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10,385 result(s) for "Weathering"
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Molecular and Supramolecular Changes in Polybutylene Succinate (PBS) and Polybutylene Succinate Adipate (PBSA) Copolymer during Degradation in Various Environmental Conditions
In this paper, the influence of the various degradation conditions, on the molecular and supramolecular structure of polybutylene succinate (PBS) and polybutylene succinate adipate (PBSA) copolymer during degradation is described. The experiment was carried out by the use of injection molded samples and normalized conditions of biodegradation in soil, composting and artificial weathering. Materials were studied by size-exclusion chromatography (SEC) coupled with multiangle laser light scattering (MALLS) detection and wide-angle X-ray diffraction (WAXD). Additionally, the physical and mechanical properties of the samples were determined. The performed experiments clearly show difference impacts of the selected degradation conditions on the macroscopic, supramolecular and molecular parameters of the studied aliphatic polyesters. The structural changes in PBS and PBSA explain the observed changes in the physical and mechanical properties of the obtained injection molded samples.
Glacially Enhanced Silicate Weathering Revealed by Holocene Lake Records
How glaciation affects CO2 ${\\text{CO}}_{2}$ drawdown by chemical weathering influences the weathering‐climate feedback strength, which controls the exogenic carbon cycle and planetary habitability. However, the role of glaciers remains elusive as glaciation alters multiple factors controlling weathering, the net effect of which is ambiguous even in directionality. To isolate and quantify the effect of glaciers, we developed a novel multi‐proxy system for constraining catchment‐scale weathering fluxes in the past. This approach utilizes the correlation between Ge/Si and Si isotope ratios in modern rivers and the preservation of these signals in lacustrine sediments. Reconstructed weathering fluxes in two Icelandic catchments with different glacial histories during the past 10,000 years show that chemical weathering fluxes are roughly 10 times higher when a catchment is glaciated versus ice‐free. The synchronous variations in weathering fluxes with the expansion and contraction of glaciers indicate that glaciation may rapidly amplify climatic variations via a positive feedback.
Quantification of physical and chemical paleoweathering at the microscale: a new concept
Weathering is a basic geological process that refers to the breaking down or dissolving of rocks and minerals on the surface of the earth. However, weathering characteristics may vary among different lithologies even under similar conditions. To evaluate and quantitatively compare the physical and chemical index of alteration among different types of rock, new concepts of paleo-weathering such as the absolute weathering degree and the relative weathering degree are proposed for microscale studies. For the quantification of physical weathering, the index of physical weathering (IPW) is introduced. The index is defined as the ratio between the area of the fractures formed during different weathering stages and the total area of the thin section under the polarizing microscope and it is corrected by the corresponding rock strength. To quantitatively compare the chemical weathering intensity among different types of rock and minerals, the following two new concepts are introduced: total weathering mass (TWM) and chemical weathering ability (CWA). While the TWM is an integral function of weathering rate and weathering time for minerals, the CWA is the sum of the TWM of each mineral in rock within a certain time period. As a case study, this concept is applied to the weathered crystalline basement below the post-Variscan nonconformity in southwestern Germany. The petrography and geochemistry of three drillings penetrating the nonconformity were investigated by polarizing microscopy, X-ray diffractometry (XRD), scanning electron microscope (SEM), X-ray fluorescence (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS). The investigations illustrate how to better extract quantitative information for both, physical and chemical weathering.
Lithium Isotope History of Cenozoic Seawater: Changes in Silicate Weathering and Reverse Weathering
Weathering of uplifted continental rocks consumes carbon dioxide and transports cations to the oceans, thereby playing a critical role in controlling both seawater chemistry and climate. However, there are few archives of seawater chemical change that reveal shifts in global tectonic forces connecting Earth ocean-climate processes. We present a 68-million-year record of lithium isotopes in seawater (δ⁷Li sw ) reconstructed from planktonic foraminifera. From the Paleocene (60 million years ago) to the present, δ⁷Li sw rose by 9 per mil (‰), requiring large changes in continental weathering and seafloor reverse weathering that are consistent with increased tectonic uplift, more rapid continental denudation, increasingly incongruent continental weathering (lower chemical weathering intensity), and more rapid CO₂ drawdown. A 5‰ drop in δ⁷Li sw across the Cretaceous-Paleogene boundary cannot be produced by an impactor or by Deccan trap volcanism, suggesting large-scale continental denudation.
Rapid soil production and weathering in the Southern Alps, New Zealand
Evaluating conflicting theories about the influence of mountains on carbon dioxide cycling and climate requires understanding weathering fluxes from tectonically uplifting landscapes. The lack of soil production and weathering rate measurements in Earth's most rapidly uplifting mountains has made it difficult to determine whether weathering rates increase or decline in response to rapid erosion. Beryllium-10 concentrations in soils from the western Southern Alps, New Zealand, demonstrate that soil is produced from bedrock more rapidly than previously recognized, at rates up to 2.5 millimeters per year. Weathering intensity data further indicate that soil chemical denudation rates increase proportionally with erosion rates. These high weathering rates support the view that mountains play a key role in global-scale chemical weathering and thus have potentially important implications for the global carbon cycle.