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Rigid PVC plastics (R-PVC) contain large amounts of chlorine, and improper disposal can adversely affect the environment. Nevertheless, there is still a lack of sufficient studies on hydrothermal treatment (HTT) for the efficient dechlorination of R-PVC. To investigate the migration mechanism of chlorine during the HTT of R-PVC, R-PVC is treated with HTT at temperatures ranging from 220 °C to 300 °C for 30 min to 90 min. Hydrochar is characterized via Fourier transform infrared spectrometry and X-ray photoelectron spectroscopy. The results revealed that the hydrothermal temperature is the key factor that affects the dechlorination of R-PVC. Dramatic dechlorination occurs at temperatures ranging from 240 °C to 260 °C, and the dechlorination efficiency increases with the increase in the hydrothermal temperature. The main mechanism for the dechlorination of R-PVC involves the nucleophilic substitution of chlorine by -OH. CaCO3 can absorb HCl released by R-PVC and hinder the autocatalytic degradation of R-PVC; hence, the dechlorination behavior of R-PVC is different from that of pure PVC resins. Based on these results, a possible degradation process for R-PVC is proposed. This study suggests that HTT technology can be utilized to convert organochlorines in R-PVC to calcium chloride, achieving the simultaneous dechlorination of R-PVC and utilization of products.

The paper presents the characteristics of unplasticized PVC composites modified with biofiller obtained from the waste eggshells of hen eggs. The composites obtained by extrusion contained from 10 phr to 40 phr of biofiller. The filler was characterized using the SEM, TG, and sieve analysis methods. The influence of the filler on the processing properties was determined using plastographometric and MFR tests. Fundamental analysis of mechanical properties was also performed, i.e., Charpy impact strength and determination of tensile properties. The mechanical properties were supported with dynamical mechanical thermal analysis, time of thermal stability, and thermogravimetric analysis. Structure analysis was also performed using SEM and X-ray microcomputed tomography (micro-CT). The processing properties of the tested composites do not give grounds for disqualifying such material from traditional processing PVC mixtures. Notably, the biofiller significantly improves thermal stability. Ground eggshells (ES) work as scavengers for the Cl radicals released in the first stage, which delays the PVC chain’s decay. Additionally, a significant increase in the value of the modulus of elasticity and softening point (VST) of the composites concerning PVC was found. Ground hen eggshells can be used as an effective filler for PVC composites.

This study develops an ontology-based decision support framework to enhance sustainable polymer recycling within the circular economy. The framework, constructed in Protégé (OWL 2), systematically captures polymer categories with emphasis on polyethylene terephthalate (PET), polylactic acid (PLA), and rigid polyvinyl chloride (PVC) as well as recycling processes, waste classifications, and sustainability indicators such as carbon footprint. Semantic reasoning was implemented using the Semantic Web Rule Language (SWRL) and SPARQL Protocol and RDF Query Language (SPARQL) to infer optimal material flows and sustainable pathways. Validation through a UK industrial case study confirmed both the framework’s applicability and highlighted barriers to large-scale recycling, including performance gaps between virgin and recycled polymers. The comparative analysis showed carbon footprints of 2.8 kg CO2/kg for virgin PET, 1.5 kg CO2/kg for PLA, and 2.1 kg CO2/kg for PVC, underscoring material-specific sustainability challenges. Validation through a UK industrial case study further highlighted additive complexity in PVC as a major barrier to large scale recycling. Bibliometric and thematic analyses conducted in this study revealed persistent gaps in sustainability metrics, lifecycle assessment, and semantic support for circular polymer systems. By integrating these insights, the proposed framework provides a scalable, data-driven tool for evaluating and optimising polymer lifecycles, supporting industry transitions toward resilient, circular, and net-zero material systems.

Despite the remarkable progress in the modification and application of polyvinyl chloride (PVC), developing processing aids for the induced crystallization of PVC and characterizing its interfacial layer remain challenges. Herein, we propose a new polymeric nucleating agent, polyamidea12-graft-styrene–maleic anhydride copolymer (PA12-g-SMA), which possesses high compatibility and crystallinity, effectively improving the crystallinity to 15.1%, the impact strength to 61.03 kJ/m2, and the degradation temperature of PVC to 267 °C through a single and straightforward processing step. Additionally, after the introduction of two different fluorescent sensors in PA12-g-SMA and PVC, the interfacial layer of the induced crystallization can be monitored in situ via a confocal laser scanning microscope (CLSM). This study highlights a rare strategy for significantly enhancing the physical properties of rigid PVC through simply adding a polymeric nucleating agent during processing, while also emphasizing the importance of visualizing the interfacial layer to understand various polymer crystallization processes.

In this paper, the effects of organic based stabilizers (OBS) are investigated and compared with traditional lead (Pb) and calcium zinc (CaZn) heat stabilizers regarding their processability, mechanical property, and thermal degradation behaviors in rigid PVC pipe applications. In addition, the effects of repeated processing cycles on the degree of gelation and the impact strength of the PVC/OBS, PVC/CaZn, and PVC/Pb are also examined. A repeated processing cycle of those three types of the heat stabilizers up to four cycles was found to increase the degree of gelation and proved no significant effect on the impact strength and heat resistance of the resulting PVC samples. The OBS showed a positive effect on preventing the autocatalytic-typed thermal degradation of the PVC samples. This leads to a longer retention time for the initial color change of the PVC/OBS compared to PVC/Pb or PVC/CaZn systems. This characteristic was related to a more uniform fusion behavior of the PVC/OBS, i.e., the lowest gelation speed and the longest fusion time. The non-isothermal kinetic parameter determined by the Kissinger and Flynn–Wall–Ozawa methods of the dehydrochlorination stage of the PVC/OBS was in satisfactory agreement and continued to compare with the PVC/Pb and PVC/CaZn systems. The results indicated that the OBS might decrease the dehydrochlorination rate of PVC, implying that PVC/OBS was more stable than PVC/Pb and PVC/CaZn systems.

A set of linear Fischer-Tropsch (FT) waxes were oxidized to various degrees by utilizing an ozonolysis method. These waxes were comprehensively characterized in tenns of their chemical composition, thennal behaviour, molecular weight distributions, and overall polarity using various analytical techniques, including Fourier transfonn infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), differential scanning calorimetry (DSC), high temperature size exclusion chromatography (HT-SEC) along with nonnal and reverse-phase high temperature solvent gradient interaction chromatography (HT-SGIC). Application-based studies were perfonned by evaluating the behaviour of these waxes in unplasticized polyvinyl chloride (uPVC) fonnulations. Analyses included hot melt mixing, single screw extrusion, scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDS), and torque rheometry. Through a combination of these techniques, the lubrication mechanism of these waxes could be explained by the Rabinovitch model. It was found that a combination of molecular size and degree of polarity play a vital role in the migration of the waxes and therefore ultimately impacts the fusion behaviour of the overall polyvinyl chloride (PVC) fonnulation. Results indicate that fusion times can greatly be altered when using oxidised waxes, and this could be promising for the development of multifunctional lubricant systems.

In modern manufacturing systems with computational complexities, decision-making with respect to dynamic rescheduling and reconfiguration in case of internal disturbances is an important issue. This paper introduces a multi-agent-based dynamic scheduling system for manufacturing flow lines (MFLs) using the Prometheus methodology (PM) considering the dynamic customer demands and internal disturbances. The PM is used for designing a decision-making system with the feature of simultaneous dynamic rescheduling. The developed system is implemented on a real MFL of a small- and medium-sized enterprise (unplasticized polyvinyl chloride (uPVC) door and window) where the dynamic customer demands and internal machine break downs are considered. The application has been completely modeled using a Prometheus design tool, which offers full support to the PM, and implemented in JACK agent-based systems. Each agent is autonomous and has an ability to cooperate and negotiate with other agents. The proposed decision-making system supports both static and dynamic scheduling. A simulation platform for testing the proposed multi-agent system (MAS) is developed, and two real scenarios are defined for evaluating the proposed system. The analysis takes into account the comparisons of the overall performances of the system models using the MAS scheduling and conventional scheduling approaches. The result of simulation indicates that the proposed MAS could increase the uptime productivity and the production rate of flexible flow-line manufacturing systems.

A tetra-ester (TE) functionalized organic compound was synthesized for the restoration the mechanical properties of the PVC/Mg(OH) 2 nanocomposites. The organically modified Mg(OH) 2 nanoparticles (OMN) were prepared by surface modification of Mg(OH) 2 nanoparticles (MDH) using a methylated tetra-phenol (TP) organic compound to achieve the homogeneous MDH distribution in the nanocomposite matrix. The results of FT-IR, XRD, and FE-SEM revealed the successful surface treating of MDH. The PVC nanocomposites were prepared by solvent blending and casting method. From the TGA analyses, the 10% mass loss temperature and the char yield of PVC containing 3% by mass of OMN and 3% by mass of TE, in N 2 atmosphere, increased by 13 °C and 7%, respectively, compared to unfilled PVC. From the microscale combustion calorimeter, a decreasing heat release rate from 125.2 to 92.8 W g –1 was observed for PVC film filled with 6% by mass of each additive, compared to unfilled PVC. The tensile test results revealed that TE and OMN have been effective for the improvement of the PVC tensile strength. For example, incorporating only 6% by mass of each filler led to an improvement in tensile strength from 58.99 to 80.58 MPa, compared to unfilled PVC.

The creep behavior of rigid polyvinyl chloride (PVC) in hydrothermal environments can compromise its long-term stability and load-bearing capacity, potentially leading to deformation or structural failure. Understanding this degradation is critical for ensuring the durability and safety of PVC in engineering applications such as pipelines and building materials. In this study, accelerated hydrothermal aging tests were carried out on PVC under controlled conditions of 60 °C and 90% relative humidity (RH). Short-term tensile creep tests at four different stress levels were conducted both before and after aging. Microstructural changes associated with the PVC’s creep behavior were analyzed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and other microscopic characterization techniques. These analyses provided a detailed microscopic interpretation of how hydrothermal exposure and applied loads influenced the macroscopic creep performance of the PVC, thereby elucidating the correlation between its macroscopic mechanical behavior and microstructural evolution. By applying the time–stress equivalence principle and the time–aging equivalence principle, the short-term creep behavior was characterized to predict long-term performance. The accelerated characterization curve can effectively predict the creep behavior of PVC under a stress level of 16 MPa over approximately 6.5 years in an environment of 60 °C and 90% RH. At the same time, the master creep modulus curve of PVC under any aging duration and stress level can be established under the specified environmental conditions of 60 °C and 90% RH. Long-term creep curves were fitted using a locally structured derivative Kelvin model, demonstrating that this model can effectively simulate the long-term creep behavior of PVC under hydrothermal conditions. The results indicate that at a stress level of 16 MPa, PVC is expected to undergo creep damage and failure after approximately 15 years in such an environment. These findings provide a critical reference for assessing the long-term performance of PVC in hydrothermal environments.

Studies that evaluate the impact of microplastic particles (MPs) often apply particles of pristine material. However, MPs are affected by various abiotic and biotic processes in the environment that possibly modify their physical and chemical characteristics, which might then result in their altered toxic effect. This study evaluated the consequence of weathering on the release of toxic leachates from microplastics. MPs derived from six marine antifouling paints, end-of-life tires, and unplasticised PVC were exposed to UV-C radiation to simulate weathering. Non-weathered and weathered MPs were leached in algae growth medium for 72 h to demonstrate additive release under freshwater conditions. The model organism, green algae Raphidocelis subcapitata, was exposed to the resulting leachates of both non-weathered and weathered MPs. The results of the growth inhibition tests showed that the leachates of weathered microparticles were more toxic than of the non-weathered material, which was reflected in their lower median effect concentration (EC50) values. Chemical analysis of the leachates revealed that the concentration of heavy metals was several times higher in the leachates of the weathered MPs compared to the non-weathered ones, which likely contributed to the increased toxicity. Our findings suggest including weathered microplastic particles in exposure studies due to their probably differing impact on biota from MPs of pristine materials.