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"Microengineering"
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A Nano-Micro Engineering Nanofiber for Electromagnetic Absorber, Green Shielding and Sensor
2021
HighlightsThe role of electron transport characteristics in electromagnetic (EM) attenuation can be generalized to other EM functional materials.The integrated functions of efficient EM absorption and green shielding open the view of EM multifunctional materials.A novel sensing mechanism based on intrinsic EM attenuation performance and EM resonance coupling effect is revealed.It is extremely unattainable for a material to simultaneously obtain efficient electromagnetic (EM) absorption and green shielding performance, which has not been reported due to the competition between conduction loss and reflection. Herein, by tailoring the internal structure through nano-micro engineering, a NiCo2O4 nanofiber with integrated EM absorbing and green shielding as well as strain sensing functions is obtained. With the improvement of charge transport capability of the nanofiber, the performance can be converted from EM absorption to shielding, or even coexist. Particularly, as the conductivity rising, the reflection loss declines from − 52.72 to − 10.5 dB, while the EM interference shielding effectiveness increases to 13.4 dB, suggesting the coexistence of the two EM functions. Furthermore, based on the high EM absorption, a strain sensor is designed through the resonance coupling of the patterned NiCo2O4 structure. These strategies for tuning EM performance and constructing devices can be extended to other EM functional materials to promote the development of electromagnetic driven devices.Graphic Abstract
Journal Article
Extracellular vesicles as a next-generation drug delivery platform
by
Wood, Matthew John Andrew
,
Herrmann, Inge Katrin
,
Fuhrmann, Gregor
in
631/61/350/354
,
631/61/54/152
,
Cardiovascular diseases
2021
Extracellular-vesicle-based cell-to-cell communication is conserved across all kingdoms of life. There is compelling evidence that extracellular vesicles are involved in major (patho)physiological processes, including cellular homoeostasis, infection propagation, cancer development and cardiovascular diseases. Various studies suggest that extracellular vesicles have several advantages over conventional synthetic carriers, opening new frontiers for modern drug delivery. Despite extensive research, clinical translation of extracellular-vesicle-based therapies remains challenging. Here, we discuss the uniqueness of extracellular vesicles along with critical design and development steps required to utilize their full potential as drug carriers, including loading methods, in-depth characterization and large-scale manufacturing. We compare the prospects of extracellular vesicles with those of the well established liposomes and provide guidelines to direct the process of developing vesicle-based drug delivery systems.
In this Review the authors discuss the biological role of extracellular vesicles and how they can be applied as drug carriers, focusing on the current state of their manufacturing and existing challenges.
Journal Article
Structured nanoscale metallic glass fibres with extreme aspect ratios
by
Squair Jordan W
,
Tileli Vasiliki
,
Löffler, Jörg F
in
Amorphous materials
,
Aspect ratio
,
Crystallization
2020
Micro- and nanoscale metallic glasses offer exciting opportunities for both fundamental research and applications in healthcare, micro-engineering, optics and electronics. The scientific and technological challenges associated with the fabrication and utilization of nanoscale metallic glasses, however, remain unresolved. Here, we present a simple and scalable approach for the fabrication of metallic glass fibres with nanoscale architectures based on their thermal co-drawing within a polymer matrix with matched rheological properties. Our method yields well-ordered and uniform metallic glasses with controllable feature sizes down to a few tens of nanometres, and aspect ratios greater than 1010. We combine fluid dynamics and advanced in situ transmission electron microscopy analysis to elucidate the interplay between fluid instability and crystallization kinetics that determines the achievable feature sizes. Our approach yields complex fibre architectures that, combined with other functional materials, enable new advanced all-in-fibre devices. We demonstrate in particular an implantable metallic glass-based fibre probe tested in vivo for a stable brain–machine interface that paves the way towards innovative high-performance and multifunctional neuro-probes.Metallic glasses possess intriguing functional properties, but controlled fabrication with nanoscale feature sizes remains challenging. Thermal co-drawing within a viscosity-matched polymer matrix enables the fabrication of uniform metallic glass fibres with feature sizes down to a few tens of nanometres, arbitrary transverse geometries and aspect ratios greater than 1010.
Journal Article
Semiconductor moiré materials
2022
Moiré materials have emerged as a platform for exploring the physics of strong electronic correlations and non-trivial band topology. Here we review the recent progress in semiconductor moiré materials, with a particular focus on transition metal dichalcogenides. Following a brief overview of the general features in this class of materials, we discuss recent theoretical and experimental studies on Hubbard physics, Kane–Mele–Hubbard physics and equilibrium moiré excitons. We also comment on the future opportunities and challenges in the studies of transition metal dichalcogenide and other semiconductor moiré materials.
This Review elaborates on the recent developments and the future opportunities and challenges of fundamental research on semiconductor moiré materials, with a particular focus on transition metal dichalcogenides.
Journal Article
Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries
2022
The stabilization of transition metals as isolated centres with high areal density on suitably tailored carriers is crucial for maximizing the industrial potential of single-atom heterogeneous catalysts. However, achieving single-atom dispersions at metal contents above 2 wt% remains challenging. Here we introduce a versatile approach combining impregnation and two-step annealing to synthesize ultra-high-density single-atom catalysts with metal contents up to 23 wt% for 15 metals on chemically distinct carriers. Translation to a standardized, automated protocol demonstrates the robustness of our method and provides a path to explore virtually unlimited libraries of mono- or multimetallic catalysts. At the molecular level, characterization of the synthesis mechanism through experiments and simulations shows that controlling the bonding of metal precursors with the carrier via stepwise ligand removal prevents their thermally induced aggregation into nanoparticles. The drastically enhanced reactivity with increasing metal content exemplifies the need to optimize the surface metal density for a given application. Moreover, the loading-dependent site-specific activity observed in three distinct catalytic systems reflects the well-known complexity in heterogeneous catalyst design, which now can be tackled with a library of single-atom catalysts with widely tunable metal loadings.
A general versatile approach combining wet-chemistry impregnation and two-step annealing is devised for the scalable synthesis of a library of ultra-high-density single-atom catalysts with drastically enhanced reactivity.
Journal Article
Two-dimensional materials for next-generation computing technologies
by
Liu, Chunsen
,
Liu, Ming
,
Wang, Shuiyuan
in
Computing time
,
Energy efficiency
,
Metal oxide semiconductors
2020
Rapid digital technology advancement has resulted in a tremendous increase in computing tasks imposing stringent energy efficiency and area efficiency requirements on next-generation computing. To meet the growing data-driven demand, in-memory computing and transistor-based computing have emerged as potent technologies for the implementation of matrix and logic computing. However, to fulfil the future computing requirements new materials are urgently needed to complement the existing Si complementary metal–oxide–semiconductor technology and new technologies must be developed to enable further diversification of electronics and their applications. The abundance and rich variety of electronic properties of two-dimensional materials have endowed them with the potential to enhance computing energy efficiency while enabling continued device downscaling to a feature size below 5 nm. In this Review, from the perspective of matrix and logic computing, we discuss the opportunities, progress and challenges of integrating two-dimensional materials with in-memory computing and transistor-based computing technologies.This Review discusses the recent progress and future prospects of two-dimensional materials for next-generation nanoelectronics.
Journal Article
Magnetic 2D materials and heterostructures
2019
The family of two-dimensional (2D) materials grows day by day, hugely expanding the scope of possible phenomena to be explored in two dimensions, as well as the possible van der Waals (vdW) heterostructures that one can create. Such 2D materials currently cover a vast range of properties. Until recently, this family has been missing one crucial member: 2D magnets. The situation has changed over the past 2 years with the introduction of a variety of atomically thin magnetic crystals. Here we will discuss the difference between magnetic states in 2D materials and in bulk crystals and present an overview of the 2D magnets that have been explored recently. We will focus on the case of the two most studied systems—semiconducting CrI3 and metallic Fe3GeTe2—and illustrate the physical phenomena that have been observed. Special attention will be given to the range of new van der Waals heterostructures that became possible with the appearance of 2D magnets, offering new perspectives in this rapidly expanding field.Until recently, the family of 2D materials was missing one crucial member — 2D magnets. This Review presents an overview of the 2D magnets studied so far and of the heterostructures that can be realized by combining them with other 2D materials.
Journal Article
The future of two-dimensional semiconductors beyond Moore’s law
by
Han, Ne Myo
,
Kim, Hyunseok
,
Lee, Sangho
in
639/301/1005/1007
,
639/925/927/1007
,
Chemistry and Materials Science
2024
The primary challenge facing silicon-based electronics, crucial for modern technological progress, is difficulty in dimensional scaling. This stems from a severe deterioration of transistor performance due to carrier scattering when silicon thickness is reduced below a few nanometres. Atomically thin two-dimensional (2D) semiconductors still maintain their electrical characteristics even at sub-nanometre scales and offer the potential for monolithic three-dimensional (3D) integration. Here we explore a strategic shift aimed at addressing the scaling bottleneck of silicon by adopting 2D semiconductors as new channel materials. Examining both academic and industrial viewpoints, we delve into the latest trends in channel materials, the integration of metal contacts and gate dielectrics, and offer insights into the emerging landscape of industrializing 2D semiconductor-based transistors for monolithic 3D integration.
This Review explores adopting 2D semiconductors to overcome the scaling bottleneck of Si-based electronics. Recent trends and potential approaches for the development of 2D materials as a channel are discussed. Following this, the prerequisites, obstacles and feasible technologies for integrating contacts and gate dielectrics with 2D semiconductor-based channels are examined. The Review also provides an industrial perspective towards facilitating monolithic 3D integration.
Journal Article
Placing nanoplastics in the context of global plastic pollution
by
Mitrano, Denise M.
,
Nowack, Bernd
,
Wick, Peter
in
639/925/357
,
639/925/929
,
Chemistry and Materials Science
2021
Numerous studies have made the ubiquitous presence of plastic in the environment undeniable, and thus it no longer comes as a surprise when scientists measure the accumulation of macroplastic litter and microplastic fragments in both urban and remote sites. Nanoplastics have recently emerged in the discussions of scientists, regulators and the public, as the weathering of macroplastics may lead to a substantial burden of nanoplastics in various ecosystems. While nanoplastics particles themselves have not (yet) been extensively measured in the environment, there is increased concern that this size fraction of plastic may be more extensively distributed and hazardous that larger-sized particles. This assessment may emanate from an unease with the term ‘nano’, which may elicit a negative response over uncertainties of the pervasiveness of nanoplastics specifically, or from the lessons learned by many years of intensive environmental health and safety research of engineered nanomaterials. Ultimately, the different physical and chemical characteristics of the different size classes of plastic pollution (macroplastics, microplastics and nanoplastics) will result in divergent fate and hazards. As nanoscientists specializing in understanding the fate, transport and interactions of nanoparticles in human and environmental systems, in this Perspective, we try to place nanoplastics in the context of global plastic pollution by assessing its sources and risks, and by assessing commonalities nanoplastics may share with other nanosized objects in environmental systems, such as engineered nanomaterials and natural colloids.
This Perspective aims to place nanoplastics in the context of global plastic pollution by assessing its sources and risks, and by assessing commonalities nanoplastics may share with other nanosized objects in environmental systems.
Journal Article
Exceptional points and non-Hermitian photonics at the nanoscale
2023
Exceptional points (EPs) arising in non-Hermitian systems have led to a variety of intriguing wave phenomena, and have been attracting increased interest in various physical platforms. In this Review, we highlight the latest fundamental advances in the context of EPs in various nanoscale systems, and overview the theoretical progress related to EPs, including higher-order EPs, bulk Fermi arcs and Weyl exceptional rings. We peek into EP-associated emerging technologies, in particular focusing on the influence of noise for sensing near EPs, improving the efficiency in asymmetric transmission based on EPs, optical isolators in nonlinear EP systems and novel concepts to implement EPs in topological photonics. We also discuss the constraints and limitations of the applications relying on EPs, and offer parting thoughts about promising ways to tackle them for advanced nanophotonic applications.
This Review discusses the latest theoretical progress related to exceptional points in non-Hermitian physics and the associated implications for emerging technologies in nanophotonics.
Journal Article