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The scattering of charged particles by oxygen ion cyclotron harmonic (OCH) waves in the inner magnetosphere is investigated by evaluating the relevant quasi‐linear diffusion coefficients. Recent studies demonstrated that OCH waves are oxygen ion Bernstein modes and their complex kinetic dispersion relation has made it challenging to assess their role in scattering charged particles. The present study calculates the quasi‐linear diffusion coefficients for the scattering of electrons and ions by OCH waves using their kinetic dispersion relation. The results show that OCH waves can effectively scatter electrons between ∼100 eV and 100s keV via Landau resonance. They are also capable of heating cold helium and oxygen ions through cyclotron resonances. Specially, it is found that the 4th harmonic of OCH waves can lead to effective heating of helium ions, while oxygen ions would interact more efficiently with lower harmonics of OCH waves. Plain Language Summary Oxygen ion cyclotron harmonic (OCH) waves observed in the inner magnetosphere often have multiple spectral peaks at harmonics of the local oxygen ion cyclotron frequency. They have been shown to be excited by hot oxygen ion loss‐cone or ring/ring‐like distributions and follow a complicated kinetic dispersion relation for oxygen ion Bernstein waves. Since OCH waves cannot be described by the relatively simple cold plasma dispersion relation, it has been difficult to calculate their diffusion coefficients in scattering charged particles in quasi‐linear theory. The present study numerically solves the kinetic dispersion relation for OCH waves and then uses the results to calculate the corresponding quasi‐linear diffusion coefficients for electrons and ions. The diffusion coefficients obtained show that OCH waves can effectively interact with ∼100 eV to 100s keV electrons and are capable of heating cold helium and oxygen ions. Thus, OCH waves have their own unique contribution to the particle dynamics in the inner magnetosphere. Key Points Quasi‐linear diffusion coefficients are evaluated for particle scattering by oxygen ion cyclotron harmonic (OCH) waves for the first time OCH waves can scatter electrons in a wide energy range (∼100 eV–100s keV) via Landau resonance OCH waves are capable of heating cold helium and oxygen ions through cyclotron resonance

Linear kinetic instability analysis based on in situ observations for one typical oxygen ion cyclotron harmonic (OCH) wave event is performed to investigate the wave excitation mechanism. The observed partial‐shell velocity distribution of energetic O+s is fitted by the superposition of multiple ring‐beam distributions. The calculated linear growth rate shows that the observed OCH waves can be excited by energetic O+s with the partial‐shell velocity distribution, and the maximum growth rate occurs at the third harmonic, coinciding with the frequency associated with the maximum peak of the wave electric field power spectral density measured. In addition, it is found that cool heavy ions have a damping effect on the OCH waves near the corresponding heavy ion cyclotron frequency. Plain Language Summary Oxygen ion cyclotron harmonic (OCH) waves observed in the terrestrial magnetosphere have multiple spectral peaks at harmonics of the local oxygen ion cyclotron frequency. This paper presents the linear kinetic instability analysis based on in situ observations of the plasma environment and ion distributions for one typical OCH wave event. The results reveal that partial‐shell distributed energetic O+s can provide free energy to excite the observed OCH waves. The growth rate versus frequency calculated using linear kinetic theory shows good agreement with the power spectral density of the observed wave electric field. Interestingly, damping of the OCH waves of the harmonics close to the oxygen (helium) ions cyclotron frequency is positively correlated with the concentration of the cool oxygen (helium) ions. Key Points Linear analysis based on observations demonstrates that partial‐shell distributed energetic O+s excite oxygen ion cyclotron harmonic waves Maximum growth rate occurs at the third harmonic, coinciding with the frequency at the largest peak of the observed power spectral density The presence of cool heavy ions damps the wave harmonics near the heavy ion cyclotron frequency

Bicoherence analysis is statistically performed for the oxygen ion cyclotron harmonic (OCH) waves observed by Van Allen Probes. While OCH waves and so‐called electromagnetic ion cyclotron harmonics have indistinguishable spectral characteristics in observation, they are believed to be excited by different mechanisms with the latter being suggested to arise from nonlinear wave‐wave coupling. Our result reveals that most of the OCH wave events have small bicoherence indices, so they are unlikely excited by wave‐wave coupling. The result is not much affected by the parameter choice in the bicoherence analysis, although increasing the subinterval length and/or reducing the subinterval overlap increases the chance of getting large bicoherence index values. Furthermore, the examination of two special events with large bicoherence indices shows that the observed phase relationship among different wave components does not align with the expectation from wave‐wave coupling. The events cannot be convincingly confirmed to be generated through wave‐wave coupling. Plain Language Summary This paper presents a statistical bicoherence analysis study of the oxygen ion cyclotron harmonic (OCH) waves observed by Van Allen Probes. OCH waves have apparent features similar to electromagnetic ion cyclotron (EMIC) harmonics in observation. Previous studies have suggested that OCH waves are excited through the oxygen ion Bernstein instability but EMIC harmonics are generated by nonlinear wave‐wave coupling. Bicoherence analysis is commonly employed for assessing wave‐wave coupling. The results of our bicoherence analysis indicate that most of the OCH events have bicoherence indices less than 0.5, so they are unlikely generated through wave‐wave coupling. The study also demonstrates that the parameter choice in bicoherence analysis affects the calculated index values, but the index values remain mostly less than 0.5 for the various reasonable parameter choices tested. In addition, a detailed analysis of the phase relationship among various electric and magnetic wave components in two specific OCH events reveals that, despite their large bicoherence indices, the observed phase relationship does not align with what would be expected if the waves are generated from wave‐wave coupling. This reminds us that having a large bicoherence index is a necessary but not sufficient condition to prove that waves are generated by wave‐wave coupling. Key Points Most of the oxygen ion cyclotron harmonic (OCH) waves observed by Van Allen Probes have small bicoherence indices Increasing the subinterval length and/or reducing the subinterval overlap increases the chance of getting large bicoherence index values Examination of two special OCH wave events with large bicoherence indices does not support them being generated from wave‐wave coupling

Negative oxygen ions are produced by plants through photosynthesis, utilizing \"tip discharge\" or the photoelectric effect, which has various functions such as sterilization, dust removal, and delaying aging. With global warming, high temperatures may affect the ability of Rchb. f. to produce negative oxygen ions. is commonly used in modern landscape planning and forest greening. In this study, was selected as the research object. By artificially simulating the climate, the control group (CK) and the high temperature stress group (HS) were set up in the experiment. The study found that compared with the control group, the ability of to produce negative oxygen ions significantly decreased when exposed to high temperature stress. Meanwhile, under high temperature stress treatment, peroxidase content increased by 102%, and proline content significantly increased by 35%. Redundancy analysis results indicated a significant correlation between the root endophytic microbial community of and negative oxygen ions, as well as physiological indicators. Under high temperature stress, may affect the regulation of physiological indicators by modifying the composition of root endophytic microbial communities, thereby influencing the ability to release negative oxygen ions.

In the current highly industrialized living environment, air quality has become an increasing public health concern. Natural environments like forests have excellent air quality due to high concentrations of negative oxygen ions originating from low-voltage ionization, without harmful ozone. Traditional negative oxygen ion generators require high voltage for corona discharge to produce ions. However, high voltage can increase electron collisions and excitations, leading to more dissociation and recombination of oxygen molecules and consequently higher ozone production. To address the challenge of generating negative oxygen ions without accompanying ozone production, this study designed and constructed a low-voltage negative oxygen ion generator based on nanometer-tip carbon fiber electrodes. The advantage of this device lies in the high curvature radius of carbon fibers, which provides high local electric field strength. This allows for efficient production of negative oxygen ions at low operating voltages without generating ozone. Experiments demonstrated that the device can efficiently generate negative oxygen ions at a working voltage as low as 2.16 kV, 28% lower than the lowest voltage reported in similar studies. The purification device manufactured in this study had a total decay constant for PM2.5 purification of 0.8967 min−1 within five minutes, compared to a natural decay constant of only 0.0438 min−1, resulting in a calculated Clean Air Delivery Rate (CADR) of 0.1535 m3/min. Within half an hour, concentrations of PM2.5, PM1, PM10, formaldehyde, and TVOC were reduced by 99.09%, 99.40%, 99.37%, 94.39%, and 99.35%, respectively, demonstrating good decay constants and CADR. These findings confirm its effectiveness in improving indoor air quality, highlighting its significant application value in air purification.

Oxygen-focused ion beam induced deposition (O-FIBID) enables the direct-write fabrication of Pt nanostructures while simultaneously enhancing purity concurrently through reactive oxygen-deposit interactions. By systematically varying the dwell time, accelerating voltage, and precursor pressure, the Pt content and conductivity can be controlled. Under optimum conditions, the Pt content reached 63 at.%. Across the dwell-time range used for resistivity measurements, the Pt content increased from 20 to 33 at.%, while the resistivity decreased from 2.9 × 10 μΩ·cm to 1.2 × 10 μΩ·cm, which is consistent with enhanced percolation through Pt grains and the lower intrinsic resistivity of the purer Pt deposit. The simulation results support a purification mechanism driven by the beam-induced activation of implanted oxygen balanced against the preferential sputtering of Pt. These results demonstrate O-FIBID as a viable method for the nanoscale direct write of conductive Pt without post-processing, and some deviations from conventional FIBID wisdom are observed. These results serve as a foundation for exploring nascent, reactive focused ion beam-induced deposition processes.

In this article, a new investigation on a low-temperature electrochemical hydrocarbon and NOx sensor is presented. Based on the mixed-potential-based sensing scheme, the sensor is constructed using platinum and metal oxide electrodes, along with an Yttria-Stabilized Zirconia (YSZ)/Strontium Titanate (SrTiO3) thin-film electrolyte. Unlike traditional mixed-potential sensors which operate at higher temperatures (>400 °C), this potentiometric sensor operates at 200 °C with dominant hydrocarbon (HC) and NOx response in the open-circuit and biased modes, respectively. The possible low-temperature operation of the sensor is speculated to be primarily due to the enhanced oxygen ion conductivity of the electrolyte, which may be attributed to the space charge effect, epitaxial strain, and atomic reconstruction at the interface of the YSZ/STO thin film. The response and recovery time for the NOx sensor are found to be 7 s and 8 s, respectively. The sensor exhibited stable response even after 120 days of testing, with an 11.4% decrease in HC response and a 3.3% decrease in NOx response.

In this study, the bipolar resistance switching behavior and electrical conduction transport properties of a neodymium oxide film's resistive random access memory (RRAM) devices for using different top electrode materials were observed and discussed. Different related electrical properties and transport mechanisms are important factors in applications in a film's RRAM devices. For aluminum top electrode materials, the electrical conduction mechanism of the neodymium oxide film's RRAM devices all exhibited hopping conduction behavior, with 1 mA and 10 mA compliance currents in the set state for low/high voltages applied. For TiN and ITO (Indium tin oxide) top electrode materials, the conduction mechanisms all exhibited ohmic conduction for the low voltage applied, and all exhibited hopping conduction behavior for the high voltage applied. In addition, the electrical field strength simulation resulted in an increase in the reset voltage, indicating that oxygen ions have diffused into the vicinity of the ITO electrode during the set operation. This was particularly the case in the three physical models proposed, and based on the relationship between different ITO electrode thicknesses and the oxygen ion concentration distribution effect of the neodymium oxide film's RRAM devices, they were investigated and discussed. To prove the oxygen concentration distribution expands over the area of the ITO electrode, the simulation software was used to analyze and simulate the distribution of the electric field for the Poisson equation. Finally, the neodymium oxide film's RRAM devices for using different top electrode materials all exhibited high memory window properties, bipolar resistance switching characteristics, and non-volatile properties for incorporation into next-generation non-volatile memory device applications in this study.

The focus of the work was on layered perovskite-related materials as potential electrolytic components of devices such as proton-conducting solid oxide fuel cells for clean energy. The possibility of isovalent substitution in the In-sublattice of the two-layer perovskite BaLa 2 In 2 O 7 has been experimentally investigated. It has been found that the replacement of half the structural positions of In 3+ ions by Y 3+ ions leads to an increase in oxygen ion conductivity due to an increase in their mobility as a result of an increase in interlayer space. It is shown that the increase in proton conductivity upon doping is due to both an increase in the mobility of the protons and an increase in their concentration. The BaLa 2 InYO 7 exhibits predominantly proton conductivity at temperatures below 500 °C.

Memristive behaviors are demonstrated in the single-layer oxide-based devices. The conduction states can be continually modulated with different pulses or voltage sweeps. Here, the p-CuAlO2- and n-ZnO-based memristors show the opposite bias polarity dependence with the help of tip electrode. It is well known that the conductivity of p-type and n-type semiconductor materials has the opposite oxygen concentration dependence. Thus, the memristive behaviors may attribute to the oxygen ion migration in the dielectric layers for the single-layer oxide based memristors. Further, based on the redox, the model of compressing dielectric layer thickness has been proposed to explain the memristive behavior.