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268 result(s) for "Tunability"
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Highly Efficient Blue‐Emitting CsPbBr3 Perovskite Nanocrystals through Neodymium Doping
Colloidal CsPbX3 (X = Br, Cl, and I) perovskite nanocrystals exhibit tunable bandgaps over the entire visible spectrum and high photoluminescence quantum yields in the green and red regions. However, the lack of highly efficient blue‐emitting perovskite nanocrystals limits their development for optoelectronic applications. Herein, neodymium (III) (Nd3+) doped CsPbBr3 nanocrystals are prepared through the ligand‐assisted reprecipitation method at room temperature with tunable photoemission from green to deep blue. A blue‐emitting nanocrystal with a central wavelength at 459 nm, an exceptionally high photoluminescence quantum yield of 90%, and a spectral width of 19 nm is achieved. First principles calculations reveal that the increase in photoluminescence quantum yield upon doping is driven by an enhancement of the exciton binding energy due to increased electron and hole effective masses and an increase in oscillator strength due to shortening of the PbBr bond. Putting these results together, an all‐perovskite white light‐emitting diode is successfully fabricated, demonstrating that B‐site composition engineering is a reliable strategy to further exploit the perovskite family for wider optoelectronic applications. Narrowband blue‐emitting CsPbBr3 perovskite nanocrystals with a photoluminescence quantum yield of 90% are achieved by B‐site doping of neodymium ions. The doping concentration can tune the emission spectrum in a controlled manner. First principles calculations reveal that dopant‐induced electronic changes dominate the bandgap tunability and the high quantum yield is associated with enhanced exciton binding energy and oscillator strength.
A Class of Organic Units Featuring Matrix‐Controlled Color‐Tunable Ultralong Organic Room Temperature Phosphorescence
A novel class of organic units (N‐1 and N‐2) and their derivatives (PNNA‐1 and PNNA‐2) with excellent property of ultralong organic room temperature phosphorescence (UORTP) is reported. In this work, N‐1, N‐2, and their derivatives function as the guests, while organic powders (PNCz, BBP, DBT) and polymethyl methacrylate (PMMA) serve as the host matrixes. Amazingly, the color of phosphorescence can be tuned in different states or by varying the host matrixes. At 77 K, all molecules show green afterglow in the monomer state but yellow afterglow in the aggregated state because strong intermolecular interactions exist in the self‐aggregate and induce a redshift of the afterglow. In particular, PNNA‐1 and PNNA‐2 demonstrate distinctive photoactivated green UORTP in the PMMA film owing to the generation of their cation radicals. Whereas the PNNA‐1@PNCz and PNNA‐2@PNCz doping powders give out yellow UORTP, showing matrix‐controlled color‐tunable UORTP. In PNCz, the cation radicals of PNNA‐1 and PNNA‐2 can stay stably and form strong intermolecular interactions with PNCz, leading to a redshift of ultralong phosphorescence. Two organic units and their derivatives with tunable UORTP in defferent states or by varying doping matrixes are reported. PNNA‐1 and PNNA‐2 demonstrate distinctive photoactived green UORTP in PMMA films. The PNNA‐1@PNCz and PNNA‐2@PNCz doping systems emit yellow UORTP, showing matrix‐controlled color‐tunable UORTP.
Electrically tunable laser based on oblique heliconical cholesteric liquid crystal
A cholesteric liquid crystal (CLC) formed by chiral molecules represents a self-assembled one-dimensionally periodic helical structure with pitch p in the submicrometer and micrometer range. Because of the spatial periodicity of the dielectric permittivity, a CLC doped with a fluorescent dye and pumped optically is capable of mirrorless lasing. An attractive feature of a CLC laser is that the pitch p and thus the wavelength of lasing λ̄ can be tuned, for example, by chemical composition. However, the most desired mode to tune the laser, by an electric field, has so far been elusive. Here we present the realization of an electrically tunable laser with λ̄ spanning an extraordinarily broad range (>100 nm) of the visible spectrum. The effect is achieved by using an electric-field-induced oblique helicoidal (OH) state in which the molecules form an acute angle with the helicoidal axis rather than align perpendicularly to it as in a field-free CLC. The principal advantage of the electrically controlled CLCOH laser is that the electric field is applied parallel to the helical axis and thus changes the pitch but preserves the single-harmonic structure. The preserved single-harmonic structure ensures efficiency of lasing in the entire tunable range of emission. The broad tuning range of CLCOH lasers, coupled with their microscopic size and narrow line widths, may enable new applications in areas such as diagnostics, sensing, microscopy, displays, and holography.
A tunable narrow single-mode bandpass filter using graphene nanoribbons for THz applications
This paper presents a tunable, single-mode narrowband optical filter designed for terahertz applications utilizing graphene nanoribbons. To attain optimal conditions, the filter was devised in three steps. It is composed of two input and output waveguides and a T-shaped resonator with nanoscale dimensions. The transmission spectrum analysis employs the three-dimensional finite difference time domain and coupled mode theory methods. Tunability is achieved through the adjustment of the nanoribbon size and the chemical potential of graphene. The filter demonstrates remarkable performance metrics, including a maximum transmission spectrum efficiency of 99%, a full width at half maximum (FWHM) of 0.115 THz, a quality factor (Q-factor) of 100, and a free spectral range (FSR) of 45 THz. The presented structure holds significant promise for integrated optical components and compact optical devices, showcasing its applicability in the terahertz frequency range. Furthermore, the inherent sensitivity of this structure to changes in the refractive index of the substrate positions it as a potential sensor.
Tunable Dielectric Properties of BaTiO3/La2O3 Composite Ceramics
BaTiO3/La2O3 nanopowders were synthesized by a low-temperature soft chemical method, and then the BaTiO3/La2O3 composite ceramics were prepared. X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM) were used to characterize the prepared powders and ceramics. And the dielectric properties of the BaTiO3/La2O3 composite ceramics were studied. The results revealed that some of La3+ ions dissolved into the lattice of BaTiO3 at Ba-site and the rest remained at grain boundaries in oxide form of La2O3. With the content of La2O3 increasing, Curie peak of the BaTiO3/La2O3 composite ceramics moved to a lower temperature, and the dielectric loss of the BaTiO3/La2O3 composite ceramics decreased significantly, while the dielectric tunability still kept a relatively high value. The dielectric permittivity and dielectric loss of BaTiO3/La2O3 composite with 10 at.% La2O3 was 227 and 0.0026 at 25 oC and 10 kHz, meanwhile the tunability was up to 17.4% under the electric field of 20 kV/cm.
A Spoof Surface Plasmon Polaritons (SSPPs) Based Dual-Band-Rejection Filter with Wide Rejection Bandwidth
This paper presents a novel single-layer dual band-rejection-filter based on Spoof Surface Plasmon Polaritons (SSPPs). The filter consists of an SSPP-based transmission line, as well as six coupled circular ring resonators (CCRRs) etched among ground planes of the center corrugated strip. These resonators are excited by electric-field of the SSPP structure. The added ground on both sides of the strip yields tighter electromagnetic fields and improves the filter performance at lower frequencies. By removing flaring ground in comparison to prevalent SSPP-based constructions, the total size of the filter is significantly decreased, and mode conversion efficiency at the transition from co-planar waveguide (CPW) to the SSPP line is increased. The proposed filter possesses tunable rejection bandwidth, wide stop bands, and a variety of different parameters to adjust the forbidden bands and the filter’s cut-off frequency. To demonstrate the filter tunability, the effect of different elements like number (n), width (WR), radius (RR) of CCRRs, and their distance to the SSPP line (yR) are surveyed. Two forbidden bands, located in the X and K bands, are 8.6–11.2 GHz and 20–21.8 GHz. As the proof-of-concept, the proposed filter was fabricated, and a good agreement between the simulation and experiment results was achieved.
A Review of Tunable Acoustic Metamaterials
Acoustic metamaterial science is an emerging field at the frontier of modern acoustics. It provides a prominent platform for acoustic wave control in subwavelength-sized metadevices or metasystems. However, most of the metamaterials can only work in a narrow frequency band once fabricated, which limits the practical application of acoustic metamaterials. This paper highlights some recent progress in tunable acoustic metamaterials based on various modulation techniques. Acoustic metamaterials have been designed to control the attenuation of acoustic waves, invisibility cloaking, and acoustic wavefront engineering, such as focusing via manipulating the acoustic impedance of metamaterials. The reviewed techniques are promising in extending the novel acoustics response into wider frequency bands, in that tunable acoustic metamaterials may be exploited for unusual applications compared to conventional acoustic devices.
Visible‐Light‐Activated Multi‐Color Tunable Time‐Dependent Afterglow Triggered by Variable Conjugation Effects via the Transformation of Matrix
Achieving multi‐color tunable time‐dependent afterglow color (TDAC) in pure organic materials under visible light excitation remains a significant challenge. Herein, TDAC composites (CDs/U) are prepared with multi‐color tunability upon visible‐light excitation. Furthermore, the TDAC mechanism is the coexistence of shorter‐lived afterglow and longer‐lived afterglow. The long‐ and short‐wavelength afterglow in CDs/U originate from highly conjugated nitrogen heterocyclic structures and abundant surface functional states, respectively. More impressively, p‐CDs/U systems (p‐phenylenediamine (p‐PD) as carbon source) exhibit dynamic TDAC behaviors with different decay rates of long‐wavelength red afterglow as varying the reaction temperature varies. The experimental results indicate that the transformation of the matrix from biuret to ammelide and then to cyanuric acid (CA) decreases the conjugation degree of p‐CDs/U systems owing to the lower pyrrolic N content. This is not conducive to long‐wavelength emission, leading to shorter lifetimes in the long‐wavelength region. Meanwhile, the theoretical calculation confirms that the matrix is critical for efficient thermally activated delayed fluorescence (TADF). Moreover, the three composites exhibit distinct TDAC behaviors because p‐PD and o‐PD develop higher conjugation during CDs formation compared to m‐PD. Finally, benefiting from the excellent TDAC characteristics of these composites, we have successfully developed multi‐mode anti‐counterfeiting and multi‐dimensional encryption. Three carbon dots (CDs)‐based composites are synthesized via heat treatment of phenylenediamine derivatives with urea. These composites exhibit time‐dependent afterglow across most of the visible spectrum under visible‐light excitation. The matrix modulation strategy regulates the degree of conjugation in the composites, effectively tuning their afterglow properties. These features provide novel strategies for applications in dynamic anti‐counterfeiting and multi‐dimensional information encryption.
Optical resonant cavities carving pathways in tunable wavelength sensitive visible-NIR organic photodetectors
Enhancing the photodetection capabilities of organic photodetectors (OPDs) is crucial for advancing applications in medical monitoring, optical communications, image sensing, and robotics, where a strong, focused peak response at a specific designed wavelength is essential for improving sensitivity, wavelength selectivity, and resolution in imaging systems. By controlled integration of ZnO layers within PBDBT:BTP-4F-based OPDs to form a Fabry-Pérot optical cavity, we developed a cost-effective approach to fabricating highly sensitive OPDs by utilizing PBDBT:BTP-4F organic bulk heterojunctions, and extended its detection wavelengths into the near-infrared (NIR) range. Our design integrates a single silver (Ag) layer that significantly enhances peak detection at a wavelength of 830 ​nm, resulting in a remarkably narrow full-width at half maximum (FWHM) wavelength of 30 ​nm and yielding a photoresponse ten times greater than that of non-resonant devices. Furthermore, by varying the thickness of the ZnO layer from 77 ​nm to 620 ​nm, we achieve high spectral tunability, allowing fine adjustments of the resonant peak across a spectrum ranging from ultraviolet (UV) and visible to NIR wavelengths. This sensitive photodetector is also well-suited for applications in photoplethysmography (PPG), effectively detecting pulse signals in the NIR spectrum which has significant potential in medical diagnostics. This work advances the integration of cost-effective, wavelength-selective spectroscopic visible-NIR OPDs, paving the way for the next generation of sensitive photodetectors.
Basic Principles of Emulsion Templating and Its Use as an Emerging Manufacturing Method of Tissue Engineering Scaffolds
Tissue engineering (TE) aims to regenerate critical size defects, which cannot heal naturally, by using highly porous matrices called TE scaffolds made of biocompatible and biodegradable materials. There are various manufacturing techniques commonly used to fabricate TE scaffolds. However, in most cases, they do not provide materials with a highly interconnected pore design. Thus, emulsion templating is a promising and convenient route for the fabrication of matrices with up to 99% porosity and high interconnectivity. These matrices have been used for various application areas for decades. Although this polymer structuring technique is older than TE itself, the use of polymerised internal phase emulsions (PolyHIPEs) in TE is relatively new compared to other scaffold manufacturing techniques. It is likely because it requires a multidisciplinary background including materials science, chemistry and TE although producing emulsion templated scaffolds is practically simple. To date, a number of excellent reviews on emulsion templating have been published by the pioneers in this field in order to explain the chemistry behind this technique and potential areas of use of the emulsion templated structures. This particular review focusses on the key points of how emulsion templated scaffolds can be fabricated for different TE applications. Accordingly, we first explain the basics of emulsion templating and characteristics of PolyHIPE scaffolds. Then, we discuss the role of each ingredient in the emulsion and the impact of the compositional changes and process conditions on the characteristics of PolyHIPEs. Afterward, current fabrication methods of biocompatible PolyHIPE scaffolds and polymerisation routes are detailed, and the functionalisation strategies that can be used to improve the biological activity of PolyHIPE scaffolds are discussed. Finally, the applications of PolyHIPEs on soft and hard TE as well as models and drug delivery in the literature are summarised.