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"Titanium"
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Titanium
Explains the characteristics of titanium, where it is found, how it is mined, and some of its uses, including ship hulls, durable tools, and pigments.
Book
Rapid Synthesis of Fast-Charging TiNbsub.2Osub.7 for Lithium-Ion Storage via Ultrafast Carbothermal Shock
The development of fast-charging lithium-ion batteries urgently requires high-performance anode materials. In this paper, through an ultrafast carbothermal shock (CTS) strategy, titanium niobium oxide (TiNb[sub.2]O[sub.7], TNO) with an optimized structure was successfully synthesized within 30 s. By regulating the synthesis temperature to 1200 °C, the TNO-1200 material was obtained. Its lattice parameters (a-axis: 17.6869 Å) and unit-cell volume (796.83 Å[sup.3]) were significantly expanded compared to the standard structure (a-axis: 17.51 Å, volume ~790 Å[sup.3]), which widened the lithium-ion migration channels. Rietveld refinement and atomic position analysis indicated that the partial overlap of Ti/Nb atoms and the cooperative displacement of oxygen atoms induced by CTS reduced the lithium-ion diffusion energy barrier. Meanwhile, the cation disorder suppressed the polarization effect. Electrochemical tests showed that after 3000 cycles at a current density of 10 C, the specific capacity of TNO-1200 reached 125 mAh/g, with a capacity retention rate of 98%. EDS mapping confirmed the uniform distribution of elements and the absence of impurity phases. This study provides an efficient synthesis strategy and theoretical basis for the design of high-performance fast-charging battery materials through atomic-scale structural engineering.
Journal Article
In-situ electron-beam synthesis of boride phases FROM LaB.sub.6/Ti system
The paper deals with the direct synthesis of titanum borides from lanthanum hexaboride layers deposited onto a titanium substrate followed by processing with a microsecond low-energy high-current electron beam (LEHCEB). It is shown how the electron-beam energy density affects the structure and properties of the obtained surface layer. The latter consists of 54 to 41 at.% B, depending on the LEHCEB processing mode. Microstructure investigations show that the surface layer is a nanostructured composite consisting of a mixture of TiB and TiB.sub.2 particles distributed in the submicrocrystalline [alpha]âTi matrix. The boride particle size ranges between 10 and 70â¯nm, depending on the synthesis modes. It is shown that the formation of the composite nanostructure improves the nanohardness and wear resistance of the synthesized surface layer. When the content of boride phases is the highest, the nanohardness grows up to 12.5â¯GPa or by 3.9 times, while the wear resistance becomes more than 5 times higher than in the initial titanium substrate.
Journal Article
3D Printed Titanium Wedges for Distraction Arthrodesis of the Subtalar Joint
Category:
Hindfoot
Introduction/Purpose:
Distraction arthrodesis of the subtalar joint is performed to restore height and correct deformity in the case of subtalar joint arthrosis, malalignment of the rear foot, calcaneal fracture, or other pathologies. Historically, autograft or allograft bone blocks were used to restore natural alignment and improve hindfoot function. Although successful use has been reported, complications associated with donor site morbidity and size limitation for autograft, as well as additional complications including nonunion, graft collapse, and loss of alignment are common. Recently, innovative advancements have enabled the use of 3D printed porous titanium implants for use, improving the union rates and reduced risk of subsidence and graft collapse.
Methods:
6 patients with subtalar collapse and anterior ankle impingement were indicated for distraction subtalar arthrodesis. Surgery was performed with a lateral approach for the distraction arthrodesis using an off the shelf 3D printed subtalar wedge and a nitinol pseudoelastic fusion rod for stabilization and fixation. Patients were followed 6 months post op for fusion and alignment. Fusion was confirmed at 3 months with CT scans and alignment was monitored with weightbearing ankle X-rays.
Results:
3D wedge incorporation and sustained correction of height and alignment was maintained over time at the subtalar joint. There were no nonunions, 2 patients reports skin healing issues due to tension on the skin with wound closure. These healed with local wound care. Improvement in preoperative to postoperative tibiotalar sagittal plane alignment was observed in all patients.
Conclusion:
The use of a 3D printed titanium wedge for distraction Arthrodesis of the subtalar joint is a safe procedure and useful procedure in short-term follow-up. This procedure does provide improvement in the patients alignment and fusion occurs with in 3 months of surgery.
Journal Article
General review of titanium toxicity
Background
Titanium is a commonly used inert bio-implant material within the medical and dental fields. Although the use of titanium is thought to be safe with a high success rate, in some cases, there are rare reports of problems caused by titanium. In most of these problematic reports, only individual reports are dominant and comprehensive reporting has not been performed. This comprehensive article has been prepared to review the toxicity of titanium materials within the medical and dental fields.
Methods
We used online searching tools including MEDLINE (PubMed), Embase, Cochrane Library, and Google Scholar by combining keywords such as “titanium implant toxicity,” “titanium implant corrosion,” “titanium implant allergy,” and “yellow nail syndrome.” Recently updated data has been collected and compiled into one of four categories: “the toxicity of titanium,” “the toxicity of titanium alloys,” “the toxicity of titanium implants,” and “diseases related to titanium.”
Results
Recent studies with regard to titanium toxicity have been increasing and have now expanded to the medical field in addition to the fields of environmental research and basic science. Problems that may arise in titanium-based dental implants include the generation of titanium and titanium alloy particles and ions deposited into surrounding tissues due to the corrosion and wear of implants, resulting in bone loss due to inflammatory reactions, which may lead to osseointegration failure of the dental implant. These titanium ions and particles are systemically deposited and can lead to toxic reactions in other tissues such as yellow nail syndrome. Additionally, implant failure and allergic reactions can occur due to hypersensitivity reactions. Zirconia implants can be considered as an alternative; however, limitations still exist due to a lack of long-term clinical data.
Conclusions
Clinicians should pay attention to the use of titanium dental implants and need to be aware of the problems that may arise from the use of titanium implants and should be able to diagnose them, in spite of very rare occurrence. Within the limitation of this study, it was suggested that we should be aware the rare problems of titanium toxicity.
Journal Article
A review—metastable β titanium alloy for biomedical applications
Titanium and its alloys have already been widely used as implant materials due to their outstanding mechanical characteristics and biocompatibility. Notwithstanding this, researchers and businesses alike have continued to actively pursue superior alloys since there are still problems which need urgent consideration. One of these is a noteworthy difference in the implant material’s elastics modulus and that of natural bone, which result into an issue of stress shielding. With prolonged use Ti alloys releases dangerous ions. The Ti alloy surface has a low bioactivity, which prolongs the healing process. β-Ti alloys could be used as viable alternatives when creating dental implants. Additionally, β-Ti alloys characteristics, such as low Young modulus, increased strength, appropriate biocompatibility, and strong abrasion and corrosion resistance, serve as the necessary evidence. Ti alloys when altered structurally, chemically, and by thermomechanical treatment thereby enabling the creation of material which can match the requirements of a various clinical practise scenarios. Additional research is needed which can focused on identifying next century Ti alloys consisting of some more compatible phase and transforming the Ti alloys surface from intrinsically bioinert to bioactive to prevent different issues. In order to give scientific support for adopting β-Ti-based alloys as an alternative to cpTi, this paper evaluates the information currently available on the chemical, mechanical, biological, and electrochemical properties of key β-titanium alloys designed from the past few years. This article is also focusing on β-titanium alloy, its properties and performance over other type of titanium alloy such as α titanium alloys. However, in-vivo research is needed to evaluate novel β titanium alloys to support their use as cpTi alternatives.
Journal Article
Bioorthogonal catalytic patch
Bioorthogonal catalysis mediated by transition metals has inspired a new subfield of artificial chemistry complementary to enzymatic reactions, enabling the selective labelling of biomolecules or in situ synthesis of bioactive agents via non-natural processes. However, the effective deployment of bioorthogonal catalysis in vivo remains challenging, mired by the safety concerns of metal toxicity or complicated procedures to administer catalysts. Here, we describe a bioorthogonal catalytic device comprising a microneedle array patch integrated with Pd nanoparticles deposited on TiO
2
nanosheets. This device is robust and removable, and can mediate the local conversion of caged substrates into their active states in high-level living systems. In particular, we show that such a patch can promote the activation of a prodrug at subcutaneous tumour sites, restoring its parent drug’s therapeutic anticancer properties. This in situ applied device potentiates local treatment efficacy and eliminates off-target prodrug activation and dose-dependent side effects in healthy organs or distant tissues.
The toxicity and complicated administration procedures of transition metal catalysts have hampered the applications of bioorthogonal catalysis in vivo. Here the authors fill the needles of a microneedle array patch with palladium nanoparticles deposited on titanium nanosheets and show that the device, applied locally on the skin of mouse models bearing melanoma, promotes intratumoural conversion of systemically injected caged doxorubicin into the active drug, reducing its toxicity and side effects.
Journal Article
Review of Antimicrobial Properties of Titanium Dioxide Nanoparticles
There is a growing interest in the utilization of metal oxide nanoparticles as antimicrobial agents. This review will focus on titanium dioxide nanoparticles (TiO2 NPs), which have been demonstrated to exhibit high antimicrobial activity against bacteria and fungi, chemical stability, low toxicity to eukaryotic cells, and therefore high biocompatibility. Despite the extensive research conducted in this field, there is currently no consensus on how to enhance the antimicrobial efficacy of TiO2 NPs. The aim of this review is to evaluate the influence of various factors, including particle size, shape, composition, and synthesis parameters, as well as microbial type, on the antibacterial activity of TiO2 NPs against bacteria and fungi. Furthermore, the review offers a comprehensive overview of the methodologies employed in the synthesis and characterization of TiO2 NPs. The antimicrobial activity of TiO2 exhibits a weak dependence on the microorganism species. A tendency towards increased antibacterial activity is observed with decreasing TiO2 NP size. The dependence on the shape and composition is more pronounced. The most pronounced antimicrobial potential is exhibited by amorphous NPs and NPs doped with inorganic compounds. This review may be of interest to specialists in biology, medicine, chemistry, and other related fields.
Journal Article