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14,117 result(s) for "Quantum efficiency"
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On the Hole Injection for III-Nitride Based Deep Ultraviolet Light-Emitting Diodes
The hole injection is one of the bottlenecks that strongly hinder the quantum efficiency and the optical power for deep ultraviolet light-emitting diodes (DUV LEDs) with the emission wavelength smaller than 360 nm. The hole injection efficiency for DUV LEDs is co-affected by the p-type ohmic contact, the p-type hole injection layer, the p-type electron blocking layer and the multiple quantum wells. In this report, we review a large diversity of advances that are currently adopted to increase the hole injection efficiency for DUV LEDs. Moreover, by disclosing the underlying device physics, the design strategies that we can follow have also been suggested to improve the hole injection for DUV LEDs.
Modeling light response of effective quantum efficiency of photosystem II for C3 and C4 crops
Effective quantum efficiency of photosystem II (Φ PSII ) represents the proportion of photons of incident light that are actually used for photochemical processes, which is a key determinant of crop photosynthetic efficiency and productivity. A robust model that can accurately reproduce the nonlinear light response of Φ PSII (Φ PSII – I ) over the I range from zero to high irradiance levels is lacking. In this study, we tested a Φ PSII – I model based on the fundamental properties of light absorption and transfer of energy to the reaction centers via photosynthetic pigment molecules. Using a modeling-observation intercomparison approach, the performance of our model versus three widely used empirical Φ PSII – I models were compared against observations for two C 3 crops (peanut and cotton) and two cultivars of a C 4 crop (sweet sorghum). The results highlighted the significance of our model in (1) its accurate and simultaneous reproduction of light response of both Φ PSII and the photosynthetic electron transport rate ( ETR ) over a wide I range from light limited to photoinhibition I levels and (2) accurately returning key parameters defining the light response curves.
Broadband photomultiplication-type polymer photodetectors and its application in light-controlled circuit
Photomultiplication-type polymer photodetectors (PM-PPDs) were achieved with polymer P3HT as donor and PY3Se-1V as acceptor based on structure of ITO/PEDOT:PSS/active layer/Al. The optimal weight ratio of P3HT to PY3Se-1V is about 100:3. Amounts of isolated electron traps are formed with PY3Se-1V surrounded by P3HT due to rather less content of PY3Se-1V in active layers and about 0.94 eV energy offset between the lowest unoccupied molecular orbitals (LUMO) of P3HT and PY3Se-1V. The optimal PM-PPDs exhibit broad spectral response from 350 to 950 nm and external quantum efficiency (EQE) values of 68,200% at 360 nm, 26,400% at 630 nm and 19,500% at 850 nm under −15 V bias. The working mechanism of PM-PPDs is attributed to the interfacial trap-assisted hole tunneling injection from external circuit. The performance of PM-PPDs can be further improved by incorporating appropriate PMBBDT with high hole mobility as the third component. The EQE values of optimal ternary PM-PPDs are increased to 105,000% at 360 nm, 40,000% at 630 nm and 31,800% at 850 nm under −15 V bias, benefiting from the enhanced hole transport in ternary active layers. The optimal ternary PM-PPDs were successfully applied in a light-controlled circuit to turn on or turn off light emitting diode (LED).
Evaluation of Average Quantum Efficiency of Industrial Digital Camera
Quantum efficiency (QE) is a critical metric for assessing the performance of industrial digital cameras. The current EMVA1288 standard relies on monochromatic light for QE measurements. Comprehensive QE tests across the visible spectrum often involve elaborate setups and extensive data acquisition. Additionally, such tests may not fully capture camera performance under broadband illumination, which is frequently encountered in industrial applications. This study introduces the concept of average quantum efficiency (AQE) using white light sources and proposes a novel testing method. Systematic experiments and data analyses were performed on two industrial digital cameras under white light sources with different spectral distributions. The results suggest that AQE testing offers a practical and efficient means to evaluate camera performance under broadband illumination, complementing existing monochromatic QE measurement methods.
Progress of InGaN-Based Red Micro-Light Emitting Diodes
InGaN-based red micro-size light-emitting diodes (μLEDs) have become very attractive. Compared to common AlInGaP-based red µLEDs, the external quantum efficiency (EQE) of InGaN red µLEDs has less influence from the size effect. Moreover, the InGaN red µLEDs exhibit a much more robust device performance even operating at a high temperature of up to 400 K. We review the progress of InGaN red μLEDs. Novel growth methods to relax the strain and increase the growth temperature of InGaN red quantum wells are discussed.
Chiral multiple-resonance thermally activated delayed fluorescence materials based on chiral spiro-axis skeleton for efficient circularly polarized electroluminescence
Chiral luminescence materials have potential applications in the field of three-dimensional displays due to their circularly polarized luminescence (CPL) characteristics. However, the further development of circularly polarized organic light-emitting diodes (CP-OLEDs) needs to meet the requirements of high efficiency, high color purity, low cost, and high dissymmetry factor (g PL or g EL ), chiral multiple resonance thermally activated delayed fluorescence (MR-TADF) materials are considered as candidates in these aspects. Herein, based on a pair of chiral spirofluorene precursors, two pairs of high-performance chiral MR-TADF emitters (( R/S )- p -Spiro-DtBuCzB and ( R/S )- m -Spiro-DtBuCzB) are developed, which exhibit strong emissions peaking at 491 and 502 nm in toluene with full-width at half-maximum values of 25 and 33 nm, respectively. In addition, small singlet–triplet energy gaps of 0.15 and 0.10 eV with high absolute photoluminescence efficiencies of 95.0% and 96.7% are observed for p -Spiro-DtBuCzB and m -Spiro-DtBuCzB molecules, respectively. OLEDs based on p -Spiro-DtBuCzB and m -Spiro-DtBuCzB display high maximum external quantum efficiencies of 29.6% and 33.8%, respectively. Most importantly, CP-OLEDs present symmetric circularly polarized electroluminescence spectra with ∣g EL ∣ factors of 3.36×10 −4 and 7.66×10 −4 for devices based on ( R/S )- p -Spiro-DtBuCzB and ( R/S )- m -Spiro-DtBuCzB enantiomers, respectively.
Improved Visible Emission from ZnO Nanoparticles Synthesized via the Co-Precipitation Method
Since ZnO nanoparticles (NPs) possess a variety of intrinsic defects, they can provide a wide spectrum of visible emission, without adding any impurity or any doping atoms. They are attracting more and more interest as a material for light sources and energy downshifting systems. However, defect emission with a high luminescence quantum efficiency (PL QY) is difficult to obtain. Here, we present the co-precipitation synthesis parameters permitting to attain ZnO NPs with highly visible PL QYs. We found that the nature of zinc precursors and alkaline hydroxide (KOH or LiOH) used in this method affects the emission spectra and the PL QY of the as-grown ZnO NPs. LiOH is found to have an advantageous effect on the visible emission efficiency when added during the synthesis of the ZnO NPs. More precisely, LiOH permits to increase the emission efficiency in the visible up to 13%. We discuss the effects of the nanoparticle size, the morphology and the surface stabilization on the enhancement of the luminescent emission efficiency. Various spectral contributions to the luminescent emission were also examined, in order to achieve a control of the defect emission to increase its efficiency.
Effects of Electron Blocking Layer Thickness on the Electrical and Optical Properties of AlGaN-Based Deep-Ultraviolet Light-Emitting Diode
The aluminum gallium nitride (AlGaN)-based deep-ultraviolet light-emitting diode (DUV-LED) has been a prominent device due to its contribution in various fields. The electron blocking layer (EBL) is an additional layer in the epitaxy of the DUV-LED with the aim of reducing the overflow of electrons and improving the hole injection, consequently increasing the performance of the DUV-LED. However, the threshold of the EBL thickness and its influence on the electrical and optical properties is still not fully understood. Hence, the purpose of this research is to investigate the effects of varying the EBL thickness, ranging from 5 nm up to 60 nm, and investigate the threshold of EBL thickness for the AlGaN-based DUV-LED. The analysis includes the internal quantum efficiency (IQE), luminescence spectrum, band diagram behavior, and the current density of the carrier. It is found that EBL thickness of 15 nm produces the highest IQE (39.69%) for the DUV-LED with a single quantum well structure, where the wavelength emitted is ~ 257 nm, which is within the ultraviolet C (UVC) range.
Type-I CdSe@CdS@ZnS Heterostructured Nanocrystals with Long Fluorescence Lifetime
Conventional single-component quantum dots (QDs) suffer from low recombination rates of photogenerated electrons and holes, which hinders their ability to meet the requirements for LED and laser applications. Therefore, it is urgent to design multicomponent heterojunction nanocrystals with these properties. Herein, we used CdSe quantum dot nanocrystals as a typical model, which were synthesized by means of a colloidal chemistry method at high temperatures. Then, CdS with a wide band gap was used to encapsulate the CdSe QDs, forming a CdSe@CdS core@shell heterojunction. Finally, the CdSe@CdS core@shell was modified through the growth of the ZnS shell to obtain CdSe@CdS@ZnS heterojunction nanocrystal hybrids. The morphologies, phases, structures and performance characteristics of CdSe@CdS@ZnS were evaluated using various analytical techniques, including transmission electron microscopy, X-ray diffraction, UV-vis absorption spectroscopy, fluorescence spectroscopy and time-resolved transient photoluminescence spectroscopy. The results show that the energy band structure is transformed from type II to type I after the ZnS growth. The photoluminescence lifetime increases from 41.4 ns to 88.8 ns and the photoluminescence quantum efficiency reaches 17.05% compared with that of pristine CdSe QDs. This paper provides a fundamental study and a new route for studying light-emitting devices and biological imaging based on multicomponent QDs.
Research Progress of AlGaN-Based Deep Ultraviolet Light-Emitting Diodes
AlGaN-based deep ultraviolet light-emitting diodes (DUV LEDs) have great application prospects in sterilization, UV phototherapy, biological monitoring and other aspects. Due to their advantages of energy conservation, environmental protection and easy miniaturization realization, they have garnered much interest and been widely researched. However, compared with InGaN-based blue LEDs, the efficiency of AlGaN-based DUV LEDs is still very low. This paper first introduces the research background of DUV LEDs. Then, various methods to improve the efficiency of DUV LED devices are summarized from three aspects: internal quantum efficiency (IQE), light extraction efficiency (LEE) and wall-plug efficiency (WPE). Finally, the future development of efficient AlGaN-based DUV LEDs is proposed.