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Inland waters, including lakes, are one of the key points of the carbon cycle. Using remote sensing data in lake monitoring has advantages in both temporal and spatial coverage over traditional in-situ methods that are time consuming and expensive. In this study, we compared two sensors on different Copernicus satellites: Multispectral Instrument (MSI) on Sentinel-2 and Ocean and Land Color Instrument (OLCI) on Sentinel-3 to validate several processors and methods to derive water quality products with best performing atmospheric correction processor applied. For validation we used in-situ data from 49 sampling points across four different lakes, collected during 2018. Level-2 optical water quality products, such as chlorophyll-a and the total suspended matter concentrations, water transparency, and the absorption coefficient of the colored dissolved organic matter were compared against in-situ data. Along with the water quality products, the optical water types were obtained, because in lakes one-method-to-all approach is not working well due to the optical complexity of the inland waters. The dynamics of the optical water types of the two sensors were generally in agreement. In most cases, the band ratio algorithms for both sensors with optical water type guidance gave the best results. The best algorithms to obtain the Level-2 water quality products were different for MSI and OLCI. MSI always outperformed OLCI, with R2 0.84–0.97 for different water quality products. Deriving the water quality parameters with optical water type classification should be the first step in estimating the ecological status of the lakes with remote sensing.

In this study, the Level-2 products of the Ocean and Land Colour Instrument (OLCI) data on Sentinel-3A are derived using the Case-2 Regional CoastColour (C2RCC) processor for the SentiNel Application Platform (SNAP) whilst adjusting the specific scatter of Total Suspended Matter (TSM) for the Baltic Sea in order to improve TSM retrieval. The remote sensing product “kd_z90max” (i.e., the depth of the water column from which 90% of the water-leaving irradiance are derived) from C2RCC-SNAP showed a good correlation with in situ Secchi depth (SD). Additionally, a regional in-water algorithm was applied to derive SD from the attenuation coefficient Kd(489) using a local algorithm. Furthermore, a regional in-water relationship between particle scatter and bench turbidity was applied to generate turbidity from the remote sensing product “iop_bpart” (i.e., the scattering coefficient of marine particles at 443 nm). The spectral shape of the remote sensing reflectance (Rrs) data extracted from match-up stations was evaluated against reflectance data measured in situ by a tethered Attenuation Coefficient Sensor (TACCS) radiometer. The L2 products were evaluated against in situ data from several dedicated validation campaigns (2016–2018) in the NW Baltic proper. All derived L2 in-water products were statistically compared to in situ data and the results were also compared to results for MERIS validation from the literature and the current S3 Level-2 Water (L2W) standard processor from EUMETSAT. The Chl-a product showed a substantial improvement (MNB 21%, RMSE 88%, APD 96%, n = 27) compared to concentrations derived from the Medium Resolution Imaging Spectrometer (MERIS), with a strong underestimation of higher values. TSM performed within an error comparable to MERIS data with a mean normalized bias (MNB) 25%, root-mean square error (RMSE) 73%, average absolute percentage difference (APD) 63% n = 23). Coloured Dissolved Organic Matter (CDOM) absorption retrieval has also improved substantially when using the product “iop_adg” (i.e., the sum of organic detritus and Gelbstoff absorption at 443 nm) as a proxy (MNB 8%, RMSE 56%, APD 54%, n = 18). The local SD (MNB 6%, RMSE 62%, APD 60%, n = 35) and turbidity (MNB 3%, RMSE 35%, APD 34%, n = 29) algorithms showed very good agreement with in situ data. We recommend the use of the SNAP C2RCC with regionally adjusted TSM-specific scatter for water product retrieval as well as the regional turbidity algorithm for Baltic Sea monitoring. Besides documenting the evaluation of the C2RCC processor, this paper may also act as a handbook on the validation of Ocean Colour data.

Chlorophyll-a (chl-a) is an important parameter of water quality and its concentration can be directly retrieved from satellite observations. The Ocean and Land Color Instrument (OLCI), a new-generation water-color sensor onboard Sentinel-3A and Sentinel-3B, is an excellent tool for marine environmental monitoring. In this study, we introduce a new machine learning model, Light Gradient Boosting Machine (LightGBM), for estimating time-series chl-a concentration in Fujian’s coastal waters using multitemporal OLCI data and in situ data. We applied the Case 2 Regional CoastColour (C2RCC) processor to obtain OLCI band reflectance and constructed four spectral indices based on OLCI feature bands as supplementary input features. We also used root-mean-square error (RMSE), mean absolute error (MAE), median absolute percentage error (MAPE), and R2 as performance indicators. The results indicate that the addition of spectral indices can easily improve the prediction accuracy of the model, and normalized fluorescence height index (NFHI) has the best performance, with an RMSE of 0.38 µg/L, MAE of 0.22 µg/L, MAPE of 28.33%, and R2 of 0.785. Moreover, we used the well-known band ratio and three-band methods for chl-a estimation validation, and another two OLCI chl-a products were adopted for comparison (OC4Me chl-a and Inverse Modelling Technique (IMT) Neural Net chl-a). The results confirmed that the LightGBM model outperforms the traditional methods and OLCI chl-a products. This study provides an effective remote sensing technique for coastal chl-a concentration estimation and promotes the advantage of OLCI data in ocean color remote sensing.

The colours from natural waters differ markedly over the globe, depending on the water composition and illumination conditions. The space-borne “ocean colour” instruments are operational instruments designed to retrieve important water-quality indicators, based on the measurement of water leaving radiance in a limited number (5 to 10) of narrow (≈10 nm) bands. Surprisingly, the analysis of the satellite data has not yet paid attention to colour as an integral optical property that can also be retrieved from multispectral satellite data. In this paper we re-introduce colour as a valuable parameter that can be expressed mainly by the hue angle (α). Based on a set of 500 synthetic spectra covering a broad range of natural waters a simple algorithm is developed to derive the hue angle from SeaWiFS, MODIS, MERIS and OLCI data. The algorithm consists of a weighted linear sum of the remote sensing reflectance in all visual bands plus a correction term for the specific band-setting of each instrument. The algorithm is validated by a set of 603 hyperspectral measurements from inland-, coastal- and near-ocean waters. We conclude that the hue angle is a simple objective parameter of natural waters that can be retrieved uniformly for all space-borne ocean colour instruments.

The launch of Ocean and Land Colour Instrument (OLCI) on board Sentinel-3A in 2016 is the beginning of a new era in long time, continuous, high frequency water quality monitoring of coastal waters. Therefore, there is a strong need to validate the OLCI products to be sure that the technical capabilities provided will be used in the best possible way in water quality monitoring and research. The Baltic Sea is an optically complex waterbody where many ocean colour products, performing well in other waterbodies, fail. We tested the performance of standard Case-2 Regional/Coast Colour (C2RCC) processing chain in retrieving water reflectance, inherent optical properties (IOPs), and water quality parameters such as chlorophyll a, total suspended matter (TSM) and coloured dissolved organic matter (CDOM) in the Baltic Sea. The reflectance spectra produced by the C2RCC are realistic in both shape and magnitude. However, the IOPs, and consequently the water quality parameters estimated by the C2RCC, did not have correlation with in situ data. On the other hand, some tested empirical remote sensing algorithms performed well in retrieving chlorophyll a, TSM, CDOM and Secchi depth from the reflectance produced by the C2RCC. This suggests that the atmospheric correction part of the processor performs relatively well while IOP retrieval part of the neural network needs extensive training with actual IOP data before it can produce reasonable estimates for the Baltic Sea.

Remote Sensing, as a driver for water management decisions, needs further integration with monitoring water quality programs, especially in developing countries. Moreover, usage of remote sensing approaches has not been broadly applied in monitoring routines. Therefore, it is necessary to assess the efficacy of available sensors to complement the often limited field measurements from such programs and build models that support monitoring tasks. Here, we integrate field measurements (2013–2019) from the Mexican national water quality monitoring system (RNMCA) with data from Landsat-8 OLI, Sentinel-3 OLCI, and Sentinel-2 MSI to train an extreme learning machine (ELM), a support vector regression (SVR) and a linear regression (LR) for estimating Chlorophyll-a (Chl-a), Turbidity, Total Suspended Matter (TSM) and Secchi Disk Depth (SDD). Additionally, OLCI Level-2 Products for Chl-a and TSM are compared against the RNMCA data. We observed that OLCI Level-2 Products are poorly correlated with the RNMCA data and it is not feasible to rely only on them to support monitoring operations. However, OLCI atmospherically corrected data is useful to develop accurate models using an ELM, particularly for Turbidity (R2 = 0.7). We conclude that remote sensing is useful to support monitoring systems tasks, and its progressive integration will improve the quality of water quality monitoring programs.

Atmospheric correction is an essential prerequisite for obtaining accurate inland water color information. An inland water atmospheric correction algorithm, ACbTC (Atmospheric Correction based on Turbidity Classification), was proposed in this study by using OLCI (Ocean and Land Color Instrument) and SLSTR (Sea and Land Surface Temperature Radiometer) synergistic observations for the first time. This method includes two main steps: (1) water turbidity classification by the GRA index (GRAdient of the spectrum index); and (2) atmospheric correction by synergistic use of OLCI and SLSTR images. The algorithm was validated with 72 in situ sampling sites in Lake Erhai, Lake Hongze, and Lake Taihu, and compared with other atmospheric correction methods, i.e., C2RCC (Case 2 Regional Coast Colour processor), MUMM (Management Unit of the North Seas Mathematical Models), FLAASH (Fast Line-of-sight Atmospheric Analysis of Hypercubes), POLYMER (POLYnomial based algorithm applied to MERIS), and BPAC (Bright Pixel Atmospheric Correction). The results show that (1) the GRA index performed better than the proposed turbidity classification indices, i.e., the Diff (spectral difference index) and the Tind (turbid index), in inland lakes by using the reflectance peak at 1020 nm in clean water; (2) the synergistic use of OLCI and SLSTR performed feasibly for atmospheric correction, and the ACbTC algorithm achieved full-band average values of the mean absolute percentage error (MAPE) = 29.55%, mean relative percentage error (MRPE) = 13.98%, and the root mean square of error (RMSE) = 0.0039 sr−1, which were more reliable than C2RCC, MUMM, FLAASH, POLYMER, and BPAC; and (3) the synergistic use of the 17th band (865 nm) on OLCI and the 5th band (1613 nm) on SLSTR are suitable for clean inland lakes, while both the 5th band (1613 nm) and 6th band (2250 nm) on SLSTR are advisable for the turbidity.

In the European Citclops project, with a prime aim of developing new tools to involve citizens in the water quality monitoring of natural waters, colour was identified as a simple property that can be measured via a smartphone app and by dedicated low-cost instruments. In a recent paper, we demonstrated that colour, as expressed mainly by the hue angle (α), can also be derived accurately and consistently from the ocean colour satellite instruments that have observed the Earth since 1997. These instruments provide superior temporal coverage of natural waters, albeit at a reduced spatial resolution of 300 m at best. In this paper, the list of algorithms is extended to the very first ocean colour instrument, and the Moderate Resolution Imaging Spectroradiometer (MODIS) 500-m resolution product. In addition, we explore the potential of the hue angle derivation from multispectral imaging instruments with a higher spatial resolution but reduced spectral resolution: the European Space Agency (ESA) multispectral imager (MSI) on Sentinel-2 A,B, the Operational Land Imager (OLI) on the National Aeronautics and Space Administration (NASA) Landsat-8, and its precursor, the Enhanced Thematic Mapper Plus (ETM+) on Landsat-7. These medium-resolution imagers might play a role in an upscaling from point measurements to the typical 1-km pixel size from ocean colour instruments. As the parameter α (the colour hue angle) is fairly new to the community of water remote sensing scientists, we present examples of how colour can help in the image analysis in terms of water-quality products.

The cyanobacterium Trichodesmium is responsible for approximately half of the ocean's nitrogen input through nitrogen fixation. Although it was first recorded near Australia in the 18th century, the knowledge of where and when large quantity of Trichodesmium around Australia could be found is still lacking. Here, using multi‐band satellite imagery acquired between 2012 and 2021, we fill this knowledge gap through the use of deep learning, designed to recognize both the spectral shapes of individual pixels and spatial morphology of surface aggregations (scums) of Trichodesmium. Trichodesmium scums were found nearly everywhere around Australia, with a cumulative footprint (i.e., where the 10‐year average density is >0.001‰) exceeding 4.6 million km2. Strong seasonality was found, with peak months between September and November. Furthermore, temperature, iron‐rich dust and black carbon aerosols, with the latter being a result of frequent bushfires, play major roles in determining the spatial distributions and seasonality of Trichodesmium. Plain Language Summary Responsible for half of the ocean's nitrogen input through nitrogen fixation, the saltwater cyanobacterium Trichodesmium is ubiquitous in global tropical and subtropical oceans but particularly abundant around Australia. However, although the earliest report goes back to the 18th century, the knowledge of where and when large quantities of Trichodesmium can be found around Australia is still incomplete. Based on satellite imagery and deep learning, we quantified relative abundance of Trichodesmium around Australia for the period of 2012–2021. Surface aggregations of Trichodesmium were found almost everywhere except the southern coast, with a cumulative footprint exceeding 4.6 million km2. Strong seasonality was found, with peak months between September and November. The spatial distributions and seasonality were found to correlate well with water temperature, iron‐rich dust from Australian desert, and black carbon aerosols from frequent bushfires. With the projected ocean warming in the coming century, Trichodesmium may expand further south, making the cumulative footprint even larger. Key Points Deep learning was applied to multi‐band satellite images to detect and quantify Trichodesmium surface scums around Australia Trichodesmium scums were found nearly everywhere around Australia with a seasonality and a cumulative footprint exceeding 4.6 million km2 Distribution and seasonality of Trichodesmium were driven by temperature, iron‐rich dust and black carbon from the mainland bushfires

Accurate and reliable estimation of gross primary productivity (GPP) is of great significance in monitoring global carbon cycles. The fraction of absorbed photosynthetically active radiation (FAPAR) and vegetation index products of the Moderate Resolution Imaging Spectroradiometer (MODIS) are currently the most widely used data in evaluating GPP. The launch of the Ocean and Land Colour Instrument (OLCI) onboard the Sentinel-3 satellite provides the FAPAR and the OLCI Terrestrial Chlorophyll Index (OTCI) products with higher temporal resolution and smoother spatial distribution than MODIS, having the potential to monitor terrain GPP. OTCI is one of the red-edge indices and is particularly sensitive to canopy chlorophyll content related to GPP. The purpose of the study is to evaluate the performance of OLCI FAPAR and OTCI for the estimation of GPP across seven biomes in 2017–2018. To this end, OLCI FAPAR and OTCI products in combination with insitu meteorological data were first integrated into the MODIS GPP algorithm and in three OTCI-driven models to simulate GPP. The modeled GPP (GPPOLCI-FAPAR and GPPOTCI) were then compared with flux tower GPP (GPPEC) for each site. Furthermore, the GPPOLCI-FAPAR and GPP derived from the MODIS FAPAR (GPPMODIS-FAPAR) were compared. Results showed that the performance of GPPOLCI-FAPAR was varied in different sites, with the highest R2 of 0.76 and lowest R2 of 0.45. The OTCI-driven models that include APAR data exhibited a significant relationship with GPPEC for all sites, and models using only OTCI provided the most varied performance, with the relationship between GPPOTCI and GPPEC from strong to nonsignificant. Moreover, GPPOLCI-FAPAR (R2 = 0.55) performed better than GPPMODIS-FAPAR (R2 = 0.44) across all biomes. These results demonstrate the potential of OLCI FAPAR and OTCI products in GPP estimation, and they also provide the basis for their combination with the soon-to-launch Fluorescence Explorer satellite and their integration with the Sentinel-3 land surface temperature product into light use models for GPP monitoring at regional and global scales.