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At present, high-damping rubber materials, widely used in the field of engineering seismic isolation, generally have the problems such as narrow effective damping temperature range, low damping loss factor and strong temperature dependence, which lead to prominent dependence of temperature and load conditions of the isolation performance of high-damping rubber isolation bearings. Research and development of high-performance high-damping rubber materials with broad effective damping temperature range, high damping loss factor and weak temperature dependence are very urgent and necessary to ensure the safety of the seismic isolation of engineering structures. This paper mainly reviews the recent progress in the research and development of high-damping rubber materials using nitrile butadiene rubber (NBR), epoxidized natural rubber (ENR), ethylene propylene diene rubber (EPDM), butyl rubber (IIR), chlorinated butyl rubber (CIIR), and bromine butyl rubber (BIIR). This is followed by a review of vulcanization and filler reinforcement systems for the improvement of damping and mechanical properties of high-damping rubber materials. Finally, it further reviews the constitutive models describing the hyperelasticity and viscoelasticity of rubber materials. In view of this focus, four key issues are highlighted for the development of high-performance high-damping rubber materials used for high-damping rubber isolation bearings.

Natural rubber is a unique biopolymer of strategic importance that, in many of its most significant applications, cannot be replaced by synthetic alternatives. The rubber tree Hevea brasiliensis is the almost exclusive commercial source of natural rubber currently and alternative crops should be developed for several reasons, including: a disease risk to the rubber tree that could potentially decimate current production, a predicted shortage of natural rubber supply, increasing allergic reactions to rubber obtained from the Brazilian rubber tree and a general shift towards renewables. This review summarizes our knowledge of plants that can serve as alternative sources of natural rubber, of rubber biosynthesis and the scientific gaps that must be filled to bring the alternative crops into production.

Natural rubber (NR) is in high demand due to its excellent elasticity and physical and mechanical properties, but production is limited and NR is in short supply. There is an urgent need to find new alternative rubber sources. Taraxacum kok-saghyz (TKS), as a green, renewable, widely planted and high content rubber producing plant, has shown broad application prospects. The extraction process is the key to developing efficient, green, and high-purity Taraxacum kok-saghyz Natural Rubber (TKNR) to replace NR in various applications. In this study, TKS roots were processed through repeated boiling to remove inulin, followed by alkaline treatment with potassium hydroxide (KOH) to isolate lignin and facilitate cell wall disruption. Subsequent enzymatic hydrolysis using pectinase and cellulase enabled the dissolution of root-structure carbohydrates, thereby obtained TKNR. Structural characterization of TKNR was conducted and compared with that of NR. The results showed that the combined alkaline and enzymatic extraction methodology effectively isolates TKNR from TKS roots. Structural analysis reveals that TKNR closely resembles NR, having comparable molecular weight and distribution, crystallinity, and crosslinking networks, with both polymers primarily consisting of cis-1,4-polyisoprene.

Guayule (Parthenium argentatum Gray) is a promising alternative source to Hevea brasiliensis for the production of natural rubber, which can reach levels of 8–9% under industrialized farming conditions. The most common method for determining rubber concentration is by accelerated solvent extraction (ASE), a technique developed by the Dionex Corporation and almost exclusively performed with the Dionex ASE-200 or 350 systems. Herein, it is sought to apply and adapt the most common methods used in the literature for the Dionex system to another extraction platform, the BÜCHI Speed Extractor E-914. Results showed that using a sand sandwich method to confine the sample in the center and exploiting a larger cell volume (80 mL) for extraction prevents the occurrence of overpressure and problems with clogging. Under optimized conditions, the coefficient of variation was <15% for both resin quantification for samples containing 5.0–15.8% of resin and for rubber quantification for samples with 1.7–10.3% rubber content. The extraction time for resin (2 cycles of 5 min each) was smaller than for rubber (2 cycles of 20 min each). It would be interesting to carry out interlaboratory comparisons to standardize the method at an international level.

In this paper, we examined the parameters of the Mooney–Rivlin model based on the effects of alternative aging and sea corrosion tests for natural rubber bearings and rubber materials in seawater. The model parameters for rubber material used in natural rubber bearings were determined using the least-squares method. Meanwhile, the time-varying law formula of the Mooney–Rivlin model parameters of rubber were fitted, and the fitting and calculated values were compared. Both fitting values and calculated values coincide with each other well. Then, the rubber material parameters were predicted based on the calculated results and combined with nonlinear auto-regressive (NAR). The predicted values were compared with both the fitting and calculated values. The average deviations between predicted and fitting values for C10 and C01 were 2.6% and 5.1%, respectively, and average deviations between predicted and calculated values for C10 and C01 were 5.2% and 4.1%. Compared results show that the predicted values are in good agreement with both the fitting and calculated values; meanwhile, the proposed time-varying law formula of the Mooney–Rivlin model parameters of rubber material have been well verified.

Protein hydrolysis enables production of peptides and free amino acids that are suitable for usage in food and feed or can be used as precursors for bulk chemicals. Several essential amino acids for food and feed have hydrophobic side chains; this property may also be exploited for subsequent separation. Here, we present methods for selective production of hydrophobic amino acids from proteins. Selectivity can be achieved by selection of starting material, selection of hydrolysis conditions, and separation of achieved hydrolysate. Several protease combinations were applied for hydrolysis of rubber seed protein concentrate, wheat gluten, and bovine serum albumin (BSA). High degree of hydrolysis (>50 %) could be achieved. Hydrophobic selectivity was influenced by the combination of proteases and by the extent of hydrolysis. Combination of Pronase and Peptidase R showed the highest selectivity towards hydrophobic amino acids, roughly doubling the content of hydrophobic amino acids in the products compared to the original substrates. Hydrophobic selectivity of 0.6 mol-hydrophobic/mol-total free amino acids was observed after 6 h hydrolysis of wheat gluten and 24 h hydrolysis of rubber seed proteins and BSA. The results of experiments with rubber seed proteins and wheat gluten suggest that this process can be applied to agro-industrial residues.

In this study, the effects of ambient temperature on the horizontal mechanical performance of isolated rubber bearings were investigated using high-speed reciprocating loading methods. A comprehensive series of 54 experimental trials are performed on the full-scale (900 mm-diameter) isolation rubber bearings, encompassing a range of temperatures (−20 °C, 0 °C, and 23 °C), shear pressures (50%, 100%, and 250%), and frequencies (0.20 Hz, 0.25 Hz, and 0.30 Hz). Because the compression-shear tests were conducted at high velocities and pressures (specifically, vertical compressive stress of 15 MPa), the equipment used in these tests was capable of generating substantial inertial and frictional forces. Appropriate correction methodologies for the precise determination of mechanical performance metrics for bearings are presented. Then, a comprehensive investigation of the effects of various loading conditions on the characteristic strength, post-yield stiffness, horizontal equivalent stiffness, and equivalent damping ratio of LRB900 (lead-core rubber bearings 900 mm-diameter) and LNR900 (linear natural rubber bearings 900 mm-diameter) is conducted. The empirical results show a discernible relationship between these characteristics and ambient temperature as the number of loading cycles increases, except for the equivalent damping ratio. Finally, empirical fitting formulations incorporating the influence of ambient temperature are presented for each performance indicator. These formulas are intended to assist designers in performing seismic design analyses by allowing them to take into consideration the effects of ambient temperature comprehensively.

As the rubber constituting laminated rubber isolation bearings is a temperature-sensitive material, its performance is susceptible to temperature disturbances. Firstly, this study systematically analyzed the effects of temperature on the mechanical properties of natural rubber bearings (LNR), lead–rubber bearings (LRB), and high–damping rubber bearings (HDR), including horizontal equivalent stiffness, equivalent damping ratio, and yield load. The variation trends of the mechanical property parameters of the three types of bearings with temperature are basically the same. LNR exhibits a strong linear variation law, while the mechanical properties of HDR bearings are the most sensitive to temperature changes. Secondly, based on the analysis of the temperature characteristics of the mechanical properties of the bearings, the temperature dependence of the seismic mitigation effect of the bearings was further studied. The results show that the displacement response of the isolation layer has the best temperature stability when using LRB bearings, and the displacement response of the superstructure is most susceptible to temperature changes when using HDR bearings. When the temperature is lower than the normal temperature, the displacement responses of isolation systems with different types of bearings all show the characteristic that the lower the temperature, the greater the deviation from the displacement response at normal temperature. Finally, to overcome the influence of temperature, a temperature-controlled isolation rubber bearing integrating laminated rubber isolation bearings with a temperature regulation system was proposed. This can solve the problems that the mechanical properties of rubber bearings deteriorate and the aging rate accelerates in a wide temperature range, which affect their isolation effect and service life. Thus, it endows new theoretical connotations to rubber isolation bearings and has practical application value for engineering seismic resistance.

With the rapid development of the economy and urbanization, the construction of the urban rail transit system has had a great impact on the work, life, and health of residents in buildings along the rail transit line. Thus, it is particularly urgent and necessary to develop base isolation technologies to control and reduce the impact of vibrations of rail transit systems on building structures. High-damping rubber isolation bearings have shown significant effectiveness in the reduction of this impact, and their isolation performance mainly depends on the mechanical and damping energy dissipation characteristics of the high-damping rubber material. This paper aims to investigate the hyper-viscoelastic properties of the high-damping rubber material used for high-damping rubber isolation bearings during the cyclic tension and compression process in the vertical direction. These properties include hyperelastic parameters, viscoelastic coefficients, and the relaxation times of the material. For this purpose, uniaxial cyclic tension and compression tests were conducted. A three-element Maxwell rheological model combining a strain energy density function was proposed for modeling the hyper-viscoelastic behaviors of the materials during the cyclic tension and compression process. Based on the obtained results, an iterative identification procedure was used to determine the constitutive parameters of the material for each loading-unloading cycle. The aforementioned parameters were further expressed as a function of the number of cycles. New insights into hyper-viscoelastic property changes in this high-damping rubber material during the cyclic tension and compression process were gained in this work. These investigations could facilitate the development of computational tools, which would regulate fundamental guidelines for the better controlling and optimization of the isolation performance of the high-damping rubber material used for high-damping rubber isolation bearings, which have a wider perspective of applications in the urban rail transit system.

In this paper, we present a new attempt to lay ballastless tracks on long-span cable-stayed bridges on high-speed railways. The arrangements of ballastless tracks laid on cable-stayed bridges can be divided into two conditions: (i) across the cable suspension-point cross-section or (ii) in discontinuity at the cable suspension-point cross-section. At present, there is a lack of in-depth research on ballastless tracks laid on long-span cable-stayed bridges, especially on the mechanical behaviors and fatigue performances of the ballastless tracks with different arrangements. For this paper, a segmental model of a long-span cable-stayed bridge was designed and built, on which full-scale ballastless tracks with two different arrangements were arranged. A series of fatigue tests and post-fatigue loading tests were carried out based on the two selected full-scale ballastless tracks. Some conclusions were drawn as follows. For the longitudinal end of the ballastless track, which is far from the loading positions, the interlayers of the ballastless tracks tend to warp up relatively, and the compressive pressures at the interlayers are also unloaded. However, there is no void or gap formed at the interlayers of the longitudinal end of the track slab due to the precompression of the rubber isolation layer. For the center of the track slab, which is close to the loading positions, the compressive deformations occur at the interlayers, and the pressures at interlayers are also increased. The maximum compressive deformation is less than 0.5 mm under the standard train axle load (170 kN), and it cannot affect the high-speed trains’ operation. With the increase of the post-fatigue loading, the load-displacement curves and the load-pressure variation curves of the ballastless tracks show apparent nonlinearity. Moreover, with the increase of the fatigue loading cycles, the compressive stiffness enhancement or degradation of the ballastless tracks are not noticeable. That is to say, the ballastless tracks laid on the long-span cable-stayed bridges with different arrangements have good mechanical behaviors, and their fatigue performances can also be guaranteed after bearing repeated loadings.