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result(s) for
"Ti-based materials"
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3D-Printed Satellite Brackets: Materials, Manufacturing and Applications
by
Behera, Ajit
,
Samal, Saswat Kumar
,
Behera, Asit
in
3-D printers
,
3D printing
,
Additive manufacturing
2022
Brackets are the load-bearing components in a satellite. The current age of satellites comprises specific brackets that set out as a link between the bodies of the satellite, reflector parts, and feeder facilities mounted at its upper end. Brackets are used to carry loads of the satellite body frame, supporting elements, batteries, and electronic goods. The article explicates the various brackets used in satellites and aircrafts. The strength of the bracket is of utmost importance since it is an important load supporting member in several assemblies of aircraft and satellites. In addition to the mechanical strength, the weight of the bracket is a major concern as it adds to the total weight of the aircraft and satellite. Thus, weight savings of brackets can be of paramount importance and Additive Manufacturing (AM) is found as an overall solution to achieve the same. Hence, in addition to various brackets used in satellites, the article presents an exhaustive review of the processing of various advanced functional materials using various AM techniques to make high strength-to-weight ratio satellite brackets. The use of DFAM by various satellite manufacturers globally for optimizing the structure of the brackets resulting in a significant weight saving of the brackets is also presented in the article.
Journal Article
Porous construction and surface modification of titanium-based materials for osteogenesis: A review
by
Ni, Shilei
,
Li, Meihua
,
Ma, Li
in
3-D printers
,
Amine oxidase (flavin-containing)
,
Biocompatibility
2022
Titanium and titanium alloy implants are essential for bone tissue regeneration engineering. The current trend is toward the manufacture of implants from materials that mimic the structure, composition and elasticity of bones. Titanium and titanium alloy implants, the most common materials for implants, can be used as a bone conduction material but cannot promote osteogenesis. In clinical practice, there is a high demand for implant surfaces that stimulate bone formation and accelerate bone binding, thus shortening the implantation-to-loading time and enhancing implantation success. To avoid stress shielding, the elastic modulus of porous titanium and titanium alloy implants must match that of bone. Micro-arc oxidation technology has been utilized to increase the surface activity and build a somewhat hard coating on porous titanium and titanium alloy implants. More recently, a growing number of researchers have combined micro-arc oxidation with hydrothermal, ultrasonic, and laser treatments, coatings that inhibit bacterial growth, and acid etching with sand blasting methods to improve bonding to bone. This paper summarizes the reaction at the interface between bone and implant material, the porous design principle of scaffold material, MAO technology and the combination of MAO with other technologies in the field of porous titanium and titanium alloys to encourage their application in the development of medical implants.
Journal Article
Ti-Based Metallic Biomaterials for Antitumor Applications
2025
Titanium (Ti)-based metallic biomaterials (MBs) are traditionally employed as mechanical supports and constraints in clinical practice, owing to their superb comprehensive mechanical properties, great corrosion resistance, and good biocompatibility. Recently, Ti-based MBs have emerged as promising candidates for antitumor applications. These developments focus on the functionalization of Ti-based MBs to inhibit tumor propagation and recurrence. This work systematically examines the antitumor approaches of Ti-based MBs and categorizes them into physical and chemical approaches. Physical strategies, such as the photothermal and photocatalytic techniques, are usually related to material-specific properties. Chemical approaches often employ controlled local drug delivery (LDD) systems. Ti-based LDD systems enable the targeted release of chemotherapeutics, metal ions, or immunomodulatory agents at tumor sites. This review highlights the efficacy of these surface-functionalized Ti-based MBs against diverse tumors. Additionally, the challenges and prospects of antitumor Ti-based MBs are also discussed.
Journal Article
On the Potential of Bulk Metallic Glasses for Dental Implantology: Case Study on Ti40Zr10Cu36Pd14
by
Chevalier, Jérôme
,
Courtois, Nicolas
,
Adrien, Jerome
in
Aluminum
,
Amorphous materials
,
Assemblies
2018
Ti40Zr10Cu36Pd14 Bulk Metallic Glass (BMG) appears very attractive for future biomedical applications thanks to its high glass forming ability, the absence of toxic elements such as Ni, Al or Be and its good mechanical properties. For the first time, a complete and exhaustive characterization of a unique batch of this glassy alloy was performed, together with ISO standard mechanical tests on machined implant-abutment assemblies. The results were compared to the benchmark Ti-6Al-4V ELI (Extra-Low-Interstitial) to assess its potential in dental implantology. The thermal stability, corrosion and sterilization resistance, cytocompatibility and mechanical properties were measured on samples with a simple geometry, but also on implant-abutment assemblies’ prototypes. Results show that the glassy alloy exhibits a quite high thermal stability, with a temperature range of 38 °C between the glass transition and crystallization, a compressive strength of 2 GPa, a certain plastic deformation (0.7%), a hardness of 5.5 GPa and a toughness of 56 MPa.√m. Moreover, the alloy shows a relatively lower Young’s modulus (96 GPa) than the Ti-6Al-4V alloy (110–115 GPa), which is beneficial to limit bone stress shielding. The BMG shows a satisfactory cytocompatibility, a high resistance to sterilization and a good corrosion resistance (corrosion potential of −0.07 V/SCE and corrosion current density of 6.0 nA/cm2), which may ensure its use as a biomaterial. Tests on dental implants reveal a load to failure 1.5-times higher than that of Ti-6Al-4V and a comparable fatigue limit. Moreover, implants could be machined and sandblasted by methods usually conducted for titanium implants, without significant degradation of their amorphous nature. All these properties place this metallic glass among a promising class of materials for mechanically-challenging applications such as dental implants.
Journal Article
Discovery of New Ti-Based Alloys Aimed at Avoiding/Minimizing Formation of α” and ω-Phase Using CALPHAD and Artificial Intelligence
2021
In this work, we studied a Ti-Nb-Zr-Sn system for exploring novel composition and temperatures that will be helpful in maximizing the stability of β phase while minimizing the formation of α” and ω-phase. The Ti-Nb-Zr-Sn system is free of toxic elements. This system was studied under the framework of CALculation of PHAse Diagram (CALPHAD) approach for determining the stability of various phases. These data were analyzed through artificial intelligence (AI) algorithms. Deep learning artificial neural network (DLANN) models were developed for various phases as a function of alloy composition and temperature. Software was written in Python programming language and DLANN models were developed utilizing TensorFlow/Keras libraries. DLANN models were used to predict various phases for new compositions and temperatures and provided a more complete dataset. This dataset was further analyzed through the concept of self-organizing maps (SOM) for determining correlations between phase stability of various phases, chemical composition, and temperature. Through this study, we determined candidate alloy compositions and temperatures that will be helpful in avoiding/minimizing formation of α” and ω-phase in a Ti-Zr-Nb-Sn system. This approach can be utilized in other systems such as ω-free shape memory alloys. DLANN models can even be used on a common Android mobile phone.
Journal Article
Critical Raw Materials Saving by Protective Coatings under Extreme Conditions: A Review of Last Trends in Alloys and Coatings for Aerospace Engine Applications
by
Piticescu, Radu Robert
,
Slobozeanu, Anca Elena
,
Grilli, Maria Luisa
in
Additive manufacturing
,
Aerospace engines
,
Aerospace industry
2021
Several applications, where extreme conditions occur, require the use of alloys often containing many critical elements. Due to the ever increasing prices of critical raw materials (CRMs) linked to their high supply risk, and because of their fundamental and large utilization in high tech products and applications, it is extremely important to find viable solutions to save CRMs usage. Apart from increasing processes’ efficiency, substitution, and recycling, one of the alternatives to preserve an alloy and increase its operating lifetime, thus saving the CRMs needed for its manufacturing, is to protect it by a suitable coating or a surface treatment. This review presents the most recent trends in coatings for application in high temperature alloys for aerospace engines. CRMs’ current and future saving scenarios in the alloys and coatings for the aerospace engine are also discussed. The overarching aim of this paper is to raise awareness on the CRMs issue related to the alloys and coating for aerospace, suggesting some mitigation measures without having the ambition nor to give a complete overview of the topic nor a turnkey solution.
Journal Article
High-pressure torsion for new hydrogen storage materials
by
Akiba, Etsuo
,
Edalati, Kaveh
,
Horita, Zenji
in
206 Energy conversion / transport / storage / recovery
,
50 Energy Materials
,
Automobile industry
2018
High-pressure torsion (HPT) is widely used as a severe plastic deformation technique to create ultrafine-grained structures with promising mechanical and functional properties. Since 2007, the method has been employed to enhance the hydrogenation kinetics in different Mg-based hydrogen storage materials. Recent studies showed that the method is effective not only for increasing the hydrogenation kinetics but also for improving the hydrogenation activity, for enhancing the air resistivity and more importantly for synthesizing new nanostructured hydrogen storage materials with high densities of lattice defects. This manuscript reviews some major findings on the impact of HPT process on the hydrogen storage performance of different titanium-based and magnesium-based materials.
Journal Article
Combined Exsolution and Electrodeposition Strategy for Enhancing Electrocatalytic Activity of Ti‐Based Perovskite Oxides in Oxygen and Hydrogen Evolution Reactions
by
Xia, Zhi
,
Naden, Aaron B.
,
Zuo, Shangshang
in
Alternative energy sources
,
bifunctional electrocatalysts
,
Crystal structure
2025
The significant interest in perovskite oxides stems from their compositional and structural flexibility, particularly in the field of electrochemistry. In this study, the double E strategy (exsolution and electrodeposition strategies) is successfully devised for synthesizing perovskite‐based bifunctional electrocatalysts, enabling simultaneous OER and HER applications with exceptional catalytic performance. The synthesized R‐LCTFe/Ni catalyst exhibits outstanding electrocatalytic activity, delivering low overpotentials of 349 and 309 mV at 10 mA cm−2 for OER and HER, respectively, indicating substantial improvements in the inherent electrocatalytic activity. Moreover, the impressive stability of R‐LCTFe/Ni under alkaline conditions underscores its potential for practical water electrolysis applications. The superior bifunctional electrocatalytic performance can be attributed to the reduced charge transfer resistance and the synergistic cooperation between exsolved Fe nanoparticles and electrodeposited Ni compounds. The successful development of the R‐LCTFe/Co catalyst further confirms the transferability of the double E strategy. Compared to R‐LCTFe/Ni, the overpotential of R‐LCTFe/Co is 58 mV higher for OER, yet 48 mV lower for HER at a current density of 10 mA cm−2. This study provides an efficient and promising approach for the fabrication of highly active perovskite‐based electrocatalysts, contributing valuable insights into the design of bifunctional electrocatalysts for OER and HER. This work presents a double E strategy (exsolution and electrodeposition) to develop R‐LCTFe/Ni and R‐LCTFe/Co perovskite‐based catalysts with high bifunctional efficiency for OER and HER. The R‐LCTFe/Ni catalyst shows low overpotentials and exceptional stability, attributed to reduced charge transfer resistance and synergy between exsolved Fe and electrodeposited Ni.
Journal Article
V–Ti-Based Solid Solution Alloys for Solid-State Hydrogen Storage
2025
Highlights
Hydrogen storage performance of V-Ti-based solid solution alloys is related to the elementary composition, phase structure, and homogeneity.
Micro-strain accumulation is responsible for capacity degradation.
Low-cost and high-performance V-Ti-based solid solution alloys with high reversible hydrogen storage capacity, good cyclic durability, and excellent activation performance should be developed.
This review details the advancement in the development of V–Ti-based hydrogen storage materials for using in metal hydride (MH) tanks to supply hydrogen to fuel cells at relatively ambient temperatures and pressures. V–Ti-based solid solution alloys are excellent hydrogen storage materials among many metal hydrides due to their high reversible hydrogen storage capacity which is over 2 wt% at ambient temperature. The preparation methods, structure characteristics, improvement methods of hydrogen storage performance, and attenuation mechanism are systematically summarized and discussed. The relationships between hydrogen storage properties and alloy compositions as well as phase structures are discussed emphatically. For large-scale applications on MH tanks, it is necessary to develop low-cost and high-performance V–Ti-based solid solution alloys with high reversible hydrogen storage capacity, good cyclic durability, and excellent activation performance.
Journal Article
Formation of the structural-phase state of titanium-matrix composites reinforced with tic during synthesis and hot pressing, and their testing as ballistic-resistant (bulletproof) protective materials
2025
Ti-40 wt% TiC and Ti-6Al-4 V- 40 wt% TiC metal matrix composites were obtained by the hydrogenated powder metallurgy approach, followed by post-sintering densification by hot pressing. The composites obtained were characterized by high hardness values, which were 700–1300 HV due to nearly-dense microstructure, high content of reinforcing titanium carbide particles and non-uniform redistribution of reinforcing phase in the matrixes. The high hardness of the composites in the as-densified state resulted in a significant improvement of ballistic performance of two-layer Ti-based metal matrix composites. It is shown that the proposed approach for the manufacturing of layered Ti-based metal matrix composites is promising for practical application.
Journal Article