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"Petroleum Pollution prevention "
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Putting a value on injuries to natural assets
Stated-preference research supports$17.2B in protections When large-scale accidents cause catastrophic damage to natural or cultural resources, government and industry are faced with the challenge of assessing the extent of damages and the magnitude of restoration that is warranted. Although market transactions for privately owned assets provide information about how valuable they are to the people involved, the public services of natural assets are not exchanged on markets; thus, efforts to learn about people's values involve either untestable assumptions about how other things people do relate to these services or empirical estimates based on responses to stated-preference surveys. Valuation based on such surveys has been criticized because the respondents are not engaged in real transactions. Our research in the aftermath of the 2010 BP Deepwater Horizon oil spill addresses these criticisms using the first, nationally representative, stated-preference survey that tests whether responses are consistent with rational economic choices that are expected with real transactions. Our results confirm that the survey findings are consistent with economic decisions and would support investing at least $ 17.2 billion to prevent such injuries in the future to the Gulf of Mexico's natural resources.
Journal Article
Two types of microorganisms isolated from petroleum hydrocarbon pollutants: Degradation characteristics and metabolic pathways analysis of petroleum hydrocarbons
The petroleum hydrocarbons in seawater have been worldwide concern contaminants. Biological method, with the advantages of low cost, minimal environmental impact, and no secondary pollution, is a promising method for petroleum hydrocarbon treatment. In this study, two strains, identified as Stenotrophomonas acidaminiphila and Ochrobactrum , were demonstrated to possess the ability to degrade petroleum hydrocarbons. The mixed culture composed of Stenotrophomonas acidaminiphila and Ochrobactrum at a 2:1 ratio was able to achieve 79.41% degradation of the total petroleum hydrocarbons after 5 days. Besides, the average removal efficiencies of C10-C30 components in petroleum hydrocarbons by Stenotrophomonas acidaminiphila , Ochrobactrum , and mixed culture were 62.98%, 59.14% and 73.30%, respectively. The possible degradation pathways of petroleum hydrocarbons had been speculated through gas chromatography-mass spectrometry (GC-MS) and differential gene expression metabolomics analyses. The toxicity of products from the biodegradation of petroleum hydrocarbons was greatly reduced.
Journal Article
Evaluation of human error in oil spill risk in tanker cargo handling operations
Cargo handling operations on board tankers pose a significant threat to the cleanliness and health of the ocean ecosystem. Incidents originating from these operations are often attributed to human error, as widely acknowledged. Therefore, it is crucial to control the human factor involved in these operations to enhance ship safety and foster a sustainable, clean marine environment. To tackle this problem, this paper presents a novel model that identifies the causal factors behind oil spills resulting from crew failure in these operations. To attain this, fuzzy Bayesian network (FBN) approach is used in this study to analyse the probabilistic correlations among the causal elements that are disclosed qualitatively and quantitatively. Sensitivity analyses and validation procedures are carried out to enhance the accuracy of results. Eliminating errors in cargo calculation is of paramount importance as research has shown that such errors lead to the largest impact on spill during loading and discharging (L&D) operations. The study’s findings offer valuable insights into the causes of L&D operation-related spills. Ship management companies, the loss-prevention division of Protection and Indemnity Clubs (P&I), and regulatory bodies may employ the research results to prevent spill repetitions and protect the marine environment.
Journal Article
Research on the oil retention effect of pneumatic oil barriers under current and wave action
The pneumatic oil barrier is a novel device that intercepts oil spills by releasing high-pressure gas underwater to form a curtain of bubbles. However, its performance can be affected by both internal factors and external influences like water flow and waves, leading to varying degrees of oil interception failure and reduced effectiveness. This study combines physical experiments with numerical simulations to analyze the impact of nozzle parameters, arrangement, flow velocity, and wave effects on oil interception loss and effective containment distance under uniform flow and wave conditions. The findings establish relationships between these factors and interception efficiency, revealing reasons for changes in effective containment distance through flow field analysis. The research indicates that the pneumatic oil barrier is effective for floating oil with flow velocities below 0.15 m/s; the optimal nozzle diameter is 1.5 mm, as increasing it affects the stability of horizontal flow and oil layers. Additionally, a dual-pipe arrangement produces a wider and more stable horizontal flow on the water surface, enhancing oil interception effectiveness, while waves can destabilize oil layers, reducing effective containment distance.
Journal Article
Biostimulation proved to be the most efficient method in the comparison of in situ soil remediation treatments after a simulated oil spill accident
The use of in situ techniques in soil remediation is still rare in Finland and most other European countries due to the uncertainty of the effectiveness of the techniques especially in cold regions and also due to their potential side effects on the environment. In this study, we compared the biostimulation, chemical oxidation, and natural attenuation treatments in natural conditions and pilot scale during a 16-month experiment. A real fuel spill accident was used as a model for experiment setup and soil contamination. We found that biostimulation significantly decreased the contaminant leachate into the water, including also the non-aqueous phase liquid (NAPL). The total NAPL leachate was 19 % lower in the biostimulation treatment that in the untreated soil and 34 % lower in the biostimulation than oxidation treatment. Soil bacterial growth and community changes were first observed due to the increased carbon content via oil amendment and later due to the enhanced nutrient content via biostimulation. Overall, the most effective treatment for fresh contaminated soil was biostimulation, which enhanced the biodegradation of easily available oil in the mobile phase and consequently reduced contaminant leakage through the soil. The chemical oxidation did not enhance soil cleanup and resulted in the mobilization of contaminants. Our results suggest that biostimulation can decrease or even prevent oil migration in recently contaminated areas and can thus be considered as a potentially safe in situ treatment also in groundwater areas.
Journal Article
Assessment of the horizontal transfer of functional genes as a suitable approach for evaluation of the bioremediation potential of petroleum-contaminated sites: a mini-review
Petroleum sludge contains recalcitrant residuals. These compounds because of being toxic to humans and other organism are of the major concerns. Therefore, petroleum sludge should be safely disposed. Physicochemical methods which are used by this sector are mostly expensive and need complex devices. Bioremediation methods because of being eco-friendly and cost-effective overcome most of the limitations of physicochemical treatments. Microbial strains capable to degrade petroleum hydrocarbons are practically present in all soils and sediments and their population density increases in contact with contaminants. Bacterial strains cannot degrade alone all kinds of petroleum hydrocarbons, rather microbial consortium should collaborate with each other for degradation of petroleum hydrocarbon mixtures. Horizontal transfer of functional genes between bacteria plays an important role in increasing the metabolic potential of the microbial community. Therefore, selecting a suitable degrading gene and tracking its horizontal transfer would be a useful approach to evaluate the bioremediation process and to assess the bioremediation potential of contaminated sites.
Journal Article
Functionalized three-dimensional graphene sponges for highly efficient crude and diesel oil adsorption
Modified Hummer’s method has been used in this study to synthesize graphene oxide (GO) solution that was utilized for the fabrication of three-dimensional (3D) graphene sponges and their subsequent functionalization through a low-cost and facile vapor-based surface enhancement approach. The functionalized 3D-graphene sponge is an excellent absorbent, which can remove more than 3300 wt.% of crude oil (calculated with respect to the original sorbent mass). The functionalization of the obtained graphene sponges with trichloro (1H,1H,2H,2H-perfluorooctyl)silane enhanced their wettability properties due to the super-hydrophobic nature of the resulting materials characterized by the contact angles in water greater than 150°. Furthermore, their elastic compression modulus (estimated by conducting a series of compression tests) was about 22.3 kPa. The equilibrium modeling of the oil removal process, which was performed by plotting Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherms, confirmed the properties of the fabricated 3D graphene sponges as exceptional absorbents for crude and diesel oil, which could be attributed to the oleophilic nature of graphene. Moreover, the obtained 3D graphene sponges could be regenerated via heat treatment, which was conducted to release the adsorbed species. After five adsorption-desorption cycles, the sorption capacity of the produced 3D graphene sponges towards crude oil reached 95% of the initial value.
Journal Article
RETRACTED: Functionalization of Magnetite Nanoparticles as Oil Spill Collector
In the present study, a new magnetic powder based on magnetite can be used as a petroleum crude oil collector. Amidoximes based on rosin as a natural product can be prepared from a reaction between hydroxylamine and rosin/acrylonitrile adducts. The produced rosin amidoximes were used as capping agents for magnetite nanoparticles to prepare hydrophobic coated magnetic powders. A new class of monodisperse hydrophobic magnetite nanoparticles was prepared by a simple and inexpensive co-precipitation method. Iron ions and iodine were prepared by the reaction between ferric chloride and potassium iodide. The structure and morphology of magnetite capped with rosin amidoxime were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscopy (TEM), zeta potential, thermogravimetric analysis (TGA) and dynamic light scattering (DLS). The magnetic properties were determined from vibrating sample magnetometer (VSM) analyses. These prepared magnetite nanoparticles were tested as bioactive nanosystems and their antimicrobial effects were investigated. The prepared nanomaterials were examined as a crude oil collector using magnetic fields. The results show promising data for the separation of the petroleum crude oil from aqueous solution in environmental pollution cleanup.
Journal Article
Advances in Understanding the Fate and Effects of Oil from Accidental Spills in the United States Beginning with the Exxon Valdez
Scientific studies of the environmental effects of oil spills in the United States have produced a steady stream of unexpected discoveries countering prior and often simplistic assumptions. In this brief review, I present how major discoveries from scientific studies of oil spill effects on marine ecosystems and environments, beginning with the 1989
Exxon Valdez
, have led to a more informed appreciation for the complexity and the severity of the damage that major spills can do to marine ecosystems and to an increasing recognition that our ability to evaluate those damages is very limited, resulting in a structural bias toward underestimation of adverse environmental effects.
Journal Article