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Scintillation materials and detectors that are used in many applications, such as medical imaging, security, oil-logging, high energy physics and non-destructive inspection, are reviewed. The fundamental physics understood today is explained, and common scintillators and scintillation detectors are introduced. The properties explained here are light yield, energy non-proportionality, emission wavelength, energy resolution, decay time, effective atomic number and timing resolution. For further understanding, the emission mechanisms of scintillator materials are also introduced. Furthermore, unresolved problems in scintillation phenomenon are considered, and my recent interpretations are discussed. These topics include positive hysteresis, the co-doping of non-luminescent ions, the introduction of an aimed impurity phase, the excitation density effect and the complementary relationship between scintillators and storage phosphors.

X-ray detection, which plays an important role in medical and industrial fields, usually relies on inorganic scintillators to convert X-rays to visible photons; although several high-quantum-yield fluorescent molecules have been tested as scintillators, they are generally less efficient. High-energy radiation can ionize molecules and create secondary electrons and ions. As a result, a high fraction of triplet states is generated, which act as scintillation loss channels. Here we found that X-ray-induced triplet excitons can be exploited for emission through very rapid, thermally activated up-conversion. We report scintillators based on three thermally activated delayed fluorescence molecules with different emission bands, which showed significantly higher efficiency than conventional anthracene-based scintillators. X-ray imaging with 16.6 line pairs mm −1 resolution was also demonstrated. These results highlight the importance of efficient and prompt harvesting of triplet excitons for efficient X-ray scintillation and radiation detection. Triplet exciton harvesting through thermally activated delayed fluorescence is shown to be effective also under X-ray excitation, increasing the efficiency and imaging quality of X-ray detectors based on organic scintillation.

Scintillation based X-ray detection has received great attention for its application in a wide range of areas from security to healthcare. Here, we report highly efficient X-ray scintillators with state-of-the-art performance based on an organic metal halide, ethylenebis-triphenylphosphonium manganese (II) bromide ((C 38 H 34 P 2 )MnBr 4 ), which can be prepared using a facile solution growth method at room temperature to form inch sized single crystals. This zero-dimensional organic metal halide hybrid exhibits green emission peaked at 517 nm with a photoluminescence quantum efficiency of ~ 95%. Its X-ray scintillation properties are characterized with an excellent linear response to X-ray dose rate, a high light yield of ~ 80,000 photon MeV −1 , and a low detection limit of 72.8 nGy s −1 . X-ray imaging tests show that scintillators based on (C 38 H 34 P 2 )MnBr 4 powders provide an excellent visualization tool for X-ray radiography, and high resolution flexible scintillators can be fabricated by blending (C 38 H 34 P 2 )MnBr 4 powders with polydimethylsiloxane. Scintillation-based X-ray detection is promising for applications in various areas ranging from security to healthcare, and low-cost and eco-friendly scintillation materials would be beneficial. Here the authors report a facile solution growth of organic manganese halide for efficient X-ray scintillation.

Upgrade of two-dimensional scintillation neutron detectors for SENJU at Materials and Life science experimental Facility in Japan Proton Accelerator Research Complex (J-PARC MLF) is underway. The detector upgrade plan includes detector developments such as thin add-in detectors, high efficiency detectors to replace the original detectors, a large square detector placed under the sample vacuum tank, rectangular detectors to replace three or six original detectors. These detectors were all developed based on 6Li:ZnS(Ag) scintillator screens and wavelength shifting (WLS) fibers. They are made compact with the same pixel size as the original detectors while improving detection efficiency.

Radiocarbon (14C) dating by liquid scintillation (LS) spectroscopy (also known as LS counting or LSC) provides an alternate method of 14C analysis where accelerator mass spectrometry (AMS) analysis is less desirable. The past, present, and future applications of the method are discussed.

In the past, the main research and use of scintillators in extreme environments were mainly limited to high energy physics and the well-logging industry, but their applications are now expanding to reactor monitoring systems, marine and space exploration, nuclear fusion, radiation therapy, etc. In this article, we review and summarize single-crystal inorganic scintillator candidates that can be applied to radiation detection in extreme environments. Crucial scintillation properties to consider for use in extreme environments are temperature dependence and radiation resistance, along with scintillators’ susceptibility to moisture and mechanical shock. Therefore, we report on performance change, with a focus on radiation resistance and temperature dependence, and the availability of inorganic scintillator for extreme environments—high radiation, temperature, humidity and vibration—according to their applications. In addition, theoretical explanations for temperature dependence and radiation resistance are also provided.

Scintillators that exhibit X-ray-excited luminescence have great potential in radiation detection, X-ray imaging, radiotherapy, and non-destructive testing. However, most reported scintillators are limited to inorganic or organic crystal materials, which have some obstacles in repeatability and processability. Here we present a facile strategy to achieve the X-ray-excited organic phosphorescent scintillation from amorphous copolymers through the copolymerization of the bromine-substituted chromophores and acrylic acid. These polymeric scintillators exhibit efficient X-ray responsibility and decent phosphorescent quantum yield up to 51.4% under ambient conditions. The universality of the design principle was further confirmed by a series of copolymers with multi-color radioluminescence ranging from green to orange-red. Moreover, we demonstrated their potential application in X-ray radiography. This finding not only outlines a feasible principle to develop X-ray responsive phosphorescent polymers, but also expands the potential applications of polymer materials with phosphorescence features. The authors achieved the X-ray-excited organic phosphorescent scintillation from copolymers through copolymerization of bromine-substituted chromophores and acrylic acid and demonstrated their potential application in X-ray radiography.

Ionospheric scintillation causes rapid fluctuations of measurements from Global Navigation Satellite Systems (GNSSs), thus threatening space-based communication and geolocation services. The phenomenon is most intense in equatorial regions, around the equinoxes and in maximum solar cycle conditions. Currently, ionospheric scintillation monitoring receivers (ISMRs) measure scintillation with high-pass filter algorithms involving high sampling rates, e.g. 50 Hz, and highly stable clocks, e.g. an ultra-low-noise Oven-Controlled Crystal Oscillator. The present paper evolves phase scintillation indices implemented in conventional geodetic receivers with sampling rates of 1 Hz and rapidly fluctuating clocks. The method is capable to mitigate ISMR artefacts that contaminate the readings of the state-of-the-art phase scintillation index. Our results agree in more than 99.9% within ± 0.05 rad (2 mm) of the ISMRs, with a data set of 8 days which include periods of moderate and strong scintillation. The discrepancies are clearly identified, being associated with data gaps and to cycle-slips in the carrier-phase tracking of ISMR that occur simultaneously with ionospheric scintillation. The technique opens the door to use huge databases available from the International GNSS Service and other centres for scintillation studies. This involves GNSS measurements from hundreds of worldwide-distributed geodetic receivers over more than one Solar Cycle. This overcomes the current limitations of scintillation studies using ISMRs, as only a few tens of ISMRs are available and their data are provided just for short periods of time.

Garnet ceramic scintillators are a class of inorganic scintillation materials with excellent overall performance. The flexibility of cation substitution in different lattice positions leads to tunable and versatile properties and a wide range of applications. This paper starts with an overview of the development history of the inorganic scintillation materials, followed by a description of major preparation methods and characterization of garnet scintillation ceramics. Great progress obtained in recent years consisting in applying the band-gap and defect engineering strategies to the garnet scintillation ceramics is reviewed. Finally, the respective problems in the preparation and performance of multicomponent garnet single crystals and ceramics and the effective solutions are discussed. The garnet scintillation ceramics with the highest application potential are summarized, and the future development directions are proposed.