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Preparation and Property Characterization of Smsub.2EuSbOsub.7/ZnBiSbOsub.5 Heterojunction Photocatalyst for Photodegradation of Parathion Methyl under Visible Light Irradiation
An unprecedented photocatalyst, Sm[sub.2]EuSbO[sub.7], was successfully fabricated in this paper, through a high-temperature solid-state calcination method, which represented its first ever synthesis. Additionally, using the solvothermal method, the Sm[sub.2]EuSbO[sub.7]/ZnBiSbO[sub.5] heterojunction photocatalyst (SZHP) was fabricated, marking its debut in this study. XRD analysis confirmed that both Sm[sub.2]EuSbO[sub.7] and ZnBiSbO[sub.5] exhibited pyrochlore-type crystal structures with a cubic lattice, belonging to the Fd3m space group. The crystal cell parameter was determined to be 10.5682 Å or 10.2943 Å for Sm[sub.2]EuSbO[sub.7] or ZnBiSbO[sub.5], respectively. The band gap width measured for Sm[sub.2]EuSbO[sub.7] or ZnBiSbO[sub.5] was 2.73 eV or 2.61 eV, respectively. Under visible light irradiation for 150 min (VLTI-150 min), SZHP exhibited remarkable photocatalytic activity, achieving 100% removal of parathion methyl (PM) concentration and 99.45% removal of total organic carbon (TOC) concentration. The kinetic constant (k) for PM degradation and visible light illumination treatment was determined to be 0.0206 min[sup.−1], with a similar constant k of 0.0202 min[sup.−1] observed for TOC degradation. Remarkably, SZHP exhibited superior PM removal rates compared with Sm[sub.2]EuSbO[sub.7], ZnBiSbO[sub.5], or N-doped TiO[sub.2] photocatalyst, accompanied by removal rates 1.09 times, 1.20 times, or 2.38 times higher, respectively. Furthermore, the study investigated the oxidizing capability of free radicals through the use of trapping agents. The results showed that hydroxyl radicals had the strongest oxidative capability, followed by superoxide anions and holes. These findings provide a solid scientific foundation for future research and development of efficient heterojunction compound catalysts.
Journal Article
Pesticides, a love story : America's enduring embrace of dangerous chemicals
\"A provocative cultural history of pesticides and their controversial use and depiction in the United States. Mart contends that--despite the sharp concerns raised by environmentalists and others since the appearance of Rachel Carson's Silent Spring--Americans have not only never resolved the inherent tension between costs and benefits presented by these chemicals, but have actually grown ever more attached to them with the passage of time\"-- Provided by publisher.
Book
A new critical social science research agenda on pesticides
The global pesticide complex has transformed over the past two decades, but social science research has not kept pace. The rise of an enormous generics sector, shifts in geographies of pesticide production, and dynamics of agrarian change have led to more pesticide use, expanding to farm systems that hitherto used few such inputs. Declining effectiveness due to pesticide resistance and anemic institutional support for non-chemical alternatives also have driven intensification in conventional systems. As an inter-disciplinary network of pesticide scholars, we seek to renew the social science research agenda on pesticides to better understand this suite of contemporary changes. To identify research priorities, challenges, and opportunities, we develop the pesticide complex as a heuristic device to highlight the reciprocal and iterative interactions among agricultural practice, the agrochemical industry, civil society-shaped regulatory actions, and contested knowledge of toxicity. Ultimately, collaborations among social scientists and across the social and biophysical sciences can illuminate recent transformations and their uneven socioecological effects. A reinvigorated critical scholarship that embraces the multifaceted nature of pesticides can identify the social and ecological constraints that drive pesticide use and support alternatives to chemically driven industrial agriculture.
Journal Article
Agriculture Development, Pesticide Application and Its Impact on the Environment
Pesticides are indispensable in agricultural production. They have been used by farmers to control weeds and insects, and their remarkable increases in agricultural products have been reported. The increase in the world’s population in the 20th century could not have been possible without a parallel increase in food production. About one-third of agricultural products are produced depending on the application of pesticides. Without the use of pesticides, there would be a 78% loss of fruit production, a 54% loss of vegetable production, and a 32% loss of cereal production. Therefore, pesticides play a critical role in reducing diseases and increasing crop yields worldwide. Thus, it is essential to discuss the agricultural development process; the historical perspective, types and specific uses of pesticides; and pesticide behavior, its contamination, and adverse effects on the natural environment. The review study indicates that agricultural development has a long history in many places around the world. The history of pesticide use can be divided into three periods of time. Pesticides are classified by different classification terms such as chemical classes, functional groups, modes of action, and toxicity. Pesticides are used to kill pests and control weeds using chemical ingredients; hence, they can also be toxic to other organisms, including birds, fish, beneficial insects, and non-target plants, as well as air, water, soil, and crops. Moreover, pesticide contamination moves away from the target plants, resulting in environmental pollution. Such chemical residues impact human health through environmental and food contamination. In addition, climate change-related factors also impact on pesticide application and result in increased pesticide usage and pesticide pollution. Therefore, this review will provide the scientific information necessary for pesticide application and management in the future.
Journal Article
Contamination from organochlorine pesticides (OCPs) in agricultural soils of Kuttanad agroecosystem in India and related potential health risk
The presence and distribution of a few organochlorine pesticides (OCPs) in the paddy fields of the Kuttanad agroecosystem (KAE) was examined in the present study. Kuttanad forms a part of the Vembanad wetland system which is a Ramsar site of international importance in the state of Kerala. This study, to the best of our knowledge, is the first report on the occurrence of OCP residues in KAE. Pesticide residue analysis was done with gas chromatograph (GC-ECD). Twenty-one soil samples were collected for the multiresidual analysis of OCPs. Sixteen OCP residues with a notable concentration were observed from the study area. α-BHC; β-BHC; γ-BHC; δ-BHC; α-chlordane; γ-chlordane; heptachlor; 4,4-DDT; 4,4-DDE; 4,4-DDD; α-endosulfan; β-endosulfan; aldrin; dieldrin; endrin aldehyde; and endrin ketone were the residues observed. The percentage-wise occurrence of OCP residues in the soil samples analysed (total of 63 samples from 21 sites, three samples per site) exhibits the following order: Σ BHC˃ Σ chlordane ˃ Σ dieldrin ˃ Σ aldrin ˃ Σ endrin˃ Σ heptachlor = endosulfan˃ Σ DDT. All pesticides detected from KAE are in the list of priority pollutants of US Environmental Protection Agency (USEPA). The distribution pattern of OCPs in the KAE soils revealed their origin as both historical and recent application of pesticides. Health risk assessment of OCP residues on human population was also conducted. The findings indicated that the concentrations of OCPs were within the permissible limits of USEPA, thus, the human population in the study area was safe.
Journal Article
Exposure Routes and Health Risks Associated with Pesticide Application
Pesticides play an important role in agricultural development. However, pesticide application can result in both acute and chronic human toxicities, and the adverse effects of pesticides on the environment and human health remain a serious problem. There is therefore a need to discuss the application methods for pesticides, the routes of pesticide exposure, and the health risks posed by pesticide application. The health problems related to pesticide application and exposure in developing countries are of particular concern. The purpose of this paper is to provide scientific information for policymakers in order to allow the development of proper pesticide application technics and methods to minimize pesticide exposure and the adverse health effects on both applicators and communities. Studies indicate that there are four main pesticide application methods, including hydraulic spraying, backpack spraying, basal trunk spraying, and aerial spraying. Pesticide application methods are mainly selected by considering the habits of target pests, the characteristics of target sites, and the properties of pesticides. Humans are directly exposed to pesticides in occupational, agricultural, and household activities and are indirectly exposed to pesticides via environmental media, including air, water, soil, and food. Human exposure to pesticides occurs mainly through dermal, oral, and respiratory routes. People who are directly and/or indirectly exposed to pesticides may contract acute toxicity effects and chronic diseases. Although no segment of the general population is completely protected against exposure to pesticides and their potentially serious health effects, a disproportionate burden is shouldered by people in developing countries. Both deterministic and probabilistic human health risk assessments have their advantages and disadvantages and both types of methods should be comprehensively implemented in research on exposure and human health risk assessment. Equipment for appropriate pesticide application is important for application efficiency to minimize the loss of spray solution as well as reduce pesticide residuals in the environment and adverse human health effects due to over-spraying and residues. Policymakers should implement various useful measures, such as integrated pest management (IPM) laws that prohibit the use of pesticides with high risks and the development of a national implementation plan (NIP) to reduce the adverse effects of pesticides on the environment and on human health.
Journal Article
Influence of QuEChERS modifications on recovery and matrix effect during the multi-residue pesticide analysis in soil by GC/MS/MS and GC/ECD/NPD
A QuEChERS extraction followed by GC/MS/MS and GC-μECD/NPD for 216 pesticide and metabolites determination in soil simultaneously were developed and compared. Volume of water, volume and polarity of solvent, and cleanup sorbents (C18, GCB, PSA) were optimized. The QuEChERS with and without purification step were applied to estimate effectiveness of the method. The recovery and matrix effect (ME) were critical parameters within each tested procedure. The optimal method without cleanup was validated. Accuracy (expressed as recovery), precision (expressed as RSD), linearity, LOQ, and uncertainty were determined. The recoveries at the three spiking levels using matrix-matched standards ranged between 65 and 116% with RSD ≤17 and 60–112% with RSD ≤18% for MS/MS and μEC/NP, respectively. The LOQ ranged from 0.005–0.01 mg/kg for MS/MS to 0.05 mg/kg for μEC/NP. The ME for most of pesticides resulted in enhancement of the signal and depended on the analyte and detection system: MS/MS showed ME from −25 to 74%, while μEC/NP from −45 to 96%. A principal component analysis was performed to explain the relationships between physicochemical parameters and ME of 216 pesticides. The QuEChERS protocol without the cleanup step is a promising option to make the method less expensive and faster. This methodology was applied in routine analysis of 263 soil samples in which p,p’ DDT was the most frequently detected (23.5% of samples) and pendimethalin with the highest concentration (1.63 mg/kg).
Journal Article
Removal of Pesticides from Lemon and Vegetables Using Electrolyzed Water Kitchen Devices
The possibility of using kitchen electrolyzed water devices (EWDs) for removing residual concentrations of pesticides (malathion, fenitrothion, and p,p′-DDT) from lemon, cucumber, and carrot surfaces was tested. Three commercial devices with different parameters were tested, and their effectiveness was compared with traditional washing methods using water. Based on the results, it was found that by using EWDs, the best removal of water-soluble pesticides was achieved with malathion and fenitrothion (reduction of up to 80%). The worst effectiveness was observed for lipophilic DDT, where a reduction of 20 to 40% was noted. Traditional methods proved to be more effective for removing DDT. Our studies have shown that EWDs can effectively remove pesticide residues; however, further studies should be conducted on a wider spectrum of pesticides and the process should be optimized.
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