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In this work, Titania was modified by sulfation or fluorination and platinum on the surface to improve the Cr (VI) reduction efficiency compared to the bare TiO2 material synthesized by the sol-gel method. The synthesized materials were characterized by XRD, SBET, UV-Vis DRS, XRF, TEM, FTIR, and XPS. The modifications led to higher stability in the Anatase phase and surface area of this semiconductor. The addition of F and Pt in TiO2 led to absorption increases in the visible region of the electromagnetic spectrum. A correlation between the new physicochemical properties obtained after TiO2 modification and the photocatalytic performance of this material was observed. The best result in chromium reduction was obtained using Pt-S-TiO2 as the photocatalyst; this material showed a suitable combination of surface area, high UV-Vis absorption, high hydroxylation, and the existence of Pt nanoparticles on the surface, which favors an increased electron-hole pair half-life. Different reaction parameters were also evaluated, which demonstrated that the best photocatalytic performance was obtained under an N2 atmosphere, a light intensity of 120 W/m2, and 2 hours of total reaction time. Likewise, it was noted that an increase in reaction time from 2 to 5 hours, had a detrimental effect on reducing Cr (VI) efficiency.

In this study, TiO 2 nanoparticles were employed as a photocatalyst for the degradation of tetracycline (TC) under visible light irradiation. The TiO 2 nanoparticles were decorated on natural pyrite (TiO 2 /NP) and characterized using XRD, FTIR, and SEM–EDX methods. This study evaluated the impacts of various operational parameters such as pH, catalyst dosage, initial TC concentration, and light intensity on TC removal. The findings revealed that under optimal conditions (pH 7, catalyst: 2 g/L, TC: 30 mg/L, and light intensity: 60 mW/cm 2 ), 100% of TC and 84% of TOC were removed within 180 min. The kinetics of TC elimination followed a first-order model. The dominant oxidation species involved in the photocatalytic elimination of TC was found to be · OH radicals in the TiO 2 /NP system. The reuse experiments showed the high capability of the catalyst after four consecutive cycles. This study confirmed that the TiO 2 /NP system has high performance in photocatalytic TC removal under optimized experimental conditions.

In this research work, we present the synthesis and characterization of four different TiO2 structures, such as nanotubes, nanocavities, nanosheets assembled on nanocavities and nanobowls assembled on nanocavities, prepared by electrochemical anodization using organic electrolytes. After synthesis, the structures were thermally annealed to pass from the amorphous phase to the anatase phase, which is one of the most important crystalline structures of TiO2 due to its high photocatalytic activity and stability. The unique morphology and topography were studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The elemental composition was determined by energy-dispersive X-ray spectroscopy (EDS). The anatase phase was verified by Raman microscopy and X-ray diffraction (XRD), the band gap energy was calculated by the Kubelka–Munk function, and the main defect states that generate the emission, as well as their lifetime, were determined by photoluminescence spectroscopy and time response photoluminescence (TRPL), respectively. The TiO2 nanomaterials were tested as catalysts in the photodegradation of a solution of methylene blue using a UV lamp at room temperature. The results showed complex morphologies and different surface roughness areas of these nanomaterials. Furthermore, a relationship between defect states, band gap energy, and photocatalytic activity was established. We found that the catalytic activity was improved as an effect of geometric parameters and oxygen vacancies.

In this review article, attention is paid towards the formation of various nanostructured stoichiometric titanium dioxide (TiO2), non-stoichiometric titanium oxide (TiO2−x) and Magnéli phase (TinO2n−1)-based layers, which are suitable for the application in gas and volatile organic compound (VOC) sensors. Some aspects related to variation of sensitivity and selectivity of titanium oxide-based sensors are critically overviewed and discussed. The most promising titanium oxide-based hetero- and nano-structures are outlined. Recent research and many recently available reviews on TiO2-based sensors and some TiO2 synthesis methods are discussed. Some promising directions for the development of TiO2-based sensors, especially those that are capable to operate at relatively low temperatures, are outlined. The applicability of non-stoichiometric titanium oxides in the development of gas and VOC sensors is foreseen and transitions between various titanium oxide states are discussed. The presence of non-stoichiometric titanium oxide and Magnéli phase (TinO2n−1)-based layers in ‘self-heating’ sensors is predicted, and the advantages and limitations of ‘self-heating’ gas and VOC sensors, based on TiO2 and TiO2−x/TiO2 heterostructures, are discussed.

We present a comparative density functional tight binding study of an organic molecule attachment to TiO2 via a carboxylic group, with the example of acetic acid. For the first time, binding to low-energy surfaces of crystalline anatase (101), rutile (110) and (B)-TiO2 (001), as well as to the surface of amorphous (a-) TiO2 is compared with the same computational setup. On all surfaces, bidentate configurations are identified as providing the strongest adsorption energy, Eads = −1.93, −2.49 and −1.09 eV for anatase, rutile and (B)-TiO2, respectively. For monodentate configurations, the strongest Eads = −1.06, −1.11 and −0.86 eV for anatase, rutile and (B)-TiO2, respectively. Multiple monodentate and bidentate configurations are identified on a-TiO2 with a distribution of adsorption energies and with the lowest energy configuration having stronger bonding than that of the crystalline counterparts, with Eads up to −4.92 eV for bidentate and −1.83 eV for monodentate adsorption. Amorphous TiO2 can therefore be used to achieve strong anchoring of organic molecules, such as dyes, that bind via a -COOH group. While the presence of the surface leads to a contraction of the band gap vs. the bulk, molecular adsorption caused no appreciable effect on the band structure around the gap in any of the systems.

This paper reports on the photocatalytic activity showed by nanocomposites of TiO2 with low density polyethylene (LDPE) and high density polyethylene (HDPE) (10, 20 wt%) for the degradation of methyl orange in aqueous medium under visible light irradiation. TiO2 was synthetized by sol-gel process, and the polymers were incorporated by impregnation. Both the pure TiO2 and the nanocomposites were characterized using different physico-chemical techniques including specific surface area analysis, X-ray diffraction analysis, transmission electron microscopy, ultraviolet-visible and photoluminescence spectroscopy, and X-ray photoelectron spectroscopy. All the prepared nanocomposites showed an absorption edge in the visible region. TiO2(90)/LDPE photocatalyst showed the best degradation efficiency after 180 minutes of reaction, without notorious decrease of degradation efficiency after three consecutive uses. Photoluminescence and X-ray photoelectron spectroscopy analyses suggested the presence of vacancies in the TiO2 structure promoted by a Ti–O–C interaction being responsible for the photocatalytic activity enhancement under visible light irradiation.

In this work, Titania was modified by sulfation or fluorination and platinum on the surface to improve the Cr (VI) reduction efficiency compared to the bare TiO2 material synthesized by the sol-gel method. The synthesized materials were characterized by XRD, SBET, UV-Vis DRS, XRF, TEM, FTIR, and XPS. The modifications led to higher stability in the Anatase phase and surface area of this semiconductor. The addition of F and Pt in TiO2 led to absorption increases in the visible region of the electromagnetic spectrum. A correlation between the new physicochemical properties obtained after TiO2 modification and the photocatalytic performance of this material was observed. The best result in chromium reduction was obtained using Pt-S-TiO2 as the photocatalyst; this material showed a suitable combination of surface area, high UV-Vis absorption, high hydroxylation, and the existence of Pt nanoparticles on the surface, which favors an increased electron-hole pair half-life. Different reaction parameters were also evaluated, which demonstrated that the best photocatalytic performance was obtained under an N2 atmosphere, a light intensity of 120 W/m2, and 2 hours of total reaction time. Likewise, it was noted that an increase in reaction time from 2 to 5 hours, had a detrimental effect on reducing Cr (VI) efficiency.

Titanium dioxide (TiO2) particles are widely used as photocatalysts due to their stability, low toxicity, and relatively low cost. However, their application is limited by a wide bandgap and a high recombination rate. This project investigated the photocatalytic performance of Ag/TiO2 catalyst, prepared by coupling Ag metal to TiO2 using the liquid impregnation method. The photocatalytic activity of different concentrations of Ag metal solutions and different pH levels of Ag/TiO2 catalyst under UV and visible light irradiation was observed. It was shown that Ag/TiO2 catalyst had the best photodegradation efficiency (83.82%) and the highest rate constant (0.03298 min-1) in 50 ppm Ag metal concentration and at pH 5 under UV light irradiation. The operating conditions were optimised by using the Design of Experiment (DOE) and Response Surface Methodology (RSM) to obtain optimum photodegradation efficiency (PE). The optimum parameters were 22.6263 ppm Ag metal solution and pH of 5, which were estimated to produce the highest photodegradation efficiency (84.0006 %) and rate constant (0.0321 min-1). The concentration of the methylene blue (MB) followed a first-order exponential decay and showed a decreasing trend from its initial concentration. In addition, the photocatalytic degradation rate of MB has been modelled successfully by Power Law kinetic model derived from the Langmuir-Hinshelwood framework. Numerical and analytical methods were implemented to solve the Langmuir-Hinshelwood equation, and both methods were very effective in agreement with the trend shown by the experimental data. In terms of photodegradation efficiency, the kinetic model has slightly over predicted the experimental model due to some minor experimental error, but the experimental data effectively complied with the theoretical micro kinetics investigations simulated using Power Law kinetic model. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

This study focused on the preparation and investigation of g-C3N4/TiO2 photocatalysts using different TiO2 morphologies (anatase nanoparticles (TPs), poorly crystalline nanotubes (aTTs), and well-crystalline anatase nanorods (TRs)) and self-synthesized g-C3N4 (CN). The synthesis of the g-C3N4/TiO2 composites was carried out using a mortar mixing technique and a g-C3N4 to TiO2 weight ratio of 1:1. In addition, the g-C3N4/TiO2 composites were annealed in a muffle furnace at 350 °C for 2 h in air. The successful formation of a g-C3N4/TiO2 composite with a mesoporous structure was confirmed using the results of XRD, N2 physisorption, and FTIR analyses, while the results of microscopic analysis techniques confirmed the preservation of TiO2 morphology in all g-C3N4/TiO2 composites investigated. UV-Vis DR measurements showed that the investigated g-C3N4/TiO2 composites exhibited visible-light absorption due to the presence of CN. The results of solid-state photoluminescence and electrochemical impedance spectroscopy showed that the composites exhibited a lower charge recombination compared to pure TiO2 and CN. For example, the charge transfer resistance (RCT) of the CNTR/2 composite of TR and CN calcined in air for 2 h was significantly reduced to 0.4 MΩ, compared to 0.9 MΩ for pure TR and 1.0 MΩ for pure CN. The CNTR/2 composite showed the highest photocatalytic performance of the materials tested, achieving 30.3% degradation and 25.4% mineralization of bisphenol A (BPA) dissolved in water under visible-light illumination. In comparison, the pure TiO2 and CN components achieved significantly lower BPA degradation rates (between 2.4 and 11.4%) and mineralization levels (between 0.6 and 7.8%). This was due to (i) the presence of Ti3+ and O-vacancies in the TR, (ii) enhanced heterojunction formation, and (iii) charge transfer dynamics enabled by a dual mixed type-II/Z scheme mechanism.

The COronaVIrus Disease (COVID-19) is a newly emerging viral disease caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). Rapid increase in the number of COVID-19 cases worldwide led the WHO to declare a pandemic within a few months after the first case of infection. Due to the lack of a prophylactic measure to control the virus infection and spread, early diagnosis and quarantining of infected as well as the asymptomatic individuals are necessary for the containment of this pandemic. However, the current methods for SARS-CoV-2 diagnosis are expensive and time consuming, although some promising and inexpensive technologies are becoming available for emergency use. In this work, we report the synthesis of a cheap, yet highly sensitive, cobalt-functionalized TiO2 nanotubes (Co-TNTs)-based electrochemical sensor for rapid detection of SARS-CoV-2 through sensing the spike (receptor binding domain (RBD)) present on the surface of the virus. A simple, low-cost, and one-step electrochemical anodization route was used for synthesizing TNTs, followed by an incipient wetting method for cobalt functionalization of the TNTs platform, which was connected to a potentiostat for data collection. This sensor specifically detected the S-RBD protein of SARS-CoV-2 even at very low concentration (range of 14 to 1400 nM (nano molar)). Additionally, our sensor showed a linear response in the detection of viral protein over the concentration range. Thus, our Co-TNT sensor is highly effective in detecting SARS-CoV-2 S-RBD protein in approximately 30 s, which can be explored for developing a point of care diagnostics for rapid detection of SARS-CoV-2 in nasal secretions and saliva samples.