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Nanophotonics has garnered intensive attention due to its unique capabilities in molding the flow of light in the subwavelength regime. Metasurfaces (MSs) and photonic integrated circuits (PICs) enable the realization of mass-producible, cost-effective, and efficient flat optical components for imaging, sensing, and communications. In order to enable nanophotonics with multipurpose functionalities, chalcogenide phase-change materials (PCMs) have been introduced as a promising platform for tunable and reconfigurable nanophotonic frameworks. Integration of non-volatile chalcogenide PCMs with unique properties such as drastic optical contrasts, fast switching speeds, and long-term stability grants substantial reconfiguration to the more conventional static nanophotonic platforms. In this review, we discuss state-of-the-art developments as well as emerging trends in tunable MSs and PICs using chalcogenide PCMs. We outline the unique material properties, structural transformation, and thermo-optic effects of well-established classes of chalcogenide PCMs. The emerging deep learning-based approaches for the optimization of reconfigurable MSs and the analysis of light-matter interactions are also discussed. The review is concluded by discussing existing challenges in the realization of adjustable nanophotonics and a perspective on the possible developments in this promising area.

In modern heat transfer systems, thermal storage not only causes the balance between demand and supply, but also improves the heat transfer efficiency in these systems. In the present study, a comprehensive review of the applications of micro- or nano-encapsulated phase change slurries (MPCMs/NPCMs), as well as their effects on thermal storage and heat transfer enhancement, has been conducted. MPCMs/NPCMs have a myriad of applications and various usages such as pipe and channel flows, photovoltaic/thermal, solar heaters, air conditioning systems, storage tanks and heat pipes that have been categorized and studied. It was found that there are many advantageous adding MPCM/NPCM to the base fluid. The most important effect is that the addition of PCMs to the base fluid can intensify the capacity of energy absorption in the base fluid. These materials can absorb a high proportion of received energy by changing their phase and prevent temperature increment of the base fluid. Thereupon, the specific heat of the fluid in the presence of the micro-/nano-capsules increases. Moreover, in most studies reviewed, heat transfer coefficient and Nusselt number increase by the addition of micro-/nano-capsules to the base fluid. Also, the addition of MPCM/NPCM to the base fluid could make this material pumpable, although increment in the concentration of micro-/nano-capsules raises the viscosity of the working fluid and thereupon the pumping power. On the other hand, for a same heat load, the pumping power decreases due to the lower required flow rate in comparison with pure working fluid. The most important factor that must be considered in the application of MPCMs/NPCMs is the complete phase change of the material. Given the favorable thermal and fluid characteristics of MPCMs/NPCMs, the utilization of these materials could be a promising method to transfer heat and store it with high efficiency and low pumping power.

While polymorphism is prevalent in crystalline solids, polyamorphism draws increasing interest in various types of amorphous solids. Recent studies suggested that supercooling of liquid phase-change materials (PCMs) induces Peierls-like distortions in their local structures, underlying their liquid-liquid transitions before vitrification. However, the mechanism of how the vitrified phases undergo a possible polyamorphic transition remains elusive. Here, using high-energy synchrotron X-rays, we can access the precise pair distribution functions under high pressure and provide clear evidence that pressure can reverse the Peierls-like distortions, eliciting a polyamorphic transition in GeTe and GeSe. Combined with simulations based on machine-learned-neural-network potential, our structural analysis reveals a high-pressure state characterized by diminished Peierls-like distortion, greater coherence length, reduced compressibility, and a narrowing bandgap. Our finding underscores the crucial role of Peierls-like distortions in amorphous octahedral systems including PCMs. These distortions can be controlled through pressure and composition, offering potentials for designing properties in PCM-based devices. The subtle distortion in atomic structure underlies the drastic changes in the properties of amorphous phase-change materials. Here authors show that that pressure can reverse the Peierls-like distortions introduced by temperature, eliciting a polyamorphic transition in GeTe and GeSe.

In this study, a dynamically tunable terahertz device based on a VO2–graphene hybrid metasurface is proposed, which realizes the dual functions of ultra-wideband absorption and efficient transmission through VO2 phase transformation. At 345 K (metallic state), the device attains an absorption efficiency exceeding 90% (average 97.06%) in the range of 2.25–6.07 THz (bandwidth 3.82 THz), showing excellent absorption performance. At 318 K (insulated state), the device achieves 67.66–69.51% transmittance in the 0.1–2.14 THz and 7.51–10 THz bands while maintaining a broadband absorption of 3.6–5.08 THz (an average of 81.99%). Compared with traditional devices, the design breaks through the performance limitations by integrating phase change material control with 2D materials. The patterned graphene design simplifies the fabrication process. System analysis reveals that the device is polarization-insensitive and tunable via graphene Fermi energy and relaxation time. The device’s excellent temperature response and wide angular stability provide a novel solution for terahertz switching, stealth technology, and sensing applications.

Optical metasurfaces, planar subwavelength nanoantenna arrays with the singular ability to sculpt wavefront in almost arbitrary manners, are poised to become a powerful tool enabling compact and high-performance optics with novel functionalities. A particularly intriguing research direction within this field is active metasurfaces, whose optical response can be dynamically tuned postfabrication, thus allowing a plurality of applications unattainable with traditional bulk optics. Designing reconfigurable optics based on active metasurfaces is, however, presented with a unique challenge, since the optical quality of the devices must be optimized at multiple optical states. In this article, we provide a critical review on the active meta-optics design principles and algorithms that are applied across structural hierarchies ranging from single meta-atoms to full meta-optical devices. The discussed approaches are illustrated by specific examples of reconfigurable metasurfaces based on optical phase-change materials.

Electrical and electronic equipment like light bulbs, computing systems, gaming systems, DVD players, and drones experiences heat generation during extensive use. The heat energy should be liberated to ensure uninterrupted performance and prevent premature failure of the devices. This study uses an experimental setup of the heat sink, phase change material, silicon carbide nanoparticles, thermocouple, and data acquisition system to control heat generation and increase heat lost to the surroundings in electronic equipment. The silicon carbide nanoparticles are mixed in varying compositions, i.e., 1wt.%, 2wt.%, and 3wt.%, in paraffin wax as the phase change material. The influence of the heat input (15W, 20W, 35W, and 45W) through the plate heater is also studied. The operating temperature of the heat sink was allowed to fluctuate between 45 and 60 °C while experimenting. The fluctuation in the temperature of the heat sink was recorded to monitor and compare the charging, dwell, and discharging periods in the heat sink. It is observed that increasing the percentage composition of silicon carbide nanoparticles in the paraffin wax resulted in increasing the peak temperature and the dwell period of the heat sink. Increasing the heat input above 15W benefited in controlling the duration of the thermal cycle. It is inferred that high heat input is beneficial in enhancing the heating period, while the percentage composition of silicon carbide in the PCM benefits by increasing the heat sink’s peak temperature and dwell period. It is concluded that high heat input, i.e., 45W, is beneficial in enhancing the heating period, while the percentage composition of silicon carbide in the PCM benefits by increasing the heat sink’s peak temperature and dwell period.

Phase change materials (PCMs) have the ability to absorb and release a large amount of energy during the process of transforming physical properties (i.e., phase transition process). PCMs are suitable for thermal energy storage and reducing energy consumption in buildings. The aim of the study is to assess the basic material properties and thermal behavior of fly ash foam concrete mixed with two different types of microencapsulated PCMs (PCM6D and PCM18D). We made five different varieties of fly ash foam concrete by replacing the equivalent unit weight of cement with PCM 0%, PCM 10% and PCM 30%. The results show that using a new type of mixer, the microencapsulated PCMs kept their spherical shapes without any cracks or damage in the foam concrete matrix. Differential scanning calorimetry analysis showed that PCM18D-30% had a latent heat capacity of 19.2 °C and 44.7 J/g, in liquid and solid phase with melting and freezing temperatures of 9.46 °C and 41.7 J/g respectively. Additionally, thermocycle analysis showed that it had maintained the temperature for 8 h within the phase change range. In conclusion, PCMs can reduce indoor temperature fluctuations and exhibit the potential for enhancing energy savings and thermal comfort of buildings.

Dielectric metasurfaces have made significant advancements in the past decade for enhancing light–matter interaction at the nanoscale. Particularly, bound states in the continuum (BICs) based on dielectric metasurfaces have been employed to enhance nonlinear harmonic generation. However, conventional nonlinear metasurfaces are typically fixed in their operating wavelength after fabrication. In this work, we numerically demonstrate tunable third harmonic generation (THG) by integrating a dielectric metasurface with the phase-change material Ge Sb Te (GST). The hybrid phase-change metasurface can support two BICs with different electromagnetic origins, which are transformed into two high-Q quasi-BICs through the introduction of structural asymmetry. The two quasi-BICs are selectively excited by controlling the polarization of incident light, and their wavelengths are tunable due to the phase transition of GST. Notably, the efficiency of THG is significantly enhanced at the fundamental wavelengths corresponding to the two quasi-BICs, and the operating wavelength for THG enhancement can be dynamically tuned through the GST phase transition. Furthermore, the wavelength of THG enhancement can be further tuned by manipulating the polarization of pump light. Additionally, a high-Q analog of electromagnetically induced transparency is numerically achieved through the interaction between a low-Q Mie resonance and a quasi-BIC mode, which also improves the THG efficiency. The high-Q polarization-controlled hybrid phase-change metasurface holds promise for applications in dynamically tunable nonlinear optical devices.

Phase-change materials (PCMs) allow for non-volatile resonance tuning of nanophotonic components. Upon switching, they offer a large dielectric contrast between their amorphous and crystalline phases. The recently introduced “plasmonic PCM” In SbTe (IST) additionally features in its crystalline phase a sign change of its permittivity over a broad infrared spectral range. While optical resonance switching in unpatterned IST thin films has been investigated before, nanostructured IST antennas have not been studied, yet. Here, we present numerical and experimental investigations of nanostructured IST rod and disk antennas. By crystallizing the IST with microsecond laser pulses, we switched individual antennas from narrow dielectric to broad plasmonic resonances. For the rod antennas, we demonstrated a resonance shift of up to 1.2 µm (twice the resonance width), allowing on/off switching of plasmonic resonances with a contrast ratio of 2.7. With the disk antennas, we realized an increase of the resonance width by more than 800% from 0.24 µm to 1.98 µm while keeping the resonance wavelength constant. Further, we demonstrated intermediate switching states by tuning the crystallization depth within the resonators. Our work empowers future design concepts for nanophotonic applications like active spectral filters, tunable absorbers, and switchable flat optics.

Hyperbolic polaritons that originate from the extreme optical anisotropy in van der Waals (vdW) crystals have gained much attention for their potential in controlling nanolight. For practical use, there has been a strong interest to develop various manipulation strategies to customize the propagation of hyperbolic polaritons on a deeply sub-diffractional scale. In this regard, phase-change materials (PCMs) that possess two phases with different refractive indices offer suitably a tunable dielectric environment. Here, we report on the tuning of hyperbolic phonon polaritons in natural vdW crystals, hexagonal boron nitride (hBN), and alpha-phase molybdenum trioxide (α-MoO ), using the plasmonic phase-change material In SbTe (IST). Unlike conventional PCMs whose both phases are dielectric, IST features a metallic crystalline phase that is stable at room temperature. The coupling between polaritons with their mirror charges in the underneath crystalline IST triggers an even stronger field confinement for polaritons. Moreover, benefited from the metallicity of laser-writable crystalline IST, we show an all-optical material platform in which crystalline IST boundaries efficiently excite and focus hyperbolic phonon polaritons in α-MoO . Our experiments highlight the possibility to obtain new degrees of freedom in polariton engineering with plasmonic PCMs, thereby expanding the toolkit of tunable nanophotonics with flexible, on-demand fabrication and reconfiguration capabilities.