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Welding metallurgy and weldability
\"This book describes the weldability aspects of many structural materials used in a wide variety of engineering structures, including steels, stainless steels, Ni-base alloys, and Al-base alloys. The basic mechanisms of weldability are described and methods to improve weldability are described. Specific topics include solidification and liquation cracking, solid-state cracking, hydrogen cracking, fracture and fatigue, and corrosion. Methods for interpretation of weld failures using computational and characterization techniques are described\"-- Provided by publisher.
Book
One-step chemical dealloying synthesis of a multi-structured Cu.sub.2Sb/Sb.sub.2O.sub.3/Cu/Cu.sub.2O nanocomposite anode for advanced sodium-ion batteries
While Sb-based anodes for sodium-ion batteries (SIBs) are attractive for their high gravimetric capacities, they suffer from poor cyclability and sluggish charge storage kinetics due to large volume changes and multiple phase transformations. In this study, we developed a multi-structured Cu.sub.2Sb/Sb.sub.2O.sub.3/Cu/Cu.sub.2O nanocomposite by a simple one-step dealloying strategy. As an anode material for SIBs, this nanocomposite exhibits good cycling performance, maintaining a reversible capacity of 223 mAh g.sup.-1 for over 200 cycles at a current density of 0.2 A g.sup.-1. Furthermore, the Cu.sub.2Sb/Sb.sub.2O.sub.3/Cu/Cu.sub.2O nanocomposite demonstrates twice the sodium-ion diffusion rate compared to pure Sb. The improved electrochemical performance can be attributed to the synergistic effects of the layered NP-Cu.sub.2Sb, Sb.sub.2O.sub.3 nanoparticles and NP-Cu/Cu.sub.2O, which provide efficient pathways for ion and electron transport, thereby enhancing the rate capability of the electrode. Additionally, the inactive Cu within the Cu.sub.2Sb and the formation of Na.sub.2O as an intermediate product effectively accommodate the volume changes that occur during (de)sodiation, preventing the pulverization of the nanocomposite. These findings highlight the potential of Sb-based materials with unique architectures and composite systems as rechargeable SIBs anodes, and this work serves as inspiration for the further development of novel alloy-type electrodes through the facile dealloying method.
Journal Article
The Characteristic of 101¯2101¯1¯ Twin of Ti-10V-2Fe-3Al under Planar Wave Detonation
The microstructure evolution of the twin of TB6 (Ti-10V-2Fe-3Al) under planar wave detonation was studied. The initial microstructure of the alloy consists of an α and β phase. It is found that twin deformation is operated in only the α phase due to the limited slip system in this phase. α grains are mainly rotated from 101¯0 to 0002 during the deformation due to the 101¯2<101¯1¯> twin. Twin variant selection is found in this study, and the orientation of all 101¯2 twins is oriented at 0002 in different α grains with different deformation degrees. The twin variant selection is well explained based on the strain relaxation along the loading axis and the Schmid factor for twinning shear.
Journal Article
Experimental and Theoretical Studies of Hydrogen Storage in LaNisub.4.4Alsub.0.3Fesub.0.3 Hydride Bed
In this article, the experimental measurements of the absorption/desorption P–C–T isotherms of hydrogen in the LaNi[sub.4.4]Fe[sub.0.3]Al[sub.0.3] alloy at different temperatures and constant hydrogen pressure have been studied using a numerical model. The mathematics equations of this model contain parameters, such as the two terms, n[sub.α] and n[sub.β,] representing the numbers of hydrogen atoms per site; N[sub.mα] and N[sub.mβ] are the receptor sites’ densities, and the energetic parameters are P[sub.α] and P[sub.β]. All these parameters are derived by numerically adjusting the experimental data. The profiles of these parameters during the absorption/desorption process are studied as a function of temperature. Thereafter, we examined the evolution of the internal energy versus temperature, which typically ranges between 138 and 181 kJmol[sup.−1] for the absorption process and between 140 and 179 kJmol[sup.−1] for the desorption process. The evolution of thermodynamic functions with pressure, for example, entropy, Gibbs free energy (G), and internal energy, are determined from the experimental data of the hydrogen absorption and desorption isotherms of the LaNi[sub.4.4]A[sub.l0.3]F[sub.e0.3] alloy.
Journal Article
Effect of C Addition on the Microstructure and Fracture Properties of In Situ Laminated Nb/Nbsub.5Sisub.3 Composites
//Nb[sub.ss] and α-Nb[sub.5]Si[sub.3] phases were detected. Meanwhile, Nb[sub.2]C was observed, and the crystal forms of Nb[sub.5]Si[sub.3] changed in the C-doped composites. Furthermore, micron-sized and nano-sized Nb[sub.2]C particles were found in the Nb[sub.ss] layer. The orientation relationship of Nb[sub.2]C phase and the surrounding Nb[sub.ss] was [001][sub.Nbss]//[010][sub.Nb2C], (200) [sub.Nbss]//(101) [sub.Nb2C]. Additionally, with the addition of C, the compressive strength of the composites, at 1400 °C, and the fracture toughness increased from 310 MPa and 11.9 MPa·m[sup.1/2] to 330 MPa and 14.2 MPa·m[sup.1/2], respectively; the addition of C mainly resulted in solid solution strengthening.
Journal Article
Current Trends in Metallic Materials for Body Panels and Structural Members Used in the Automotive Industry
The development of lightweight and durable materials for car body panels and load-bearing elements in the automotive industry results from the constant desire to reduce fuel consumption without reducing vehicle performance. The investigations mainly concern the use of these alloys in the automotive industry, which is characterised by mass production series. Increasing the share of lightweight metals in the entire structure is part of the effort to reduce fuel consumption and carbon dioxide emissions into the atmosphere. Taking into account environmental sustainability aspects, metal sheets are easier to recycle than composite materials. At the same time, the last decade has seen an increase in work related to the plastic forming of sheets made of non-ferrous metal alloys. This article provides an up-to-date systematic overview of the basic applications of metallic materials in the automotive industry. The article focuses on the four largest groups of metallic materials: steels, aluminium alloys, titanium alloys, and magnesium alloys. The work draws attention to the limitations in the development of individual material groups and potential development trends of materials used for car body panels and other structural components.
Journal Article
Comparing the Corrosion Resistance of 5083 Al and Alsub.2Osub.33D/5083 Al Composite in a Chloride Environment
In this study, an Al[sub.2]O[sub.3]3D/5083 Al composite was fabricated by infiltrating a molten 5083 Al alloy into a three-dimensional alumina reticulated porosity ceramics skeleton preform (Al[sub.2]O[sub.3]3D) using a pressureless infiltration method. The corrosion resistance of 5083 Al alloy and Al[sub.2]O[sub.3]3D/5083 Al in NaCl solution were compared via electrochemical impedance spectroscopy (EIS), dynamic polarization potential (PDP), and neutral salt spray (NSS) tests. The microstructure of the two materials were investigated by 3D X-ray microscope and scanning electron microscopy aiming at understanding the corrosion mechanisms. Results show that an Al[sub.2]O[sub.3]3D/5083 Al composite consists of interpenetrating structure of 3D-continuous matrices of continuous networks 5083 Al alloy and Al[sub.2]O[sub.3]3D phase. A large area of strong interfaces of 5083 Al and Al[sub.2]O[sub.3]3D exist in the Al[sub.2]O[sub.3]3D/5083 Al composite. The corrosion development process can be divided into the initial period, the development period, and the stability period. Al[sub.2]O[sub.3]3D used as reinforcement in Al[sub.2]O[sub.3]3D/5083 Al composite improves the corrosion resistance of Al[sub.2]O[sub.3]3D/5083 Al composite via electrochemistry tests. Thus, the corrosion resistance of Al[sub.2]O[sub.3]3D/5083 Al is higher than that of 5083 Al alloy. The NSS test results indicate that the corrosion resistance of Al[sub.2]O[sub.3]3D/5083 Al was lower than that of 5083 Al alloy during the initial period, higher than that of 5083 Al alloy during the development period, and there was no obvious difference in corrosion resistance during the stability period. It is considered that the elements in 5083 Al alloy infiltrated into the Al[sub.2]O[sub.3]3D/5083 Al composite are segregated, and the uniform distribution of the segregated elements leads to galvanic corrosion during the corrosion initial period. The perfect combination of interfaces of Al[sub.2]O[sub.3]3D and the 5083 Al alloy matrix promotes excellent corrosion resistance during the stability period.
Journal Article
Short-range order and its impact on the CrCoNi medium-entropy alloy
Traditional metallic alloys are mixtures of elements in which the atoms of minority species tend to be distributed randomly if they are below their solubility limit, or to form secondary phases if they are above it. The concept of multiple-principal-element alloys has recently expanded this view, as these materials are single-phase solid solutions of generally equiatomic mixtures of metallic elements. This group of materials has received much interest owing to their enhanced mechanical properties
1
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5
. They are usually called medium-entropy alloys in ternary systems and high-entropy alloys in quaternary or quinary systems, alluding to their high degree of configurational entropy. However, the question has remained as to how random these solid solutions actually are, with the influence of short-range order being suggested in computational simulations but not seen experimentally
6
,
7
. Here we report the observation, using energy-filtered transmission electron microscopy, of structural features attributable to short-range order in the CrCoNi medium-entropy alloy. Increasing amounts of such order give rise to both higher stacking-fault energy and hardness. These findings suggest that the degree of local ordering at the nanometre scale can be tailored through thermomechanical processing, providing a new avenue for tuning the mechanical properties of medium- and high-entropy alloys.
Metal alloys consisting of three or more major elemental components show enhanced mechanical properties, which are now shown to be correlated with short-range order observed with electron microscopy.
Journal Article
Experimental and Mathematical Investigation of Hydrogen Absorption in LaNisub.5 and Lasub.0.7Cesub.0.1Gasub.0.3Nisub.5 Compounds
In the present study, the hydrogen-absorption properties of the LaNi[sub.5] and the La[sub.0.7]Ce[sub.0.1]Ga[sub.0.3]Ni[sub.5] compounds were determined and compared. This work is therefore divided into two parts: an experimental part that presents and discusses the kinetics and isotherms of hydrogen absorption in the two compounds at two different temperatures (298 K and 318 K). In addition, the temperature variations inside the hydride bed were determined. In the second section, the experimental isotherms were compared to a numerical model processed using statistical physics. Following that, thanks to the perfect agreement between the experimental data and the proposed model, the stereographic and energetic parameters associated with the hydrogen absorption reaction, such as the number of hydrogen atoms per receptor site (n[sub.1], n[sub.2]), the densities of the sites (N[sub.m1], N[sub.m2]), the half-saturation pressures (P[sub.1], P[sub.2]) and the absorption energies (ΔE[sub.1], ΔE[sub.2]) for each receptor site, were calculated. All of these parameters are acquired by making numerical adjustments to the experimental data. Thermodynamic functions, such as internal energy and Gibbs energy, which regulate the absorption process, were then identified using these parameters. For both compounds, all of the aforementioned were compared and discussed in relation to initial temperature and pressure. The results demonstrated that the hydrogen-storage properties in LaNi[sub.5] are enhanced by more than 30% of stored mass and kinetics when Ce and Ga are substituted at the La sites.
Journal Article
Friction Stir Welding of Aluminum in the Aerospace Industry: The Current Progress and State-of-the-Art Review
The use of the friction stir welding (FSW) process as a relatively new solid-state welding technology in the aerospace industry has pushed forward several developments in different related aspects of this strategic industry. In terms of the FSW process itself, due to the geometric limitations involved in the conventional FSW process, many variants have been required over time to suit the different types of geometries and structures, which has resulted in the development of numerous variants such as refill friction stir spot welding (RFSSW), stationary shoulder friction stir welding (SSFSW), and bobbin tool friction stir welding (BTFSW). In terms of FSW machines, significant development has occurred in the new design and adaptation of the existing machining equipment through the use of their structures or the new and specially designed FSW heads. In terms of the most used materials in the aerospace industry, there has been development of new high strength-to-weight ratios such as the 3rd generation aluminum–lithium alloys that have become successfully weldable by FSW with fewer welding defects and a significant improvement in the weld quality and geometric accuracy. The purpose of this article is to summarize the state of knowledge regarding the application of the FSW process to join materials used in the aerospace industry and to identify gaps in the state of the art. This work describes the fundamental techniques and tools necessary to make soundly welded joints. Typical applications of FSW processes are surveyed, including friction stir spot welding, RFSSW, SSFSW, BTFSW, and underwater FSW. Conclusions and suggestions for future development are proposed.
Journal Article