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"Silicon steels"
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Magnetic Properties and Strengthening Mechanism of Cu-Bearing Non-Oriented Silicon Steel
2025
The effects of Cu content on the microstructure, texture, precipitates, and magnetic and mechanical properties of 0.20 mm-thick non-oriented silicon steel (3.0% Si-0.8% Al-0.5% Mn) were systematically investigated using optical microscopy, X-ray diffraction, electron backscatter diffraction, and transmission electron microscopy. The strengthening mechanisms of Cu-bearing high-strength non-oriented silicon steel were further elucidated. Increasing Cu content inhibited grain growth and suppressed the development of the α*-fiber texture in annealed sheets, while promoting the formation of γ-fiber texture. As a result, the P1.0/400 and B50 values deteriorated. The P1.0/400 and B50 values of 1.47% Cu non-oriented silicon steel were 13.930 W/kg and 1.614 T, respectively. However, due to the solid solution strengthening effect of 0.5% Cu and partial precipitation strengthening, the Rp0.2 increased by 43 MPa. After aging treatment at 550 °C for 20 min, the P1.0/400 values of the aged sheets slightly increased, while the B50 values remained almost unchanged. In the aged sheets containing 1.0–1.5% Cu, clustered Cu-rich precipitates with average sizes of 2.71 nm and 13.28 nm were observed. The crystal structure of these precipitates transitioned from the metastable B2-Cu to the stable FCC-Cu. These precipitates enhanced the Rp0.2 of the non-oriented electrical steel to 241 MPa and 269 MPa through cutting and bypass mechanisms, respectively. A high-strength non-oriented silicon steel with balanced magnetic and mechanical properties was developed for driving motors of new energy vehicles by utilizing nanoscale Cu-rich precipitates formed through aging treatment. The optimized steel exhibits a yield strength of 708 MPa, a magnetic induction B50 of 1.639 T, and high-frequency iron loss P1.0/400 of 14.77 W/kg.
Journal Article
Numerical and Experimental Investigation of Orientation Deviation in Shear Band in Grain-Oriented Silicon Steel
2025
As a critical factor for the magnetic properties of grain-oriented silicon steel, the orientation accuracy of shear bands is closely related to the matrix orientation deviation from 111 . This work investigates the orientation rotation of shear bands in 111 matrices with various types of deviation during cold rolling, using a visco-plastic self-consistent model that incorporates a two-dimensional inclined angle of the shear band dependent on matrix orientation. When the matrix orientation deviates from 111 along φ1, φ2, or both axes, the φ1 deviation of the shear band decreases, and the φ2 deviation is larger than φ1. Compared with a uniaxially deviated 111 matrix, a biaxially deviated matrix along φ1 and φ2 axes produces a higher shear band deviation from Goss due to the increased φ2 deviation. This suggests that improving the orientation accuracy of the shear band is necessary to decrease the matrix deviation from 111 in the φ1 and especially φ2 axes.
Journal Article
Effect of Tensile Stress Annealing on the Texture, Grain Size, and Magnetic Properties of Ultra-Thin Grain-Oriented Silicon Steel
This study systematically investigated the influence of annealing tension on the microstructure, texture, and magnetic properties of ultra-thin grain-oriented silicon steel, which is of great significance for achieving the preparation of high-quality ultra-thin grain-oriented silicon steel. The research indicates that tension primarily affects the magnetic properties by influencing the intensity of the η-fiber texture ( //RD) and the grain size during the annealing process, exhibiting a consistent trend across different annealing temperatures. That is, the proportion of η-oriented grains (or the intensity of the η-fiber texture) first decreased and then increased with increasing tension. Correspondingly, the magnetic induction (B
) decreased initially and then increased with the rise in annealing tension. Specifically, when annealed at 800 °C for 30 min, B
decreased to 1.79 T under 24 MPa tension and then recovered to 1.86 T under 40 MPa tension. When annealed at 775 °C for 30 min, B
decreased to 1.81 T under 24 MPa tension and subsequently recovered to 1.88 T under 40 MPa tension. In terms of grain size, the annealing tension promoted an increase in the average grain size. The synergistic effect of microstructure and texture led to a trend where the iron loss value (P
) of the ultra-thin strip under tension first increased and then decreased: when annealed at 800 °C for 30 min, the iron loss initially increased to 14.68 W/kg and then decreased with increasing tension; similarly, when annealed at 775 °C for 30 min, the iron loss first increased to 18.81 W/kg and then decreased with increasing tension. The evolution of the microstructure and texture is determined by the competition between the nucleation and growth of η-oriented grains and other grains during recrystallization: in the nucleation stage, the annealing tension reduced the strong advantage of η-oriented grains to some extent; however, it is speculated that η-oriented grains possess an advantage during the grain growth stage.
Journal Article
Investigation and Application of Magnetic Properties of Ultra-Thin Grain-Oriented Silicon Steel Sheets under Multi-Physical Field Coupling
2022
Nowadays, energy shortages and environmental pollution have received a lot of attention, which makes the electrification of transportation systems an inevitable trend. As the core part of an electrical driving system, the electrical machine faces the extreme challenge of keeping high power density and high efficiency output under complex workin g conditions. The development and research of new soft magnetic materials has an important impact to solve the current bottleneck problems of electrical machines. In this paper, the variation trend of magnetic properties of ultra-thin grain-oriented silicon steel electrical steel (GOES) under thermal-mechanical-electric-magnetic fields is studied, and the possibility of its application in motors is explored. The magnetic properties of grain-oriented silicon steel samples under different conditions were measured by the Epstein frame method and self-built multi-physical field device. It is verified that the magnetic properties of grain-oriented silicon steel selected within 30° magnetization deviation angle are better than non-grain-oriented silicon steel. The magnetic properties of the same ultra-thin grain-oriented silicon steel as ordinary non-oriented silicon steel deteriorate with the increase in frequency. Different from conventional non-grain-oriented silicon steel, its magnetic properties will deteriorate with the increase in temperature. Under the stress of 30 Mpa, the magnetic properties of the grain-oriented silicon steel are the best; under the coupling of multiple physical fields, the change trend of magnetic properties of grain-oriented silicon steel is similar to that of single physical field, but the specific quantitative values are different. Furthermore, the application of grain-oriented silicon steel in interior permanent magnet synchronous motor (IPM) for electric vehicles is explored. Through a precise oriented silicon steel motor model, it is proved that the magnetic flux density of stator teeth increases by 2.2%, the electromagnetic torque of motor increases by 2.18%, and the peak efficiency increases by 1% after using grain-oriented silicon steel. In this paper, through the investigation of the characteristics of grain-oriented silicon steel, it is preliminarily verified that grain-oriented silicon steel has a great application prospect in the drive motor (IPM) of electric vehicles, and it is an effective means to break the bottleneck of current motor design.
Journal Article
The Multiple Effects of RE Element Addition in Non-Oriented Silicon Steel
2025
High-grade non-oriented silicon steel with high magnetic induction and low iron loss produced with low carbon emissions is crucial for the development of new energy and energy-saving motors. In this paper, the trace mixed rare earth (RE) elements exhibit a great potential to enhance magnetic properties in a lower carbon emission process by multiple effects on microstructure, texture, and inclusion in non-oriented silicon steel. With the trace-doped RE elements (0.004–0.030%), RE-rich precipitates preferentially form and subsequently adsorb fine inclusions below 1 μm to transform into spherical or ellipsoidal shape, which results in a significant increase in final recrystallization grain size. Moreover, the favorable λ texture ( //ND) is promoted while the detrimental γ texture ( //ND) is reduced, owing to the advantages in size and quantity of λ grains during the nucleation process. The improved magnetic properties of higher B50 and lower P15/50 are achieved with 0.004% RE at lower annealing temperature ranges. The increased λ texture is attributed to the heterogeneity in microstructure and texture as well as the grain boundary segregation of RE elements. However, a higher RE content (0.072%) leads to a deterioration in magnetic performance due to the formation of more stable RE-rich precipitates, smaller grains, and stronger γ texture. An iron loss calculation model was also proposed to guide the design of high-grade non-oriented silicon steel by incorporating the multiple effects of RE elements on grain size, recrystallization texture, and inclusion.
Journal Article
Study on the Performance of a High-Speed Motor, Considering the Effect of Temperature on the Properties of High-Strength Non-Oriented Silicon Steel
2024
Considering the high-speed and high power density technical specifications of new energy vehicle motors, there is a growing demand for rotor strength as motor peak speeds reach 20,000 r/min and beyond. The utilization of non-oriented silicon steel with a high yield strength in rotors has emerged as a promising approach to increase motor speed. However, the magnetic and mechanical properties of high-strength silicon steel under variable temperature conditions have not been fully explored, particularly in regards to their impact on motor torque, efficiency, and speed. This manuscript investigates the behavior of high-strength silicon steel before and after annealing and at different temperatures, analyzing its influence on high-speed motor performance. The validity and feasibility of this study are confirmed through prototype testing, providing a comprehensive reference for engineering design.
Journal Article
Analysis of Typical Inclusion Evolution and Formation Mechanism in the Smelting Process of W350 Non-Oriented Silicon Steel
2025
The production of silicon steel involves complex metallurgical processes, where the kind, composition, size, and quantity of the inclusions generated affect the silicon steel properties. This article is based on the smelting process for W350 non-oriented silicon steel produced by a certain factory. By systematically sampling, at key nodes of the converter–RH refining–tundish smelting process, the change in cleanliness of molten steel in the whole smelting process, the evolution of typical inclusions, and the transformation rules for the precipitated phase were analyzed by means of SEM-EDS, ASPEX, and Thermal-Calc. The results indicate that the total oxygen mass fraction in the steel decreases by more than 95% after deoxidation alloying, and the average oxygen mass fraction in the RH outbound steel is 0.0012%. While the nitrogen mass fraction shows a rising trend as a whole, the average nitrogen mass fraction in the tundish steel reaches approximately 0.0014%. Before RH refining, large Al2O3–CaO–SiO2 and Al2O3–CaO–SiO2–MgO composite inclusions are the main inclusions. MnO and Al2O3–SiO2–MnO inclusions are the main inclusions after RH inlet and RH decarburization. After RH deoxidation with aluminum, the inclusions were almost entirely transformed into Al2O3 inclusions. After RH alloying, with the content of Si and Mn increased, the inclusions transformed into Al2O3–SiO2–MnO inclusions. The number of inclusions from RH desulfurization to the RH outbound stage declined significantly, and composite inclusions containing CaS and precipitates such as AlN and MnS began to appear. The inclusions’ main types were Al2O3–MgO–CaS, AlN–MnS, AlN, and Al2O3–MgO. The inclusions inside the tundish were the same, but the numbers were slightly increased due to the secondary oxidation of molten steel. More than 80% of the oxide inclusions in the whole process were between 1 μm and 5 μm in size. The average size and the number of inclusions per unit area reached 5.45 μm and 63.1 per mm2, respectively, after RH deoxidation, and respectively decreased to 3.71 μm and 1.9 per mm2 during the RH outbound stage, but both increased slightly in the tundish. Thermodynamic calculation shows that Al2O3–MgO inclusions are formed when w([Mg]) > 0.0033% in molten steel at 1873 K. Under the actual temperature of 1828K and w([Al]s) = 0.6515%, the range of w([Mg]) corresponding to the stable existence of Al2O3–MgO is between 0.0053% and 0.1676%. The liquidus temperature of W350 non-oriented silicon steel is 1489 °C. MnS and AlN inclusions are precipitated successively with the solidification of molten steel, and the precipitation temperatures are 1460.7 °C and 1422.2 °C, respectively. As the temperature decreases, the sequence of inclusion precipitation calculated in liquid was as follows: Al2O3–CaO → 2Al2O3–CaO + MnS → 6Al2O3–CaO → Al2O3 + AlN + MnS + CaS.
Journal Article
Influence Mechanisms of Trace Rare-Earth Ce on Texture Development of Non-Oriented Silicon Steel
2025
The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution of the 114 and γ-fiber textures. During the recrystallization process, as the recrystallization fraction of annealed sheets increased, the intensity of α-fiber texture decreased, while the intensities of α*-fiber and γ-fiber textures increased. The 111 grains preferentially nucleated in the deformed γ-grains and their grain-boundary regions and tended to form a colony structure with a large amount of nucleation. In addition, the 100 and 114 grains mainly nucleated near the deformed α-grains, which were evenly distributed but found in relatively small quantities. The hindering effect of trace Ce on dislocation motion in cold-rolled sheets results in a 2–7% lower recrystallization ratio for the annealed sheets, compared to conventional annealed sheets. Trace Ce suppresses the nucleation and growth of γ-grains while creating opportunities for α*-grain nucleation. During grain growth, trace Ce reduces γ-grain-boundary migration rate in annealed sheets, providing growth space for 114 grains. Consequently, the content of the corresponding 114 texture increased by 6.4%, while the γ-fiber texture content decreased by 3.6%.
Journal Article
Influence Mechanisms of Cold Rolling Reduction Rate on Microstructure, Texture and Magnetic Properties of Non-Oriented Silicon Steel
2024
The effects of cold rolling reduction on the microstructure, recrystallization behavior, and magnetic properties of 3.0%Si-0.8%Al-0.3%Mn steel were studied by X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). With the reduction rates of 78%, 85% and 87% in the cold rolled sheet, the width of the deformation band becomes narrower, the number of intragranular shear bands decreases, and the proportion of grain boundaries increases. The intensity of the α and γ fibers texture in the cold rolled sheet is enhanced, and the annealed sheet is dominated by the γ fibers texture and the content increases from 26.0% to 34.5%. During the recrystallization process, the Goss and γ-grains nucleate first. The λ-grains nucleate mainly at the grain boundaries of the deformed α-grains, and the α-grains ultimately recrystallize. With the increase in the cold rolling reduction rate, the γ-grains develop into the main texture due to a large amount of nucleation at the deformation band and grain boundary. The λ-grains with a high mobility do not have a numerical advantage, and the increase in the texture content is very small. The content of the unfavorable γ fiber texture in the annealed sheet increases, the magnetic induction intensity B50 decreases, Pe and Pt decrease significantly, and the critical grain size with the lowest iron loss decreases from 136.2 to 109.4 μm.
Journal Article
Application of Thermodynamic Calculations in the Study of Slag Melting Characteristics and Aluminum Loss Control
2025
According to the production process requirements of oriented silicon steel in a certain steel mill, optimization of the slag composition ratio is studied through thermodynamic calculations. The CaO-SiO2-Al2O3-FeO-MgO slag system is studied using FactSage thermodynamic software (FactSage 8.1), and a slag optimization plan is proposed based on industrial experiments involving changes in the composition ratio of the slag, calculation and analysis of the melting characteristics of RH refining slag, further verification through orthogonal experiments, and observations of the slag state, temperature, and composition relationship through phase diagrams. This study provides theoretical guidance for finding a suitable slag composition ratio based on the influence of slag on dissolved aluminum in steel liquid. Research has shown that, combined with thermodynamic analysis, slag melting characteristics, component content calculations, and industrial experiments, the range of RH refining slag composition suitable for production in this steel mill is slag in the range of 1.3~1.5 alkalinity, 25~30% Al2O3, 5~6% MgO, and 1–2% FeO.
Journal Article