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Coronae, which are weak electrical discharges, have long been hypothesized to form on trees under thunderstorms, though never directly observed, characterized, or quantified. Using a newly developed instrument that measures ultraviolet emissions from coronae, the first direct observations and quantifications of coronae are presented for two trees under a thunderstorm in North Carolina. Coronae moved sporadically among leaves on every tree branch in a narrow field of view while the thunderstorm was directly overhead. Coronae emitted ∼1011 photons at 260 nm, corresponding to electrical currents of ∼1 μA, derived from unique measurements relating corona intensity to tree electrical current. Similar results across four additional storm intercepts from Florida to Pennsylvania give rise to a vision of swaths of scintillating corona glow as thunderstorms pass over forests. Such widespread coronae have implications for the removal of hydrocarbons emitted by trees, subtle tree leaf damage, and limited thunderstorm electrification.

In this paper, Ba-doped SnO 2 (SnO 2 :Ba), Mg-doped SnO 2 (SnO 2 :Mg) and Ce-doped SnO 2 (SnO 2 :Ce) nanostructured thin films were prepared on the glass substrate via a simple and low-cost nebulizer spray pyrolysis method. The crystal structure and morphology of all the samples were investigated by X-ray diffraction (XRD) and field-emission-scanning electron microscopy (FE-SEM), respectively. XRD results suggest that all the samples are polycrystalline with the tetragonal rutile structure. FE-SEM analysis exhibits a uniform surface morphology with homogenous distribution of grains. The transmittance measurement suggests that SnO 2 :Ba sample exhibits high transparency above 90% in the visible region. We find that doping causes an increase in the band gap, this behavior is explained by the Burstein–Moss effect. Two emission bands in the ultraviolet and visible regions are observed in the photoluminescence spectra. Hall effect measurement reveals that all the samples are degenerate and exhibit n-type semiconducting nature with carrier concentration in the order of 10 18  cm −3 . Ba doping induces the lowest resistivity of 0.047 Ω·cm associated with an increase in carrier concentration of 8.38 × 10 18  cm −3 and mobility of 15.87 cm 2  V −1  s −1 . In contrast, the incorporation of Mg and Ce in SnO 2 reduces the mobility and conductivity, which may be associated with the grain boundary scattering. Highlights The Ba, Ce and Mg-doped SnO 2 thin films were prepared by spray pyrolysis method. Pyramidal-like and spherical-like nano-crystals were investigated. All samples have a polycrystalline tetragonal rutile structure with nanometric dimensions. The Ba-doped SnO 2 sample showed excellent optoelectronic properties. Strong near-ultraviolet emission peak at ~386 nm was observed in photoluminescence spectra.

The sp2-bonded layered compound boron nitride (BN) exists in more than a handful of different polytypes (i.e., different layer stacking sequences) with similar formation energies, which makes obtaining a pure monotype of single crystals extremely tricky. The co-existence of polytypes in a similar crystal leads to the formation of many interfaces and structural defects having a deleterious influence on the internal quantum efficiency of the light emission and on charge carrier mobility. However, despite this, lasing operation was reported at 215 nm, which has shifted interest in sp2-bonded BN from basic science laboratories to optoelectronic and electrical device applications. Here, we describe some of the known physical properties of a variety of BN polytypes and their performances for deep ultraviolet emission in the specific case of second harmonic generation of light.

Lanthanide-doped upconversion nanoparticles (UCNPs) are capable of converting near-infra-red excitation into visible and ultraviolet emission. Their unique optical properties have advanced a broad range of applications, such as fluorescent microscopy, deep-tissue bioimaging, nanomedicine, optogenetics, security labelling and volumetric display. However, the constraint of concentration quenching on upconversion luminescence has hampered the nanoscience community to develop bright UCNPs with a large number of dopants. This review surveys recent advances in developing highly doped UCNPs, highlights the strategies that bypass the concentration quenching effect, and discusses new optical properties as well as emerging applications enabled by these nanoparticles.

Magnetospheric accretion models predict that matter from protoplanetary disks accretes onto stars via funnel flows, which follow stellar magnetic field lines and shock on the stellar surfaces 1 – 3 , leaving hot spots with density gradients 4 – 6 . Previous work has provided observational evidence of varying density in hot spots 7 , but these observations were not sensitive to the radial density distribution. Attempts have been made to measure this distribution using X-ray observations 8 – 10 ; however, X-ray emission traces only a fraction of the hot spot 11 , 12 and also coronal emission 13 , 14 . Here we report periodic ultraviolet and optical light curves of the accreting star GM Aurigae, which have a time lag of about one day between their peaks. The periodicity arises because the source of the ultraviolet and optical emission moves into and out of view as it rotates along with the star. The time lag indicates a difference in the spatial distribution of ultraviolet and optical brightness over the stellar surface. Within the framework of a magnetospheric accretion model, this finding indicates the presence of a radial density gradient in a hot spot on the stellar surface, because regions of the hot spot with different densities have different temperatures and therefore emit radiation at different wavelengths. An observed one-day difference between the peaks of emission of ultraviolet and optical light from the hot spot on GM Aurigae indicates that the hot spot has a radial density gradient.

Photon upconversion of near-infrared (NIR) irradiation into ultraviolet-C (UVC) emission offers many exciting opportunities for drug release in deep tissues, photodynamic therapy, solid-state lasing, energy storage, and photocatalysis. However, NIR-to-UVC upconversion remains a daunting challenge due to low quantum efficiency. Here, we report an unusual six-photon upconversion process in Gd 3+ /Tm 3+ -codoped nanoparticles following a heterogeneous core-multishell architecture. This design efficiently suppresses energy consumption induced by interior energy traps, maximizes cascade sensitizations of the NIR excitation, and promotes upconverted UVC emission from high-lying excited states. We realized the intense six-photon-upconverted UV emissions at 253 nm under 808 nm excitation. This work provides insight into mechanistic understanding of the upconversion process within the heterogeneous architecture, while offering exciting opportunities for developing nanoscale UVC emitters that can be remotely controlled through deep tissues upon NIR illumination. Photon upconversion with near-infrared excitation and ultraviolet emission has many applications, but suffers from low quantum efficiency. Here, the authors report a six-photon upconversion process in nanoparticles with heterogeneous core-multishell structure, that regulate the energy transfer pathway.

SDO/HMI and SDO/AIA data for the 24th solar-activity cycle are analyzed using a quicker and more accurate method for resolving π ambiguities in the transverse component of the photospheric magnetic field, yielding new results and confirming some earlier results on the magnetic properties of leading and following magnetically connected spots and single spots. The minimum inclination of the field lines to the positive normal to the solar surface α min within umbrae is smaller in leading than in following spots in 78% of the spot pairs considered; the same trend is found for the mean angle 〈 α 〉 in 83% of the spot pairs. Positive correlations between the α min values and the 〈 α 〉 values in leading and following spots are also found. On average, in umbrae, the mean values of 〈 B 〉, the umbra area S , and the angles α min and 〈 α 〉 decrease with growth in the maximum magnetic field B max in both leading and following spots. The presence of a positive correlation between B max and S is confirmed, and a positive correlation between 〈 B 〉 and S in leading and following spots has been found. Themagnetic properties of the umbrae of magnetically connected pairs of spots are compared with the contrast of the He II 304 emission above the umbrae, C 304 . Spots satisfying certain conditions display a positive correlation between C 304− L and 〈 α L 〉 for the leading (L) spots, and between C 304− L / C 304− F and l L / l F , where l L ( l F ) are the lengths of the field lines connecting leading (L) or following (F) spots from the corresponding spot umbrae to the apex of the field line.

Coherent ultraviolet light is important for applications in environmental and life sciences. However, direct ultraviolet lasing is constrained by the fabrication challenge and operation cost. Herein, we present a strategy for the indirect generation of deep-ultraviolet lasing through a tandem upconversion process. A core–shell–shell nanoparticle is developed to achieve deep-ultraviolet emission at 290 nm by excitation in the telecommunication wavelength range at 1550 nm. The ultralarge anti-Stokes shift of 1260 nm (~3.5 eV) stems from a tandem combination of distinct upconversion processes that are integrated into separate layers of the core–shell–shell structure. By incorporating the core–shell–shell nanoparticles as gain media into a toroid microcavity, single-mode lasing at 289.2 nm is realized by pumping at 1550 nm. As various optical components are readily available in the mature telecommunication industry, our findings provide a viable solution for constructing miniaturized short-wavelength lasers that are suitable for device applications. Constructing ultraviolet lasing is of great significance for basic research and medical use. Here the authors present a strategy for generating ultraviolet lasing through a tandem upconversion process with ultralarge anti-Stokes shift (1260 nm).

In this research, a facile co-precipitation method was used to synthesize pure and Mg-doped ZnO nanoparticles (NPs). The structure, morphology, chemical composition, and optical and antibacterial activity of the synthesized nanoparticles (NPs) were studied with respect to pure and Mg-doped ZnO concentrations (0–7.5 molar (M) %). X-ray diffraction pattern confirmed the presence of crystalline, hexagonal wurtzite phase of ZnO. Scanning electron microscope (SEM) images revealed that pure and Mg-doped ZnO NPs were in the nanoscale regime with hexagonal crystalline morphology around 30–110 nm. Optical characterization of the sample revealed that the band gap energy ( E g ) decreased from 3.36 to 3.04 eV with an increase in Mg 2+ doping concentration. Optical absorption spectrum of ZnO redshifted as the Mg concentration varied from 2.5 to 7.5 M. Photoluminescence (PL) spectra showed UV emission peak around 400 nm. Enhanced visible emission between 430 and 600 nm with Mg 2+ doping indicated the defect density in ZnO by occupying Zn 2+ vacancies with Mg 2+ ions. Photocatalytic studies revealed that 7.5% Mg-doped ZnO NPs exhibited maximum degradation (78%) for Rhodamine B (RhB) dye under UV-Vis irradiation. Antibacterial studies were conducted using Gram-positive and Gram-negative bacteria. The results demonstrated that doping with Mg ions inside the ZnO matrix had enhanced the antibacterial activity against all types of bacteria and its performance was improved with successive increment in Mg ion concentration inside ZnO NPs.

Terrestrial gamma-ray flashes (TGFs) are transient gamma-ray emissions from thunderstorms, generated by electrons accelerated to relativistic energies in electric fields. Elves are ultraviolet and optical emissions excited in the lower ionosphere by electromagnetic waves radiated from lightning current pulses. We observed a TGF and an associated elve using the Atmosphere-Space Interactions Monitor on the International Space Station. The TGF occurred at the onset of a lightning current pulse that generated an elve, in the early stage of a lightning flash. Our measurements suggest that the current onset is fast and has a high amplitude—a prerequisite for elves—and that the TGF is generated in the electric fields associated with the lightning leader.