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TiAl alloys are lightweight, show decent corrosion resistance and have good mechanical properties at elevated temperatures, making them appealing for high-temperature applications. However, polysynthetic twinned TiAl single crystals fabricated by crystal-seeding methods face substantial challenges, and their service temperatures cannot be raised further. Here we report that Ti–45Al–8Nb single crystals with controlled lamellar orientations can be fabricated by directional solidification without the use of complex seeding methods. Samples with 0° lamellar orientation exhibit an average room temperature tensile ductility of 6.9% and a yield strength of 708 MPa, with a failure strength of 978 MPa due to the formation of extensive nanotwins during plastic deformation. At 900 °C yield strength remains high at 637 MPa, with 8.1% ductility and superior creep resistance. Thus, this TiAl single-crystal alloy could provide expanded opportunities for higher-temperature applications, such as in aeronautics and aerospace. Increasing the temperature of jet engines requires materials that are stable against degradation. Towards this goal, growth of TiAl alloys with high strength and ductility, as well as superior creep resistance, is reported at high temperatures.

The surfaces of large austenitic stainless-steel sheets, which have side lengths of at least 1 m a sheet thickness of at least 6 mm, used for food tanks and sliding plates in seismic isolation devices, must be finished to a mirror surface. Polishing is performed to improve the surface quality of such sheets and dry machining is typically applied. The problems associated with dry machining are the exhaust heat of machining and treatment of chips. A transition to wet machining is required to solve these problems. In our laboratory, we have developed a wet polishing machine and researched the selection of grinding wheels to develop wet polishing technology for large stainless-steel sheets. In this study, to reduce tool cost and reuse resources, we attempted to manufacture a recycled grinding wheel using snippets of grinding wheel scraps. A polyvinyl alcohol (PVA) aqueous solution was used as the bonding agent for the recycled grinding wheel to reduce environmental load. To overcome the ease of dissolution of PVA in water, we attempted to improve the water resistance of the PVA aqueous solution by incorporating an organic titanium compound. This is one of our efforts to contribute to sustainable development goals. The results are summarized below. (1) A recycled grinding wheel was fabricated by kneading crushed pieces of grinding wheel scrap with a bonding agent. (2) The maintenance of the shape of the recycled grinding wheel was controlled by the concentration of the bonding agent. (3) The recycled grinding wheel with a PVA bonding agent was vulnerable to water. In contrast, the recycled grinding wheel to which the organic titanium compound was added exhibited improved water resistance. (4) The polishing of stainless-steel sheets using the plain PVA recycled wheel was relatively ineffective, but polishing using the recycled wheel with the titanium additive was comparable to polishing with a new grinding wheel.

ZnSe, ZnSe-TiO[sub.2] microspheres and nanostructured TiO[sub.2] obtained by hydrothermal and sol–gel methods were tested against Staphylococcus aureus ATCC 25923 and Micrococcus lysodeikticus ATCC 4698 before and after lysozyme (Lys) loading. Morphological characterization of inorganic matrices and hybrid organic–inorganic complexes were performed by microscopy techniques (SEM, AFM and Dark Field Hyperspectral Microscopy). Light absorption properties of ZnSe, ZnSe-TiO[sub.2] and TiO[sub.2] powders were assessed by UV–visible spectroscopy and their ability to generate reactive oxygen species (•OH and O[sub.2] [sup.•−]) under visible light irradiation was investigated. Antibacterial activity of ZnSe, ZnSe-TiO[sub.2], TiO[sub.2], Lys/ZnSe, Lys/ZnSe-TiO[sub.2] and Lys/TiO[sub.2] samples under exposure to visible light irradiation (λ > 420 nm) was tested against Staphylococcus aureus and Micrococcus lysodeikticus and correlated with ROS photogeneration.

There is a tremendous increase in the demand for converting biomaterials into high-quality industrially manufactured human body parts, also known as medical implants. Drug delivery systems, bone plates, screws, cranial, and dental devices are the popular examples of these implants - the potential alternatives for human life survival. However, the processing techniques of an engineered implant largely determine its preciseness, surface characteristics, and interactive ability with the adjacent tissue(s) in a particular biological environment. Moreover, the high cost-effective manufacturing of an implant under tight tolerances remains a challenge. In this regard, several subtractive or additive manufacturing techniques are employed to manufacture patient-specific implants, depending primarily on the required biocompatibility, bioactivity, surface integrity, and fatigue strength. The present paper reviews numerous non-degradable and degradable metallic implant biomaterials such as stainless steel (SS), titanium (Ti)-based, cobalt (Co)-based, nickel-titanium (NiTi), and magnesium (Mg)-based alloys, followed by their processing via traditional turning, drilling, and milling including the high-speed multi-axis CNC machining, and non-traditional  abrasive water jet machining (AWJM), laser beam machining (LBM), ultrasonic machining (USM), and electric discharge machining (EDM) types of subtractive manufacturing techniques. However, the review further funnels down its primary focus on Mg, NiTi, and Ti-based alloys on the basis of the increasing trend of their implant applications in the last decade due to some of their outstanding properties. In the recent years, the incorporation of cryogenic coolant-assisted traditional subtraction of biomaterials has gained researchers’ attention due to its sustainability, environment-friendly nature, performance, and superior biocompatible and functional outcomes fitting for medical applications. However, some of the latest studies reported that the medical implant manufacturing requirements could be more remarkably met using the non-traditional subtractive manufacturing approaches. Altogether, cryogenic  machining among the traditional routes and EDM among the non-traditional means along with their variants, were identified as some of the most effective subtractive manufacturing techniques for achieving the dimensionally accurate and biocompatible metallic medical implants with significantly modified surfaces.

Efficient, chemically stable and cheap materials are highly required as electrodes in the ions-electrosorption-based technologies such as supercapacitors and capacitive deionization desalination. Herein, facile preparation of titanium oxide-incorporated activated carbon using cheap precursors is introduced for this regard. The proposed material was synthesized using the solubility power of the subcritical water to partially dissolve titanium oxide particles to be adsorbable on the surface of the activated carbon. Typically, an aqueous suspension of commercial TiO.sub.2 particles (P25) and activated carbon was autoclaved at 180°C for 10 h. The physiochemical characterizations indicated high and uniform distribution of the inorganic material on the surface of the activated carbon. The ionic electrosorption capacity was highly improved as the specific capacitance increased from 76 to 515 F/g for the pristine and modified activated carbon, respectively at 5 mV/s in 0.5 M sodium chloride solution. However, the weight content of titanium oxide has to be adjusted; 0.01% is the optimum value. Overall, the study introduces novel and simple one-pot procedure to synthesis powerful titanium oxide-based functional materials from cheap solid titanium precursor without utilization of additional chemicals.

Most high-performance thermoelectric materials require either expensive, rare, or toxic elements. By doping TiNiSn, a low-cost, abundant thermoelectric compound, with copper as an n-type donor, some optimization can be performed for such materials. Ti(Ni[sub.1-x] Cux)Sn was synthesized by arc melting followed by heat treatment and hot pressing. The resulting material was analyzed for its phases using XRD and SEM and its transport properties. Cu undoped and 0.05/0.1% doped samples showed no additional phases in addition to the matrix half-Heusler phase, while the 1% copper doping initiated some Ti[sub.6] Sn[sub.5] and Ti[sub.5] Sn[sub.3] precipitation. The transport properties showed that copper acts as an n-type donor while also lowing the lattice thermal conductivity of the materials. the sample containing 0.1% copper showed the best figure of merit, ZT, with a maximal value of 0.75 and an average value of 0.5 through 325–750 K showing a 125% improvement over the undoped sample of TiNiSn.

Titanium silicalite-1 (TS-1) is a zeolitic material with MFI framework structure, in which 1 to 2 per cent of the silicon atoms are substituted for titanium atoms. It is widely used in industry owing to its ability to catalytically epoxidize olefins with hydrogen peroxide (H 2 O 2 ), leaving only water as a byproduct 1 , 2 ; around one million tonnes of propylene oxide are produced each year using this process 3 . The catalytic properties of TS-1 are generally attributed to the presence of isolated Ti( iv ) sites within the zeolite framework 1 . However, despite almost 40 years of experimental and computational investigation 4 – 10 , the structure of these active Ti( iv ) sites is unconfirmed, owing to the challenges of fully characterizing TS-1. Here, using a combination of spectroscopy and microscopy, we characterize in detail a series of highly active and selective TS-1 propylene epoxidation catalysts with well dispersed titanium atoms. We find that, on contact with H 2 17 O 2 , all samples exhibit a characteristic solid-state 17 O nuclear magnetic resonance signature that is indicative of the formation of bridging peroxo species on dinuclear titanium sites. Further, density functional theory calculations indicate that cooperativity between two titanium atoms enables propylene epoxidation via a low-energy reaction pathway with a key oxygen-transfer transition state similar to that of olefin epoxidation by peracids. We therefore propose that dinuclear titanium sites, rather than isolated titanium atoms in the framework, explain the high efficiency of TS-1 in propylene epoxidation with H 2 O 2 . This revised view of the active-site structure may enable further optimization of TS-1 and the industrial epoxidation process. A combination of spectroscopy, microscopy and theoretical calculations shows that the reactivity of titanium silicalite-1 as an epoxidation catalyst is due to the presence of dinuclear titanium sites.

Improving soft tissue attachment and reducing bacterial colonization on titanium abutments are key factors for the long-term maintenance of healthy soft and hard peri-implant tissues. This in vitro study was conducted to compare the biocompatibility and antibacterial activity of four different surfaces: uncoated Ti6Al4V, anodized, and coated with titanium nitride or zirconium nitride. Surface topography was investigated with a high-resolution system for measuring surface finishes. Human gingival fibroblast (HGF) adhesion and proliferation were examined using MTT assay, Scanning Electron Microscopy (SEM) imaging, immunofluorescence analysis and real-time PCR for selected target genes. The hemolysis and AMES tests were performed to assess the chemical compounds' blood compatibility and mutagenic potential, respectively. Antibacterial activity was tested against five bacterial strains isolated from the oral cavity (Streptococcus salivarius, S. sanguinis, S. mutans, S. sobrinus, S. oralis), and the percentage of dead bacteria was calculated. Roughness measurements confirmed a substantial similarity between the surfaces and their compatibility with clinical applications. MTT assay, SEM analysis and immunofluorescence staining showed adhesion and proliferation of HGFs cultured on all the examined surfaces. PCR confirmed that HGFs produced extracellular matrix components efficiently on all the surfaces. No hemolytic activity was detected, and the AMES test confirmed the surfaces' clinical safety. For all tested bacterial strains, biofilms grown on the zirconium nitride surface showed a higher percentage of dead bacteria than on the other disks. The titanium nitride surface inactivated bacterial biofilms, too, but to a lesser extent.

A numerical simulation of convective heat transfer coefficient (h[sub.conv] ) was studied with Cu-Water and TiO[sub.2] -Water nanofluids flowing through a circular tube subjected to uniform wall heat flux boundary conditions under laminar and turbulent regimes. Four different concentrations of nanofluids (ɸ = 0.5, 1, 1.5 and 2%) were used for the analysis and the Reynolds number (Re) was varied from laminar (500 to 2000) to turbulent flow regime (5000 to 20,000). The dependence of h[sub.conv] on Re and ɸ was investigated using a single-phase Newtonian approach. In comparison to base fluid, average h[sub.conv] enhancements of 10.4% and 7.3% were noted, respectively, for the maximum concentration (ɸ = 2%) and Re = 2000 for Cu-Water and TiO[sub.2] —water nanofluids in the laminar regime. For the same ɸ under the turbulent regime (Re = 20,000), the enhancements were noted to be 14.6% and 13.2% for both the nanofluids, respectively. The random motion (Brownian motion) and heat diffusion (thermophoresis) by nanosized particles are the two major slip mechanisms that have more influence on the enhancement of h[sub.conv] . In addition, the Nusselt number (Nu) of the present work was validated for water with the Shah and Dittus Boelter equation and found to have good agreement for both the regimes.

Many established, but also potential future applications of NiTi-based shape memory alloys (SMA) in biomedical devices and solid-state refrigeration require long fatigue life with 10 7 –10 9 duty cycles 1 , 2 . However, improving the fatigue resistance of NiTi often compromises other mechanical and functional properties 3 , 4 . Existing efforts to improve the fatigue resistance of SMA include composition control for coherent phase boundaries 5 – 7 and microstructure control such as precipitation 8 , 9 and grain-size reduction 3 , 4 . Here, we extend the strategy to the nanoscale and improve fatigue resistance of NiTi via a hybrid heterogenous nanostructure. We produced a superelastic NiTi nanocomposite with crystalline and amorphous phases via severe plastic deformation and low-temperature annealing. The as-produced nanocomposite possesses a recoverable strain of 4.3% and a yield strength of 2.3 GPa. In cyclic compression experiments, the nanostructured NiTi micropillars endure over 10 8 reversible-phase-transition cycles under a stress of 1.8 GPa. We attribute the enhanced properties to the mutual strengthening of nanosized amorphous and crystalline phases where the amorphous phase suppresses dislocation slip in the crystalline phase while the crystalline phase hinders shear band propagation in the amorphous phase. The synergy of the properties of crystalline and amorphous phases at the nanoscale could be an effective method to improve fatigue resistance and strength of SMA. Increasing the fatigue life of shape memory alloys often compromises other mechanical properties such as yield strength and plastic deformation behaviour. Introducing a mixed nanostructure of crystalline and amorphous phases can enable superelasticity in NiTi micropillars with recoverable strain of 4.3%, yield strength of 2.3 GPa and 10 8 reversible-phase transition cycles under a stress of 1.8 GPa.