Explore the vast range of titles available.

The anion of pyridine, C₅H₅N⁻, has been thought to be short lived in the gas phase and was only previously observed indirectly. In the condensed phase, C₅H₅N⁻ is known to be stabilized by solvation with other molecules. We provide in this study striking results for the formation of isolated C₅H₅N⁻ from microdroplets of water containing dissolved pyridine observed in the negative ion mass spectrum. The gas-phase lifetime of C₅H₅N⁻ is estimated to be at least 50 ms, which is much longer than previously thought. The generated C₅H₅N⁻ captured CO₂ molecules to form a stable (Py-CO₂)⁻ complex, further confirming the existence of C₅H₅N⁻. We propose that the high electric field at the air–water interface of a microdroplet helps OH⁻ to transfer an electron to pyridine to form C₅H₅N⁻ and the hydroxyl radical •OH. Oxidation products of the Py reacting with •OH are also observed in the mass spectrum recorded in positive mode, which further supports this mechanism. The present study pushes the limits of the reducing and oxidizing power of water microdroplets to a new level, emphasizing how different the behavior of microdroplets can be from bulk water. We also note that the easy formation of C₅H₅N⁻ in water microdroplets presents a green chemistry way to synthesize value-added chemicals.

The ITER neutral beam system will be equipped with radio-frequency (RF) negative ion sources, based on the IPP Garching prototype source design. Up to 100 kW at 1 MHz is coupled to the RF driver, out of which the plasma expands into the main source chamber. Compared to arc driven sources, RF sources are maintenance free and without evaporation of tungsten. The modularity of the driver concept permits to supply large source volumes. The prototype source (one driver) demonstrated operation in hydrogen and deuterium up to one hour with ITER relevant parameters. The ELISE test facility is operating with a source of half the ITER size (four drivers) in order to validate the modular source concept and to gain early operational experience at ITER relevant dimensions. A large variety of diagnostics allows improving the understanding of the relevant physics and its link to the source performance. Most of the negative ions are produced on a caesiated surface by conversion of hydrogen atoms. Cs conditioning and distribution have been optimized in order to achieve high ion currents which are stable in time. A magnetic filter field is needed to reduce the electron temperature and co-extracted electron current. The influence of different field topologies and strengths on the source performance, plasma and beam properties is being investigated. The results achieved in short pulse operation are close to or even exceed the ITER requirements with respect to the extracted ion currents. However, the extracted negative ion current for long pulse operation (up to 1 h) is limited by the increase of the co-extracted electron current, especially in deuterium operation.

Neutral beam injection is one of the most important methods of plasma heating in thermonuclear fusion experiments, allowing the attainment of fusion conditions as well as driving the plasma current. Neutral beams are generally produced by electrostatically accelerating ions, which are neutralised before injection into the magnetised plasma. At the particle energy required for the most advanced thermonuclear devices and particularly for ITER, neutralisation of positive ions is very inefficient so that negative ions are used. The present paper is devoted to the description of the phenomena occurring when a high-power multi-ampere negative ion beam travels from the beam source towards the plasma. Simulation of the trajectory of the beam and of its features requires various numerical codes, which must take into account all relevant phenomena. The leitmotiv is represented by the interaction of the beam with the background gas. The main outcome is the partial neutralisation of the beam particles, but ionisation of the background gas also occurs, with several physical and technological consequences. Diagnostic methods capable of investigating the beam properties and of assessing the relevance of the various phenomena will be discussed. Examples will be given regarding the measurements collected in the small flexible NIO1 source and regarding the expected results of the prototype of the neutral beam injectors for ITER. The tight connection between measurements and simulations in view of the operation of the beam is highlighted.

Negative ions are important in many areas of science and technology, e.g., in interstellar chemistry, for accelerator-based radionuclide dating, and in anti-matter research. They are unique quantum systems where electron-correlation effects govern their properties. Atomic anions are loosely bound systems, which with very few exceptions lack optically allowed transitions. This limits prospects for high-resolution spectroscopy, and related negative-ion detection methods. Here, we present a method to measure negative ion binding energies with an order of magnitude higher precision than what has been possible before. By laser-manipulation of quantum-state populations, we are able to strongly reduce the background from photodetachment of excited states using a cryogenic electrostatic ion-beam storage ring where keV ion beams can circulate for up to hours. The method is applicable to negative ions in general and here we report an electron affinity of 1.461 112 972(87) eV for 16 O. High-precision measurements are useful to find isotopic shifts and electron correlation. Here the authors measure electron affinity and hyperfine splitting of atomic oxygen with higher precision than previous studies.

Neutral beam injection (NBI) based on a negative ion source is one of the basic heating and current drive systems designed for ITER required to reach its goals of the operation with high fusion power, Pfus ∼ 500 MW with fusion gain, Q = 10 for 400 s in a baseline scenario, and Pfus > 250 MW, Q = 5 operation for 3600 s in an advanced scenario. A total power of 33 MW from the two heating neutral beam (HNB) injectors is envisaged in the present scenario. The scope of the present paper is to provide an overview of the main aspects of the interaction of the HNBs with the ITER plasma. Various operational scenarios with different mixtures of the main ion species, He, H, DD and DT, foreseen at different phases of the ITER operation are considered.

This paper deals with a study of H−/D− negative ion surface production on diamond in low pressure H2/D2 plasmas. A sample placed in the plasma is negatively biased with respect to plasma potential. Upon positive ion impacts on the sample, some negative ions are formed and detected according to their mass and energy by a mass spectrometer placed in front of the sample. The experimental methods developed to study negative ion surface production and obtain negative ion energy and angle distribution functions are first presented. Different diamond materials ranging from nanocrystalline to single crystal layers, either doped with boron or intrinsic, are then investigated and compared with graphite. The negative ion yields obtained are presented as a function of different experimental parameters such as the exposure time, the sample bias which determines the positive ion impact energy and the sample surface temperature. It is concluded from these experiments that the electronic properties of diamond materials, among them the negative electron affinity, seem to be favourable for negative-ion surface production. However, the negative ion yield decreases with the plasma induced defect density.

The heating neutral beam injectors (HNBs) of ITER are designed to deliver 16.7 MW of 1 MeV D0 or 0.87 MeV H0 to the ITER plasma for up to 3600 s. They will be the most powerful neutral beam (NB) injectors ever, delivering higher energy NBs to the plasma in a tokamak for longer than any previous systems have done. The design of the HNBs is based on the acceleration and neutralisation of negative ions as the efficiency of conversion of accelerated positive ions is so low at the required energy that a realistic design is not possible, whereas the neutralisation of H− and D− remains acceptable ( 56%). The design of a long pulse negative ion based injector is inherently more complicated than that of short pulse positive ion based injectors because: negative ions are harder to create so that they can be extracted and accelerated from the ion source; electrons can be co-extracted from the ion source along with the negative ions, and their acceleration must be minimised to maintain an acceptable overall accelerator efficiency; negative ions are easily lost by collisions with the background gas in the accelerator; electrons created in the extractor and accelerator can impinge on the extraction and acceleration grids, leading to high power loads on the grids; positive ions are created in the accelerator by ionisation of the background gas by the accelerated negative ions and the positive ions are back-accelerated into the ion source creating a massive power load to the ion source; electrons that are co-accelerated with the negative ions can exit the accelerator and deposit power on various downstream beamline components. The design of the ITER HNBs is further complicated because ITER is a nuclear installation which will generate very large fluxes of neutrons and gamma rays. Consequently all the injector components have to survive in that harsh environment. Additionally the beamline components and the NB cell, where the beams are housed, will be activated and all maintenance will have to be performed remotely. This paper describes the design of the HNB injectors, but not the associated power supplies, cooling system, cryogenic system etc, or the high voltage bushing which separates the vacuum of the beamline from the high pressure SF6 of the high voltage (1 MV) transmission line, through which the power, gas and cooling water are supplied to the beam source. Also the magnetic field reduction system is not described.

This work represents the first attempt to model the full-size ITER negative ion source prototype including expansion, extraction and part of the acceleration regions keeping the resolution fine enough to resolve every single aperture of the extraction grid. The model consists of a 2.5-dimensional Particle-in-Cell/Monte Carlo Collision representation of the plane perpendicular to the filter field lines. Both the magnetic filter and electron deflection fields have been included. A negative ion current density of j H − = 500 A m − 2 produced by neutral conversion from the plasma grid is used as fixed parameter, while negative ions produced by electron dissociative attachment of vibrationally excited molecules and by ionic conversion on plasma grid are self-consistently simulated. Results show the non-ambipolar character of the transport in the expansion region driven by electron magnetic drifts in the plane perpendicular to the filter field. It induces a top-bottom asymmetry detected up to the extraction grid which in turn leads to a tilted positive ion flow hitting the plasma grid and a tilted negative ion flow emitted from the plasma grid. As a consequence, the plasma structure is not uniform around the single aperture: the meniscus assumes a form of asymmetric lobe and a deeper potential well is detected from one side of the aperture relative to the other side. Therefore, the surface-produced contribution to the negative ion extraction is not equally distributed between both the sides around the aperture but it come mainly from the lower side of the grid giving an asymmetrical current distribution in the single beamlet.

The Negative Ions at the Lunar Surface (NILS) instrument is a compact mass resolving negative ion and electron analyser flown on the Chinese Chang’E-6 mission to the Moon. NILS measures negative ions and electrons in the energy range of 3 eV/q to 3 keV/q with a mass resolution m / Δ m of about 2. The mass resolution is sufficient to separate charge-converted solar wind protons and sputtered negatively charged atoms form the surface. An electro-magnetic electron suppression system allows to switch between electron and ion measurements. The fan-shaped field of view is divided into 16 discrete angular pixels that are scanned sequentially. For each viewing direction, an electron and an ion energy spectrum is acquired in 4.06 s. NILS has a mass of 919 g, excluding cables and multi-layer insulation. Power consumption is on average 2.7 W during nominal operations.

Plasma parameter measurements for negative hydrogen (H−) ion sources have been playing an important role in clarifying fundamental physics related to negative ion production and destruction processes. Measured data of beam properties, such as H− ion current density with the co-extracted electron current and the emittance, were correlated to local concentration of charged particles and temperature often characterized by Langmuir probes and optical emission spectrometry. Langmuir probes coupled to pulse lasers quantified local H− ion densities from early days of H− ion source development, while the cavity ring down photodetachment method removed Langmuir probes from contemporary large-size high power density ion sources. Technological progress has made source plasma diagnostics possible during beam extraction, which has thrown light on the transport of H− ions during the application of the extraction electric field. The advancement of plasma diagnostics for high intensity H− ion sources are summarized in this report together with recent results from the research and development negative ion source being operated for collaborative research programs at National Institute for Fusion Science.