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Carbon materials with defect-rich structure are highly demanded for various electrochemical scenes, but encountering a conflict with the deteriorative intrinsic conductivity. Herein, we build a highway-mediated nanoarchitecture that consists of the ordered pseudographitic nanodomains among disordered highly nitrogen-doped segments through a supramolecular self-assembly strategy. The “order-in-disorder” nanosheet-like carbon obtained at 800 °C (O/D NSLC-800) achieves a tradeoff with high defect degree (21.9 at% of doped nitrogen) and compensated electrical conductivity simultaneously. As expected, symmetrical O/D NSLC-800 electrodes exhibit superior capacitive deionization (CDI) performance, including brackish water desalination (≈82 mg NaCl g −1 at a cell voltage of 1.6 V in a 1000 mg L −1 NaCl solution) and reusage of actual refining circulating cooling water, outperforming most of the reported state-of-the-art CDI electrodes. The implanted pseudographitic nanodomains lower the resistance and activation energy of charge transfer, which motivates the synergy of hosting sites of multiple nitrogen configurations. Our findings shed light on electrically conductive nanoarchitecture design of defect-rich materials for advanced electrochemical applications based on molecular-level modulation. Carbon materials are widely used in electrochemical technologies. However, their intrinsic conductivity deteriorates over time. Here the authors build a highway-mediated nanoarchitecture of ordered pseudographitic nanodomains to promote charge transfer for electrochemical ion capture.

Climate change, global population growth, and rising standards of living have put immense strain on natural resources, resulting in the unsecured availability of water as an existential resource. Access to high-quality drinking water is crucial for daily life, food production, industry, and nature. However, the demand for freshwater resources exceeds the available supply, making it essential to utilize all alternative water resources such as the desalination of brackish water, seawater, and wastewater. Reverse osmosis desalination is a highly efficient method to increase water supplies and make clean, affordable water accessible to millions of people. However, to ensure universal access to water, various measures need to be implemented, including centralized governance, educational campaigns, improvements in water catchment and harvesting technologies, infrastructure development, irrigation and agricultural practices, pollution control, investments in novel water technologies, and transboundary water cooperation. This paper provides a comprehensive overview of measures for utilizing alternative water sources, with particular emphasis on seawater desalination and wastewater reclamation techniques. In particular, membrane-based technologies are critically reviewed, with a focus on their energy consumption, costs, and environmental impacts.

Solar still is one of the economic and eminent ways of desalinating the available sea/brackish water into potable water. However, the distillate output from the solar still is moderate and various researches are being conducted to improve the productivity of solar still. In this research, a novel bottom finned (solid and hollow) absorber basin is designed and developed to enhance the heat transfer between absorber and phase change material (PCM) which further improves the freshwater productivity from the solar still. The results of the investigation are compared with the conventional solar still. The three single-slope solar stills considered developed for evaluating the effect of modification on the freshwater productivity are (i) conventional solar still (CSS), (ii) solar still with hollow finned absorber inserted in energy storage (SSHFES), and (c) solar still with solid finned absorber inserted in energy storage (SSSFES). The investigation results reported that the SSHFES has greater productivity when compared with the SSSFES and CSS. The freshwater productivity from the SSHFES is 4085 mL/m 2 day, whereas the freshwater productivity from SSSFES and CSS is 3485 mL/m 2 day and 2885 mL/m 2 day, respectively. The efficiency of SSHFES and SSSFES is increased by 41.67% and 20.81% relative to the CSS. It is observed from economic analysis that the cost per liter (CPL) freshwater produced by SSHFES, SSSFES and CSS is about ₹ 2.3 ($ 0.032), ₹ 2.5 ($ 0.034), and ₹2.6 ($ 0.036), respectively. The payback periods of SSHFES, SSSFES, and CSS is 6.3 months, 6.8 months, and 7.1 months, respectively. Also, the enviroeconomic analysis conferred that the carbon credit gained from the SSHFES is $189.28 whereas SSSFES and CSS gained only $158.2 and $132.02. Based on the current study, it is observed that the solar still with hollow finned absorber inserted in energy storage (SSHFES) is effective when compared to others and it is viable for potable water production at cheaper costs.

Due to current water stress, there is a problem with hygiene and sanitation in many parts of the world. According to predictions from the United Nations, more than 2.7 billion people will be challenged by water scarcity by the middle of the century. The water industry is increasingly interested in desalination of the sea, ocean, and brackish water. Desalination processes are widely classified as thermal or membrane technologies. In the Middle East, thermal desalination remains the primary technology of choice, but membrane processes, for example reverse osmosis (RO), have evolved rapidly and in many other parts of the world are currently even surpassing thermal processes. The purpose of this paper is to review the renewable energy source, the technology, desalination systems, and their possible integration with renewable energy resources and their cost. This article suggests that the most practical renewable desalination techniques to be used are the solar photovoltaic integrated RO desalination process, the hybrid solar photovoltaic-wind integrated RO desalination process, the hybrid solar photovoltaic-thermal (PVT) integrated RO desalination process, and the hybrid solar photovoltaic-thermal effect distillation (PVT-MED) desalination process. However, intensive research is still required to minimize the cost, reduce the heat loss, enhance the performance, and increase the productivity.

Water is the most important natural element present on earth for humans, yet the availability of pure water is becoming scarce and decreasing. An increase in population and rise in temperatures are two major factors contributing to the water crisis worldwide. Desalinated, brackish water from the sea, lake, estuary, or underground aquifers is treated to maximize freshwater availability for human consumption. However, mismanagement of water storage, distribution, or quality leads to serious threats to human health and ecosystems. Sensors, embedded and smart devices in water plants require proactive monitoring for optimal performance. Traditional quality and device management require huge investments in time, manual efforts, labour, and resources. This research presents an IoT-based real-time framework to perform water quality management, monitor, and alert for taking actions based on contamination and toxic parameter levels, device and application performance as the first part of the proposed work. Machine learning models analyze water quality trends and device monitoring and management architecture. The results display that the proposed method manages water monitoring and accessing water parameters efficiently than other works.

Brackish water desalination, using the reverse osmosis (BWRO) process, has become common in global regions, where vast reserves of brackish groundwater are found (e.g., the United States, North Africa). A literature survey and detailed analyses of several BWRO facilities in Florida have revealed some interesting and valuable information on the costs and energy use. Depending on the capacity, water quality, and additional scope items, the capital cost (CAPEX) ranges from USD 500 to USD 2947/m3 of the capacity (USD 690–USD 4067/m3 corrected for inflation to 2020). The highest number was associated with the City of Cape Coral North Plant, Florida, which had an expanded project scope. The general range of the operating cost (OPEX) is USD 0.39 to USD 0.66/m3 (cannot be corrected for inflation), for a range of capacities from 10,000 to 70,000 m3/d. The feed-water quality, in the range of 2000 to 6000 mg/L of the total dissolved solids, does not significantly impact the OPEX. There is a significant scaling trend, with OPEX cost reducing as plant capacity increases, but there is considerable scatter based on the pre- and post-treatment complexity. Many BWRO facilities operate with long-term increases in the salinity of the feedwater (groundwater), caused by pumping-induced vertical and horizontal migration of the higher salinity water. Any cost and energy increase that is caused by the higher feed water salinity, can be significantly mitigated by using energy recovery, which is not commonly used in BWRO operations. OPEX in BWRO systems is likely to remain relatively constant, based on the limitation on the plant capacity, caused by the brackish water availability at a given site. Seawater reverse osmosis facilities, with a very large capacity, have a lower OPEX compared to the upper range of BWRO, because of capacity scaling, special electrical energy deals, and process design certainty.

BACKGROUND AND OBJECTIVES: Energy efficiency plays a crucial role in the success and sustainability of desalination technologies. Energy considerations are intricately linked with every aspect of planning, management, and operation in water desalination. This study aims to evaluate and enhance energy requirements, energy efficiency, and the economic feasibility of the Hashemite University photovoltaic brackish water reverse osmosis desalination plant at Hashemite University. METHODS: This study's aims were achieved by conducting an energyaudit and detailed assessment to identify the energy efficiency considerations that should be integrated into the facility's planning, management, and operation strategies. To ensure accurate and reliable data collection and enable a comprehensive analysis of the plant's energy performance, portable energy analyzers and loggers were employed to measure energy consumption, and measurements and verification techniques were recommended and implemented to establish the required baseline. A regression model was utilized to determine the potential energy savings resulting from energy conservation measures. This involved determining the expected savings by calculating the area between two curves: the new actual consumption of the brackish water reverse osmosis plant after implementing energy conservation measures and the curve generated by the model representing the usual consumption in the absence of energy conservation measures. FINDINGS: This study underscores the challenges faced by desalination, particularly regarding intensive energy consumption. It also presents innovative ways to achieve sustainability by emphasizing energy efficiency, integrating renewable energy, and advocating for a holistic water management approach. It was determined that the maximum specific energy consumption of the Hashemite University photovoltaic brackish water reverse osmosis plant was 0.625 kilowatts per cubic meter. This reflects the actual consumption and energy performance of the plant, which was found to be 192 percent more efficient than the estimated specific energy and 144 percent more efficient than the calculated specific energy. No energy conservation measures were implemented at this stage, as the plant was already operating efficiently. The measured data shall be considered as a baseline for future investigations and monitoring and evaluation of the plant. Many challenges were identified during the current work, including the low quality of raw water and minimal demand for freshwater, which resulted in lower operation hours outside of sun peak hours, while the direct utilization of photovoltaic energy is recommended. CONCLUSION: Renewable energy and energy recovery were recognized as potential sources for energy savings to achieve sustainable and long-term feasible operation and cost recovery at the Hashemite University photovoltaic brackish water reverse osmosis plant. The feasibility of the plant showed a fast payback period of up to 1.1 years. Utilizing clean solar photovoltaic energy to power the brackish water reverse osmosis plant led to a considerable reduction of greenhouse gases (mainly carbon dioxide). The estimated amount of carbon dioxide reduction during the project's lifetime was 1,289,600 kilograms. The integration of solar energy showed promise for further enhancing energy efficiency and sustainability. This study contributes to making the desalination sector more environmentally friendly and economically viable, which is of paramount importance in addressing global water scarcity concerns.

Electrochemical water desalination has been a major research area since the 1960s with the development of capacitive deionization technique. For the latter, its modus operandi lies in temporary salt ion adsorption when a simple potential difference (1.0–1.4 V) of about 1.2 V is supplied to the system to temporarily create an electric field that drives the ions to their different polarized poles and subsequently desorb these solvated ions when potential is switched off. Capacitive deionization targets/extracts the solutes instead of the solvent and thus consumes less energy and is highly effective for brackish water. This paper reviews Capacitive Deionization (mechanism of operation, sustainability, optimization processes, and shortcomings) with extension to its counterparts (Membrane Capacitive Deionization and Flow Capacitive Deionization).

Freshwater scarcity appears clearly in coastal areas of Egypt despite the existence of a large amount of seawater around. Solar still is the cheapest and oldest way to desalinate seawater and brackish water. In the proposed study, single-slope solar still was examined in the climatic conditions of Qena, Egypt (Latitude: 26.16°, longitude: 32.71°). The purpose of the study was to analyze the energy storage behavior inside the phase change materials and to enhance the solar still productivity during both daytime and nighttime operation. The performance of the proposed solar still was tested under the use of phase change material (RT42PCM) with different quantities of 2, 4, and 6 kg in weight, which was placed inside the basin area. Furthermore, the optimum phase change material quantity was compared with simple conventional solar still without phase change material. The results showed that the productivity of the proposed solar still in the case of using 4-kg phase change material was higher than that for using 2-kg phase change material and 6-kg phase change material by about 18.6 and 27.7%, respectively. Moreover, the average daily efficiency is 68, 57.2, and 53.6%, respectively. The use of 4-kg phase change material in the basin caused an enhancement in the proposed solar still productivity by about 29.7% and the average daily efficiency was 66.7 and 51.5%, respectively, in comparison with simple solar still without phase change material. It was additionally seen that in the case of using phase change material, more yield was gotten over during the nighttime and the average basin water temperature was increased due to its high ability to store thermal energy inside. Furthermore, the produced freshwater could be used in different life applications, because of its appropriate ranges of total dissolved solids, pH, hardness, and water clarity.

Artificial water channels (AWCs) show the potential for overcoming the permeability-selectivity tradeoff of polyamide (PA) membranes. However, the availability of biomimetic materials and limitations posed by fabrication-induced defects make the development of AWC-PA membranes a daunting task. Herein, we synthesize imidazolylethyl-ureidoethyl-phenyl (IUP) compounds to form AWC by self-assembling and provide a strategy to seamlessly incorporate AWC in defect-free PA membranes. IUP compounds are molecularly designed with enhanced nature to form AWC due to π-π stacking interactions. In addition, nanosized colloid AWC aggregates can be obtained in water directly with the aid of sodium dodecyl sulfate (SDS) and conveniently incorporated into PA layers. The AWC not only promotes the preferential selective passage of water but also exhibits good compatibility with the surrounding PA matrix. The biomimetic membranes demonstrate a water permeance of 4.3 L·m −2 ·h −1 ·bar −1 and NaCl rejection of 99.3%, much higher than that observed with marketed state-of-the-art membranes. Mechanism understanding reveals that the compatible interaction between AWC, SDS and PA matrix is a necessary requisite to fabricate defect-free AWC-PA layers. This strategy can be easily extended to industrial scale and the biomimetic membranes may represent the development direction of the next generation of high-performance reverse osmosis membranes. Artificial water channels can potentially overcome the permeability-selectivity trade-off of polyamide membranes, though fabrication methods often cause defects limiting possible membranes. Here, the authors report imidazolylethyl-ureidoethyl-phenyl based artificial water channel in a defect-free polyamide membrane.