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"Rocks, Sedimentary"
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Influence of sulfate reduction rates on the Phanerozoic sulfur isotope record
Phanerozoic levels of atmospheric oxygen relate to the burial histories of organic carbon and pyrite sulfur. The sulfur cycle remains poorly constrained, however, leading to concomitant uncertainties in O ₂ budgets. Here we present experiments linking the magnitude of fractionations of the multiple sulfur isotopes to the rate of microbial sulfate reduction. The data demonstrate that such fractionations are controlled by the availability of electron donor (organic matter), rather than by the concentration of electron acceptor (sulfate), an environmental constraint that varies among sedimentary burial environments. By coupling these results with a sediment biogeochemical model of pyrite burial, we find a strong relationship between observed sulfur isotope fractionations over the last 200 Ma and the areal extent of shallow seafloor environments. We interpret this as a global dependency of the rate of microbial sulfate reduction on the availability of organic-rich sea-floor settings. However, fractionation during the early/mid-Paleozoic fails to correlate with shelf area. We suggest that this decoupling reflects a shallower paleoredox boundary, primarily confined to the water column in the early Phanerozoic. The transition between these two states begins during the Carboniferous and concludes approximately around the Triassic–Jurassic boundary, indicating a prolonged response to a Carboniferous rise in O ₂. Together, these results lay the foundation for decoupling changes in sulfate reduction rates from the global average record of pyrite burial, highlighting how the local nature of sedimentary processes affects global records. This distinction greatly refines our understanding of the S cycle and its relationship to the history of atmospheric oxygen.
Journal Article
Sedimentary rocks
Explores Earth science's natural processes, how geologists study sedimentary rocks, and how sedimentary rocks relate to our daily life.
Book
ISRM-Suggested Method for Determining the Mode I Static Fracture Toughness Using Semi-Circular Bend Specimen
The International Society for Rock Mechanics has so far developed two standard methods for the determination of static fracture toughness of rock. They used three different core-based specimens and tests were to be performed on a typical laboratory compression or tension load frame. Another method to determine the mode I fracture toughness of rock using semi-circular bend specimen is herein presented. The specimen is semi-circular in shape and made from typical cores taken from the rock with any relative material directions noted. The specimens are tested in three-point bending using a laboratory compression test instrument. The failure load along with its dimensions is used to determine the fracture toughness. Most sedimentary rocks which are layered in structure may exhibit fracture properties that depend on the orientation and therefore measurements in more than one material direction may be necessary. The fracture toughness measurements are expected to yield a size-independent material property if certain minimum specimen size requirements are satisfied.
Journal Article
What are sedimentary rocks?
\"An introduction to a physical feature of the environment that tells us a great deal about the Earth's geological history, it's current state, and the shape of things to come.\"--Provided by publisher.
Book
Ocean oxygenation in the wake of the Marinoan glaciation
Data are presented that support the idea of an oxygenation event in the immediate aftermath of the Marinoan glaciation, pre-dating previous estimates for post-Marinoan oxygenation by more than 50 million years.
A breath of oxygen for the early metazoans
Macroscopic metazoans first appeared in the fossil record shortly after the termination of the late Cryogenian (Marinoan) glaciation about 635 million years ago. It has been suggested that an oxygenation event at about this time was the driving factor behind the rise of the metazoans, but current estimates suggest that oxygenation occurred between 580 million and 550 million years ago, well after initial animal diversification. New geochemical data from early Ediacaran organic-rich black shales of the basal Doushantuo Formation in South China now suggest that the oxidation event occurred more than 50 million years earlier, in the immediate aftermath of the Marinoan glaciation. The data provide evidence for a significant postglacial oxygenation and support a link between the most severe glaciations in Earth's history, the oxygenation of Earth's surface and the earliest emergence of complex animals.
Metazoans are likely to have their roots in the Cryogenian period
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, but there is a marked increase in the appearance of novel animal and algae fossils shortly after the termination of the late Cryogenian (Marinoan) glaciation about 635 million years ago
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. It has been suggested that an oxygenation event in the wake of the severe Marinoan glaciation was the driving factor behind this early diversification of metazoans and the shift in ecosystem complexity
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. But there is little evidence for an increase in oceanic or atmospheric oxygen following the Marinoan glaciation, or for a direct link between early animal evolution and redox conditions in general
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. Models linking trends in early biological evolution to shifts in Earth system processes thus remain controversial
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. Here we report geochemical data from early Ediacaran organic-rich black shales (∼635–630 million years old) of the basal Doushantuo Formation in South China. High enrichments of molybdenum and vanadium and low pyrite sulphur isotope values (Δ
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S values ≥65 per mil) in these shales record expansion of the oceanic inventory of redox-sensitive metals and the growth of the marine sulphate reservoir in response to a widely oxygenated ocean. The data provide evidence for an early Ediacaran oxygenation event, which pre-dates the previous estimates for post-Marinoan oxygenation
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by more than 50 million years. Our findings seem to support a link between the most severe glaciations in Earth’s history, the oxygenation of the Earth’s surface environments, and the earliest diversification of animals.
Journal Article
What are sedimentary rocks?
It all starts with erosion for sedimentary rock. Worn down bits of rock become pressed together under pressure into strata, or layers. The formation of rock such as sandstone, shale, limestone, and dolomite is explained.
Book
Stable Prenucleation Calcium Carbonate Clusters
Calcium carbonate forms scales, geological deposits, biominerals, and ocean sediments. Huge amounts of carbon dioxide are retained as carbonate ions, and calcium ions represent a major contribution to water hardness. Despite its relevance, little is known about the precipitation mechanism of calcium carbonate, and specified complex crystal structures challenge the classical view on nucleation considering the formation of metastable ion clusters. We demonstrate that dissolved calcium carbonate in fact contains stable prenucleation ion clusters forming even in undersaturated solution. The cluster formation can be characterized by means of equilibrium thermodynamics, applying a multiple-binding model, which allows for structural preformation. Stable clusters are the relevant species in calcium carbonate nucleation. Such mechanisms may also be important for the crystallization of other minerals.
Journal Article
Sedimentary rocks
Learn about sedimentary rocks, what they are, how they form, and what they can be used for.
Book
Propagation from meteorological to hydrological drought in the Horn of Africa using both standardized and threshold-based indices
There have been numerous drought propagation studies in data-rich countries, but not much has been done for data-poor regions (such as the Horn of Africa, HOA). In this study, we characterize meteorological, soil moisture and hydrological drought and the propagation from one to the other for 318 catchments in the HOA to improve understanding of the spatial variability in the drought hazard. We calculate the standardized precipitation index (SPI), standardized soil moisture index (SSMI) and standardized streamflow index (SSI). In addition, we use the variable threshold method to calculate the duration of drought below a predefined percentile threshold for precipitation, soil moisture and discharge. The relationship between meteorological and soil moisture drought is investigated by finding the SPI accumulation period that has the highest correlation between SPI and SSMI, and the relationship between meteorological and hydrological drought is analysed by the SPI accumulation period that has the highest correlation between SPI and SSI time series. Additionally, we calculated these relationships with the ratio between the threshold-based meteorological-drought duration and soil moisture drought duration and the relation between threshold-based meteorological-drought duration and streamflow drought duration. Finally, we investigate the influence of climate and catchment characteristics on these propagation metrics. The results show that (1) the propagation from SPI to SSMI and the mean drought duration ratio of meteorological to soil moisture drought (P / SM) are mainly influenced by soil properties and vegetation, with the short accumulation periods (1 to 4 months) of SPI in catchments with arable land, high mean annual precipitation, and low sand and silt content, while longer accumulations (5 to 7 months) are in catchments with low mean annual upstream precipitation and shrub vegetation; (2) the propagation from SPI to SSI and precipitation-to-streamflow duration ratio are highly influenced by the climate and catchment control, i.e. geology, elevation and land cover, with the short accumulation times in catchments with high annual precipitation, volcanic permeable geology and cropland and the longer accumulations in catchments with low annual precipitation, sedimentary rocks and shrubland; and (3) the influence of mean annual upstream precipitation is more important for the propagation from SPI to SSI than from SPI to SSMI. Additionally, precipitation accumulation periods of approximately 1 to 4 months in wet western areas of the HOA and of approximately 5 to 7 months in the dryland regions are found. This can guide forecasting and management efforts as different drought metrics are thus of importance in different regions.
Journal Article