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Effect of minor chemical structures such as 1,2-diol content, ethylene content, tacticity, a degree of polymerization, and a degree of saponification of the main chain on biodegradability of polyvinyl alcohol (PVA) is summarized. Most PVA-degraders are Gram-negative bacteria belonging to the Pseudomonads and Sphingomonads, but Gram-positive bacteria also have PVA-degrading abilities. Several examples show symbiotic degradation of PVA by different mechanisms. Penicillium sp. is the only reported eukaryotic degrader. A vinyl alcohol oligomer-utilizing fungus, Geotrichum fermentans WF9101, has also been reported. Lignolytic fungi have displayed non-specific degradation of PVA. Extensive published studies have established a two-step process for the biodegradation of PVA. Some bacteria excrete extracellular PVA oxidase to yield oxidized PVA, which is partly under spontaneous depolymerization and is further metabolized by the second step enzyme (hydrolase). On the other hand, PVA (whole and depolymerized to some extent) must be taken up into the periplasmic space of some Gram-negative bacteria, where PVA is oxidized by PVA dehydrogenase, coupled to a respiratory chain. The complete pva operon was identified in Sphingopyxis sp. 113P3. Anaerobic biodegradability of PVA has also been suggested.

In this present work, a PVA/PVP-blend polymer was doped with various concentrations of neodymium oxide (PB-Nd+3) composite films using the solution casting technique. X-ray diffraction (XRD) analysis was used to investigate the composite structure and proved the semi-crystallinity of the pure PVA/PVP polymeric sample. Furthermore, Fourier transform infrared (FT-IR) analysis, a chemical-structure tool, illustrated a significant interaction of PB-Nd+3 elements in the polymeric blends. The transmittance data reached 88% for the host PVA/PVP blend matrix, while the absorption increased with the high dopant quantities of PB-Nd+3. The absorption spectrum fitting (ASF) and Tauc’s models optically estimated the direct and indirect energy bandgaps, where the addition of PB-Nd+3 concentrations resulted in a drop in the energy bandgap values. A remarkably higher quantity of Urbach energy for the investigated composite films was observed with the increase in the PB-Nd+3 contents. Moreover, seven theoretical equations were utilized, in this current research, to indicate the correlation between the refractive index and the energy bandgap. The indirect bandgaps for the proposed composites were evaluated to be in the range of 5.6 eV to 4.82 eV; in addition, the direct energy gaps decreased from 6.09 eV to 5.83 eV as the dopant ratios increased. The nonlinear optical parameters were influenced by adding PB-Nd+3, which tended to increase the values. The PB-Nd+3 composite films enhanced the optical limiting effects and offered a cut-off laser in the visible region. The real and imaginary parts of the dielectric permittivity of the blend polymer embedded in PB-Nd+3 increased in the low-frequency region. The AC conductivity and nonlinear I-V characteristics were augmented with the doping level of PB-Nd+3 contents in the blended PVA/PVP polymer. The outstanding findings regarding the structural, electrical, optical, and dielectric performance of the proposed materials show that the new PB-Nd+3-doped PVA/PVP composite polymeric films are applicable in optoelectronics, cut-off lasers, and electrical devices.

ZnO-doped Polyvinyl alcohol/polyvinyl pyrrolidone (PVA/PVP) polymeric films were prepared in this study through an easy and inexpensive solution-casting method. The scope of the study was based on the structural, dielectric, and optical parameters, as well as on the optical limiting effects of the ZnO-doped polymer blend (PB) as nanocomposite films. The X-ray diffraction (XRD) analysis indicated that the synthesized nanocomposites were semicrystalline. The calculated crystalline size of the polymeric semicrystalline peak decreased as ZnO increased or enhanced the blend polymer. Fourier’s transformer infrared (FT-IR) study confirmed a substantial dispersion of ZnO nanoparticles in a polymeric PVA/PVP matrix. The optical absorption properties suggested focusing on the surface plasmonic peak (SPR). The refractive index values ranged from 1.718 for the pure PB ZnO0 sample in the Hossam, Ibrahim, and Heba model to 3.036 for the PB ZnO5 film from the Anani model. Nonlinear optical parameters (χ((3)), and n(2)) were calculated and analyzed for the PB ZnO nanocomposite films under investigation. The maximum value for χ((1)) was 0.550, while for χ((3)), its susceptibility value was 155.85 × 10−13 esu, and for the nonlinear refractive index (n((2)), it was 20.87 × 10−11 esu. A gradual decrease was revealed in the optical limiting sources, as a high content of ZnO was induced in the blend PVA/PVP polymer. Due to their unique properties, these materials can be used in electronic and optoelectronic devices.

The use of polymeric blended nanofibres is one of the recent applications in the food and liquid packaging. The current research aims to prepare the nanofibers coatings from the blend of polymeric materials via the electro spinning technique 0.08 weight ratio concentration of polyvinyl alcohol (PVA) dissolved in water, as well as, (0.2 weight ratio concentration ) of poly vinyl pyrrolidone (PVP) were used to obtain different volume proportions of (PVA:PVP) solutions include (100:0, 80:20,70:30, 50:50, 20:80, and 0:100). The electro spinning system was organized with pumping conditions (20 kV for the applied voltage, 20 cm pumping distance, 1ml/hr pumping rate) and a needle diameter with 0.4mm diameter. The properties of the polymeric solutions involve (viscosity, surface tension, and electrical conductivity of the liquid) were examined. A scanning electron microscope technique was used to study the surface properties of the prepared films, and the contact angle via the contact angle analyzer was examined. The results of a scanning electron microscope proved that the diameter of the nano fibers increases with increasing the concentration and viscosity of solutions and decreasing its electrical conductivity. Also, the results of the contact angle analyzer showed an increase the hydrophilic property via increasing percentage of polyvinylpyrrolidone.

The zinc oxidenanoparticles(ZnO NPs) were prepared in two media. The first one was in an aqueous medium resulting from the reaction of urea with zinc acetate at 0.3M concentration in both of them in deionized water. The second medium is a polymeric solution which is a dissolving of 4% polyvinyl alcohol (PVA)in deionized water with zinc acetate. The nanoparticles were obtained after the two media were irradiated with ultraviolet rays for 30 min. According to the characterization of the XRD, FESEM, and UV-visible, the polymeric medium gives a less granular size in addition to its ease of use and handling.

A highly selective, sensitive caffeic acid (CA) detection based on calcium oxide nanoparticles (CaO NPs) derived from extract of Moringa oleifera leaves decorated graphitic carbon nitride covalently grafted poly vinyl alcohol (CaO/g-C 3 N 4 /PVA) nanocomposite modified glassy carbon electrode (GCE) was studied. A facile sonochemical method was adapted to synthesis nanomaterials and characterized by HR-TEM (High resolution transmission electron microscopy), FT-IR (Fourier transform infrared spectroscopy), XRD (X-ray diffraction), FE-SEM (Field emission scanning electron microscopy), EDX (Energy dispersive X-ray analysis), Mapping and BET (Brunauer-Emmett-Teller) analysis, and electrochemical techniques. The nanocomposite modified GCE exhibited an excellent catalytic performance to the oxidation of CA under optimized conditions owing to better electron transfer efficiency, conductivity and high surface area of the electrode material. The present electrochemical sensor showed high selectivity towards the determination of 10 µM CA in the presence of 100-fold higher concentrations of interferents. The modified CA sensor exhibited a wide sensing linear range from 0.01 µM to 70 µM and the detection limit (LOD) was found to be 0.0024 µM (S/ N  = 3) in 0.1 M phosphate buffer saline (PBS) as a supporting electrolyte at pH 7.0. The fabricated CA sensor provides an excellent stability, reproducibility and selectivity for the determination of CA. The modified CA sensor was applied to real blood plasma samples and obtained good recovery (97.6-100.1%) results.

Polyvinyl alcohol (PVA)/carboxyl methyl cellulose sodium (CMC)/Na2CO3 composite films with different contents of Na2CO3 were prepared by blending and solution-casting. The effect of Na2CO3 on the microstructure of PVA/CMC composite film was analyzed by Fourier-transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), differential scanning calorimetry (DSC), and atomic force microscopy (AFM). Its macroscopic properties were analyzed by water sorption, solubility, and dielectric constant tests. The results show that the microstructure of PVA/CMC/Na2CO3 composite films was different from that of PVA and PVA/CMC composite films. In addition, compared to PVA and PVA/CMC composite films, the water sorption of PVA/CMC/Na2CO3 composite films relatively increased, the solubility in water significantly decreased, and the dielectric properties significantly improved. All these results indicate that the hydrogen bonding interaction between PVA and CMC increased and the crystallinity of PVA decreased after the addition of Na2CO3. This was also a direct factor leading to increased water sorption, decreased solubility, and enhanced dielectric properties. The reaction mechanism of PVA, CMC, and Na2CO3 is proposed to further evaluate the effect of Na2CO3 on the microstructure and macroscopic properties of PVA/CMC/Na2CO3 composite films.

The aqueous solution cast method was used to create the biodegradable polymer nanocomposite (PNC) films from a blend of poly (vinyl alcohol) PVA and poly (vinyl pyrrolidone) PVP (70/30 wt %) and Fe 2 O 3 nanoparticles (NPs). These PNC films were characterized using X-ray diffraction, scanning electron microscopy SEM, Fourier transform infrared spectroscopy FTIR, and ultraviolet-visible spectroscopy. XRD and FTIR results indicate that Fe + 3 NPs interact with the host polymer. Optical, electrical, mechanical, and radiation shielding measurements were performed on the PNC films. From the optical measurements, the indirect optical band gap drops from 4.86 eV for the pure blend to 4.26 eV at the greatest NPs concentration. Optical limiting characterization shows that the output power of He-Ne and solid-state green laser beams is reduced from 22.98 to 3.6 mW and 6.59 to 1.4 mW, respectively, when the Fe 2 O 3 NPs content in the blend matrix is increased to 6 wt %. The NGCal software was utilized to calculate nuclear radiation shielding properties. The findings demonstrated that when the concentration of Fe 2 O 3 rose, the PNC films half-value layer and mean free path decreased. Mechanical measurements demonstrate that increasing the Fe 2 O 3 content significantly improves nanocomposite films’ yield and tensile strength. Tensile strength is measured at 27.03 MPa for the composite film containing 6 wt % Fe 2 O 3 , which is significantly higher than the 8.66 MPa of the pure (PVA-PVP) film. Compared to the other samples under examination, the 6 wt % Fe 2 O 3 sample yielded the best results (based on the analyzed optical, electrical, mechanical, and radiation shielding properties).

Dually crosslinked graphene oxide reinforced alginate/polyvinyl alcohol (PVA) double network (DN) hydrogels were prepared via a facile freeze/thaw method followed by soaking in a Ca2+ solution. The morphology and structure of the hydrogels were systematically examined by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The effects of pH, dosage of hydrogel, adsorption time, and temperature on the adsorptive property of DN hydrogels towards methylene blue (MB) were also studied. Results indicated that the hydrogels exhibited typical 3D porous structures and had an efficient adsorption effect towards MB due to strong interactions between DN hydrogels and MB molecules. The adsorption isotherm was found to coincide with the Langmuir model with a monolayer adsorption. The highest adsorption capacity of DN hydrogels for MB was examined as 480.76 mg·g−1.

Thorough research on materials with negative permittivity is essential to address various application scenarios and their electromagnetic interference shielding capabilities must be carefully examined. This study focuses on the development of Bambuseae/MWCNT/MnFe 2 O 4 /PVA metacomposites through a simple sol–gel method. By adjusting the multi-walled carbon nanotubes (MWCNTs) content, the permittivity of the metacomposites was altered. When the MWCNT content was at 0.064 and 0.256 g, there was a noticeable observation of negative permittivity, mainly attributed to Lorentz model. The Bambuseae/MWCNT/MnFe 2 O 4 /PVA metacomposites showcased an exceptional shielding effectiveness of − 43.2827 dB for a thickness of 1 mm. The negative permittivity led to a significant impedance mismatch, causing the metacomposite surface to reflect the majority of electromagnetic waves. Moreover, the presence of plasma oscillations and the formation of conductive networks by MWCNTs enhanced the metacomposites’ ability to absorb electromagnetic waves within the material due to their high conductivity and polarization loss. Additionally, the Bambuseae/MWCNT/MnFe 2 O 4 /PVA metacomposites displayed remarkable optical-electrical conversion and remarkable durability in the production of flexible electronic devices like light-dependent resistors, indicating their potential use in harsh working conditions.