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1,047 result(s) for "Vertical diffusion"
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The dynamics of local learning in global value chains : experiences from East Asia
\"This book investigates the process and mechanism of the capability development of East Asian local manufacturers, which has underpinned their phenomenal rise in the worlds competitive landscape of industrial production during the last few decades\"--Provided by publisher.
Nutrient Vertical Flux in the Indonesian Seas as Constrained by Non‐Atmospheric Helium‐3
The Indonesian seas are a renowned global biodiversity hotspot, yet nutrient sources and fluxes (especially the vertical flux) sustaining this richness remain unclear. Here, we used non‐atmospheric helium‐3 (3He) to constrain the vertical diffusion coefficient (Kd) in the Indonesian seas, which ranges from 5.2 × 10−5 to 2.3 × 10−3 m2 s−1 and averages 6.6 × 10−4 m2 s−1, a value notably higher than those found in the open ocean and in most marginal seas. We estimated that 6.9 ± 7.9 mmol m−2 d−1 of nitrate (NO3−) is vertically transported into the surface mixed layer, that is, >90% of the total NO3− required to support a net community production (NCP) of 470 ± 467 mg‐C m−2 d−1. Regions with narrow straits, steep topography and dynamic circulation with strong vertical mixing display high NCP and chlorophyll‐a, suggesting that vertical nutrient transport dominates biological productivity. Findings highlight the importance of vertical mixing in supplying nutrients and maintaining the extraordinary biological productivity and diversity in the Indonesian seas. Plain Language Summary The Indonesian seas, at the center of the Indo‐Pacific Intersection, are recognized as a global hotspot of marine biodiversity. However, nutrient (e.g., nitrate) cycling in the Indonesian seas is poorly understood, such that nutrient sources and fluxes sustaining biological production remain unknown. The Indonesian seas lie on a plate tectonic belt, where intense submarine hydrothermal venting releases abundant primordial isotopic helium (3He) into the ocean interior that outgasses at surface providing an ideal tracer of vertical transport. We find that vertical diffusion in the Indonesian seas is notably stronger than those found in the open ocean and in most marginal seas, with a mean vertical diffusion coefficient (Kd) of 6.6 × 10−4 m2 s−1. Nitrate is vertically transported into the surface mixed layer at a rate of 6.9 ± 7.9 mmol m−2 d−1, which supports >90% of net community production (NCP) in the Indonesian seas. Here, narrow straits, steep and irregular topography and dynamic circulation with strong vertical mixing result in high chlorophyll‐a concentrations (a measure of primary producers' biomass) and NCP. This vertical nutrient transport supplies essential conditions for algal growth and “fuels” food web biological productivity. Thus, we suggest that strong vertical mixing plays a key role in making the Indonesian seas a global biodiversity hotspot. Key Points The Indonesian seas present strong and spatially variable vertical mixing Vertical mixing supplies >90% of nutrients in the surface mixed layer of Indonesian seas Here, vertical nutrient supply provides essential biogenic elements supporting high net community production and a biodiversity hotspot
A Clear View of a Cloudy Brown Dwarf Companion from High-resolution Spectroscopy
Direct imaging studies have mainly used low-resolution spectroscopy (R ∼ 20–100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC (R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS, we analyze the KPIC high-resolution spectrum (2.29–2.49 μm) and the archival low-resolution spectrum (1–2.2 μm) of the benchmark brown dwarf HD 4747 B (m = 67.2 ± 1.8 M Jup, a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1σ–2σ. The retrieved parameters from the K-band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H2O, and CH4 (volume-mixing ratio of log(CH4) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory.
Evaluating the Impact of Improvements in the Boundary Layer Parameterization on Hurricane Intensity and Structure Forecasts in HWRF
As part of the Hurricane Forecast Improvement Project (HFIP), recent boundary layer physics upgrades in the operational Hurricane Weather Research and Forecasting (HWRF) Model have benefited from analyses of in situ aircraft observations in the low-level eyewall region of major hurricanes. This study evaluates the impact of these improvements to the vertical diffusion in the boundary layer on the simulated track, intensity, and structure of four hurricanes using retrospective HWRF forecasts. Structural metrics developed from observational composites are used in the model evaluation process. The results show improvements in track and intensity forecasts in response to the improvement of the vertical diffusion. The results also demonstrate substantial improvements in the simulated storm size, surface inflow angle, near-surface wind profile, and kinematic boundary layer heights in simulations with the improved physics, while only minor improvements are found in the thermodynamic boundary layer height, eyewall slope, and the distributions of vertical velocities in the eyewall. Other structural metrics such as warm core anomaly and warm core height are also explored. Reasons for the structural differences between the two sets of forecasts with different physics are discussed. This work further emphasizes the importance of aircraft observations in model diagnostics and development, endorsing a developmental framework for improving physical parameterizations in hurricane models.
Nighttime ozone in the lower boundary layer: insights from 3-year tower-based measurements in South China and regional air quality modeling
Nighttime ozone in the lower boundary layer regulates atmospheric chemistry and surface ozone air quality, but our understanding of its vertical structure and impact is largely limited by the extreme sparsity of direct measurements. Here we present 3-year (2017–2019) measurements of ozone in the lower boundary layer (up to 500 m) from the Canton Tower in Guangzhou, the core megacity in South China, and interpret the measurements with a 1-month high-resolution chemical simulation from the Community Multiscale Air Quality (CMAQ) model. Measurements are available at 10, 118, 168, and 488 m, with the highest (488 m) measurement platform higher than the typical height of the nighttime stable boundary layer that allows direct measurements of ozone in the nighttime residual layer (RL). We find that ozone increases with altitude in the lower boundary layer throughout the day, with a vertical ozone gradient between the 10 and 488 m heights (ΔO3/ΔH10–488 m) of 3.6–6.4 ppbv hm−1 in nighttime and 4.4–5.8 ppbv hm−1 in daytime. We identify a high ozone residual ratio, defined as the ratio of ozone concentration averaged over nighttime to that in the afternoon (14:00–17:00 LT), of 69 %–90 % in January, April, and October, remarkably higher than that in the other three layers (29 %–51 %). Ozone in the afternoon convective mixing layer provides the source of ozone in the RL, and strong temperature inversion facilitates the ability of RL to store ozone from the daytime convective mixing layer. The tower-based measurement also indicates that the nighttime surface Ox (Ox= O3+NO2) level can be an effective indicator of RL ozone if direct measurement is not available. We further find significant influences of nocturnal RL ozone on both the nighttime and the following day's daytime surface ozone air quality. During the surface nighttime ozone enhancement (NOE) event, we observe a significant decrease in ozone and an increase in NO2 and CO at the 488 m height, in contrast to their changes at the surface, a typical feature of enhanced vertical mixing. The enhanced vertical mixing leads to an NOE event by introducing ozone-rich and NOx-poor air into the RL to enter the nighttime stable boundary layer. The CMAQ model simulations also demonstrate an enhanced positive contribution of vertical diffusion (ΔVDIF) to ozone at the 10 and 118 m heights and a negative contribution at the 168 and 488 m heights during the NOE event. We also observe a strong correlation between nighttime RL ozone and the following day's surface maximum daily 8 h average (MDA8) ozone. This is tied to enhanced vertical mixing with the collapse of nighttime RL and the development of a convective mixing layer, which is supported by the CMAQ diagnosis of the ozone budget, suggesting that the mixing of ozone-rich air from nighttime RL downward to the surface via the entrainment is an important mechanism for aggravating ozone pollution the following day. We find that the bias in CMAQ-simulated surface MDA8 ozone the following day shows a strong correlation coefficient (r= 0.74) with the bias in nighttime ozone in the RL, highlighting the necessity to correct air quality model bias in the nighttime RL ozone for accurate prediction of daytime ozone. Our study thus highlights the value of long-term tower-based measurements for understanding the coupling between nighttime ozone in the RL, surface ozone air quality, and boundary layer dynamics.
Revision of Convection and Vertical Diffusion Schemes in the NCEP Global Forecast System
A new physics package containing revised convection and planetary boundary layer (PBL) schemes in the National Centers for Environmental Prediction’s Global Forecast System is described. The shallow convection (SC) scheme in the revision employs a mass flux parameterization replacing the old turbulent diffusion-based approach. For deep convection, the scheme is revised to make cumulus convection stronger and deeper to deplete more instability in the atmospheric column and result in the suppression of the excessive grid-scale precipitation. The PBL model was revised to enhance turbulence diffusion in stratocumulus regions. A remarkable difference between the new and old SC schemes is seen in the heating or cooling behavior in lower-atmospheric layers above the PBL. While the old SC scheme using the diffusion approach produces a pair of layers in the lower atmosphere with cooling above and heating below, the new SC scheme using the mass-flux approach produces heating throughout the convection layers. In particular, the new SC scheme does not destroy stratocumulus clouds off the west coasts of South America and Africa as the old scheme does. On the other hand, the revised deep convection scheme, having a larger cloud-base mass flux and higher cloud tops, appears to effectively eliminate the remaining instability in the atmospheric column that is responsible for the excessive grid-scale precipitation in the old scheme. The revised PBL scheme, having an enhanced turbulence mixing in stratocumulus regions, helps prevent too much low cloud from forming. An overall improvement was found in the forecasts of the global 500-hPa height, vector wind, and continental U.S. precipitation with the revised model. Consistent with the improvement in vector wind forecast errors, hurricane track forecasts are also improved with the revised model for both Atlantic and eastern Pacific hurricanes in 2008.
Can Lagrangian Tracking Simulate Tracer Spreading in a High-Resolution Ocean General Circulation Model?
To model tracer spreading in the ocean, Lagrangian simulations in an offline framework are a practical and efficient alternative to solving the advective–diffusive tracer equations online. Differences in both approaches raise the question of whether both methods are comparable. Lagrangian simulations usually use model output averaged in time, and trajectories are not subject to parameterized subgrid diffusion, which is included in the advection–diffusion equations of ocean models. Previous studies focused on diffusivity estimates in idealized models but could show that both methods yield similar results as long as the deformations-scale dynamics are resolved and a sufficient amount of Lagrangian particles is used. This study compares spreading of an Eulerian tracer simulated online and a cloud of Lagrangian particles simulated offline with velocities from the same ocean model. We use a global, eddy-resolving ocean model featuring 1/20° horizontal resolution in the Agulhas region around South Africa. Tracer and particles were released at one time step in the Cape Basin and below the mixed layer and integrated for 3 years. Large-scale diagnostics, like mean pathways of floats and tracer, are almost identical and 1D horizontal distributions show no significant differences. Differences in vertical distributions, seen in a reduced vertical spreading and downward displacement of particles, are due to the combined effect of unresolved subdaily variability of the vertical velocities and the spatial variation of vertical diffusivity. This, in turn, has a small impact on the horizontal spreading behavior. The estimates of eddy diffusivity from particles and tracer yield comparable results of about 4000 m 2 s −1 in the Cape Basin.
Ozone affected by a succession of four landfall typhoons in the Yangtze River Delta, China: major processes and health impacts
Landfall typhoons can significantly affect O3 in the Yangtze River Delta (YRD) region. In this study, we investigate a unique case characterized by two multiday regional O3 pollution episodes related to four successive landfall typhoons in the summer of 2018 in the YRD. The results show that O3 pollution episodes mainly occurred during the period from the end of a typhoon to the arrival of the next typhoon. The time when a typhoon reached the 24 h warning line and the time when the typhoon dies away in mainland China can be roughly regarded as time nodes. Meanwhile, the variations of O3 were related to the track, duration and landing intensity of the typhoons. The impact of typhoons on O3 was like a wave superimposed on the background of high O3 concentration in the YRD in summer. When a typhoon was near the 24 h warning line before it landed on the coastline of the YRD, the prevailing wind originally from the ocean changed to be from inland, and it transported lots of precursors from the polluted areas to the YRD. Under influences of the typhoon, the low temperature, strong upward airflows, more precipitation and wild wind hindered occurrences of high O3 episodes. After the passing of the typhoon, the air below the 700 hPa atmospheric layer was warm and dry, and the downward airflows resumed. The low troposphere was filed with high concentration of O3 due to O3-rich air transported from the low stratosphere and strong photochemical reactions. It is noteworthy that O3 was mainly generated in the middle of the boundary layer (∼ 1000 m) instead of at the surface. High O3 levels remained in the residual layer at night, and would be transported to the surface by downward airflows or turbulence by the second day. Moreover, O3 can be accumulated and trapped on the ground due to the poor diffusion conditions because the vertical diffusion and horizontal diffusion were suppressed by downward airflows and light wind, respectively. The premature deaths attributed to O3 exposure in the YRD during the study period were 194.0, more than the casualties caused directly by the typhoons. This work has enhanced our understanding of how landfall typhoons affect O3 in the YRD and thus can be useful in forecasting O3 pollution in regions strongly influenced by typhoon activities.
Effects of atmospheric circulations on the interannual variation in PM2.5 concentrations over the Beijing–Tianjin–Hebei region in 2013–2018
The Chinese government has made many efforts to mitigate fine particulate matter pollution in recent years by taking strict measures on air pollutant reduction, which has generated the nationwide improvements in air quality since 2013. However, under the stringent air pollution controls, how the wintertime PM2.5 concentration (i.e., the mass concentration of atmospheric particles with diameters less than 2.5 µm) varies and how much the meteorological conditions contribute to the interannual variations in PM2.5 concentrations are still unclear, and these very important for the local government to assess the emission reduction of the previous year and adjust mitigation strategies for the next year. The effects of atmospheric circulation on the interannual variation in wintertime PM2.5 concentrations over the Beijing–Tianjin–Hebei (BTH) region in the period of 2013–2018 are evaluated in this study. Generally, the transport of clean and dry air masses and an unstable boundary layer in combination with the effective near-surface horizontal divergence or pumping action at the top of the boundary layer benefits the horizontal or vertical diffusion of surface air pollutants. Instead, the co-occurrence of a stable boundary layer, frequent air stagnation, positive water vapor advection and deep near-surface horizontal convergence exacerbate the wintertime air pollution. Favorable circulation conditions lasting for 2–4 d are beneficial for the diffusion of air pollutants, and 3–7 d of unfavorable circulation events exacerbates the accumulation of air pollutants. The occurrence frequency of favorable circulation events is consistent with the interannual variation in seasonal mean PM2.5 concentrations. There is better diffusion ability in the winters of 2014 and 2017 than in other years. A 59.9 % observed decrease in PM2.5 concentrations in 2017 over the BTH region could be attributed to the improvement in atmospheric diffusion conditions. It is essential to exclude the contribution of meteorological conditions to the variation in interannual air pollutants when making a quantitative evaluation of emission reduction measurements.
Concurrence of Temperature and Humidity Inversions in Winter in Qingdao, China
Concurrence of temperature inversion (TI) and humidity inversion (HI) is a particular configuration of the atmospheric boundary layer with important implications for early warning of fog formation. With a microwave radiometer device deployed in a 2‐month winter campaign at a coastal island in Qingdao, China, we here examine the relationship between TI and HI, and investigate the underneath mechanisms. Cases of temperature inversion are further divided into surface‐based temperature inversion (SBTI) and elevated temperature inversion (ETI), which show different relationship with HI. SBTI typically occurs at night with its strength significantly and positively correlated with HI. ETI also shows a high degree of temporal overlap with HI, but its strength has no obvious relationship with HI. The main explanation for this phenomenon is that ETI may block the vertical diffusion of water vapor, resulting in the formation of HI. Plain Language Summary Temperature inversion (TI) and humidity inversion (HI) often occur simultaneously. Knowledge of their concurrence is, however, still quite limited, due to the lack of continuous observations. Using a 2‐month winter observation data set, obtained with a microwave radiometer device deployed in Qingdao, China, a coastal city of the Yellow Sea, we carefully examined the correlation between TI and HI. TI is furthermore regrouped into surface‐based temperature inversion (SBTI) and elevated temperature inversion (ETI). Although SBTI and ETI both occur frequently, accompanied with HI, the underneath physical mechanism seems different. For SBTI, the bottom of HI absorbs the radiation emitted from the ground, increases the temperature difference between the land and atmosphere, and finally enhances SBTI. However, ETI plays the role of blocking the water vapor turbulent diffusion and contributes to the development of HI. Key Points Both surface‐based temperature inversion (SBTI) and elevated temperature inversion (ETI) show concurrence with humidity inversion (HI) Theories of water vapor condensation and turbulent diffusion blockage may not be sufficient for the concurrence of SBTI and HI ETI blocks the upward turbulent diffusion of water vapor, contributing to the formation of HI