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   Agricultural soil contaminated by phosphogypsum pile stocked in plan air remains a major problem in M’Dhilla city southwestern of Tunisia. The present effort aimed to enhance the knowledge of trace elements and radioactivity abundance and to assess the corresponding environment. X-ray fluorescence spectroscopy was used to evaluate the trace elements, radioactive elements, and major element concentrations. Our finding revealed that the mean values of U and Th in all the soil profiles ranged from 0.283 to 2.875 mg.kg −1 and from 0.797 to 1.491 mg.kg −1 respectively. The statistical analyses indicated that uranium abundance has non-significant correlation with the most of trace metals; it shows a moderate correlated with Sr and inverse correlation with P 2 O 5 . Contamination factors indicate that the studied soil ranged from uncontaminated to significantly contaminated. Thus, the pollution load index values classify the sites from background values to high pollution sites. The findings of this study will help improve the environmental conditions of M’Dhilla city by addressing contamination issues through targeted interventions. The study’s findings highlight the importance of a periodic environmental monitoring such as soil remediation in the study area. This research fills a critical gap in the current understanding of contamination management in this region.

Terrestrial ecosystems are receiving elevated inputs of nitrogen (N) from anthropogenic sources and understanding how these increases in N availability affect soil microbial communities is critical for predicting the associated effects on belowground ecosystems. We used a suite of approaches to analyze the structure and functional characteristics of soil microbial communities from replicated plots in two long-term N fertilization experiments located in contrasting systems. Pyrosequencing-based analyses of 16S rRNA genes revealed no significant effects of N fertilization on bacterial diversity, but significant effects on community composition at both sites; copiotrophic taxa (including members of the Proteobacteria and Bacteroidetes phyla) typically increased in relative abundance in the high N plots, with oligotrophic taxa (mainly Acidobacteria ) exhibiting the opposite pattern. Consistent with the phylogenetic shifts under N fertilization, shotgun metagenomic sequencing revealed increases in the relative abundances of genes associated with DNA/RNA replication, electron transport and protein metabolism, increases that could be resolved even with the shallow shotgun metagenomic sequencing conducted here (average of 75 000 reads per sample). We also observed shifts in the catabolic capabilities of the communities across the N gradients that were significantly correlated with the phylogenetic and metagenomic responses, indicating possible linkages between the structure and functioning of soil microbial communities. Overall, our results suggest that N fertilization may, directly or indirectly, induce a shift in the predominant microbial life-history strategies, favoring a more active, copiotrophic microbial community, a pattern that parallels the often observed replacement of K -selected with r -selected plant species with elevated N.

Hexavalent Chromium (Cr(VI)) contamination in soils poses significant ecological risks due to its mobility and toxicity, with retention mechanisms governed by interactions between soil properties and Cr(VI). However, the quantitative roles of key soil parameters in Cr(VI) retention remain poorly resolved, particularly across diverse soil types. This study investigated Cr(VI) retention behaviors in 16 Chinese soils (15 types) through batch experiments, isothermal adsorption model, correlation analysis and path analysis. The results showed that the retention of Cr(VI) in acidic soils was significantly higher than in alkaline soils. Acidic soils (pH < 5.4) with higher concentrations of exchangeable Fe(II) (Exch-Fe(II)) exhibited strong Cr(VI) holding capabilities,while Alkaline soils (pH > 7.3) with highest content of CaCO3 show negligible Cr(VI) reactions.Cr(VI) retention was high at soil pH values below approximately 5.5, but declined sharply at higher pH values. The Langmuir model was only suitable for describing acidic soils (pH < 5.4), while the Freundlich equation was applicable to all soils. Correlation analysis revealed that soil pH, the content of soil organic matters(SOM), Exch-Fe(II), complexed iron (Com-Fe), and clay were significantly related to the Cr(VI) retention (p < 0.01), whereas the CaCO3 content was negatively related to the Cr(VI) retention (p < 0.05).Path analysis revealed that soil pH was the most important direct factor, followed by Exch-Fe(II), Com-Fe, clay, in determining Cr(VI) retention in natural soil. CEC and CaCO3 content had only limited directly effects on the Cr(VI) retention. Additionally, The content of SOM, Amorphous iron oxides(Amo-Fe), and Easily reducible manganese(Er-Mn) content had little directly effect on Cr(VI) retention. To validate these findings, Cr(VI) retention was measured in all soils after adjusting their pH to 4.3, 6, and 8. The results highlighted soil pH and Exch-Fe(II) content were the most decisive factors for evaluating Cr(VI) retention in natrual soils,whereas SOM content was an unreliable parameter for assessing this process.

In this work, radioactivity investigations of soil samples from neutral and agricultural sites in Punjab (India) have been carried out to study the impact of land use patterns. Analyzing soil samples radiological, mineralogical, and physicochemical attributes has employed state-of-the-art techniques. The mean activity concentration of 238 U/ 226 Ra, 232 Th, 40 K, 235 U, and 137 Cs, measured using a carbon fiber endcap p-type HPGe detector, in neutral land was observed as 58.03, 83.95, 445.18, 2.83, and 1.16 Bq kg −1 , respectively. However, in vegetation land, it was found to be 40.07, 64.68, 596.74, 2.26, and 1.90 Bq kg −1 , respectively. In the detailed activity analysis, radium equivalent (Ra eq ) radioactivity is in the safe prescribed limit of 370 Bq kg −1 for all investigated soil samples. However, the dosimetric investigations revealed that the outdoor absorbed gamma dose rate (96.08 nGy h −1 ) and consequent annual effective dose rate (0.12 mSv y −1 ) for neutral land and the gamma dose rate (82.46 nGy h −1 ) and subsequent annual effective dose rate (0.10 mSv y −1 ) for vegetation land marginally exceeded the global average. The soil’s physicochemical parameters (pH, EC, and porosity) from both sites were measured, and their correlations with radionuclides were analyzed. Various heavy metals of health concern, namely, chromium (Cr), arsenic (As), copper (Cu), cobalt (Co), cadmium (Cd), lead (Pb), mercury (Hg), selenium (Se), and zinc (Zn), were also evaluated in soil samples using Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS). Pollution Load Index (PLI) and Ecological Risk Index (RI) revealed that vegetation land was more anthropogenically contaminated than neutral land, with maximum contamination from Hg and As.

The objective of the research was to examine microbial characteristics, metabolites produced, and the potential radiological risks present in mining soils located in Keana, North Central Nigeria. Soil samples were collected from various locations within Keana, Nasarawa State. Bacterial isolation was carried out, and molecular techniques were employed to characterize the bacteria found in the collected soil samples. Additionally, the susceptibility of these isolates to antibiotics was determined, and the bacteria screened for their ability to produce metabolites. The isolated bacteria were classified into three groups: Actinobacteria, Firmicutes, and Proteobacteria. The analysis of the spectra revealed that 1595 compounds were produced, including carboxylic acids, nitro compounds, aldehydes, anhydrides, esters, ketones, amides, phenols, alcohols, alkanes, alkenes, alkynes, and arenes. Some of the metabolites produced were oleic acid, 1,3-dioxolane, linoelaidic acid and oleic acid, 1-nonadecene, butylated hydroxytoluene, diisooctyl phthalate, bis(2-ethylhexyl) phthalate among others, and 1,2-benzenedicarboxylic acid (85.32%) as the most produced metabolite. Among the antibiotics tested, levofloxacin and ciprofloxacin exhibited the strongest antibacterial properties against the isolates. Airborne gamma-ray spectrometry analysis identified elevated levels of potassium, thorium, and uranium in the soils, indicating potential environmental hazards. However, no significant correlation was found between the presence of bacteria and radioactive elements. These findings emphasize the importance of comprehensive environmental monitoring in Keana to address potential health risks associated with microbial contamination and radioactive materials. Additionally, the study highlighted the role of microbial diversity in Keana soils in promoting the production of secondary metabolites with potential applications in pharmaceutical and industrial sectors..

The need to maintain soil health and produce more food worldwide has increased, and soil analysis is essential for its management. Although spectroscopy has emerged as an important tool, it is important to focus primarily on predictive modeling procedures rather than specific protocols. This article aims to contribute to a routine work sequence in a hybrid laboratory that seeks to provide the best data for its users. In this study, 18,730 soil samples from the state of Paraná, Brazil, were analyzed using three different laboratories, sensors and geometries for data acquisition. Thirty soil properties were analyzed, some using different chemical methodologies for comparison purposes. After a spectral reading, two literary protocols were applied, and the final prediction results were observed. We applied cubist models, which were the best for our population. The combination of different spectral analysis systems, with a standardized protocol using LB for the ISS detection of discrepant samples, was shown to significantly improve the accuracy of predictions for 21 of the 30 soil properties analyzed, highlighting the importance of choosing the extraction methodology and improving data quality, which have a significant impact on laboratory analyses, reaffirming spectroscopy as an essential tool for the efficient and sustainable management of soil resources.

The continuously rising interest in chemical sensors’ applications in environmental monitoring, for soil analysis in particular, is owed to the sufficient sensitivity and selectivity of these analytical devices, their low costs, their simple measurement setups, and the possibility to perform online and in-field analyses with them. In this review the recent advances in chemical sensors for soil analysis are summarized. The working principles of chemical sensors involved in soil analysis; their benefits and drawbacks; and select applications of both the single selective sensors and multisensor systems for assessments of main plant nutrition components, pollutants, and other important soil parameters (pH, moisture content, salinity, exhaled gases, etc.) of the past two decades with a focus on the last 5 years (from 2017 to 2021) are overviewed.

Microplastics (MPs) are an emerging environmental issue that might endanger the health of agricultural soil. Even though several research on the particular toxicity of MPs to species have been carried out, there is little information on MPs’ impacts on soil physicochemical properties and heavy metals (HMs) availability of HMs contaminated and without contaminated soils. This study examined the changes in soil characteristics for both HMs contaminated and without contaminated soils by five distinct MPs, including Polyethylene (PE), Polyethylene terephthalate (PET), Polystyrene Foam (PS), Polyamide (PA), and a combination of these four types of MPs (Mixed MPs), at two different concentrations (0.2% and 1%; w/w), where soil incubation experiments were setup for this studies and the standard analytical techniques employed to measure soil characteristics and toxic metal availability. After the ending of soil incubation studies (90 days), significant changes have been observed for physicochemical properties [bulk density, porosity, water holding capacity, pH, electrical conductivity (EC), organic carbon (OC), and organic matter (OM)]. The soil nutrients change in descending order was found as NH 4 + -N> PO 4 3+ > Na > Ca > NO 3 - > Mg for lower concentrations of MPs compared to higher concentrations. The HMs availability is reducing with increasing MPs concentration and the descending order for metal availability was as follows Pb > Zn > Cd > Cr > Cu > Ni. Based on MP type, the following descending order of MPs PS > Mix (MPs) > PA > PET > PE, respectively act as a soil properties influencer. Usually, effects were reliant on MPs’ category and concentrations. Finally, this study concludes that MPs may modify metal movements, and soil quality; consequently, a possible threat will be created for soil health.

Sale of organic foods is one of the fastest growing market segments within the global food industry. People often buy organic food because they believe organic farms produce more nutritious and better tasting food from healthier soils. Here we tested if there are significant differences in fruit and soil quality from 13 pairs of commercial organic and conventional strawberry agroecosystems in California. At multiple sampling times for two years, we evaluated three varieties of strawberries for mineral elements, shelf life, phytochemical composition, and organoleptic properties. We also analyzed traditional soil properties and soil DNA using microarray technology. We found that the organic farms had strawberries with longer shelf life, greater dry matter, and higher antioxidant activity and concentrations of ascorbic acid and phenolic compounds, but lower concentrations of phosphorus and potassium. In one variety, sensory panels judged organic strawberries to be sweeter and have better flavor, overall acceptance, and appearance than their conventional counterparts. We also found the organically farmed soils to have more total carbon and nitrogen, greater microbial biomass and activity, and higher concentrations of micronutrients. Organically farmed soils also exhibited greater numbers of endemic genes and greater functional gene abundance and diversity for several biogeochemical processes, such as nitrogen fixation and pesticide degradation. Our findings show that the organic strawberry farms produced higher quality fruit and that their higher quality soils may have greater microbial functional capability and resilience to stress. These findings justify additional investigations aimed at detecting and quantifying such effects and their interactions.

Salinization is the accumulation of water-soluble salts in the soil solum or regolith to a level that impacts on agricultural production, environmental health, and economic welfare. Salt-affected soils occur in more than 100 countries of the world with a variety of extents, nature, and properties. No climatic zone in the world is free from salinization, although the general perception is focused on arid and semi-arid regions. Salinization is a complex process involving the movement of salts and water in soils during seasonal cycles and interactions with groundwater. While rainfall, aeolian deposits, mineral weathering, and stored salts are the sources of salts, surface and groundwaters can redistribute the accumulated salts and may also provide additional sources. Sodium salts dominate in many saline soils of the world, but salts of other cations such as calcium, magnesium, and iron are also found in specific locations. Different types of salinization with a prevalence of sodium salts affect about 30% of the land area in Australia. While more attention is given to groundwater-associated salinity and irrigation salinity, which affects about 16% of the agricultural area, recent investigations suggest that 67% of the agricultural area has a potential for 'transient salinity', a type of non-groundwater-associated salinity. Agricultural soils in Australia, being predominantly sodic, accumulate salts under seasonal fluctuations and have multiple subsoil constraints such as alkalinity, acidity, sodicity, and toxic ions. This paper examines soil processes that dictate the exact edaphic environment upon which root functions depend and can help in research on plant improvement.