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"Rubber Permeability."
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Hydraulic rubber dam : an effective water management technology
\"Hydraulic Rubber Dam: An Effective Water Management Technology is the go-to source for information on the materials, manufacture, mechanics and functional benefit of rubber dams in water management. Readers will find a detailed background on water conservation and coverage, how inflatable rubber dam technology contributes to the picture, and information on the proper manufacture and use of rubber dams to increase water storage for release and delivery during drought. In addition, the book presents tactics on the even distribution of water across populations, how to increase water use efficiency, conservation, and how to prevent flooding. In particular, this book details specialist manufacturing techniques, including the development of rubber compounds and fabric, the bonding and anchoring systems which hold the rubber dam to the underlying concrete structure, and inflation and deflation mechanisms for rubber dams. The book provides a holistic lifecycle assessment of rubber dams to give additional insight to readers looking to deploy rubber dam technology\"--Page 4 of cover.
Filler Effects on H2 Diffusion Behavior in Nitrile Butadiene Rubber Blended with Carbon Black and Silica Fillers of Different Concentrations
2022
Filler effects on H2 diffusion in nitrile butadiene rubbers (NBRs) blended with carbon black and silica fillers of different concentrations are first investigated by employing a volumetric analysis. Total uptake, solubility, and diffusivity of hydrogen for ten filled-NBR, including neat NBR, are determined in an exposed pressure range of 1.3 MPa~92.6 MPa. Filler dependence on hydrogen uptake and diffusion is distinctly observed in the NBRs blended with high abrasion furnace (HAF) carbon black (CB) fillers compared to NBRs blended with medium thermal furnace (MT) CB and silica filler, which is related to the specific surface area of carbon black and interface structure. The HAF CB filled-NBR follows dual sorption behavior combined with Henry’s law and the Langmuir model, responsible for two contributions of solubility from polymer and filler. However, a single gas sorption behavior coming from the polymer is observed satisfying Henry’s law up to 92.6 MPa for NBR blended with MT CB filled-NBR and silica filled-NBR. Diffusion demonstrates Knudsen and bulk diffusion behavior below and above, respectively, at certain pressures. With increasing pressure, the filler effect on diffusion is reduced, and diffusivity converges to a value. The correlation observed between diffusivity and filler content (or crosslink density) is discussed.
Journal Article
Gamma Irradiation Resistance of Four Elastomers for Nuclear Sealing Applications
2025
The reliability of rubber materials in nuclear sealing applications depends on their resistance to ionizing radiation. To explicitly reveal the differences in radiation damage mechanisms among rubbers with varying molecular structures, this study investigated four typical elastomers—natural rubber (NR), butyl rubber (IIR), chloroprene rubber (CR), and nitrile rubber (NBR)—under 60Co γ-irradiation at cumulative doses of 1, 10, and 100 kGy. By coupling macroscopic physical testing (mechanical, permeability) with microstructural characterization (FT-IR, DSC, crosslink density), a correlation between material structure and irradiation behavior was established. The results indicate that main-chain saturation dictates the dominant degradation mechanism: unsaturated rubbers (NR, CR, NBR) are dominated by cross-linking, macroscopically manifested as increased hardness and reduced ductility; conversely, saturated rubber (IIR) is dominated by main-chain scission, leading to a paste-like transition at 100 kGy and a complete loss of mechanical load-bearing and barrier functions. Comparatively, NR exhibited optimal overall stability due to “clean” cross-linking without significant oxidation. The overall radiation resistance ranking within the 0–100 kGy range is NR > CR > NBR > IIR. This study clarifies the “structure-mechanism-property” evolution law, providing a critical theoretical basis for lifetime prediction and rational material selection of rubber components in nuclear environments.
Journal Article
Transcriptomics integrated with widely targeted metabolomics reveals the cold resistance mechanism in Hevea brasiliensis
2023
The rubber tree is the primary source of natural rubber and is mainly cultivated in Southeast Asian countries. Low temperature is the major abiotic stress affecting the yield of the rubber tree. Therefore, uncovering the cold resistance mechanism in the rubber tree is necessary. The present study used RNA-sequencing technology and ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) to analyze the transcriptomic and metabolomic changes in two rubber tree clones with different cold resistance capacities (temperature-sensitive Reyan 8-79 and cold-resistant Yunyan 77-4) at 0 h, 2 h, 6 h, and 20 h of exposure to 4°C. Independent analysis of the transcriptome and metabolitome showed that under prolonged low-temperature treatment, Yunyan 77-4 expressed more genes involved in regulating enzyme activity, changing cell permeability, and synthesizing significant metabolites, such as flavonoids and amino acids, than Reyan 8-79. The KEGG annotation and enrichment analysis identified arginine metabolism and biosynthesis of flavonoids as the major pathway associated with cold resistance. Integrated transcriptome and metabolome analysis showed that the increase in the expression of genes modulated flavonoid biosynthesis, arginine biosynthesis, and anthocyanins biosynthesis, resulting in higher levels of metabolites, such as naringenin chalcone, apigenin, dihydroquercetin, cyanidin 3-glucoside, L-arginosuccinate, N-acetyl-ornithine, ornithine, and N-acetyl-glutamate, in Yunyan 77-4 than in Reyan 8-79 after prolonged low-temperature treatment. Phylogenetic analysis identified the genes, such as CHS ( gene356 ) and F3H ( gene33147 ) of flavonoid biosynthesis and NAGS ( gene16028, gene33765 ), ArgC ( gene2487 ), and ASS ( gene6161 ) of arginine biosynthesis were the key genes involved in the cold resistant of rubber tree. Thus, the present study provides novel insights into how rubber clones resist cold and is a valuable reference for cold-resistance breeding.
Journal Article
Mechanical Properties of Silica Fume Modified High-Volume Fly Ash Rubberized Self-Compacting Concrete
by
Musarat, Muhammad Ali
,
Tayeh, Bassam A.
,
Haruna, Sani
in
Aggregates
,
Carbon footprint
,
Cement hydration
2021
The existing form of self-compacting concrete (SCC) comprises of a large amount of powdered and fine materials. In this study, a part of the cementitious material was replaced with constant high-volume fly ash, and a portion of fine aggregates was substituted by crumb rubber (CR). Besides that, silica fume (SF) was added, with the hope that by implementing a new type of nanomaterial, the loss in mechanical strength due to previous modifications such as rubberization and replacement will be prevented. Two variables were found to influence the constituent/component in the mix design: SF and CR. The proportion of SF varies from 0% to 10%, while that of CR from 0% to 30% by volume of the total river sand, where 55% of cement was replaced by the fly ash. A total of 13 rubberized SCC samples with CR and SF as controlling variables were made, and their design mix was produced by a Design of Experiment (DOE) under the Response Surface Methodology (RSM). The results reveal a slight increase in the mechanical properties with the addition of SF. The theoretical mathematical models and equation for each different mechanical strength were also developed after incorporating the experimental results into the software.
Journal Article
Effect of Rubber Particle Size and Content on the Mechanical Properties of Rubber–Clay Mixtures Solidified by EICP
Using the enzyme-induced carbonate precipitation (EICP) technique to solidify rubber and clay mixtures as lightweight backfill is a feasible way to reduce waste tire impacts and boost rubber recycling in geotech engineering. In this study, a comprehensive laboratory investigation, including triaxial compression, oedometer, permeability, and nuclear magnetic resonance (NMR) tests, was conducted on EICP-reinforced rubber particle solidified clay (hereafter referred to as EICP-RC solidified clay) to evaluate the effects of rubber particle content and size on the mechanical behavior of the improved soil under various solidification conditions and to elucidate the solidification mechanism. The results show that although rubber particles inhibit EICP, they significantly enhance the mechanical properties of the samples. The addition of 5% rubber particles (rubber A) increased cohesion by 11% and the internal friction angle by 18% compared to EICP-treated clay without rubber. Additionally, incorporating smaller-sized tire particles facilitated pore filling, resulting in lower compression and swelling indices and reduced permeability coefficients, making these materials suitable for use behind retaining walls and in embankment construction.
Journal Article
Monotonic and cyclic triaxial testing of untreated and polyurethane-treated soil and soil–rubber mixtures
by
Farooq, Mohammad Adnan
,
Nimbalkar, Sanjay
in
Complex Fluids and Microfluidics
,
Confining
,
Cyclic loading
2024
The present research focuses on developing alternate sustainable base materials for a high-speed slab track. In this study, a series of monotonic triaxial, cyclic triaxial and permeability tests were conducted on four types of materials, viz. mix-A (gravel soil), mix-B (soil mixed with rubber), mix-C (polyurethane foam adhesive (PFA)-treated soil), and mix-D (PFA-treated soil–rubber mixture). The influence of cyclic loading frequency, effective confining pressure, drainage condition and relative density on the deformation, excess pore water pressure, resilient modulus and damping ratio of these different mixes is evaluated. The monotonic triaxial test results indicate that the PFA treatment of mix-A and mix-B increased their shear strength and critical state strength. In contrast, incorporating rubber into mix-A and mix-C helped enhance their ductility. The cyclic triaxial test results show that the PFA treatment of mix-A and mix-B significantly reduced the magnitude of deformation and generation of excess pore water pressure, which caused these untreated mixes to fail prematurely under lower confinement to which a typical base layer is subjected. The influence of cyclic loading frequency and effective confining pressure on the material's response differed for untreated and treated soil. The permeability test results indicate good drainage for mix-D comparable to mix-A.
Journal Article
Gas Barrier, Rheological and Mechanical Properties of Immiscible Natural Rubber/Acrylonitrile Butadiene Rubber/Organoclay (NR/NBR/Organoclay) Blend Nanocomposites
by
Rouxel, Didier
,
Thomas, Martin George
,
Maria, Hanna J.
in
Butadiene
,
Carbon dioxide
,
Communication
2020
In this paper, gas permeability studies were performed on materials based on natural rubber/acrylonitrile butadiene rubber blends and nanoclay incorporated blend systems. The properties of natural rubber (NR)/nitrile rubber (NBR)/nanoclay nanocomposites, with a particular focus on gas permeability, are presented. The measurements of the barrier properties were assessed using two different gases—O2 and CO2—by taking in account the blend composition, the filler loading and the nature of the gas molecules. The obtained data showed that the permeability of gas transport was strongly affected by: (i) the blend composition—it was observed that the increase in acrylonitrile butadiene rubber component considerably decreased the permeability; (ii) the nature of the gas—the permeation of CO2 was higher than O2; (iii) the nanoclay loading—it was found that the permeability decreased with the incorporation of nanoclay. The localization of nanoclay in the blend system also played a major role in determining the gas permeability. The permeability of the systems was correlated with blend morphology and dispersion of the nanoclay platelets in the polymer blend.
Journal Article
Effect of size variation of fibre-shaped waste tyre rubber as fine aggregate on the ductility of self-compacting concrete
by
Singh, Amardeep
,
Gupta, Trilok
,
Chaudhary, Sandeep
in
Aquatic Pollution
,
Atmospheric Protection/Air Quality Control/Air Pollution
,
brittleness
2023
Abandoning shredded waste tyre rubber (WTR) in cement-based mixes facilitates safe waste tyre disposal and conserves the natural resources used in construction materials. The engineering properties of such environment-friendly materials needed to be evaluated for field applications. This study examined integrating WTR fibre on microstructural, static load, and ductility properties of self-compacting concrete (SCC). The WTR fibre of 0.60–1.18-, 1.18–2.36-, and 2.36–4.75-mm sizes was used as fine aggregate at 10%, 20%, and 30% replacement levels. Microstructural characterisation of hardened concrete specimens was done by scanning electron microscopy. The compressive strength and static modulus of elasticity tests were used to examine static load resistance, while drop weight and rebound impact tests were used to investigate impact load resistance. The water permeability test was performed as a measure of the durability of SCC with WTR fibre. Relationships have been studied between dynamic MOE and impact tests and rebound and drop weight impact testing. The Weibull two-parameter distribution was used to analyse the drop weight test statically. The results show that WTR fibre size variations efficiently lowered the concrete stiffness reducing the brittleness. Furthermore, incorporating WTR fibre improved the impact resistance of SCC.
Journal Article
A Review of the Durability-Related Features of Waste Tyre Rubber as a Partial Substitute for Natural Aggregate in Concrete
2022
As the number of discarded tyres continues to increase, causing serious environmental problems, the need of recycling the waste tyre rubber become extremely urgent in worldwide. Today, there is an increasing focus on recyclable materials. The reuse of waste tyre rubber in concrete contributes to sustainable development. In the past 10 years, numerous experiments on the recovery of rubber from waste tyres to produce concrete products have been conducted. In this review, we conclude the major achievement of rubberized concrete (RC) durability, discuss and analyse the influence of rubber replacement rates, replacement patterns, particle size and treatment methods. Results show that an increase in rubber content can improve the chloride penetration resistance, acid and sulphate attack resistance, freeze–thaw resistance, and alkali–silica reaction damage resistance of concrete, and the content of 5–20% has a significant improvement effect. Rubber replacing fine aggregate is the best scheme for durability, followed by cement and coarse aggregate. In addition, the recommended rubber particle size is 0–3 mm. However, the rubber particle has adverse effects on abrasion resistance, impermeability, water absorption resistance and carbonation resistance. The pre-treatment of rubber or the addition of supplementary cementitious materials are effective and viable ways of improving the durability of RC. Further research is needed on the long-term durability of RC, as well as on ductility, energy absorption, and thermal and corrosion resistance.
Journal Article