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2,734 result(s) for "Parallel flow"
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Dynamics Near the Subcritical Transition of the 3D Couette Flow I: Below Threshold Case
The authors study small disturbances to the periodic, plane Couette flow in the 3D incompressible Navier-Stokes equations at high Reynolds number Re. They prove that for sufficiently regular initial data of size $\\epsilon \\leq c_0\\mathbf {Re}^-1$ for some universal $c_0 > 0$, the solution is global, remains within $O(c_0)$ of the Couette flow in $L^2$, and returns to the Couette flow as $t \\rightarrow \\infty $. For times $t \\gtrsim \\mathbf {Re}^1/3$, the streamwise dependence is damped by a mixing-enhanced dissipation effect and the solution is rapidly attracted to the class of \"2.5 dimensional\" streamwise-independent solutions referred to as streaks.
Enhancement thermal stability and CO2 adsorption property of ZIF-8 by pre-modification with polyaniline
In this study, the thermal stability and CO2 adsorption property of ZIF-8 were effectively improved by using parallel flow-drop solvothermal method. -NH2 was successfully introduced into the surface of ZIF-8 and their structures by pre-modification with polyaniline. XRD analysis shown that the intensity of ZIF-8 characteristic peak increased with the increase doped content of polyaniline, but the crystal structure of ZIF-8 remained unchanged. FTIR analysis shown that the two new peaks at 1609 and 690 cm−1 can be attributed to the -NH2 bonding of ZIF-8. TGA analysis shown that the thermal stability of NH2-ZIF-8 was 632.71 °C. SEM analysis shown that the increase of CO2 adsorption property was due to the increase of NH2-ZIF-8 cubic crystal system. It was found that BET surface area was 789.7 m2g−1, micropore volume was 0.55 cm3g−1, pore size was 0.99 nm by taking the molar ratio of metal ions to ligands being 1:2, and the molar ratios of polyaniline to metal ions being 12%.
Effect of obstacle arrangement and depth in parallel flow fields on the performance of PEMFC
To improve the problems of uneven oxygen distribution in the parallel flow field and water accumulation in the center of the pole plate, this paper divides the flow field into three parts, designs different types of schemes with the arrangement and depth of obstacles, and analyzes the water-oxygen distribution, velocity distribution, and output power on the cathode side using numerical simulation. It is found that when the obstacles are arranged in the third part, the uniformity of velocity and oxygen concentration is enhanced the most and its drainage capacity is the best; when the depth of obstacles is studied, it is found that with the increase of depth, the maximum power density increases and then decreases, but the pressure drop will continue to rise, and when the depth is 0.6 mm, the maximum net power density can be obtained. Therefore, the use of suitable obstacle arrangement and depth in the flow field can enhance cell performance and improve the uniformity of oxygen and water distribution.
Characterization of Limestone Surface Impurities and Resulting Quicklime Quality
Quicklime, rich in CaO(s), is generated by calcining limestone at high temperatures. Parallel-flow regenerative lime kilns are the most energy-effective industrial method available today. To prevent major disruptions in such kilns, a high raw material quality is necessary. Under some conditions, impurity-enriched material may adhere to limestone pebbles and enter the kiln. In this study, limestone and corresponding quicklime were analyzed to evaluate the extent and composition of surface impurities and assess the effect on quicklime product quality, here defined as free CaO. This was performed by sampling and analyzing limestone, quarry clay, laboratory-produced quicklime, and industrially produced quicklime with XRF, SEM/EDX, and XRD; interpretations were supported by thermodynamic equilibrium calculations. In the laboratory-produced quicklime, the surface impurities reacted with calcium forming Larnite, Gehlenite, Åkermanite and Merwinite, reducing the quicklime quality. The results showed that the limestone surface layer comprised 1.2 wt.-% of the total mass but possessed 4 wt.-% of the total impurities. The effect on industrially produced quicklime quality was lower; this indicated that the limestone surface impurities were removed while the material moved through the kiln. Multicomponent chemical equilibrium calculations showed that the quarry clay was expected to be fully melted at 1170 °C, possibly leading to operational problems.
Amplified parallel antigen rapid test for point-of-care salivary detection of SARS-CoV-2 with improved sensitivity
In the ongoing COVID-19 pandemic, simple, rapid, point-of-care tests not requiring trained personnel for primary care testing are essential. Saliva-based antigen rapid tests (ARTs) can fulfil this need, but these tests require overnight-fasted samples; without which independent studies have demonstrated sensitivities of only 11.7 to 23.1%. Herein, we report an Amplified Parallel ART (AP-ART) with sensitivity above 90%, even with non-fasted samples. The virus was captured multimodally, using both anti-spike protein antibodies and Angiotensin Converting Enzyme 2 (ACE2) protein. It also featured two parallel flow channels. The first contained spike protein binding gold nanoparticles which produced a visible red line upon encountering the virus. The second contained signal amplifying nanoparticles that complex with the former and amplify the signal without any linker. Compared to existing dual gold amplification techniques, a limit of detection of one order of magnitude lower was achieved (0.0064 ng·mL – 1 ). AP-ART performance in detecting SARS-CoV-2 in saliva of COVID-19 patients was investigated using a case–control study (139 participants enrolled and 162 saliva samples tested). Unlike commercially available ARTs, the sensitivity of AP-ART was maintained even when non-fasting saliva was used. Compared to the gold standard reverse transcription-polymerase chain reaction testing on nasopharyngeal samples, non-fasting saliva tested on AP-ART showed a sensitivity of 97.0% (95% CI: 84.7–99.8); without amplification, the sensitivity was 72.7% (95% CI: 83.7–94.8). Thus, AP-ART has the potential to be developed for point-of-care testing, which may be particularly important in resource-limited settings, and for early diagnosis to initiate newly approved therapies to reduce COVID-19 severity. Graphical abstract
Enriched Finite Volume Approximations of the Plane-Parallel Flow at a Small Viscosity
We investigate viscous boundary layers of the plane-parallel flow, governed by the stationary Navier–Stokes equations under a certain symmetry. Following the analysis in Gie et al. (Annales de l’Institut Henri Poincaré C. Analyse Non Linéaire, 2018), we first construct the so-called corrector, which is an analytic approximation of the velocity vector field near the boundary. Then, by embedding the corrector function into the classical Finite Volume schemes, we construct the semi-analytic enriched Finite Volume schemes for the plane-parallel flow, and numerically verify that our new enriched schemes reduce significantly the computational error of classical schemes especially near the boundary, and hence produce more accurate approximations without introducing any finer mesh near the boundary.
Steady-State Bifurcation of a Non-parallel Flow Involving Energy Dissipation over a Hartmann Boundary Layer
A plane non-parallel vortex flow in a square fluid domain is examined. The energy dissipation of the flow is dominated by viscosity and linear friction effect of a Hartmann layer. This is a traditional Navier–Stokes flow when the linear friction effect is not involved, whereas it is a magnetohydrodynamic flow when the energy dissipation is fundamentally dominated by the friction. It is proved that linear critical values of a spectral problem are nonlinear thresholds leading to the onset of secondary steady-state flows, the nonlinear phenomenon observed in laboratory experiments.
CFD Analysis of Co-firing of Coke and Biomass in a Parallel Flow Regenerative Lime Kiln
The lime industry is a highly energy intensive industry, with a huge presence worldwide. To reduce both production costs and pollutants emissions, some lime production plants are introducing more environmentally-friendly energy sources, such as local agro-industry residues. In this paper, a numerical tool is presented, which simulates a large-scale Parallel Flow Regenerative (PFR) kiln that currently uses coke as main fuel. The developed tool aims at investigating the combustion process under conditions of co-firing of coke and biomass and to assist the plant operators in the optimization of such operating conditions. To achieve this goal, a two-way coupling Euler–Lagrange approach is used to model the dynamics of the particulate phase and their interaction with the gas phase. Pyrolysis, volatiles oxidation and char oxidation are modelled by kinetics/diffusion-limited model (for heterogeneous reactions) and mixture fraction approach (for homogeneous reactions). Moreover, two methods are investigated for representing the limestone bed: a porous medium (PM) approach and a “solid blocks” (BM) tridimensional mesh. Comparison of the results for the case of 100% coke showed that the ideal “blocks” method is more accurate as it adequately simulates the scattering of fuel particles through the PFR kiln anchor, which is limited with the PM approach. Moreover, the temperature profile, maximum and minimum temperatures, as well as CO 2 and O 2 concentrations at outlet, are comprised in the expected range for this technology, according to available literature. Finally, the predicted results of a co-firing case with 60% biomass (in mass) were validated with measurements in an industrial facility, with production capacity of 440 calcium oxide tons per day. The results suggest that the model is fairly accurate to predict gas temperature, as well as O 2 and NO X concentrations at the kiln outlet. Although some improvements are recommended to refine the CFD predictions, these promising results and the high computational efficiency laid the foundation for future modelling of co-firing of coke and biomass, as well as the modelling of the lime calcination process. It also paves the way for facilitating the reduction of pollutant emissions thus contributing to a more sustainable lime production. Graphical Abstract
Facile Synthesis of CeO2 Nanosheets via a Parallel Flow Precipitation Route
In this work, CeO 2 nanosheet was facile synthesized via a parallel flow precipitation route, using cerium chloride trihydrate and sodium carbonate as the cerium source, without using any surfactants and templates. The results show that the CeO 2 nanosheets have a median particle size (D 50 ) of 118 nm, a range ( R ) of 0.69, a surface area of 3.01 m 2 /g, a pore diameter of 27.96 nm, a pore volume of 0.02 cm 3 /g, and a loss on ignition (L.O.I.) of < 1%. Furthermore, the activation energy of CeO 2 nanocrystal growth during the calcination process is about 30.5 kJ/mol, indicating that the controlling link of the crystallite growth is the interfacial chemical reaction. Ostwald ripening (OR) mechanism has a synergistic effect with Oriented attachment (OA) mechanism during the process of nucleation and growth of Ce 2 (CO 3 ) 3 crystal grains.
Controlling Microdroplet Inner Rotation by Parallel Carrier Flow of Sesame and Silicone Oils
We developed a method for passively controlling microdroplet rotation, including interior rotation, using a parallel flow comprising silicone and sesame oils. This device has a simple 2D structure with a straight channel and T-junctions fabricated from polydimethylsiloxane. A microdroplet that forms upstream moves into the sesame oil. Then, the largest flow velocity at the interface of the two oil layers applies a rotational force to the microdroplet. A microdroplet in the lower oil rotates clockwise while that in the upper oil rotates anti-clockwise. The rotational direction was controlled by a simple combination of sesame and silicone oils. Droplet interior flow was visualized by tracking microbeads inside the microdroplets. This study will contribute to the efficient creation of chiral molecules for pharmaceutical and materials development by controlling rotational direction and speed.