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Thermophotovoltaics (TPVs) convert predominantly infrared wavelength light to electricity via the photovoltaic effect, and can enable approaches to energy storage 1 , 2 and conversion 3 – 9 that use higher temperature heat sources than the turbines that are ubiquitous in electricity production today. Since the first demonstration of 29% efficient TPVs (Fig. 1a ) using an integrated back surface reflector and a tungsten emitter at 2,000 °C (ref. 10 ), TPV fabrication and performance have improved 11 , 12 . However, despite predictions that TPV efficiencies can exceed 50% (refs. 11 , 13 , 14 ), the demonstrated efficiencies are still only as high as 32%, albeit at much lower temperatures below 1,300 °C (refs. 13 – 15 ). Here we report the fabrication and measurement of TPV cells with efficiencies of more than 40% and experimentally demonstrate the efficiency of high-bandgap tandem TPV cells. The TPV cells are two-junction devices comprising III–V materials with bandgaps between 1.0 and 1.4 eV that are optimized for emitter temperatures of 1,900–2,400 °C. The cells exploit the concept of band-edge spectral filtering to obtain high efficiency, using highly reflective back surface reflectors to reject unusable sub-bandgap radiation back to the emitter. A 1.4/1.2 eV device reached a maximum efficiency of (41.1 ± 1)% operating at a power density of 2.39 W cm –2 and an emitter temperature of 2,400 °C. A 1.2/1.0 eV device reached a maximum efficiency of (39.3 ± 1)% operating at a power density of 1.8 W cm –2 and an emitter temperature of 2,127 °C. These cells can be integrated into a TPV system for thermal energy grid storage to enable dispatchable renewable energy. This creates a pathway for thermal energy grid storage to reach sufficiently high efficiency and sufficiently low cost to enable decarbonization of the electricity grid. Two-junction TPV cells with efficiencies of more than 40% are reported, using an emitter with a temperature between 1,900 and 2,400 °C, for integration into a TPV system for thermal energy grid storage.

Thermophotovoltaic power conversion utilizes thermal radiation from a local heat source to generate electricity in a photovoltaic cell. It was shown in recent years that the addition of a highly reflective rear mirror to a solar cell maximizes the extraction of luminescence. This, in turn, boosts the voltage, enabling the creation of record-breaking solar efficiency. Now we report that the rear mirror can be used to create thermophotovoltaic systems with unprecedented high thermophotovoltaic efficiency. This mirror reflects low-energy infrared photons back into the heat source, recovering their energy. Therefore, the rear mirror serves a dual function; boosting the voltage and reusing infrared thermal photons. This allows the possibility of a practical >50% efficient thermophotovoltaic system. Based on this reflective rear mirror concept, we report a thermophotovoltaic efficiency of 29.1 ± 0.4% at an emitter temperature of 1,207 °C.

We present an overview of opto-electronic characterization techniques for solar cells including light-induced charge extraction by linearly increasing voltage, impedance spectroscopy, transient photovoltage, charge extraction and more. Guidelines for the interpretation of experimental results are derived based on charge drift-diffusion simulations of solar cells with common performance limitations. It is investigated how nonidealities like charge injection barriers, traps and low mobilities among others manifest themselves in each of the studied cell characterization techniques. Moreover, comprehensive parameter extraction for an organic bulk-heterojunction solar cell comprising PCDTBT:PC 70 BM is demonstrated. The simulations reproduce measured results of 9 different experimental techniques. Parameter correlation is minimized due to the combination of various techniques. Thereby a route to comprehensive and accurate parameter extraction is identified.

Interest in germanium electronic devices is experiencing a comeback thanks to their suitability for a wide range of new applications, like CMOS transistors, quantum technology or infrared photonics. Among these applications, Ge-based thermophotovoltaic converters could become the backbone of thermo-electrical batteries. However, these devices are still far from the efficiency threshold needed for industrial deployment, with surface recombination as the main limiting factor for the material. In this work, we discuss the main passivation techniques developed for germanium photovoltaic and thermophotovoltaic devices, summarizing their main advantages and disadvantages. The analysis reveals that surface recombination velocities as low as 2.7 cm/s and 1.3 cm/s have already been reported for p-type and n-type germanium, respectively, although improving surface recombination velocities below 100 cm/s would result in marginal efficiency gains. Therefore, the main challenge for the material is not reducing this parameter further but developing robust and reliable processes for integrating the current techniques into functional devices.

Thermophotovoltaic power conversion utilizes thermal radiation from a local heat source to generate electricity in a photovoltaic cell. It was shown in recent years that the addition of a highly reflective rear mirror to a solar cell maximizes the extraction of luminescence. This, in turn, boosts the voltage, enabling the creation of record-breaking solar efficiency. Now we report that the rear mirror can be used to create thermophotovoltaic systems with unprecedented high thermophotovoltaic efficiency. This mirror reflects low-energy infrared photons back into the heat source, recovering their energy. Therefore, the rear mirror serves a dual function; boosting the voltage and reusing infrared thermal photons. This allows the possibility of a practical >50% efficient thermophotovoltaic system. Based on this reflective rear mirror concept, we report a thermophotovoltaic efficiency of 29.1 ± 0.4% at an emitter temperature of 1,207 °C.

At midnight on 27–28 June 2016, a Tibetan Plateau (TP) Vortex (TPV) generated over the western TP that subsequently caused a downstream record-breaking rainstorm and extremely severe natural disaster. Based on reanalysis data and satellite imagery, this study investigates the formation of this TPV from a potential vorticity (PV) perspective. Results show that, in late June 2016, a remarkable circulation anomaly occurred over the TP and its peripheral area, with easterly flow in the middle and lower troposphere developing in the subtropical zone, replacing the normal westerly flow there. Its forefront merged with the southwesterly flow from the west and penetrated and converged over the western TP where the surface was warmer than normal, forming a low-level jet and downward slantwise isentropic surfaces in-situ. When the air parcel slid down the slantwise isentropic surface, its vertical relative vorticity developed owing to slantwise vorticity development associated with PV restructuring. At the same time, the penetrating southwesterly flow brought abundant water vapor to the western TP and induced increasing sub-cloud entropy and air ascent there. Low-layer cloud formed and the cloud liquid water content increased. The strong latent heat that was released in association with the formation of cloud produced strong diabatic heating near 400 hPa at night and strong PV generation below. The normal diurnal variation was interrupted and the vortex was generated near the surface. These results demonstrate that, against a favorable circulation background, both adiabatic and diabatic PV processes are crucial for TPV genesis.

Ethylene–propylene–diene monomer (EPDM) rubber is one of the rapidly developing synthetic rubbers for use as a gasket material in proton exchange membrane (PEM) fuel cell applications. Despite its excellent elastic and sealing properties, EPDM faces challenges such as molding processability and recycling ability. To overcome these challenges, thermoplastic vulcanizate (TPV), which comprises vulcanized EPDM in polypropylene matrix, was investigated as a gasket material for PEM fuel cell applications. TPV showed better long-term stability in terms of tension and compression set behaviors under accelerated aging conditions than EPDM. Additionally, TPV exhibited significantly higher crosslinking density and surface hardness than EPDM, regardless of the test temperature and aging time. TPV and EPDM showed similar leakage rates for the entire range of test inlet pressure values, regardless of the applied temperature. Therefore, we can conclude that TPV exhibits a similar sealing capability with more stable mechanical properties compared with commercialized EPDM gaskets in terms of He leakage performance.

The Tibetan Plateau vortex (TPV) is a key system triggering rainfall over the Tibetan Plateau (TP) during the boreal summer. The TPV genesis mechanisms are complicated and its classification is a great challenge. This study attempts to elucidate these aspects. By introducing the standardized index of 24-h increment of equivalent potential temperature Δ 24 h θ e at 500 hPa, all the TPV cases generated in June between 1980 and 2016 are classified as either positive or negative. Composite analysis is subsequently applied to the extremes of these two types, i.e., the first and last fifth-percentile cases with extremely negative and positive standardized Δ 24 h θ e , respectively. Results indicate that 70% of them occur in relatively warmer and wetter environments, with diabatic heating dominating the positive type and the dynamic effect of large-scale circulation dominating the negative type. For the extremely positive cluster, the geopotential-height increment over the TP exhibits a negative/west–positive/east dipole, which enhances the southerly flow over the western TP, while forming surface water–vapor convergence. Consequently, strong condensation heating occurs near the sub-cloud level, resulting in the development of potential vorticity below and eventually TPV genesis. For the negative cluster, local shear lines at 500 hPa and upstream troughs at 250 hPa occur at the TPV genesis location. In conjunction with anomalous westerlies, positive potential vorticity is generated in situ due to zonal advection. The retardation caused by the Kunlun Mountains on the impinging westerly flow associated with side-boundary friction also contributes to TPV genesis southeast of the mountains.

With the ongoing reduction in manufacturing costs, minimal mass, and substantial adaptability, ultra-thin thermophotovoltaic (TPV) cells are garnering increasing scholarly interest. Nevertheless, ultra-thin TPV cells are impeded by the limitation of their absorption capabilities when juxtaposed with traditional bulk cell alternatives. Consequently, the enhancement of absorption in ultra-thin TPV cells is of paramount importance and constitutes the principal objective of this investigation. This study elucidates a hemispherical-coupled light-trapping mechanism that incorporates an ultra-thin film of gallium antimonide (GaSb) situated between an upper two-dimensional (2D) hemispherical metallic lattice and a lower metallic layer. The absorption spectra for the proposed configuration have consequently been calculated employing the finite-difference time-domain (FDTD) method. The proposed design achieved a notable conversion efficiency of 45.32% under black-body radiation at a temperature of T = 2023 K. Moreover, the short-circuit current density and open-circuit voltage parameters for the cell are significantly enhanced due to the plasmonic absorption augmentation provided by the suggested light-trapping architecture. These findings are expected to advance the evolution of innovative, cost-effective methodologies for the production of high-efficiency ultra-thin TPV solar cells.

Driven by the need to design sustainable polymeric materials that remain superior mechanical properties after recycling, this work is centred on the effect of multiple recycling of thermoplastic vulcanizates (TPVs). Among thermoplastic elastomers, TPVs combine several favourable characteristics such as damping, light weight, ease of processing by means of injection moulding, design flexibility and recyclability. Multiple processing of a commercially available PP/EPDM TPV by shredding and injection moulding was followed by analytical investigations on rheological and thermo-mechanical properties using melt rheological measurements, dynamic mechanical analysis, differential scanning calorimetry analysis and mechanical tests. The results show that key performance parameters of the TPV such as Young’s modulus, stress at 100% strain as well as stress and strain at break only change slightly. Stress at 100% strain can be used as a quality indicator as it decreases linearly with every recycling step. This study opens new opportunities to increase the content of recycled PP/EPDM TPV and even manufacture technical components with 100% recycled material.