior urethral stricture diagnosis: Using methylene blue dye. Turk J Urol 2017; 43(4): 502-6.

Hydrogel from corncob cellulose was synthesized in this investigation. The synthesized Hydrogel was characterized by SEM, XRD, and FTIR instruments. As the results indicate the synthesized hydrogel has required and important features, these suggest the suitability of hydrogel for the adsorption of methylene blue dye (MBD). Three important process variables (dosage, contact time, and initial concentration) with three levels were studied during the adsorption process at 30 °C and neutral pH. The efficiency of hydrogel for adsorption of MBD was determined in each experiment. The experimental results were statistically analyzed and interpreted. The maximum removal efficiency was achieved at 2.22 g/L of dosage, 80.36 min of contact time, and 74.54 mg/L of initial concentration. At this condition, 98.25% of MBD was achieved through experimental tests. Kinetics, isotherm, and thermodynamics studies were performed. Langmuir isotherm is more suitable to describe the adsorption process and the Pseudo second-order kinetic model fits this process. From the thermodynamics studies, all negative values of change in Gibbs free energy (ΔG°), and positive value of change in enthalpy (ΔH°), and change in entropy (ΔS°) indicate that the carried out experimental process is a spontaneous and endothermic. Moreover, the regeneration experiment for adsorbent was performed. The treatment of real textile industry waste water was conducted and the removal efficiency of hydrogel was 64.76%. This removal percentage reduction from sythetic aqueous solution is due to involvement of other pollutants in the real waste water. The synthesized hydrogel adsorbent is suitable up to the third cycle without significant loss in removal efficiency.

This article presents a one-step ultrasonication technique for generating biomass carbon dots (BCDs) from neem bark (Azadirachta indica) powder. The BCDs were characterized using modern techniques such as UV–Vis, FTIR, Raman, XRD, HRTEM, FESEM, EDAX, and Zeta potential analyses. Unlike traditional nanocomposite bed systems, this study utilized BCDs as a liquid-phase adsorbent for the regenerative adsorption of the environmentally harmful dye, methylene blue (MB), through an in-situ precipitation reaction. This involved the formation of BCDs-MB adduct via an electrostatic mechanism. The adsorption capacity and percentage of removal were remarkable at 605 mg g –1 and 64.7% respectively, exceeding various solid-based adsorption methods in the literature. The Langmuir isotherm and pseudo-second-order kinetics model provided an excellent fit for this system. The calculated thermodynamic parameter, Gibbs free energy change (ΔG) was negative, indicating a spontaneous, exothermic, and physisorption-based mechanism. The regenerative capacity of our system was further demonstrated by successfully extracting and recovering the MB dye (64%) using ethyl alcohol as the solvent. This method provides an efficient means of recovering valuable cationic organic dye compounds from contaminated environments.

Biological and green synthesis of nanomaterial is a superior choice over chemical and physical methods due to nanoscale attributes implanted in a green chemistry matrix, have sparked a lot of interest for their potential uses in a variety of sectors. This research investigates the growing relevance of nanocomposites manufactured using ecologically friendly, green technologies. The transition to green synthesis correlates with the worldwide drive for environmentally sound procedures, limiting the use of traditional harsh synthetic techniques. Herein, manganese was decorated on ZnO NPs via reducing agent of Withania- extract and confirmed by UV-spectrophotometry with highest peak at 1:2 ratio precursors, and having lower bandgap energy (3.3 eV). XRD showed the sharp peaks and confirms the formation of nanoparticles, having particle size in range of 11–14 nm. SEM confirmed amorphous tetragonal structure while EDX spectroscopy showed the presence of Zn and Mn in all composition. Green synthesized Mn-decorated ZnO-NPs screened against bacterial strains and exhibited excellent antimicrobial activities against gram-negative and gram-positive bacteria. To check further, applicability of synthesized Mn-decorated Zn nanocomposites, their photocatalytic activity against toxic water pollutants (methylene blue (MB) dye) were also investigated and results showed that 53.8% degradation of MB was done successfully. Furthermore, the installation of green chemistry in synthesizing nanocomposites by using plant extract matrix optimizes antibacterial characteristics, antioxidant and biodegradability, helping to build sustainable green Mn decorated ZnO nanomaterial. This work, explains how biologically friendly Mn-doped ZnO nanocomposites can help reduce the environmental impact of traditional packaging materials. Based on these findings, it was determined that nanocomposites derived from biological resources should be produced on a wide scale to eradicate environmental and water contaminants through degradation.

The development of a non-malignant and sustainable treatment approach for eradicating mephitic organic dyes from freshwater resources is a daunting task. In a similar vein, the current work investigates the mitigation of methylene blue (MB) dye utilizing titanium dioxide nanoparticles (CS-TiO2 NPs) synthesized using cannabis sativa (bhang) leaf extract via a greener approach. The CS-TiO2 NPs are well characterized through XRD, FE-SEM, HR-TEM, UV-Vis spectroscopy, FTIR spectroscopy, and EDS spectroscopy. Microscopic studies confirm that the average particle size distribution of the individual particles was found to be in the range of 12.5 ± 1.5 nm, whereas the average size of the CS-TiO2 NPs aggregates is 24.5 ± 11.5 nm. Additionally, the synthesized CS-TiO2 NPs manifested remarkable photocatalytic degradation potential against methylene blue dye with a degradation efficiency of 98.2% and an apparent rate constant of 0.0398 min−1. As a result, this research offers a green/sustainable alternative for water purification.

The dried form of the brown seaweed Sargassum latifolium was tested for its ability to remove toxic Methylene Blue Dye (MBD) ions from aqueous synthetic solutions and industrial wastewater effluents. In a batch adsorption experiment, different initial concentrations of MBD (5, 10, 20, 30, and 40 mg L−1), sorbent dosages (0.025, 0.05, 0.1, 0.2, 0.3, 0.4, and 0.5 g L−1), contact time (5, 10, 15, 30, 60, 120 min), pH (3, 5, 8, 10, and 12), and temperature (30, 40, 50, 60 °C) were observed. Dried powder of S. latifolium was characterized before and after adsorption of MBD using different techniques, such as FTIR, SEM, UV visible spectral examination, and BET techniques. The BET surface area suggests the formation of S. latifolium was 111.65 m2 g−1, and the average pore size was 2.19 nm. The obtained results showed that at an MBD concentration of 40 mg L−1, the adsorption was rapid in the first 5, 10, and 15 min of contact time, and an equilibrium was reached in about 60 and 120 min for the adsorption. At the optimum temperature of 30 °C and the adsorbent dose of 0.1 g L−1, approximately 94.88% of MBD were removed. To find the best-fit isotherm model, the error function equations are applied to the isotherm model findings. Both Tempkin and Freundlich isotherm models could appropriate the equilibrium data, as well as the pseudo 2nd order kinetics model due to high correlation coefficients (R2). Thermodynamic and Freundlich model parameters were assessed and showed that the mechanism of the sorption process occurs by an endothermic and physical process. According to the results of the experiments, S. latifolium is a promising environmentally friendly approach for eliminating MBD from the aqueous solution that is also cost-effective. This technology could be useful in addressing the rising demand for adsorbents employed in environmental protection processes.

Herein, MoS2-ZnO heterostructure nanorods were hydrothermally synthesized and characterized in detail using several compositional, optical, and morphological techniques. The comprehensive characterizations show that the synthesized MoS2/ZnO heterostructure nanorods were composed of wurtzite hexagonal phase of ZnO and rhombohedral phase of MoS2. The synthesized MoS2/ZnO heterostructure nanorods were used as a potent photocatalyst for the decomposition of methylene blue (MB) dye under natural sunlight. The prepared MoS2/ZnO heterostructure nanorods exhibited ~97% removal of MB in the reaction time of 20 min with the catalyst amount of 0.15 g/L. The kinetic study revealed that the photocatalytic removal of MB was found to be in accordance with pseudo first-order reaction kinetics with an obtained rate constant of 0.16262 min−1. The tremendous photocatalytic performance of MoS2-ZnO heterostructure nanorods could be accredited to an effective charge transportation and inhibition in the recombination of photo-excited charge carriers at an interfacial heterojunction. The contribution of active species towards the decomposition of MB using MoS2-ZnO heterostructure nanorods was confirmed from scavenger study and terephthalic acid fluorescence technique.

In this study, a CuBTC/ZnO chitosan composite was synthesized for the adsorptive removal of methylene blue dye from aqueous streams. Characterization techniques, namely, scanning electron microscopy, Brunauer-Emmett-Teller, Fourier transform infrared, X-ray diffraction, and thermogravimetric techniques, were used to characterize CuBTC, ZnO, and CuBTC/ZnO chitosan composites. The scanning electron microscopy images revealed the rough and porous structures of the CuBTC/ZnO chitosan composite. The composites were tested for the adsorption capacity and removal efficiency towards the methylene blue dye by varying adsorbent dosage, adsorbate concentration, pH, and contact time. The pseudo-second-order and Langmuir models were the best fit for the adsorption of methylene blue on CuBTC/ZnO chitosan composite beads, indicating that the adsorption was monolayer and chemical in nature. The equilibrium dose of the composites was 1.6 g L−1, and the contact time was 90 min with a removal efficiency of 98.75%. The maximum adsorption capacity was 50.07 mg g−1. Regeneration of the composites was performed to check the reusability of the synthesized CuBTC/ZnO chitosan composite beads. The active oxygenated species generated by the photocatalytic action of ZnO on the contaminated water was responsible for the degradation of methylene blue. The reported composite beads can be used for up to 5 cycles to remove methylene blue.

Bamboo chip (BC) biomass was used as an alternative precursor for producing high surface area and mesoporous bamboo chip activated carbon using KOH activation with pyrolysis process. Various characterization methods were employed to study the morphological characteristics, material crystallinity, surface area property, elemental composition, and surface functional group of the bamboo chip activated carbon (BCAC). The Brunauer–Emmett–Teller analysis showed that the bamboo chip activated carbon has a high surface area (720.69 m 2 /g) and mesoporous structure (mean pore diameter 7.32 nm). The adsorption property of bamboo chip activated carbon for the removal of methylene blue (MB) from aqueous media was evaluated. The effect of key adsorption parameters such as the bamboo chip activated carbon dose (A: 0.02–0.1 g/L), pH (B: 3–10), temperature (C: 30–50 °C), and time (D: 5–20 min) was optimized using a response surface methodology–Box–Behnken design. The kinetics of adsorption obeyed a pseudo-first order. The adsorption equilibrium was well described by the Freundlich isotherm model. The maximum adsorption capacity ( q m ) of MB dye was found to be 305.3 mg/g at 40 °C. The MB dye adsorption mechanism onto bamboo chip activated carbon surface indicates various dye–adsorbent interactions: electrostatic attraction, π – π interaction, and H-bonding. This study demonstrates the utility of bamboo chip as a biomass precursor for the efficient synthesis of activated carbon with favorable cationic dye adsorption properties.